CUMULATIVE TEST -1 (CT-1)

JEE ADVANCED
TARGET : JEE (ADVANCED)-2013
DATE : 21-04-2013

COURSE NAME : REVISION CLASSES

HINTS & SOLUTIONS

PAPER-1
PART-I (Physics)
1.
A square coil ..................................
Sol. (A)
If the coil is rotated about axis (i)
and (ii), Amplitude of emf will be
E1 = E2 = N (r2)B
If it is any rotated about axis (iii),
it will not cut flux
So, E3 = 0
If it rotates about axis (iv), its angular velocity can be restored
into two components. The emf will be induced only due to y :

6.
A uniformly charged ..................................
Sol. (A)
Let Q be the charge on the ring. The electric field at point P is

Qx
QR
1
1
4 0 ( x 2 R 2 )3 / 2 = 4 0 (2R 2 )3 / 2

E=

The rotating charged (Q) ring is equivalent to a ring in which

current flows, such that

Qv
2 R

The magnetic field at point P is

and that will be

E4 = (N) (r2)
2.

.
B
2

2R 2

0
4

B=

2 3/2 =

(x R )

QvR
0
4 (2R 2 )3 / 2

In the figure ..................................

1
E
c2
=
=
B 0 0 v
v

Ans. (C)

3.
A planet is ..................................
Sol. (B)
As per Kepler's law, areal velocity remain constant

7.
A total charge ..................................
Sol. ( A)

dA
m v 1 r1
J
1
1
=
=
=
r v =
r v .
dt
2m
2m
2 1 1
2 2 2

i i i i
i 0, 0 , 0 , 0 , 0 ,........,
2

4.
Figure shows ..................................
Sol. (A)
x11 = x22

rp R R 0

1 =

0 bt
0

(R 0 R rp ) .

q=

5.
In the circuit ..................................
Sol. (B)

R=

i=

i0
2

t/T

2n

i0
2 t/T

dt =

i0 T
n 2

i0 T
n 2

q
T

ln 2 Ans. initial value of the current

8.
Two point mass ..................................
Sol. (B)

am1 = am3 0

am1 = am2 0

Fm1 m3 Fm2 = 0

R = 10

9.

RESONANCE

dq =

i0 =

12

R = 8
R 5

12 R = 8R + 40

8 16

Tn = t, n = t/T

p
R
R
. . 0 =
. . 1
p
(R 0 bt rp R) p

If pot. drop between A and B is

also 8V,
then no currrent will pass through the galvanomter.
Potential difference across

i0

In the circuit ..................................

Ans. (ABCD)

SOL210413 - 1

10. Two conducting ..................................

Sol. (ABD)

V10 cm

K (2)
10cm

V 20cm =

18. The drift speed ..................................

Sol. ( A)

K (3 )
20cm

Vd =

V 10cm > V 20cm

So after connection electrons will flow from larger sphere
to smaller sphere.
After rearrangement potential energy of system is least.
11. The figure shows ..................................
Sol. (BC)
Appyling Gauss theorem to volume containing cuboid
indicated by ABCD

E
0 q
A enc
0
k
A

or

j dA = E dA =
3

2 k R

20.

v1

( 3i 3 j 2k ) =

(5 3 )2

14. A solid non ..................................

Sol. (AD)
In uniformly charged sphere, electric field increases as
one moves away from the centre.
15. The charge ..................................
Sol. (D)
The capacitance of the conducting shell of radius
C = 40 R
Charge Q = (40 R) V0
As charge is conserved.
Q is also equal to (40 r)V.
16. The surface ..................................
Sol. (B)
The volume of the drop = volume of the liquid contained in the
bubble
r= 3

3R 2 t

so the surface area of the drop

S = 4 r2 = 4 (3R2 t)2/3 = 4 (9R4 t2)1/3
17. Assuming current ..................................
Sol. (B)

i
V
E . 200 18 10 2

2
j=
=
A R. A
R A = 900 2 10 4 = 200 A/m
Alt : j = E =

. E
RA

RESONANCE

4 Kq1 q2

=
3
m.r

v1 =

Kq1 q2
r

4 9 109 10 5 10 5

=2
3
100 10 3 3

22.

6
RqB 10 10 10
=
= 2 m/s
m
5 10 5

3mv 12
4

Velocity of approach = v1 + v2 = 3 m/s.

1
sin =
, = 30 , = 90 = 60
2

4
r3 = (4 R2) t
3

v2

1
1
Kq1 q2
mv12 +
2mv22 =

2
2
r

=R v=

15

2m=200g

m=100g

R R 25 + 10 R = 75
R = 10 m

mv
qB

2
2 10 8

100

8
3 = 3 10 =

Two point charges ..................................

An s . 12
Sol. v1 = 2v2

13. A charged particle ..................................

Sol. (ABCD)
2

3 16 10 6

The gravitational ..................................

An s . 60

v B E

k 2 R 3
3

21.

12. A charged particle ..................................

Sol. (ABD)

R2 (R 5)2 =

3 =

k r . 2r dr =

108 1 m 1

E At
1
E
k 0 At = 0
2k
2
k

( i j ) ( 2i 3k ) =

= 2.5 cm/s

Electric field ..................................

