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    Answers ON 4.1.4 AMINES

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    This document contains answers to exam questions about amines from an F324 module exam. It discusses the properties and reactions of amines, including: - Diamines have two amine groups and their positions are denoted by numbering around the ring. - Aromatic amines can be reduced to aliphatic amines using tin and HCl or hydrogen gas. - Primary amines can act as bases by accepting protons from acids to form ammonium salts or dative covalent bonds with chlorine. - Aromatic amines can be synthesized through a two-step process involving diazonium salt formation and reaction with phenols to form azo dyes.

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    Answers ON 4.1.4 AMINES

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    l
    103 views9 pages
    This document contains answers to exam questions about amines from an F324 module exam. It discusses the properties and reactions of amines, including: - Diamines have two amine groups and their positions are denoted by numbering around the ring. - Aromatic amines can be reduced to aliphatic amines using tin and HCl or hydrogen gas. - Primary amines can act as bases by accepting protons from acids to form ammonium salts or dative covalent bonds with chlorine. - Aromatic amines can be synthesized through a two-step process involving diazonium salt formation and reaction with phenols to form azo dyes.

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    4.1.4_Mark_Scheme

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    This document contains answers to exam questions about amines from an F324 module exam. It discusses the properties and reactions of amines, including: - Diamines have two amine groups and their positions are denoted by numbering around the ring. - Aromatic amines can be reduced to aliphatic amines using tin and HCl or hydrogen gas. - Primary amines can act as bases by accepting protons from acids to form ammonium salts or dative covalent bonds with chlorine. - Aromatic amines can be synthesized through a two-step process involving diazonium salt formation and reaction with phenols to form azo dyes.

    Copyright:

    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    103 views9 pages

    Answers ON 4.1.4 AMINES

    Uploaded by

    l
    This document contains answers to exam questions about amines from an F324 module exam. It discusses the properties and reactions of amines, including: - Diamines have two amine groups and their positions are denoted by numbering around the ring. - Aromatic amines can be reduced to aliphatic amines using tin and HCl or hydrogen gas. - Primary amines can act as bases by accepting protons from acids to form ammonium salts or dative covalent bonds with chlorine. - Aromatic amines can be synthesized through a two-step process involving diazonium salt formation and reaction with phenols to form azo dyes.

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    ANSWERS

    ON
    4.1.4 AMINES

    TAKEN FROM
    F324
    MODULE EXAMS

    1.

    2.

    3.

    4.

    5.

    6.

    7.

    (a)

    (b)
    (c) phenylammonium chloride

    8.

    9.

    10.
    (a)

    (i)

    (b)

    Diamino
    two/2 amine groups (1)
    1,4
    their position on the ring / numbering of carbons
    around ring (or shown on a diagram) (1)

    (i)

    reduction / redox (1)

    (ii)

    tin and HCl (1)


    conc acid under reflux (1)

    or H2 gas + Ni/Pd catalyst

    (iii)
    O N

    NO

    H N

    NH

    H2O as product (1)


    and the equation balanced (1)

    (c)

    (i)

    accepts H using the lone pair (on N) (1)


    which is donated/forms a (dative) covalent bond (1)

    either mark can be obtained with a good diagram

    (ii)
    -

    C l H 3N

    NH

    Cl

    correct structure with charges shown (1)(1)


    one mark for either: just one neutralised,

    both neutralised, but without Cl ,


    both neutralised, but no charges shown
    11.

    12.

    13.
    st

    1 stage
    aromatic amine / named aromatic amine / structure (1)
    sodium nitrite / nitrous acid (1)
    +
    HCl/H2SO4 (but not conc) /H (1)
    at <10C (1)
    which forms a diazonium salt / ion (1)
    if more than four are given, mark any wrong reagents,
    conditions first
    nd

    2 stage
    the product from the first stage mixed with the phenol AW (1)
    (in excess) hydroxide / alkali (1)

    allow correct formulae for the reagents

    (b)

    (i)

    O H
    N
    N

    SO

    Na

    SO

    Na

    (1)

    allow any benzene rings as well as N=N circled, as long as no


    other groups are

    (ii)

    (c)

    16 carbon and 10.. hydrogen atoms


    (1)
    (1)

    Na / NaOH / OH etc (1)

    (d)

    O H

    SO

    Na

    (1)

    H 2N

    SO

    Na

    (1)

    allow 1 mark if they are both correct, but in the wrong boxes

    only penalise a slip with SO3 Na once


    [13]

    14.

    15.
    15.

    16.

    17.

    18.

    19.
    20.
    21.
    22.
    23.
    24.
    25.
    26.
    27.

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