Coffee History
Coffee History
Coffee History
According to a coffee history legend, an Arabian shepherd named Kaldi found his goats dancing joyously around a dark green leafed shrub with bright red cherries in the southern tip of the Arabian Peninsula. Kaldi soon determined that it was the bright red cherries on the shrub that were causing the peculiar euphoria and after trying the cherries himself, he learned of their powerful effect. The stimulating effect was then exploited by monks at a local monastery to stay awake during extended hours of prayer and distributed to other monasteries around the world. Coffee was born. Despite the appeal of such a legend, recent botanical evidence suggests a different coffee bean origin. This evidence indicates that the history of the coffee bean beagan on the plateaus of central Ethiopia and somehow must have been brought to Yemen where it was cultivated since the 6th century. Upon introduction of the first coffee houses in Cairo and Mecca coffee became a passion rather than just a stimulant. For more coffee legends and details about the history of the coffee bean, visit National Geographic.com. Main sections in this Category Coffee Preparation: Brewing, Roasting, Grinding. Coffee Plant Coffee Origins Overview Coffee Cupping: Method, Conditions. Coffee Buying: Overview, Classification, Grading. Coffee Books: Coffee, Espresso, Business, Market
dry. Medium - Rich brown color. Very small droplets of oil appear on Dark surface. The acidity is slowly diminished and body is most potent. This is the ideal roast for a well blended espresso. Dark Deep brownish/black color. The bean has spots of oil or is completely oily. Subtle nuances are diminished. Flavor decreases, while body dominates. Very Dark Black surface covered with oil. All subtle nuances are gone, aroma is minor, and body is thin. This roast is characteristic of American espresso.
a a a a a a a a b
Pyruvic cis- and trans-but-eenoic cis- and trans-2methylbut- 2-enoic 3-methylbut-2-enoic methylpropenoic oxalic malonic succinic 3-methylene butanedioic glutaric Malic
b b b b b b b b b b b
pKa = 3.08, 22 mole/100 mL.1 0.11% dry matter. Concentration independent of roast.2 0.06% dry matter. Concentration independent of roast.2
pKa = 3.40 / 5.11, 58-76 mole/100 mL.1 0.17-0.5% dry matter at med roast. Max at light roast.2
b b b b b
pKa = 3.14 / 4.77 / 6.39, 75-189 mole/100 mL.1 0.37-0.5% dry matter, max at light roast.2
b c d
4-monocaffeoylquinic acid
5-monocaffeoylquinic acid 3,4-dicaffeoylquinic acid 3,5-dicaffeoylquinic acid 4,5-dicaffeoylquinic acid 3-feruloylquinic acid 4-feruloylquinic acid 5-feruloylquinic acid 3,4-pcoumaroylquinic acid 3,5-pcoumaroylquinic acid 4,5-pcoumaroylquinic acid Quinic
The chlorogenic acids have an astringent taste due to its ability to precipitate salivary proteins onto the mucous membranes. Therefore it may also be responsible for heightened body.2 At dark roasts, 80% of the CGA's may be lost resulting in a residual CGA content of 2.2-2.4%.2
d d d d d d d d d e pKa = 3.40, 123-242 mole/100 mL.1 0.6-0.8% dry matter at med. roast. Concentration increases inversely with chlorogenic acid.2
e e f
pKa = 2.12 / 7.21 / 12.67, 65-108 mole/100 mL.1 0.54% of dry matter.2
Sources 1. Clifford, M. Tea and Coffee Trade J. 159: 8. 1987. 35-39. 2. Illy, A. and Viani, R. Espresso Coffee: The Chemistry of Quality. 107110. 3. Clarke, R.J. The Flavour of Coffee. In Dev. Food Science. 3B: 1-47. 1986. 147.
