Untitled
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Untitled
a. CH
2
= C = CH
2
b.CH
3
-CH=CH-CH
2
+
c. CH
3
- C
+
= CH
2
d.CH
3
-CH=CH-CH
2
(b)
6 5 6 5
3
|
C H C C H
CH
(c)
3
3
|
CH C H
CH
(d)
3
3
3
|
|
CH
CH C
CH
(b)
2
CH CH
+
= (c)
2 2
CH CH C H
+
=
115.P-chlorophenol is stronger acid than phenol because
(a) Cl is less electronegative than oxygen atom
(b) Of the-I effect of a halogen which is greater than its +R effect
(c) Of +R effect of Cl which is stronger than its-I effect
(d) Of +R effect of Cl.
116.The stability of a carbonium ion (carbocation) seconds upon
(a) The bond angle of the attached group
(b) The substrate with which it reacts
(c) The inductive effect of the attached group
(d) None of the above
117.Which of the following species is paramagnetic in nature?
(a) Free radical (b) Carbonium ion (c) Both (a) and (b) (d) None of these
118.In the carbonium ion, the carbon atom bearing positive charge is____ hybridised
(a) sp (b) sp
2
(c)sp
3
(d) unhybridised
119.The shape of carbanion is
(a) Linear (b) Planar (c) Pyramidal (d) None
120.State of hybridisation of carbon atom of carbene in the triplet state is
(a) sp
2
(b)sp (c) sp
3
(d) None of these
121.The bond that undergoes heterolytic cleavage most readily is
(a) C-C (b) C-O (c) C-H (d) O-H
122.The shape of the carbonium ion is
(a) Triangular planar (b) V-shaped (c) Pyramidal (d) None of these
123.Carbanion is iso-structural with
(a) Free radical (b) Carbonium ion (c) Ammonia (d) Carbene
124.Delocalisation of electrons involving -bonds known as ____effect.
(a) Mesomeric (b) Tautomeric (c) Electromeric (d) Hyperconjugative
125.Which one of the following series contains electrophiles only?
(a)
2 3 3
, , H O SO H O
+
(b)
3 2 3
, , NH H O AlCl (c)
3 3 2
, , AlCl SO NO
+
(d)
2 3
, , H O Cl NH
+.
126.The order of stability of free radical is
(a) Tertiary > Allyl > Benzyl(b) Allyl > Benzyl >Tertiary (c) Benzyl >Allyl >Tertiary(d) Tertiary > Benzyl > Alyl
127.Inductive effect involves :
(a) - e
(b) - e