An s 15

Sol. =

EA 0
qenc =
k

Electrostatic energy stored in dielectric medium

2

19.

200
J
=
22
ne
5 10 1.6 10 19

The potentiometer ..................................

Ans. 30
Sol: Since the cross sectional area of the parts AN and NB are in
the ratio 1 :4 , the resistance per unit length will be in the ratio
4:1 and therefore the potential gradient in the part NB will be
four times that in the part AN i.e. 4V/m .Let CN be x meter and
ND be (0.2x) meter.
The potential difference across CD = 1 x + (0.2 x) 4 =0.5(given)
x = 0.1 m.

PART-II (Chemistry)
23. PCl5 + H2O

H3PO4 + HCl ...............

Sol. (D)
PCl5 + 4H2O

H3PO4 + 5HCl

POAC for 'P' atom

1 mole of PCl5 = n mole of (HPO3)n

mass of PCl5
320
=n
208.5
80 n
mass of PCl5 = 834 gm.
24. Calculate relative rate ...............
Sol. (B)

rO 2

nO 2

MCH4

rCH 4

= n

CH4

MO 2

3
16

2
32

3
16
=
4 2
32

SOL210413 - 2

25. At 1400 K, Kc = 2.5103 for the ...........

Sol. (C)

(A) PV = nRT

V=

nR
nR
T log V = log
+ log T
P
P

3 3

10 10
QC =

2 4

10 10

243
10 2 = 7.59 102 > Kc
32

so, reaction will proceed in backward direction.

26. Which of the following planes .....................
Sol. (D)
(B) V =
27. 40 ml of

nR
nR
T TV =
T2
P
P

M
solution of a .....................
4

Sol. (A)
HA + OH
mmoles

10

A + H2O

10
10

volume of Ba(OH)2 added =

[A] =

10
6 = 60 ml
1

10
1

M
100 10

(C)

A + H2O

V nR
V
nR
=
= log
log
T
P
T
P

HA + OH

t=0 0.1
0.1x

10 14
0.01
x2

= Kh =

12
2
0 .1 x
2 10
x = [OH] = 0.02 M
[H+] =

KW
[OH ]

= 5 1013 M.

28. Select the correct statement..............

Sol. (A)
29. 20 gm of an impure mixture ......................
Sol. (C)
Moles of NaHC2O4 = moles of H2C2O4 = moles of Na2C2O4 = a
Meq. of NaOH = Meq. of H2C2O4 + Meq of NaHC2O4
40 0.2 = a 2 1000 + a 1 1000

32. Which of the following ................

Sol. (ABC)
33. A radioactive element X ....................
Sol. (ABC)
34. 100 ml of 0.1 M aq. soluiton .................
Sol. (BCD)
HNO2 + OH NO2 + H2O]
At equivalent point of titration
[NO2] =

8
8
3a =
, a=
1000
3000

10
1
=
100 50
15

1
1
1
1.18
= 7 + 2.5
pKa +
log
= 8.91
2
2
2
15

Meq. of KMnO4 = Meq. of NaHC2O4 + meq of H2C2O4 + Meq. of

Na2C2O4
V 0.4 5 = (a 2 1000 + a 1 1000) 2

pH = 7 +

6a 1000 2
V=
= 16 ml.
2

HNO2 + OH NO2 + H2O

30. The relationship between osmotic ..................

Sol. (C)
p = CRT, order of conc is : urea > glucose > sucrose

After adding 20 ml of Ba(OH)2

10
6

4
= 5 + 0.3 0.48 = 4.82
6

pH = pKa + log

After adding 100 ml Ba(OH)2 solution

31. Among the plots which represents ................

Sol. (ABC)

RESONANCE

SOL210413 - 3

[OH] =

10
1
=
200
20

Ct = C0 eKt

pOH = log 20 = 1.3

pH = 12.7

35. For the reaction, X (g) + Y (g)

Ct =

3Z (g)..................

K=

ln 2

T1/ 2

3
0.2 ln 2510

3
2.510
2 e

Sol. (ABC)
X (g)
t=0
teq

a
ax

Y (g)

3Z (g)

Ct = (0.1) eln(D)

a
ax

Ct =

0 .1

3x

ln 2
At equilibrium
[X] [Y] = (a x) (a x) = 0
3[X] + [Z] = 3(a x) + 3x = 3a

[ Z]
3x
= (a x) +
=a
3
3

[Y] +

rate = K(Ct) =

2.5 10

0 .1

= 6.93 mole L Sec1.

1

39. If edge length of the cube is ..................

Sol. (A)

3[X] + 3[Y] + 2[Z] = 3(a x) + 3(a x) + 6x = 6a.

36. Choose the correct statement..................
Sol. (ABCD)
equivalent of oxidising agent = equivalents of reducing agent.