Notes a. Volatile Aliphatic Carboxylic b. Non-Volatile Aliphatic Carboxylic c. Heterocyclic furanoid carboxylic d. Chlorogenic e. Alicyclic/phenolic e. Inorganic
In regards to the concentration of citric, malic, lactic, pyruvic and acetic acid, Blank found that a typical medium roast coffee consisted of 0.30%, 0.22%, 0.13%, 0.07%, and 0.27% of each acid, respectively (Clarke, 25). At very light roasts, Blank found that the
total concentration of these acids was around 1.58%, while at dark roasts these acids could drop down to 0.71%. Chlorogenic acids have been found to make up around 7% of the dry basis weight of Arabica coffee. The 3-CQA isomer-the largest isomer present-is found at 4-5%. Clifford and Jarvis found over 17 chlorogenic acid-like substances in 42 robusta samples. The chlorogenic acids are largely degraded during the roasting process mainly into quinic acid. Excessive quinic acid has been associated with unfavorable sourness when coffees are roasted too dark or brewed coffee is left on a heater plate. This sourness, however, is contradictory to the rise in pH and reduced perceived acidity at darker roasts and is likely operating under a different mechanism. In a study by the Technical Unit of the International Coffee Organization, they reported on the acid concentration in coffee at different particle sizes, water temperature, and extraction times. The results have been detailed in Table 2, 3, and 4, respectively. Table 2. Acid concentrations at different grind sizes. All brewing was carried out at 94C for 5 minutes. (Source: ICO Sensory). Acids Course Grind Fine Grind Extra Fine Size (mg/L) (mg/L) Grind (mg/L) Lactic Acid 109.67 194.50 308.33 Acetic Acid 242.67 225.67 209.00 Citric Acid 325.00 461.00 440.00 Malic Acid 119.33 137.00 163.67 Phosphoric 68.33 77.33 82.00 Quinic Acid 435.33 495.00 510.00 Chlorogenic 700.00 1,064.67 1,177.00 Palmitic Acid 5.03 5.90 3.63 Linoleic Acid 6.27 5.97 4.50 Table 3. Concentration of extracted acids at different brewing temperatures. All coffees were brewed using a fine grind for 5 minutes. (Source: ICO Sensory). Acids 70C (mg/L) 94C (mg/L) 100C (mg/L) Lactic Acid 121.00 194.50 187.33 Acetic Acid 151.33 225.67 187.00 Citric Acid 388.33 461.00 332.00 Malic Acid 131.00 137.00 122.00 Phosphoric Acid 86.33 77.33 80.00 Quinic Acid 348.33 495.00 383.33 Chlorogenic Acids 872.67 1,064.67 1,067.67 Palmitic Acid 3.26 5.90 6.53 Linoleic Acid 3.83 5.97 8.30
Table 4. Concentration of extracted acids at different brewing times. All coffees brewed were of a fine grind and were brewed at 94C. (Source: ICO Sensory). 1 Minute 5 Minutes 14 Minutes Acids (mg/L) (mg/L) (mg/L) Lactic Acid 56.67 194.50 125.67 Acetic Acid 261.00 225.67 242.00 Citric Acid 343.33 461.00 355.33 Malic Acid 109.33 137.00 100.33 Phosphoric 75.00 77.33 75.67 Quinic Acid 525.00 495.00 556.67 Chlorogenic 955.00 1,064.67 988.33 Palmitic Acid 4.97 5.90 5.87 Linoleic Acid 6.70 5.97 6.37
Virtually no free amino acids are still present after roasting for 5 min at 220C (Maier, 568). However, the amino acids are important during the Maillard reaction in the production of aromatics early in the roasting process. Phosphoric acid has been implicated as a major contributor to perceived acidity by Maier and Rivera, but an alternate conclusion has been reached by Griffin and Blauch who suggest that phosphoric acid might contribute, but is not directly correlated to the perceived acidity. The phosphate concentrations found in the latter study are nearly identical to those found for phosphoric acid in the Technical Unit Quality Series No 9 by the ICO. It is still unknown which acids are imperative to recreate the acidity experienced in coffee. It is generally understood that citric acid, malic acid, and acetic acid are the most important because they exist in high proportions and have low pKa's. However, due to highly complex buffering effects and the wide distributions of salts and acids present in coffee, it is difficult to predict the exact mechanism and agents responsible for the perceived acidity in coffee.
Coffee Roasting
Coffee roasting is a chemical process by which aromatics, acids, and other flavor components are either created, balanced, or altered in a way that should augment the flavor, acidity, aftertaste and body of the coffee as desired by the roaster.
