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    Solutions For Reactor Kinetics

    Uploaded by

    zy_yf
    This document contains two chemistry assignment questions. 1) The first question asks to find the conversion of reactant A flowing through a vessel where it undergoes a zero-order reaction. The mean conversion is calculated to be 5.0%. 2) The second question provides a rate law and asks to suggest a mechanism consistent with it. The suggested mechanism involves Eley-Rideal kinetics where ethylene E adsorbs on the catalyst surface and reacts with gas phase hydrogen. The rate-limiting step is the reaction of adsorbed ethylene with hydrogen.

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    Download as PDF, TXT or read online from Scribd

    Solutions For Reactor Kinetics

    Uploaded by

    zy_yf
    148 views2 pages
    This document contains two chemistry assignment questions. 1) The first question asks to find the conversion of reactant A flowing through a vessel where it undergoes a zero-order reaction. The mean conversion is calculated to be 5.0%. 2) The second question provides a rate law and asks to suggest a mechanism consistent with it. The suggested mechanism involves Eley-Rideal kinetics where ethylene E adsorbs on the catalyst surface and reacts with gas phase hydrogen. The rate-limiting step is the reaction of adsorbed ethylene with hydrogen.

    Original Description:

    NUS reactor kinetics solutions. solutions to homework questions

    Original Title

    Solutions for Reactor Kinetics

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    © Attribution Non-Commercial (BY-NC)

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    This document contains two chemistry assignment questions. 1) The first question asks to find the conversion of reactant A flowing through a vessel where it undergoes a zero-order reaction. The mean conversion is calculated to be 5.0%. 2) The second question provides a rate law and asks to suggest a mechanism consistent with it. The suggested mechanism involves Eley-Rideal kinetics where ethylene E adsorbs on the catalyst surface and reacts with gas phase hydrogen. The rate-limiting step is the reaction of adsorbed ethylene with hydrogen.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    148 views2 pages

    Solutions For Reactor Kinetics

    Uploaded by

    zy_yf
    This document contains two chemistry assignment questions. 1) The first question asks to find the conversion of reactant A flowing through a vessel where it undergoes a zero-order reaction. The mean conversion is calculated to be 5.0%. 2) The second question provides a rate law and asks to suggest a mechanism consistent with it. The suggested mechanism involves Eley-Rideal kinetics where ethylene E adsorbs on the catalyst surface and reacts with gas phase hydrogen. The rate-limiting step is the reaction of adsorbed ethylene with hydrogen.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    CN2116E Assignment #2 (due 19-04-2013) CN2116E-XJP-2013-Assignment #2

    1

    Name: _________________
    Matric. No: _________________

    QUESTION 1 (25 marks)
    A liquid macrofluid reacts according to R A as it flows through a vessel. Find the conversion
    of A for the following flow pattern and kinetics.



    Solution
    (a) Using the segregation model, dt t E t X X
    batch
    ) ( ) (
    0
    =
    }


    For a batch reactor we have

    0 A
    A
    C
    r
    dt
    dX
    =
    From the reaction kinetics, we have
    zero order reaction, min mol/lit 3 =
    A
    r and mol/lit 6
    0
    =
    A
    C
    Solving for X(t), we have

    2min for t 1, X
    min 2 for , 5 . 0 5 . 0 ) (
    > =
    s = = t t X t t X

    From the flow pattern (a), we have
    3 t 0 for , min
    3
    1
    ) (
    1
    s s =

    t E
    Therefore, the mean conversion for a zero order reaction is

    3
    2
    )
    3
    1
    ( ) 1 ( )
    3
    1
    ( ) 5 . 0 (
    3
    2
    2
    0
    = + =
    } }
    dt dt t X



    CN2116E Assignment #2 (due 19-04-2013) CN2116E-XJP-2013-Assignment #2
    2


    QUESTION 2 (25 marks)
    The rate law for the hydrogenation (H) of ethylene (E) to form ethane (A) over a cobalt-
    molybdenum catalyst is
    E E
    H E
    E
    P K
    P kP
    r
    +
    =
    1
    '
    Suggest a mechanism and rate-limiting step consistent with the rate law.


    Solution

    A E H
    H C H C H
    Cat
    +
    +
    6 2 4 2 2


    Only E adsorb on catalytic surface. Eley-Rideal kinetics.
    H S E S s
    E
    S E
    v E AE ADE
    C C k r E
    K
    C
    C C k r E

    = + +
    |
    |
    .
    |

    \
    |
    = +
    S A H S
    S S E

    Site balance:
    ) 1 (
    E E v S E v T
    C K C C C C + = + =



    Therefore

    T E S
    E E
    H E
    E E
    T E E H S
    s
    C K k k
    P K
    P kP
    C K
    C C K C k
    r
    =
    +
    =
    +
    =
    1 1

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