EqMnO = Eq 2
Fe
4
nMnO 5 = n 2 1
Fe
4
Eq Cr

2
2O 7

nCr

2
2O 7

EqFe2

6=

nFe2

nCr

2
2O 7

nCu2S

Total number of unit cells =

n
[SO4 2 ] =

SO4 2

Vsol (L )

Ea 1

+ lnA
R T
Ea 1

+ log[A]
2.303R T

slope of B graph =

= 0.78

1.2 N A
= 7.5 1021.
12 8

1.2 104 NA / NA
103

Molarity of Fe2 (SO4 )3 =

logK =

42. x g of Fe2 (SO4 )3 was dissolved ...............

Sol. (16)

37. Slope of straight line in graphB ....................

Sol. (B)

lnK =

dC C

40. Total number of diamond unit ................

Sol. (C)

EqCu2S

6=

r=

nMnO 5 = nCu S 8
2
4
2
2O 7

2a

41. How many number of next .................

Sol. (12)

EqMnO = EqCu S
2
4

Eq Cr

4 dC C sin(5444') =

nFe2 (SO4 )3

38. The rate of reaction ................

Sol. (A)
For Ist order reaction.

rate = K[N2O5]t

RESONANCE

= 0.04 M

= M V L = 0.04 1 = 0.02

mFe2 (SO4 )3 = 0.04 400 = 16 g = x

43. In a closed container NO2 was ................

Sol. (80)
2 NO2

N2O4

100 x

x/2 mol

Ea
2.303 R = 6670

Ea = 6670 2.303 8.314 J = 127710 J = 127.71 KJ.

1.2 101
3

= 1.2 101 M

x
2
mole fraction of N2O4 =

200 2x + x =

(100 x )

2
x =
3
2

3x
2

200 = 1.5 x + x

SOL210413 - 4

x=

1
S
=
2
4
2

200
= 80 Ans.
2.5

S=1
44. The conductivity of an aqueous ................
Sol. (11)

m
= 0.015 =

So

and m = 0.000033 5 103

50. The value of ................................

sin cos sin cos cos sin

Sol. (A)

sin

cos

sin cos cos sin

sin

cos

sin cos cos sin

0.033 5
= 11 Ans.
0.015

sin cos sin

= cos

sin

cos

sin

cos

sin +
sin

PART-III (Mathematics)
45. Sum of squares of ......................................
Sol. (B) sin2 + cos2 + tan2 + cot2 + cosec2 + sec2
1 + tan2 + cot2 + 1 + cot2 + 1 + tan2
3 + 2(tan2 + cot2) 7
46. If 1, 2 be the roots ...................................
Sol. (D) 1 + 2 = 32, 1, 2 = 16, 3 + 4 = 32
3 4 = 1
4

= 12 + 22 + 32 + 42

i 1

= (32)2 2(16) + (32)2 2.1

= 2014

sin cos cos

sin

Sol. (A) (1 + )(1 +

22

23

(1 ) (1 ) .... (n terms)

1
2 1
a 2 2 4
4a
a

1
a

4 +2

2a

a4 +

2a 4

49.
Sol. (B) 21/4 22/8 23/16 24/32........
21/4 + 2/8 + 3/16 + 4/32+......... = 2S

1 2 3
4

+..........
4 8 16 32

1
S=
2

1 2
3
+
+
+..........
8 16 32

-----------------------------------------------

1
S 1 1 1

=
+..............
2 4 8 16 32

S
=
2

1
4
1

1
2

1 2.

1
1
1
1
+ 2.
2.
+ 2.
+..........
3
5
2
4

1 1 1 1

..... = 1 2(1 n 2)
2 3 4 5

53. If z1 and z2 are lying ..................................

Sol. (AB) |z 3| 4 represents circle and its interior whose centre is
(3,0) and radius 4.
|z 1| + |z + 1| = 3 represents set of all points on the boundary of
ellipse when foci at S(1, 0) and S(1,0).
Minimum value of |z1 z2| is 0 when z1 and z2 at the intersection

of circle and ellipse |z1 z2|max if z1(7, 0) and z2

|z1 z2|max = 7 +

range

3 17
=
2 2

17
0, 2

54. If f(x) =

Sol. (ABC)

RESONANCE

4
n 4 n e = n
e

+2

21/4 41/8 81/16 161/32 .....................................

S=

1
1
1
1

+............
1.2 2.3 3.4 4.5

= 1 + 2 n 2 =

1
4

Sol. (D)

1
....................................
1.2

1 2

= a4 +

cos = 0 + 0
cos

1 1 1 1 1 1 1

1 + +.....
2 2 3 3 4 4 5

, if n be even
, if n be odd

48. If , are the roots ....................................

Sol. (C) 4 + 4 = (2 + 2)2 2()2
= [( + )2 2]2 2()2

cos

52. The sum of

(2)( )( 2)( ).... (n terms)

1
=
2

cos

sin

51. If B is a non singular matrix and A is a square matrix such that B

1AB exists, then det (B1AB) is equal to
Sol. (D) det (B1AB) = det(AB1B) = det(AI) = det (A)
[ B1A = AB1]
So det(B1AB) = det A

47. If is imaginary cube ..................................

2)

sin

x 2 4x 3
x2 x 1
f(x) =

....................................

