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    The document discusses properties of fluids by examining phase diagrams and equations of state. It looks at ideal gas laws and relationships, then real fluid equations of state. Examples of phase diagrams for CO2 are presented, comparing pressure-temperature and pressure-volume diagrams. The differences between real and ideal gases are also explored.

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    228 views5 pages
    The document discusses properties of fluids by examining phase diagrams and equations of state. It looks at ideal gas laws and relationships, then real fluid equations of state. Examples of phase diagrams for CO2 are presented, comparing pressure-temperature and pressure-volume diagrams. The differences between real and ideal gases are also explored.

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    Chemical Engineering Thermodynamics

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    The document discusses properties of fluids by examining phase diagrams and equations of state. It looks at ideal gas laws and relationships, then real fluid equations of state. Examples of phase diagrams for CO2 are presented, comparing pressure-temperature and pressure-volume diagrams. The differences between real and ideal gases are also explored.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    228 views5 pages

    Volume Expansivity

    Uploaded by

    S S S REDDY
    The document discusses properties of fluids by examining phase diagrams and equations of state. It looks at ideal gas laws and relationships, then real fluid equations of state. Examples of phase diagrams for CO2 are presented, comparing pressure-temperature and pressure-volume diagrams. The differences between real and ideal gases are also explored.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
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    of 5

    Chap3PropertiesofFluids

    Firstexaminephasediagrams the experimental i t ld data t th that tequations ti of fstate t t (EOS)endeavour topredict Reviewidealgaslawconceptand relationshipsusing LookatEOSsforrealfluids(cubicequationsin particularandgeneralised correlations.)

    PhaseDiagrams
    PhaseDiagramspresentexperimentaldata thatequationsofstatearetryingtopredict. Phasediagramsaremoreaccuratebecause theydonotcontainmodelinadequacies. Equationsofstatearemeanttoapproximate informationwithinaphasediagram
    ManyEOSshavebeendevelopedbutnoneare abletopredictallsubstancesinallphases(yet)

    ExamplePhaseDiagram
    PTdiagramGeneric

    Q1.Whatisthedifference betweenagasandavapour? Q2.Whatisasupercriticalgas? Q3.Whatisthefluidregionand whyisitspecified?

    Fig3.1intext

    ExamplePhaseDiagram
    PTdiagramforCO2

    ApplicationoftheGibbsphaserule: Q.ForliquidCO2inequilibriumwithCO2gas,howmanydegreesoffreedomdowehave? Q.ForCO2gas,howmanydegreesoffreedomdowehave?

    ExamplePhaseDiagrams
    PVphasediagramforCO2
    Question:Whathappensifwecompress CO2isothermallyat20C? Question:Whyarentthereanyabrupt volumechangesforisothermsaboveTc?

    ComparisonofPTandPVforCO2

    PVTDiagramForIdealGas

    Example:MakeyourownPVdiagramusingideal gaslaw

    Differencesbetweenrealandidealgases
    Moleculesinrealgasesinteractwithoneanother (exceptinthelimitasP>0) Longrangeandshortrangeintermolecularforces changethecompressibilityofthegas
    Longrangeattractiveforcesbetweenmoleculestend toattractmolecules:Gasismorecompressible comparedtoidealcase Shortrangerepulsiveforcestendtopushtwo moleculesaway: y Gasislesscompressible p (tends ( to expand)comparedtoidealcase Atmediumpressures,attractiveforcestendto dominate(duetodistancesbetweenmolecules),at highpressuresrepulsiveforcestendtodominate
    8

    Differencesbetweenrealandidealgases
    Thecompressibilityofarealgasisdefinedby:

    Todoyourself:DerivethefollowingEOSforarealgas

    Otherdifferences: Realgas Idealgas

    Asaconsequence:

    Idealvs Realgascomparison

    (Actuallyfromvander Waalsequation)
    10

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