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    Thermo Hidro

    Uploaded by

    Muhammad Shohibi
    The document summarizes several common equations of state used to model the behavior of gases and liquids, including the ideal gas law, van der Waals, Redlich-Kwong, Peng-Robinson, and Benedict-Webb-Rubbin equations. Each equation relates pressure, volume, temperature, and other parameters and incorporates empirical constants that are specific to different substances. The equations can be used to calculate thermodynamic properties and model real gas and liquid behavior accounting for intermolecular forces and volume.

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    © All Rights Reserved
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    Thermo Hidro

    Uploaded by

    Muhammad Shohibi
    21 views11 pages
    The document summarizes several common equations of state used to model the behavior of gases and liquids, including the ideal gas law, van der Waals, Redlich-Kwong, Peng-Robinson, and Benedict-Webb-Rubbin equations. Each equation relates pressure, volume, temperature, and other parameters and incorporates empirical constants that are specific to different substances. The equations can be used to calculate thermodynamic properties and model real gas and liquid behavior accounting for intermolecular forces and volume.

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    ThermoHidro

    Original Title

    ThermoHidro

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    © © All Rights Reserved

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    The document summarizes several common equations of state used to model the behavior of gases and liquids, including the ideal gas law, van der Waals, Redlich-Kwong, Peng-Robinson, and Benedict-Webb-Rubbin equations. Each equation relates pressure, volume, temperature, and other parameters and incorporates empirical constants that are specific to different substances. The equations can be used to calculate thermodynamic properties and model real gas and liquid behavior accounting for intermolecular forces and volume.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    21 views11 pages

    Thermo Hidro

    Uploaded by

    Muhammad Shohibi
    The document summarizes several common equations of state used to model the behavior of gases and liquids, including the ideal gas law, van der Waals, Redlich-Kwong, Peng-Robinson, and Benedict-Webb-Rubbin equations. Each equation relates pressure, volume, temperature, and other parameters and incorporates empirical constants that are specific to different substances. The equations can be used to calculate thermodynamic properties and model real gas and liquid behavior accounting for intermolecular forces and volume.

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    EQUATIONS OF STATE

    Ideal Gas
    (Only valid for gas at low pressure conditions)

    Pv = RT
    Van der Waals

    P=

    RT
    a
    2
    vb v

    or P + 2 (v b ) = RT
    v

    Relation with Z = compressibility factor:

    Pv
    b
    a
    Z=
    = 1+

    RT
    v b RTv
    27 R 2Tc2
    a=
    64 Pc

    and

    b=

    RTc
    8 Pc

    For mixtures:

    a = xi ai

    and

    b = xibi

    Van der Waals EOS, in term of Z:

    Z 3 (B + 1)Z 2 + AZ AB = 0

    with

    B=

    bP
    RT

    and

    A=

    aP
    (RT )2

    Redlich-Kwong

    P=

    RT
    a
    0.5
    v b T v(v + b )

    Relation with Z = compressibility factor:

    a / R 2T 2.5 b / v
    Pv
    1

    =

    Z=
    RT 1 b / v b / RT 1 + b / v
    0.4278 R 2Tc2.5
    a=
    Pc

    and

    b=

    0.0867 RTc
    Pc

    For mixtures:

    a = xi ai

    and

    b = xibi

    Redlich-Kwong EOS, in term of Z:

    Z 3 Z 2 + A B 2 B Z AB = 0

    with

    B=

    bP
    RT

    and

    A=

    aP
    (RT )2

    Peng-Robinson

    RT
    a(T )
    P=

    v b v(v + b ) + b(v b )
    Relation with Z = compressibility factor:

    Z=

    Pv
    1
    a(T )
    =

    RT 1 b / v ((v + b ) + b(1 b / v ))RT

    0.45724 R 2Tc2
    a (T ) =
    (T )
    Pc

    and

    b=

    0.0778 RTc
    Pc

    (T ) = 1 + (0 .37464 + 1 .54226 0 .26992 2 )1

    T
    Tc

    For mixtures:

    a = xi ai

    b = xibi

    and

    Peng-Robinson EOS, in term of Z:

    ) (

    Z 3 + (B 1)Z 2 + A 3B 2 2 B Z + B 2 + B 3 AB = 0

    with

    B=

    bP
    RT

    and

    A=

    aP
    (RT )2

    Benedict-Webb-Rubbin (BWR)
    2
    Co 2

    3
    6
    3 1 + d
    exp d 2
    P = RTd + Bo RT Ao 2 d + (bRT a )d + ad + cd
    2
    T
    T

    Relation with Z = compressibility factor:


    2
    Pv
    Ao
    Co
    a 2 a 5
    2 1 + d
    = Bo

    Z=
    d + b
    d + cd
    exp d 2
    d +
    2
    3
    RT
    RT RT
    RT
    RT
    RT

    where

    d=

    1
    ;
    v

    Bo, Ao, Co, b, a, c, , are emphirical constants

    for each substances.


    For mixtures, use appropriate mixing rules such as:

    Bo = xi Boi

    b=

    [ x (b ) ]

    1/ 3 3

    [ x ( ) ]

    1/ 3 3

    Calculations of other properties from EOS

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