x 2 4x 3
x2 x 1

=y

SOL210413 - 5

3
, 0
2

(y 1)x2 + (y 4) x + (y 3) = 0
D0
3y2 8y 4 0

y 4 2 7

3
3

n 1
(1 r 11)
8a(r 11 1) ar
=
(1 r )
r 1
r 10

y 4 2 7

3
3

8 = r n 11
0

4 2 7 4 2 7
,

3
3

a = 4, b = 2, c = 7 and d = 3

55. If A =

3
5

and det (3A2013 + A2014) = 2 (1 + + 2)

111 336

then, where ,, are integers

Sol. (ABC) A =

3
5

111 336

111 333

= (2013)2013 [111 9]
= (2013)2013 32 (1 + 10 + 102)

n (x + z) + n (x 2y + z) = 2 n (x z) is
Sol. (AD) n (x + z)(x 2y + z) = n (x z)2
56. If

(x2 2xy + xz + xz 2yz + z2) = x2 + z2 2xz

4xz = 2xy + 2yz

xy x
yz = z

2xz
= y and
xz

57. If sin + cos =

ar 9 (r n 9 1) 2ar n 1 9 (1 r n 9 )
=
(r 1)
1 r
r n 9

r
r = 21/9

|A| = 1680 + 333 = 2013

det (3A2013 + A2014) = |A2013 (3I + A)|
= |A2013 ||3I + A| = (2013)2013

ar 9 (r n 9 1)
(r 1)
=2
n 9

n 1 1 1
(ar ) 9
1
r r

1
1
r

then a value of tan satisfies which

5
2

8= 2

n 11
9

n = 38
59. (B) Locus of u, when .................................
60. (C) Axis of locus of ...................................
Sol. BM = y 0 = 1(x 1)
x+y=1

u 1

= t + i(1 t)

x = 2t and y = 2t(1 t), where u = x + y

(x 1)2 = 2(y 1/2)
axis x = 1
61. If the equation does .....................................
62. If the graph of the ..................................
Sol.61. (C) Since D < 0 so the sign of quadratic polynomial is same
for all values of x.
f(0) = a2 + b2 + c2 ab bc ca > 0
so graph is mouth opening upward a > 0

of the following equation

62. (B) Product =

2 = 1
Sol. (ABC)
+

5
1 tan 2
1 tan 2
2
2
2 tan

2x
1 x

2 +

1 x2
1 x

1 tan 2

1
5

(let

tan

[2x + 1 x2] 5 + 1 + x2 = 0
4x2 10x 6 = 0
2x2 5x 3 = 0
2x2 6x + x 3 = 0
(x 3)(2x + 1) = 0
x = 3,

1
2

58. In a G.P. the ratio of the.........................

a(r11 1)
1
r 1
Sol. (BD)
111 = 8
arn1 1
r

1
1
r

RESONANCE

= x)
2

a 2 b 2 c 2 ab bc ca
a

mouth opening downwards

Product < 0

a<0

63. If |z1| = 1, |z2| = 2, ...................................

Ans. 02
Sol. z1 z1

1 , z 2 z2 4 , z 3 z 3 9

9
4
1
12

=
z 3 z 2 z1 | z1z 2 z 3 |
| z3 z 2 z1 | =

12
6

|z1 + z2 + z3| = 2
64. The number of integral ..............................
Ans. 00
Sol. log1/2 (logx 2 (x2 3x + 3)) > 0
0 < logx 1 (x2 3x + 3) < 1
now x2 3x + 3 > 0 x R
Case -I 0 < x 2 < 1
2<x<3
x2 3x + 3 > x 2 and x2 3x + 3 < 1
x2 4x + 5 > 0 and x2 3x + 2 < 0

SOL210413 - 6

 x (1, 2)
Intersection of x (1, 2) and x (2, 3) will give x
Case-II x 2 > 1
x>3
1 < x2 3x + 3 < x 2
x2 4x + 5 > 0 and x2 3x + 2 > 0
x
65. If a = log63147, b ................................
Ans. 10

log 7 147 log 7 (3 7 2 )

2 log7 3
Sol. a =
=
=
2
log 7 63 log 7 (7 3 ) 1 2 log 7 3
log37

b=

2a
2a 1

V AB = E x(0).(2) = B 0r

6
R 2 2 =10 100 0.01 0.0036 = 48 mV

VAB=B0

Ex(0) = Ex(P)
2.
A time varying .................................
Sol. (A)
The magnetic field does not pass through the loop. Hence flux
remains zero. As there is no change in flux, there is no induced
current.
3.
Two very long .................................
Sol. (C)
The field at O due to small element dx is
dE =

1
dx
.
4 0 x 2

Hence due to one wire

3b
3 log7 3
= log73 =
3b 1
1 3 log 7 3

3b
2a
=
3b 1 2a 1

1
0

66. Number of positive ....................................

Ans. 04
Sol. 8, x, y are in H.P.

towards left.

