Midterm 1
Midterm 1
(a) Assuming the cubic lattice with a=6 A, what are the volume densities of Ti, Ca, and O atoms? (b) A variety of perovskite called dysanalyte has the Ti atoms replaced by Nb (niobium) atoms. If the density (mass of a unit volume) is the same for both minerals, what is the ratio of their lattice constants? The respective atomic weights are Ca:40, O:16, Ti:48, and Nb:93.
(2) A system of non-interacting particles in an innite potential well in the ground state (n = 1) is illuminated by light. At certain wavelengths, the system absorbs the light due to elevation of particles to higher energy levels. (a) If the ground state energy E1 =1 eV, light of which wavelength will elevate the particles to the n = 2 energy level? (b) In the 300700 nm range, the experiment detected two absorption lines: 1 =330.7 nm and 2 =620 nm. What is the ground state energy? Hint: to simplify the calculations, you can use the fact that photon energy in eV is 1240 related to its wavelength in nm as E (eV) = . (nm) (3) The conduction and valence bands in a semiconductor can be described as Ec (k) = E1 E2 cos ka and Ev (k) = E3 + E4 cos2 ka, respectively, where E1 =6 eV, E2 =1 eV, E3 =3.5 eV, E4 =0.5 eV, a=2 A. What is the hole to electron mass ratio? (4) The distribution of electrons in a semiconductor is described by the Fermi-Dirac probability function. The probability to nd an electron with energy 8 eV at T =300 K is the same as the probability to nd an electron with energy 9 eV at T =600 K. What is the Fermi energy (assuming that it does not depend on temperature)?