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Tutorial 2 Questions

The document provides 18 chemistry problems involving calculation of enthalpy change (ΔH) values for various reactions using standard enthalpy of formation values provided. The problems involve setting up thermochemical equations and calculating the ΔH for the given reaction based on summation of the standard enthalpies of reactants and products.

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iveco
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1K views

Tutorial 2 Questions

The document provides 18 chemistry problems involving calculation of enthalpy change (ΔH) values for various reactions using standard enthalpy of formation values provided. The problems involve setting up thermochemical equations and calculating the ΔH for the given reaction based on summation of the standard enthalpies of reactants and products.

Uploaded by

iveco
Copyright
© Attribution Non-Commercial (BY-NC)
Available Formats
Download as DOC, PDF, TXT or read online on Scribd
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1.

Calculate H for the reaction: NH3(g) + HCl(g) -----> NH4Cl(s)


Given that:
½N2(g) + 1½H2(g) -----> NH3(g)     H = -46.1 kJ/mol
½H2(g) + ½Cl2(g) ------> HCl(g)     H = -92.3 kJ/mol
½N2(g) + 2H2(g) + ½Cl2(g) -----> NH4Cl(s)     H = -314.4 kJ/mol
[Ans: H = -176.0 kJ/mol]

2. Calculate H for the reaction: C2H4 (g) + H2 (g) C2H6 (g), from the following data.
C2H4 (g) + 3 O2 (g) 2 CO2 (g) + 2 H2O (l) H = -1411. kJ

C2H6 (g) + 3½ O2 (g) 2 CO2 (g) + 3 H2O (l) H = -1560. kJ

H2 (g) + ½ O2 (g) H2O (l) H = -285.8 kJ


[Ans: H = -137 kJ]

3. Calculate H for the reaction 4 NH3 (g) + 5 O2 (g) 4 NO (g) + 6 H2O (g), from the
following data.

N2 (g) + O2 (g) 2 NO (g) H = -180.5 kJ

N2 (g) + 3 H2 (g) 2 NH3 (g) H = -91.8 kJ

2 H2 (g) + O2 (g) 2 H2O (g) H = -483.6 kJ


[Ans: H = -1628. kJ]

4. Find H for the reaction 2H2(g) + 2C(s) + O2(g)  C2H5OH(l), using the following
thermochemical data.

C2H5OH (l) + 2 O2 (g) 2 CO2 (g) + 2 H2O (l) H = -875. kJ

C (s) + O2 (g) CO2 (g) H = -394.51 kJ

H2 (g) + ½ O2 (g) H2O (l) H = -285.8 kJ


[Ans: -486 KJ]

5. Calculate H for the reaction CH4 (g) + NH3 (g) HCN (g) + 3 H2 (g), given:

N2 (g) + 3 H2 (g) 2 NH3 (g) H = -91.8 kJ

C (s) + 2 H2 (g) CH4 (g) H = -74.9 kJ

H2 (g) + 2 C (s) + N2 (g) 2 HCN (g) H = +270.3 kJ


[Ans: 256 KJ]
6. Calculate for the reaction 2 Al (s) + 3 Cl2 (g) 2 AlCl3 (s) from the data.

2 Al (s) + 6 HCl (aq) 2 AlCl3 (aq) + 3 H2 (g) H = -1049. kJ

HCl (g) HCl (aq) H = -74.8 kJ

H2 (g) + Cl2 (g) 2 HCl (g) H = -1845. kJ

AlCl3 (s) AlCl3 (aq) H = -323. kJ


[Ans: -6387 KJ]

7. Find the ΔH for the reaction below, given the following reactions and subsequent ΔH
values: PCl5(g)  →  PCl3(g)  +  Cl2(g)

P4(s)  +  6Cl2(g)  →  4PCl3(g)            ΔH = -2439 kJ


4PCl5(g)  →  P4(s)  +  10Cl 2(g)         ΔH = 3438 kJ
[Ans: 249.8 kJ]

8. Find the ΔH for the reaction below, given the following reactions and subsequent ΔH
values: 2CO2(g)  +  H2O(g)  →  C 2H2(g) +  5/2O2(g)
C2H2(g) + 2H2(g)  →  C2H6(g)                              ΔH  =-94.5 kJ
H2O(g)  →  H2(g) + 1/2O2 (g)                               ΔH  =71.2 kJ
C2H6(g) +  7/2O2(g)  →  2CO2(g)  +  3H2O(g)     ΔH  =-283 kJ

[Ans: 235 kJ]

9. Find the ΔH for the reaction below, given the following reactions and subsequent ΔH
values: N2H4(l)  +  H2(g)  →  2NH3(g)

N2H4(l)  +  CH4O(l)  →  CH2O(g)  +  N2(g)  +  3H2 (g)         ΔH = -37 kJ


N2(g)  +  3H2(g)  →  2NH 3(g)                                                ΔH = -46 kJ
CH4O(l)  →  CH2O(g) +  H 2(g)                                              ΔH = -65 kJ
[Ans: -18 kJ]