. =
4 0 a 2 0 a

4.
A sphere of .................................
Sol. (B)

x=

16 y
y8

E=

x=

16( y 8) 128
( y 8)

UE =

16

dx

Net field at O is
E=

x = 16

x2

.
4 0 a

E=

1 a.b
= 10
2
ab

dx

Q
4 0 r 2

Q2

1
0 E2
2

32 2 0 r 4

5.
A satellite is .................................
Sol. ( A)

128
y8

In AOB : - cos 60 =

128
y8 >0

R
OB = 2 R
OB

Here gravitational force will provide the required centripetal

force.

128
y 8 < 16

GMm
Hence

8<y+8
y+8>8
y + 8 = 16,32,,64,128
4 ordered pairs

= m(OB) 2

(OB )2
GM

PAPER-2
PART-I (Physics)

(OB)

GM
=

(2R )

GM
=

8 R3

6.
In a region .................................
Sol. (C)
As the magnetic field is along the x-axis, the magnetic
force will be along () z-axis from t = 0 to t = T 0 and along
(+)ve z-axis from t = T 0 to t = 2T 0 .

1.
A uniform magnetic .................................
Sol. (C)
Ex(0) = Ex(P)
The xcomponent of field at any point P
on the line AB is same as the field at O.
Considering a circular loop of radius r :
E 0(2r) =

dB
r2
dt

B 0r
r
E 0 = (B 0)
=
2
2

For t = 0 to t = T 0 :
At t =
( B = B 0t)

T0
2

x-coordinate =

( V0 cos ) T0
P0
=
2
2

(Since pitch = P0 = (V0cos)T0)

RESONANCE

SOL210413 - 7

y-coordinate = 0 (from figure)

and z-coordinate = 2 R0 (from figure)
Hence (A) is correct.
Similarly at t =

If loop law is applied to the left hand loop in clockwise direction

E

3T0
;
2

coordinates are

VR2

3 P0

, 0 , 2 R 0 Hence (B) is correct.

Note: z -coordinate will be + 2R0, because from t = T0 to

t = 2T0, direction of B changes.

As the charge will perform circular motion about x-axis, the
two extremes from x-axis are 4R0 from each other.
Hence (C) is also incorrect.
Hence only (D) is correct.
7.
Initially the block .................................
Sol. (B)

m MDielectric
K

T = 2

(emf )2
R

=0

= E = 12 V

i.e. VR2

does not change during the charging process.

13. Find the value .................................

Sol. (B)
12 = (0.6)
X = (0.7)
X = 14
Rseries = 12 + 14 = 26
14. If you fail to .................................
Sol. (D)
The maximum P.D. which we can measure by this potentiometer is V. Any change can be done which assures p.d.
across R or X less then or equal to V.
15. Surface charge .................................
Sol. ( A)

8.
A uniform circular .................................
Sol. (A)
The induced emf in the circular loop = B (PQ) v = B a v.
Therefore electrical power consumed by the circular loop
=

VR2

E=

40 10
= 100 V/m
0 .3

(near the plate the electric field has to be uniform

it is almost due to the plate).
For conducting plate

(Bav )2
R

E=

= 0E

Therefore, = 8.85 1012 100

=
8.85 1010 C/m 2
16. How much work .................................
Sol. (D)
W = q.dV
= 1 106[20 (20)]
=
4 105 J.
17.
9.
If Gravitational .................................
Sol. (A)
|Gravitational field due to 2nd at P| = |Gravitation field due to 1st
at Q|
P
at P
Gravitational field due to 1st
+ Gravitational field due to 2nd
M
2R

G( 2M)
=

4R

GM
=

Sol.

2R 2
M

By symmetry VB = VF
No current in the resistor joining B and F and in similar resistors
like between G and B etc.
The currents are assumed as shown in the figure using
symmetry.
Applying KVL along DBCD, we have VD i/2 R iR + E + 2E = VD

2R

GM
G f due to 2nd at P =

2R 2

10. A light weight .................................

Sol. (B)
The electrostatic force at right end of rod is F = QE. Then
tension at a distance x from right end of rod is
T=

Consider the circuit .................................

Ans. (A) r;
(B) s ; (C) s ; (D) r

F 1
L

i = 2E/R =
18.

Two masses .................................

An s . 8

net extension
L

T dx
FL
YA 2YA
0

2 4
8
1

GM
Sol. E =

QEL
=
2 YA

11. The potential .................................

Sol. (C)
Using Vc = E (1 et/)
Vc = 12 (1 e2)
= 10.4 V
12. The potential .................................
Sol. (D)

RESONANCE

r2

|E1| =

G 800
G 450
= 2G = |E2| =
= 2G
400
225

|E| =

E1 E 2

2 2 G

19.

Two long straight .................................

An s . 4
Sol. The net magnetic force
on conducting sphere is

SOL210413 - 8

F (PQ B 0k )
F=I
20.

Sol.

B0

I P

4V

6V

6V

2
1

1F 10V

Total pressure of gases = PA + PB + PC

= 3(a+b)
= 3(0.15) = 0.45 atm

Q = 4V 1F = 4C

24. The number of atoms in 100 g ...............

Sol. (B)
a = 200 pm = 200 1010 cm = 2 108 cm
volume = (2 108)3

No. of atoms =

2 0 = 5

22.

