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P24 Answers Kweyete Albert

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CHAPTER 24- Practice Exercise A.

Kweyete
Organic Chemistry
1. Which of the following is (are) a saturated hydrocarbon? (underline your choice)

alkane alkyne alkene cycloalkane cycloalkene aromatic hydrocarbon

2. Identify the following general formulas as alkanes, alkenes, alkynes, and cycloalkanes.

CnHn CnH2n CnH2n+2 CnH2n-2


Alkyne alkenes, cycloalkanes alkanes (cycloalkenes), alkynes, (diene)
3. Which one of the following is (are) an alkene with a carbon-carbon double bond?

C4H10 C6H14 C4H8 CH4 C6H10 C2H2 C5H10 C2H2 C6H6

4. How many carbon atoms are in each of the following contain?

Butane Octane Nonane Propyne Acetylene cycolpentane


4 8 9 3 2 5
5. Write the IUPAC name for each of the following structure.

.a) 2,4-dimethylhexane
.b) 2,2,3-trimethylhexane
.c) ethyne
.d) 3,4-dimethylhexane
.e) 2,4-dimethyl-1-pentene
.f) 2-pentene
.g) 1-bromo,2-methyl-benzene
.h) cis-1-bromo-4-chloro-cis-2,3-dimethylcyclohexane

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6. Write the condensed structures for the following compounds.

(a) 3, 3, 4- trimethylheptane CH3CH2C(CH3)2CH(CH3)(CH2)2CH3


(b) 2, 3- dimethylbutane CH3CH(CH3)CH(CH3)2
(c) 1, 3- dibromopentane CH2BrCH2CHBrCH2CH3 .
(d) 3, 4- dimethylhexane CH3CH2CH(CH3)CH(CH3)CH2CH3
(e) cis- 2, 3- dichloro-2-butene cis-CH3CCl=CClCH3
(f) trans- 1, 2- dibromocyclobutane trans-C4H6(Br)2 .
(g) 4- ethyl- 3, 3- dimethylheptane CH3CH2C(CH3)2CH(C2H5)(CH2)2CH3
(h) p- xylene p-(CH3)C6H4(CH3)
(i) m – chlorobenzoic acid m-ClC6H4COOH
(j) Diethyl ether CH3CH2OCH2CH3 .
(k) 3 - nitrophenol m-(NO2)C6H4OH
(l) cyclobutylcyclopentane C5H9(C4H7)

7. Which class of functional group do the following belong to?


O O
 
(a)  OH alcohol___ (b)  CHO aldehyde___ (c)  C - H _aldehyde (d)  C  OH carboxylic acid

(e)  CO  carbonyl ( f)  NH2 amine ( g)  O  ether (i)  COO  esther

8. Complete the following sentences:

(a) The term hydrocarbon is used to denote compounds that contain carbon & hydrogen, only.

(b) Pentane and isopentane are what type of isomer? ( structural, geometrical )

(c) Dichlorobenzene has 3 aromatic isomers. (ortho, meta, para isomers)

(d) Cyclohexene has 2 hydrogen less than cyclohexane.

(e) Alcohols have higher boiling point due to hydrogen bonding.

9. Match the following general formulas.

(a) R - OH (b) R - CHO (c) R - COOH (d) R - CO – R (e) R - O - R (f) R - COOR (g) R - NH - R

(e) ( I ) Ether (d) ( V ) Ketone (b) ( II ) Aldehyde (a) ( VI) Alcohol

(f) ( III) Ester (g) (VII) Amine (c) ( IV) Carboxylic acid

10. Which of the following compounds does contain a carbonyl group? Please circle.

I. Aldehyde II. Alcohol III. Ketone IV. Ether V. Ester VI. Amine VII. Amide VII.Carboxylic acid

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11.Identify(classify) the following oxygen-containing compounds as ketone, aldehyde, ether, ………

(a) carboxylic acid


(b) ketone
(c) aldehyde
(d) alcohol
(e) ether
(f) ether
(g) amide

12. Name the following alcohols.

a) butanols
b) 2-butanol
c) 2-methyl-2-butanol
d) Ethylene glycol
e) Phenol
f) 2-propanol (OR Isopropyl alcohol)
g) 2,2-dimethyl propanol

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13. Name the following alkyl groups.

a) methyl
b) ethyl
c) propyl
d) isopropyl
e) n-butyl
f) isobutyl
g) secondary butyl
h) tertiary butyl
i) phenyl
j) benzyl

14. How many structural isomers do the following compounds have?

C3H8 C4H10 C5H12 C6H14 C4H9Cl C3H5Br


1 2 3 5 4 4

15. Identify the following pairs as structural isomers, geometrical isomers, alike, or non-isomers.

I. structural isomers
II. alike
III. geometrical isomers*****
IV. structural isomers
V. non-isomers

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16. What is the product of the following reactions.

a) CH3-CH2-CHBr-CH3
b) CH3-CHBr-CHBr-CH3
c) CH3-CBr(CH3)-CH3

d)

e) 3CO2 + 4H2O

O

f) CH3-O-C- CH3

g)

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h) O

C-OCH3

OH

i)

j)

k) C17H35COONa + C2H5OH
l) CH3-CH2-O-CH2-CH3 .

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