10. Find the ΔH for the reaction below, given the following reactions and subsequent ΔH
values: H2SO4(l)  →  SO3(g)  +  H2O(g)

H2S(g)  +  2O2(g)  →  H2SO4(l)                                  ΔH = -235.5 kJ


H2S(g)  +  2O2(g)  →  SO 3(g)  +  H2O(l)                    ΔH = -207 kJ
H2O(l)  →  H2O(g)                                                      ΔH = 44 kJ
[Ans: 72 kJ]

11. Find the ΔH for the reaction below, given the following reactions and subsequent ΔH
values: 2C2H4O(l) + 2H2O(l)  →  2C2H6O(l) +  O2(g)

C2H6O(l)  +  3O2(g)  →  2CO2(g)  +  3H2O(l)            ΔH = -685.5 kJ


C2H4O(l)  +  5/2O2(g)  →  2CO2(g)  +  2H2O(l)         ΔH = -583.5 kJ
[Ans: 204.0 kJ]
12. Find the ΔH for the reaction below, given the following reactions and subsequent ΔH
values: N2(g) +  2O2(g)  →  2NO 2(g)

N2(g)  +  3H2(g)  →  2NH3(g)                                  ΔH = -115 kJ


2NH3(g)  +  4H2O(l)  →  2NO2(g)  +  7H2(g)          ΔH = -142.5 kJ
H2O(l)  →  H2(g)  +  1/2O 2(g)                                 ΔH = -43.7 kJ
[Ans: -83 kJ]

13. Find the ΔH for the reaction below, given the following reactions and subsequent ΔH
values: CO2(g)  →  C(s) +  O2(g)

H2O(l)  →  H2(g)  +  1/2O2(g)                                    ΔH = 643 kJ


C2H6(g)  →  2C(s) +  3H 2(g)                                     ΔH = 190.6 kJ
2CO2(g) +  3H2O(l)  →  C 2H6(g) + 7/2O2(g)            ΔH = 3511.1 kJ
[Ans: 886 kJ]

14. Find the ΔH for the reaction below, given the following reactions and subsequent ΔH
values: N2H4(l)  +  CH4O(l)  →  CH2O(g)  +  N2(g)  +  3H2 (g)

2NH3(g)  →  N2H4(l)  +  H2(g)                 ΔH = 22.5 kJ


2NH3(g)  →  N2(g)  +  3H 2(g)                 ΔH = 57.5 kJ
CH2O(g) +  H2(g)  →  CH 4O(l)               ΔH = 81.2 kJ
[Ans: -46.2 kJ]

15. Find the ΔH for the reaction below, given the following reactions and subsequent ΔH
values: 1/2H2(g)  +  1/2Cl2(g)  →  HCl(g)

COCl2(g)  +  H2O(l)  →  CH2Cl2(l)  +  O2(g)                               ΔH = 47.5 kJ


2HCl(g)  +  1/2O2(g)  →  H 2 O(l)  +  Cl2(g)                                 ΔH = 105 kJ
CH2Cl2(l) +  H2(g)  +  3/2O 2(g)  →  COCl2(g)  +  2H 2O(l)         ΔH = -402.5 kJ
[Ans: -230 kJ]

16. Find the ΔH for the reaction below, given the following reactions and subsequent ΔH
values: C2H2(g) +  5/2O2(g)  →  2CO2(g)  +  H2O(g)

C2H6(g)  →  C2H 2(g) + 2H2(g)                              ΔH = 283.5 kJ


H2(g) + 1/2O2(g)  →  H2O(g)                                ΔH = -213.7 kJ
2CO2(g)  +  3H2O(g)  →  C2H6(g) +  7/2O2(g)      ΔH = 849 kJ
[Ans: -705 kJ]

17. Find the ΔH for the reaction below, given the following reactions and subsequent ΔH
values: HCl(g) + NaNO2(s) → HNO2(l) + NaCl(s)

2NaCl(s) + H2O(l) →  2HCl(g) + Na2O(s)                 ΔH = 507 kJ


NO(g) + NO2(g) + Na2O(s) → 2NaNO2(s)             ΔH = -427 kJ
NO(g) + NO2(g) → N2O(g) + O2(g)                         ΔH = -43 kJ
2HNO2(l) → N2O(g) + O2(g) + H 2O(l)                    ΔH = 34 kJ
[Ans: -78 kJ]
18. Find the ΔH for the reaction below, given the following reactions and subsequent ΔH
values: Zn(s) +  1/8S8(s)  +  2O2(g)  →  ZnSO4(s)

Zn(s) + 1/8S8(s)   →   ZnS(s)                                   ΔH = -183.92 kJ


2ZnS(s) + 3O2(g)   →   2ZnO(s) + 2SO2(g)            ΔH = -927.54 kJ
2SO2(g) + O2(g)   →   2SO3(g)                              ΔH = -196.04 kJ
ZnO(s) + SO3(g)   →   ZnSO4 (s)                           ΔH = -230.32 kJ
[Ans: -976.03 kJ]

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