In the circuit .................................

Ans. 5
Sol. During the steady state the capacitors are fully charged and
will behave like open circuit. So the current will flowing outer
loop only. The current in the outer loop will be =

(B) H3BO3 + glycerin

0.1 x

30
= 3 Amp, in
10

x = 0.1

glycerin =
3A

+ q1

Applying KVL in loop-I

q q1
+
15 = 0 q + q1 = 30
2
2

= 5 1024

(H3BO3 glycerin) is 0.90.

x

ax

80
= 0.08;
100
80
= 4.44 M
20 0.9

.... (1)

26. What molar ratio of Sn and Cl2 ................

Sol. (A)
Sn + Cl2 SnCl2 + SnCl4
a
2a
moles of Sn taken = a + 2a = 3a
moles of Cl2 taken = a + 4a = 5a

Applying KVL in loop-II

molar ratio of Sn to Cl2 =

q q1
q1
6 + 10
=0
10
2

10 (2 10 8 )3

a x = 4.44

a = 4.44 + 0.08 = 4.52 M

i=0

d a

3 =

25. The equilibrium constant ..................

Sol. (B)

clockwise direction. Charge distribution on the plates of

capacitors are as shown in figure.

+
C3 (q - q1)

4 100

ZA

A spherical shell .................................

An s . 5

+
q
-

101 = b 0.05 = b

a = 2 0.05 = 0.10 atm

1F 10V

6V

4
4
1 = 6 V;
4

1
9 10 3
= b3 =
103
8
72
1

Figure shows a .................................

Ans. 4

4
E= 1

4
21.

2 RB0

Sol.

I
O

3a
3
=
5a
5

.... (2)

On solving equation (1) and (2) we get

q1 = 10C

PART-II (Chemistry)
23. X(s)

A(g) + 2B(g) .................

27.

Sol. (B)
X(s)

A(g) + 2 B(g)
a

(2a + 2b)
C(g) + 2 B(g)

Y(s)
b

(2a + 2b)

K p1
a
Kp2 = b = 2

Three graphs are plotted between ...............

Sol. (A)
As T increases, graph moves upwards

a = 2b

K p1 = a (2a + 2b)2 9 103 = 2b(6b)2

28. If equal volume of following ......................

Sol. (D)
106M Hg22+ + 109M I

9 103 = 2b 36b2

RESONANCE

SOL210413 - 9

965 10
= 0.1
96500

9
10 24
10 6 10
IP =

=
= 1.25 1025 > Ksp

8
2
2

No. of faradays =

When Galvanometer replaced by the battery following reaction

take place at electrode
Cathode :
Zn2+ (aq.) + 2e
Zn(s)
initial mole
2 mole
0.1 mole

precipitation of Hg2I2 will occur.

29. Two aqueous solutions A ..................
Sol. (D)
In solution A : Cu2+ + 2e Cu ; 2H2O O2 + 4H+ + 4e
(pH decreases)
In solution B : 2Br Br2 + 2e ; 2H2O + 2e H2 + 2OH
(pH increases)

after reaction 2

1.95 mole

30. An ionic compound XY .................

Sol. (B)

Concentration of [Zn2+] =

a
The nearest distance between two X-atoms is

a
so

Cu(s) Cu+2 (aq) + 2e

initial mole

2 2 and a = 4

Concentration of [Cu2+] =

32. An ideal solution contains two ..................

Sol. (B)
PT = PA0 XA +

Ecell = E0cell

1.25 1930 60
= 1.5
96500

mass of H2SO4 consumed = 1.5 = 1.5 98 = 147 g.

1
4
+ 200
=180 torr..
5
5

n1
N

Ecell = E0cell

( Zn 2 )
2.303 RT
log
(Cu 2 )
nF

= 0.76 + 0.34

2
0.06
log
= 1.07 volt.
0 .2
2

34. If Galvanometer is replaced ................

Sol. (B)

( Zn 2 )
1.95
0.06
2.303 RT
log
log
2 = 1.1
(
Cu
)
0.25
nF
2

a
< 1000
Rb

200 <

400 cal <

a
< 2000 cal
b

0.4 kcal <

a
< 2 kcal
b

H2
CH4
CO2

Temperature = T1

36.
P

If the above plot is replotted at ..................