Roasting Coffee Beans The first stage is endothermic. The green beans are slowly dried to become a yellow color and the beans begin to smell like toast or popcorn. The second step, often called the first crack, occurs at approximately 205 C (400 F) in which the bean doubles in size, becomes a light brown color, and experiences a weight loss of approximately 5%. The corresponding Agtron number for this color is between 95-90 (Davids, 68-69). In the next step the temperature rises from 205 C to approximately 220 C, the color changes from light brown to medium brown (Agtron # 60-50), and a weight loss of approximately 13% occurs (Davids, 68-69). The resulting chemical process is called pyrolysis and is characterized by a change in the chemical composition of the bean as well as a release of CO2. The second step is followed by a short endothermic period which is followed by another exothermic step called the second crack. This second pyrolysis occurs between 225-230C, and the roast color is defined as medium-dark brown (Agtron #50-45) (Davids, 68-69). The second pop is much quicker sounding and the beans take on an oily sheen. Espresso potential is maximized in roasting when you maximize the sweetness and aroma of the coffee while minimizing the bitterness and acidity. Most people focus on the latter and therefore roast extremely dark, yet without sweetness and aroma the espresso will never be palatable. This explains the unpopularity of straight espresso and the popularity of espresso based drinks where either milk or other flavors are used to replace the sweetness that was lost by roasting darkly. From 170-200C the sugars in coffee begin to caramelize. From tasting pure sugar versus its caramelized component it is evident that uncaramelized sugar is much sweeter. The dark color of coffee is directly related to the caramelization of the sucrose in coffee. Therefore, to maximize sweetness you want to minimize the carmelization of sucrose, yet you do not want to roast too lightly or bitter tasting compounds will not thermally degrade. Stop the roast somewhere between the end of the first crack and less than half way through the second crack. Do not roast well into or past the second crack. We recommend a roasting chamber temperature somewhere between 205215C. Realizing the danger of the following suggestion we might recommend a color similar to the one below. Note: All monitors, computers, and internet browsers will display the color slightly different. This is only a recommendation to point out that this color is preferable to the almost black color you will frequently observe for espresso. To get a better idea of roasting colors order the Agtron roasting classification kit from the SCAA
Coffee roasting
From Wikipedia, the free encyclopedia
Dark roasted coffee beans Roasting coffee transforms the chemical and physical properties of green coffee beans into roasted coffee products. The roasting process is what produces the characteristic flavor of coffee by causing the green coffee beans to expand and to change in color, taste, smell, and density. Unroasted beans contain similar acids, protein, and caffeine as those that have been roasted, but lack the taste. Heat must be applied for the Maillard and other chemical reactions to occur.
As green coffee is more stable than roasted, the roasting process tends to take place close to where it will be consumed. This reduces the time that roasted coffee spends in distribution, giving the consumer a longer shelf life. The vast majority of coffee is roasted commercially on a large scale, but some coffee drinkers roast coffee at home in order to have more control over the freshness and flavor profile of the beans.
Contents
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1 Process 2 Equipment o 2.1 Degree of roasting o 2.2 Determining degree of roast o 2.3 Degree of roast pictorial o 2.4 Caffeine content by roast level o 2.5 Roast naming confusions 3 Roast flavors 4 Home roasting 5 Packaging 6 Emissions and control 7 Gallery 8 See also 9 References 10 External links
[edit] Process
The coffee roasting process follows coffee processing and precedes coffee brewing. It consists essentially of sorting, roasting, cooling, and packaging but can also include grinding in larger scale roasting houses. In larger operations, bags of green coffee beans are hand or machine-opened, dumped into a hopper, and screened to remove debris. The green beans are then weighed and transferred by belt or pneumatic conveyor to storage hoppers. From the storage hoppers, the green beans are conveyed to the roaster. Roasters typically operate at temperatures between 240275 C (464527 F), and the beans are roasted for a period of time ranging from 3 to 30 minutes.[1] Initially, the process is endothermic (absorbing heat), but at around 175 C (347 F) it becomes exothermic (giving off heat).[2] For the roaster, this means that the beans are heating themselves and an adjustment of the roaster's heat source might be required. At the end of the roasting cycle, the roasted beans are dumped from the roasting chamber and cooled with forced air. Sometimes, in large commercial roasters, the beans are first quenched with a fine water mist. Torrefacto is a roasting process used in Spain and parts of Latin America involving the addition of sugar.
[edit] Equipment
The most common roasting machines are of two basic types: drum and hot-air, although there are others including packed bed, tangential and centrifugal roasters. Roasters can operate in either batch or continuous modes. Drum machines consist of horizontal rotating drums that tumble the green coffee beans in a heated environment. The heat source can be supplied by natural gas, liquefied petroleum gas (LPG), electricity, or even wood. The most common employ indirectly heated drums where the heat source is under the drum. Direct-fired roasters are roasters in which a flame contacts the beans inside the drum; very few of these machines are still in operation. Hot-air roasters force heated air through a screen or perforated plate under the coffee beans with sufficient force to lift the beans. Heat is transferred to the beans as they tumble and circulate within this fluidized bed.
roasts. When the beans are at about 224227 C (435441 F), or a medium roast, they emit a "second crack." This is the dividing point between medium and dark roasts.
