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Strong, Weak, or Non-Electrolyte?

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Strong, Weak, or Non-Electrolyte?

For the purposes of this course, use these criteria to determine if a substance is a strong,
weak, or non-electrolyte when dissolved in water (aqueous solution):
1. All ionic compounds are strong electrolytes, because they mostly break up into ions as
they dissolve in water. Even insoluble ionic compounds (e.g., AgCl, PbSO
4
, CaCO
3
) are
strong electrolytes, because the small amounts that do dissolve in water do so principally
as ions; i.e., there is virtually no undissociated form of the compound in solution.
2. Molecular compounds may be non-electrolytes, weak electrolytes, or strong electrolytes,
depending on whether they dissolve without ion formation, a little ion formation, or
mostly ion formation, respectively. Examples:
Molecular Compound Electrolyte Type Species in Solution
sucrose (table sugar) non-electrolyte molecules only
acetic acid (HC
2
H
3
O
2
= HOAc) weak electrolyte molecules and some ions
hydrogen chloride (HCl) strong electrolyte ions only
3. Strong acids and strong bases are strong electrolytes [e.g., HCl(aq), H
2
SO
4
(aq), HClO
4
(aq);
NaOH(aq)]. There are virtually no molecules of a strong acid or base in solution, only ions.
Know the strong acids and bases on the accompanying hand-out "Strong and Weak Acids
and Bases". Assume that any other acid or base you encounter in this course is weak, unless
told to the contrary. [Note: Mg(OH)
2
, an insoluble compound, is a strong base because it is an
ionic compound and therefore a strong electrolyte.]

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