Sol. (C)
As temperature increases, graph moves upwards.
37. The value of H ................
Sol. (D)

1
Slope = tan30 =

RESONANCE

0.25
1

1.1 0.03 0.9 = 1.073

5 180 5Ps = Ps
Ps = 150 torr.
33. The emf of cell at 298 K ...............
Sol. (A)

0.1
2

35. Which of the following is correct ...............

Sol. (B)
200 < TB < 1000

PB0 XB

PT = 100

0.2 +

0.1 mole

0.25 mole

31. When lead acid accumulator .................

Sol. (D)

P 0 Ps
Ps

0.2 mole

after reaction

20
g/cm3
3

No of faraday electricity withdrawn =

1.95
1

Anode :

z(moler mass )
4 64
40
d=
=
3
23
8 3 =
NA a
6 10 ( 4 10 )
6

0.1
2

H
R

SOL210413 - 10

PART-III (Mathematics)

H =

38. Which of the following statements .................

Sol. (C)
H > O
Endothermic reaction
Y intercept = +ve S > 0
for endothermic reaction, as T , K .
The value of equilibrium constant K is unaffected by pressure
changes.
39. Boyles temperature (TB) .................
Ans.
(A) q,r,s (B) p, r (C) r (D) p,r

45. A six digit number ..................................

Sol. (B)
|(a + b + c) 7| should be a multiple of 11.
(a + b + c) can be either 7 or 18.
a,b,c are in G.P. (let a,ar, ar2)
a(1 + r + r2) = 7 or 18
only possible a(1 + r + r2) = 7 for
a = 1, r = 2
a(1 + r + r2) = 18
a and r should be integers another possible values can be a = 6,
r=1
but a, b, c are distinct.
46. Number of integers ..............................
Sol. (A) |a| |b| = |a + b|
ab 0 and |a| |b|
(x2 + x 2)(x2 + 7x + 12) 0 and |x2 + x 2| > |x2 + 7x + 12|
(x + 2)(x 1)(x + 3)(x + 4) 0

40. Henrys law constant for CO2 ...............

Sol. (9)

n CO2
PCO = KH.xCO
2

= KH

= KH

n CO2 n water

x [4, 3] [2, 1]
and 2(x2 + 4x + 5)( 6x 14) 0
(3x + 7) 0
x 7/3
Only integers are 4 and 3

nCO2
n water

2.5 105 = 2.5 108

47. In the interval [0, 2] ............................

Sol. (B) logcos(sin2) = 2
cos > 0, cos 1 and sin2 > 0
sin2 = cos2
2sin cos cos2 = 0
cos [2sin cos] = 0
cos 0, 2sin = cos
tan = 1/2
in [0, 2] has two values for which tan= 1/2.
One in [0, /2] and the other one in [, 3/2]. But for the second
value cos will be negative.

nCO 2
162 / 18

nCO = 9 103
2

41. The gas phase decomposition ..............

Sol. (5%)
% yield of CH2CO =

k2
k 1 k 2 100 = 5%.

42. A cell reaction ; Zn + 2Fe3+

2Fe2+ + Zn2+

.....................

Sol. (5)
S = nF

dE
1.718 1.2
= 2 96500
= 5000 Joule/K.
dt
20

43. Calcium sulphate CaSO4 is .................

Sol. (2)
Moles of CaSO4 =

0.816
= 6 103
136

0.216
Moles of H2O =
= 1.2 102
18

1
2
and sin2 =
=
>0
1 tan 2 1 1
4
2 tan

so only one value is possible.

48. In a ABC, cos3A + cos3B + cos3C = 1 then
Sol. (C) cos3A + cos3B + cos3C = 1

3A 3B 3C
sin
sin
=1
2 2 2

1 4 sin

either A =

2
2
2
or B =
or C =
3
3
3

49. For the cubic equation ...............................

Sol. (C) Let , , are the roots

Moles of H2O
Moles of CaSO 4 = 2.

+ + =
44. The value of vrms for a gas X .................
Sol. (4 )
[(vrms)X] 546C = [(vmp)Y]273C

3RTx
=
Mx

2RTY
MY

3 819 2 546
=
MY
9

27
9
, =
8
2

we know that

()1/3
3

here

3
=
3
2

and

()1/3 =

MY = 4 amu

RESONANCE

3
2
SOL210413 - 11

3
2

===

4n

S =

=
50. If , are roots of the ..............................
Sol. (C) Here , are imaginary cube roots of unity
5 = 2 , 8 =
equation is x2 + x + 1 = 0

52. If A =

1
2

1 1 1 1 1 1

......
1 1 1 3 3 5

1
2

Sol. y =

x2 x d
x 2 2x d

x2 (1 y) + x (1 2y) + d (1 y) = 0
(2y 1)2 4d(1 y)2 0
{if y 1}
4y2 (d 1) + 4y(1 2d) + 4d 1 0
for d = 4
{for y = 1, x = 0}

cos sin cos sin

sin cos sin cos

A2 =

cos 2 sin 2

sin 2 cos 2

5 3
6 , 2

for d = 0

y=

cos n sin n
An =

sin n cos n

x2 x
x 2 2x

Domain x 0, 2

sin n
0 0
n =

0 0
cos n

n

53. Find the sum of the.............................

1
1
1
1
+
+
+
+.......
1 3 15 35

The reciprocal of each term is

1, 3, 15, 35,....
\ /\ /\ /
4 12 20
\ / \ /
8 8
Let general terms an2 + bn + c
1 = a + b + c
3 = 4a + 2b + c
15 = 9a + 3b + c
a = 4, b = 8, c = 3

55. (C) If the range of function is.........................

56. (C) What will be the range,...............................