22 C (72 F) Green Beans Green coffee beans as they arrive at the dock. They can be stored for up to two years. Saudi coffee is prepared using unroasted beans. 195 C (383 F) Cinnamon Roast The first and lightest roast level, immediatel y before first crack. Light brown, toasted grain flavors with sharp acidic tones. 165 C (329 F) Drying Phase As beans roast, they lose water and increase in size.
205 C (401 F) New England Roast Moderate light brown, still acidic but not bready, a traditional roast for Northeaster n U.S. Coffee, at first crack.
210 C (410 F) American Roast Medium light brown, the traditional roast for the Eastern U.S. First crack ending. 225 C (437 F) Full City Roast Medium dark brown with occasional oil sheen, good for varietal character and bittersweet flavors. At the beginning of second crack. 240 C (464 F) French Roast Dark brown, shiny with oil, burnt undertones, acidity diminished. At the end of second
220 C (428 F) City Roast Medium brown, the norm for most of the U.S., good for tasting the varietal character of a bean. 230 C (446 F) Vienna Roast Moderate dark brown with light surface oil, more bittersweet, caramel-y flavor, acidity muted. In the middle of second crack. Occasionall y used for espresso blends. 245 C (473 F) Italian Roast Very dark brown and shiny, burnt tones become more distinct, acidity almost
crack. A popular roast for espresso blends. 250 C (482 F) Spanish Roast Extremely dark brown, nearly black and very shiny, charcoal and tar tones dominate, flat, with thin body.
is so dominant that it can be difficult to distinguish the origin of the beans used in the roast. Below, roast levels and their respective flavors are described.[11] These are qualitative descriptions, and thus subjective. As a rule of thumb, the "shinier" the bean is, the more dominant the roasting flavors are. Notes Surface Flavor After several minutes the beans pop or Cinnamon "crack" and visibly roast, half expand in size. This Lighter-bodied, higher acidity, Light Dry city, New stage is called first no obvious roast flavor England crack. American mass-market roasters typically stop here. Sweeter than light roast; more body exhibiting more balance Full city, After a few short in acid, aroma, and American, minutes the beans complexity. Smoother than the Medium regular, reach this roast, Dry traditional American breakfast, which U.S. specialty "medium" roast, but may brown sellers tend to prefer. display fewer of the distinctive taste characteristics of the original coffee.[12] After a few more minutes the beans Somewhat spicy; complexity is High, Full begin popping again, Slightly traded for heavier body/mouthViennese, Roast and oils rise to the shiny feel. Aromas and flavors of Continental surface. This is roast become clearly evident. called second crack. After a few more minutes or so the Smokey-sweet; light bodied, Double beans begin to Very but quite intense. None of the French Roast smoke. The bean oily inherent flavors of the bean sugars begin to are recognizable. carbonize. Roast level
[edit] Packaging
Extending the shelflife of roasted coffee relies on maintaining an optimum environment to protect it from exposure to heat, oxygen, and light. Roasted coffee has an optimal typical shelf life of 2 weeks, and ground coffee about 15 minutes. Without some sort of preservation method, coffee becomes stale. The first large scale preservation technique was vacuum packing in cans. However, because coffee emits CO2 after roasting, coffee to be vacuum packed must be allowed to degas for several days before it is sealed. To allow more immediate packaging, pressurized canisters or foil-lined bags with pressurerelief valves can be used. Refrigeration and freezing retards the staling process. Roasted whole beans can be considered fresh for up to one month if kept cool.[citation needed] Once coffee is ground it is best used immediately.
