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General Organic Chemistry - Sheet - 1 (Classification of Organic Compound) Level - 1

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Page 1 of 4 CCP - SANKALP_GOC-1-PH-IV

CPP
GENERAL ORGANIC CHEMISTRY - SHEET – 1
(CLASSIFICATION OF ORGANIC COMPOUND)

LEVEL - 1
1. The compound which has one isopropyl group is:
(A) 2,2,3,3-tetramethyl pentane (B) 2,2-dimethyl pentane
(C) 2,2,3-trimethyl pentane (D) 2-methyl pentane

2. How many secondary carbon atoms does methyl cyclopropane have?


(A) None (B) One (C) Two (D) Three

3. Which of the following is the first member of ester homologous series?


(A) Ethyl ethanoate (B) Methyl ethanoate (C) Methyl methanoate (D) Ethyl methanoate

CH3
4.
CH3
and
,
CH3
Numbers of secondary carbon atoms present in the above compounds are respectively:
(A) 6,4,5 (B) 4,5,6 (C) 5,4,6 (D) 6,2,1

5. The number of primary, secondary and tertiary amines possible with the molecular formula C 3H9N is:
(A) 1,2,2 (B) 1,2,1 (C) 2,1,1 (D) 3,0,1

6. The minimum number of secondary carbon atoms required to form a ring is


(A) 6 (B) 5 (C) 3 (D) 4

7. All the following are composed of secondary carbon atoms only except
(A) propane (B) Cylohexane (C) Aniline (D) Phenol

8. The simplest alkene containing three primary carbon atoms is


(A) Isobutylene (B) –butylene (C) –butylene (D) Isopentane

9. The simplest alkyne containing at least one primary, one secondary and one tertiary carbon atom is named
(A) Isobutyne (B) 2–butyne (C) 3–methyl–1butyne (D) 2,3–dimethyl–1–butyne

10. The number of primary, secondary, tertiary and quaternary carbon atoms in iso–octane is given by the set
(A) 5, 0, 2, 1 (B) 5, 1, 0, 2 (C) 5, 1, 1, 1 (D) None

11. How many  and  bonds are present in each of the following molecules?
(a) HC  CCH = CHCH3 (b) CH2  C = CHCH3

LEVEL - 2

12. How many 1°carbon atom will be present in a simplest hydrocarbon having two 3° and one 2° carbon atom?
(A) 3 (B) 4 (C) 5 (D) 6

13. How many carbons are in simplest alkyne having two branching?
(A) 5 (B) 6 (C) 7 (D) 8

14. The group of hetrocylic compounds is:


(A) Phenol, Furan (B) Furan, Thiophene (C) Thiophene, Phenol (D) Furan, Aniline

15. When vinyl carbon & allyl carbon are joined each other, we get
(A) Conjugated alkadiene (B) cumulative alkadiene
(C) Penta-1, 4-diene (D) Allenes

16. Which of the following is a heterocyclic compound?

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Page 2 of 4 CCP - SANKALP_GOC-1-PH-IV
HC CH HC COOH HC CH HC CH
| | | |
(A) HC CH (B) HC COOH (C) HC CH (D) HC CH

17. The minimum number of carbon atoms in an alkyne having one quaternary carbon atom is
(A) 5 (B) 6 (C) 7 (D) 4

18. The minimum number of carbon atoms in an alkene having a quaternary carbon is
(A) 8 (B) 4 (C) 5 (D) 6

19. The minimum number of carbon atoms in an alkane having four primary carbon atoms is :
(A) 4 (B) 8 (C) 5 (D) 6

20. The minimum number of carbon atoms in an alkane, alkene and alkyne with one smallest side chain is given
by the set
(A) 3, 4, 5 (B) 4, 4, 5 (C) 4, 5, 5, (D) 4, 6, 4

21. The total number of carbon atoms and the number of sp 3 hybridised carbon atoms in the simplest alkyne
containing a tertiary carbon atom is given by the set:-
(A) 3, 4 (B) 5, 3 (C) 3, 2 (D) 4, 2

SUBJECTIVE

1. What is functional group?

2. Write down the functional group of following

i) 2° amine ii) N-substituted amide


iii) thioether v) thiol
vi) Ester vii) thial
viii) acid anhydride ix) Nitrile
x) isonitrile

3. What do you mean by homologous series? Write down the important characteristic of homologous
series.

4. How many functional groups are present in the following structures? (Identify them)
i) OH ii) O H 2C CH3
O H H O H
H3C C C C C CH2
Cl C C CH3
CH3 N COOR
COOH H H CH3
iii) Ph NH2 O iv) OH CH3
CN
C C C C CH2 SH H3C C C CH3
CHO CHS
OH C Br HOC C SH

O H

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Page 3 of 4 CCP - SANKALP_GOC-1-PH-IV
v) OH

C CN

OHC O CH3 O

O H C C O C CH3

H3C C O C COCl

6. Give the hybridisation of all carbon in the followings


i) ii) H
O
H3C CH C
CH C CH2 C C
C H

H
iii) iv) H

H2C CH HC C C C C C C
C C CH2 CH3
H
HC C CH2 CH3

7. How many carbon is allylic, vinylic, benzylic in the following styructures.


i) H H H H H H

H2C C C C C C C C CH2

H H H H
ii) H H

C C C

H H

iii) CH3 H CH3 H

H3C C C C C C

CH3 H H H

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Page 4 of 4 CCP - SANKALP_GOC-1-PH-IV
ANSWER KEY – GENERAL ORGANIC CHEMISTRY - SHEET – 1
1. D
2. C
3. C
4. A
5. C
6. C
7. A
8. A
9. C
10. D
11. (a)  = 10,  = 3 (b)  = 9,  = 2
12. B
13. D
14. B
15. C
16. A
17. B
18. D
19. C
20. B
21. B
——

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