A2 =

Sol. (B)

n 1

54. The locus represented................................

Sol. (D) It is the sum of the distance from two fixed point which is
less than the distance between there two fixed points so
no locus.

cos sin
Sol. (B) A =

sin cos

cos n
n
A
lim
= nlim
sin n
n n

8n 3

(2n 3)(2n 1)

n 1

cos sin

, ...........................
sin cos

2 (2n 3) (2n 1)

51. Let A and B are two ................................

Sol. (A) AB = A and BA = B
A2 = A, B2 = B
A and B are idempotent
(A + B)2 = A2 + AB + BA + B2
= 2(A + B)
(A + B)3 = (A + B)(A + B)2
= (A + B)2(A + B)
= 2(A + B)2 = 22(A + B)
(A + B)5 = 24(A + B)

n 1

a 3
9
27
27
= 3 =
3=
a=
2 2
4
4
2

y=

x ( x 1)
x( x 2 )

y=

x 1
x2

(x 0)

xy + 2y = x + 1
x(y 1) = 1 2y
x=

1 2y
y 1

x 0, 2
1 2 y
y 1,
0, 2
y 1
y

1
2

Range y R

1
1,
2

1
Tn =

4n 8n 3

RESONANCE

57. (A) What is the value ..........................

58. (B) What is the value ...........................

SOL210413 - 12

Sol. loge(1 + x) = x

3
x5
x2 x
x4
+

+
........
3
5
2
4

2 n 2 1 =

r 1

put x = 1

c = 2 n 2 1

1 1 1 1
+

+
........
2 3 4 5

n 2 = 1

(2r 1)(2r )(2r 1)

59.

(A) Value of

b+c=1

a21c31 + a22 c32 ....................

60. (C) If all the elements of the .......................

1 1 1
+
+
+.......
n 2 =
1 .2 3 . 4 5 . 6

61. The number of solutions ..................

Ans. A - q, B - p, C - p,r,s, D - s
Sol. (A) by graph

(B) by graph

(2r 1)(2r )

n 2 =

(C) 2cos2 + 4sin2cos2 = 2

r 1

4sin2 cos2 = 2sin2

sin2 = 0 or cos2 = 1/2

1
2

n 2 =

= n, = n /4

r (2r 1)
r 1

(D)
2 n 2 = a

..............(1)
cos2 + 2cos cos2 = cos
cos2 + cos3 = 0

1 1 1 1 1 1
Similarly n 2 = 1
2 3 4 5 6 7

n 2 = 1

1
2 cos 1
=
cos 2
cos

1
1
1

2.3 4.5 6.7

2cos

cos = 0
2
2

62. If a solution of equation ........................

Ans. 1

1
1
1 n 2 =
+
+......
2 . 3 4 .5

Sol. (x2 2.22009 x + 24018) + |x 22009| 2 = 0

(x 22009)2 + |x 22009| 2 = 0
Let |x 22009| = t
t2 + t 2 = 0

n 2 =

(t + 2)(t 1) = 0

(2r)(2r 1)

t 2, |x 22009| = 1

r 1

x 22009 = 1 or x 22009 = 1
x = 22009 + 1 or x = 22009 1

n 2 =

1
2

2r
r 1

1
2

r
63. If sin2 + tan2 =

2(1

n 2 ) = b

............(2)
Ans. 2

(1) + (2)
a+b=2

Sol.

n 2 =

and

1
1
1
+
+
+..........
1.2 3.4 5.6

n 2 = 1

2 n 2 = 1 +

8
......................
15

1
1

.............
2.3
4 .5

1 1
1
1

+
+.......
1 .2 2 .3 3 .4 4 .5

2 tan
2

1 tan

2 tan
2

1 tan

solving the equation

8
15

tan = 2

6
6
4

1
3
2 and ..........................
64. A =
1 4 3
Ans. 1

RESONANCE

SOL210413 - 13

Sol. By cayley hamilton theorem

66. If three positive number ..............................

|A | = 0

Ans. 4

6
6
4

3
2 =0
1
1
4 3

2ac
2ac
c
a
c
a

Sol.
c
2ac
2ac
2a
2c
ac
ac
a

(4 )[(3 )( 3) + 8] 6[(3 ) + 2] + 6[4 + 3 ] = 0

(4 )[8 9 + 2) + 6[+ 1] + 6( 1) = 0
(2 1)(4 ) = 0

a(a c 2c ) c(2a a c)
+
2a(a c c ) 2c(a c a)

a 3c 3a c
3 a c

4
+
=1+
2a
2c
2 c a

42 3 4 + = 0
A will satisfy this equation
4A2 A3 4I3 + A = 0
4A1 = A2 + 4A + I3

A1 =

1
1
A2 + (A) + (I3)
4

++=1

1 1 1

..... =
......... = 2 4 8

=4

65. The roots of the equation...............................

Ans. 3
Sol. If z1, z2, z3 are the vertices of an equilateral triangle then
z12 + z22 + z32 = z1z2+ z2z3 + z3z1
(z1 + z2 + z3)2 = 3(z1z2+ z2z3 + z3z1)
p2 = 3q

RESONANCE

SOL210413 - 14