dryness that the coffee produces under the edges of your tongue and on the back of your palate. The role acidity plays in coffee is not unlike its role as related to the flavor of wine. It provides a sharp, bright, vibrant quality. With out sufficient acidity, the coffee will tend to taste flat. Acidity should not be confused with sour, which is an unpleasant, negative flavor characteristic. Aroma Aroma is a sensation that is difficult to separate from flavor. Without our sense of smell, our only taste sensations would be: sweet, sour, salty, and bitter. The aroma contributes to the flavors we discern on our palates. Subtle nuances, such as "floral" or "winy" characteristics, are derived from the aroma of the brewed coffee. Body Body is the feeling that the coffee has in your mouth. It is the viscosity, heaviness, thickness, or richness that is perceived on the tongue. A good example of body would be that of the feeling of whole milk in your mouth, as compared to water. Your perception of the body of a coffee is related to the oils and solids extracted during brewing. Typically, Indonesian coffees will possess greater body than South and Central American coffees. If you are unsure of the level of body when comparing several coffees, try adding an equal amount of milk to each. Coffees with a heavier body will maintain more of their flavor when diluted. Flavor Flavor is the overall perception of the coffee in your mouth. Acidity, aroma, and body are all components of flavor. It is the balance and homogenization of these senses that create your overall perception of flavor. The following are typical flavor characteristics: General flavor characteristics:
Richness-refers to body and fullness
Complexity- the perception of multiple flavors Balance- the satisfying presence of all the basic taste
characteristics where no one over-powers another Typical specific desirable flavor characteristics:
Bright, Dry, Sharp, or Snappy- [typical of Central American
coffees]
Caramelly -candy like or syrupy Chocolaty- an aftertaste similar to unsweetened chocolate or
vanilla
Delicate- a subtle flavor perceived on the tip of the tongue
spicy
Fruity- an aromatic characteristic reminiscent of berries or
citrus
Mellow- a round, smooth taste, typically lacking acid Nutty- an aftertaste similar to roasted nuts Spicy- a flavor and aroma reminiscent of spices Sweet- free of harshness Wildness- a gamey flavor that is not usually considered
[typical of Kenyan and Yemeni coffees] Typical specific undesirable flavor characteristics:
Bitter- perceived on the back of the tongue, usually a result
of over roasting
Bland- neutral in flavor Carbony- burnt charcoaly overtones Dead- see "flat" Dirty- a mustiness reminiscent of eating dirt Earthy- see "dirty" Flat- lack of acidity, aroma, and aftertaste Grassy- an aroma and flavor reminiscent of freshly cut lawn
Harsh- a caustic, clawing, raspy characteristic Muddy- thick and dull Musty- a slight stuffy or moldy smell [not always a negative
Aroma is a major component of taste, try to do this where there are no strong, perfume-like smells in the air.
4. Steep for 2-3 minutes. The coffee should form a crust or cap on top of the water. While steeping, check the coffee for any sour smells. Sour smells are bad and could indicate old or rancid coffee. 5. Gently break the crust with your spoon by pushing the grounds back exposing the water. You should notice a fine-celled foam. If there is no foam, the coffee may not be fresh. Again smell the coffee because much of the fragrance is trapped under this crust. Pay extra attention to the fragrance because it is so important to the taste. As you continue to break the crust, the grounds will sink to the bottom of the cup. 6. Fill your spoon with the brewed coffee avoiding the floating grounds. 7. Slurp the coffee into your mouth with some force. This will mix air with the coffee and disperse it evenly throughout your mouth. 8. Swirl the coffee around your mouth to get a good feel for the overall flavor. 9. Spit the coffee out and rinse mouth with water before tasting another. While you are tasting the coffee, here are the major characteristics you should be paying attention to: Acidity - The sensation of dryness in the back and under the edges of your mouth. This is a desirable quality and not to be confused with sour (which is considered a bad quality of coffee). Acidity creates a lively, bright taste which without it, the coffee would taste flat. Aroma Without aroma, we could only taste sweet, sour, bitter and salty. This is where we get the subtle differences such as floral, nutty or fruity. Body The way the coffee feels in your mouth, its viscosity or heaviness. The best way to describe it is the comparison to how whole milk feels in your mouth compared to water. If you are unsure as to the level of body in the different coffees, add an equal amount of milk to each one and the one with the heavier body will retain more of its flavor when diluted. Flavor This is the overall perception of the three characteristics above. Flavor can be rich (full bodied), complex (multi-flavored), or balanced (no one characteristic over powers the other. Here are some terms used to describe DESIRABLE flavor qualities: Bright or dry highly acidic leaving a dry aftertaste Caramelly caramel like or syrupy Chocolaty aftertaste similar to unsweetened chocolate or vanilla Earthy a soily-like quality (sometimes unfavorable) Fragrant an aroma ranging from floral to nutty to spicy, etc. Fruity having a citrus or berry scent Mellow a smooth taste lacking acidity but not flat Nutty similar to roasted nuts Spicy an exotic aroma of various spices Sweet a lack of harshness Wild a gamey flavor rarely, but sometimes considered favorable Winy aftertaste resembling a mature wine Here are some terms used to describe UNDESIRABLE flavor qualities:
Bitter aftertaste perceived on the back of the tongue Bland neutral in flavor Carbony burnt charcoal flavors Earthy a musty, soily-like quality Flat lacking aroma, acidity, and aftertaste Grassy aroma and taste of grass Harsh a caustic, raspy quality Muddy thick and flat Musty slightly stuffy smell (sometimes desirable in aged coffees) Rubbery a smell of burnt rubber Sour a tart flavor such as unripe fruit Turpeny a flavor resembling turpentine Watery a lack of body Wild a gamey flavor