----------------------- Page 1----------------------AIEEE - 2002 Physics and Chemistry 1. Which statement is incorrect ?

(a) all reversible cycles have same efficiency (b) reversible cycle has more efficiency than an irreversible one (c) Carnot cycle is a reversible one (d) Carnot cycle has the maximum efficiency in all cycles 2. Length of a string tied to two rigid supports is 40 cm. Maximum length (wave length in cm) of a stationary wave produced on it is (b) 80 (c) 40 (d)120 3. The power factor of an AC circuit having resistance (R) and inductance (L) connected in series and an angular velocity is (a) (d) R/ L R/(R 4. lution (c) increase span of observation rsion 5. The kinetic energy needed to project a body of mass m from the earth su rface (radius R) to infinity is (a) mgR/2 (b) 2mgR (c) mgR (d) mgR/4 6. If an ammeter is to be used in place of a voltmeter, then we must conne ct with the ammeter a (a) low resistance in parallel e in parallel (c) high resistance in series in series (b) high resistanc (d) low resistance (d) have low dispe (b) 2 2 2 1/ 2 R/(R L ) 2 + 2 2 1/ 2 (c) L ) L/ R (a) 20

An astronomical telescope has a large aperture to (a) reduce spherical aberration (b) have high reso

7. If in a circular coil A of radius R, current I is flowing and in anothe r coil B of radius 2R a current 2I is flowing, then the ratio of the magnetic fields B and B , produc ed by them will be A B (a) 1 (d) 4 (b) 2 (c) 1/2

0 8. If two mirrors are kept at 60 to each other, then the number of images formed by them is (b) 6 (c) 7 (d) 8 9. A wire when connected to 220 V mains supply has power dissipation P . N ow the wire is cut into 1 two equal pieces which are connected in parallel to the same supply. Po wer dissipation in this case is P . Then P : P is 2 2 1 (b) 4 (c) 2 (d) 3 10. If 13.6 eV energy is required to ionize the hydrogen atom, then the ene rgy required to remove an electron from n = 2 is (a) 10.2 eV (d) 6.8 eV (b) 0 eV (c) 3.4 eV (a) 1 (a) 5

11. Tube A has both ends open while tube B has one end closed, otherwise th ey are identical. The ratio of fundamental frequency of tube A and B is (a) 1 : 2 (b) 1 : 4 (c) 2 : 1 (d) 4 : 1 12. A tuning fork arrangement (pair) produces 4 beats / sec with one fork o f frquency 288 cps. A little wax is placed on the unknown fork and it then produces 2 beats / sec. The frequency of the unknown fork is (a) 286 cps (d) 288 cps (b) 292 cps (c) 294 cps

1 ----------------------- Page 2----------------------13. A wave y = a sin(t kx) on a string meets with another wave producing a nod e at x = 0. Then the equation of the unknown wave is (a) y = a sin(t + kx) (c) y = a sin(t kx) (b) y = a sin(t + kx) (d) y = a sin(t kx)

14. On moving a charge of 20 coulombs by 2cm, 2 J of work is done, then the p otential difference between the points is (a) 0.1 V (b) 8 V (c) 2 V

(d) 0.5 V 15. If an electron and a proton having same momenta enter perpendicular to a magnetic field, then (a) curved path of electron and proton will be same (ignoring the sense o f revolution) (b) they will move undeflected (c) curved path of electron is more curved than that of the proton 16. (d) path of proton is more curved In a simple harmonic oscillator, at the mean position (a) kinetic energy is minimum, potential energy is maximum (b) both kinetic and potential energies are maximum (c) kinetic energy is maximum, potential energy is minimum (d) both kinetic and potential energies are minimum 17. Initial angular velocity of a circular disc of mass M is 1 . Then two smal l spheres of mass m are attached gently to diametrically opposite points on the edge of the disc. What is the final angular velocity of the disc? M+ m M (a (d) M M+ 2m -1 18. The minimum velocity (in ms ) with which a car driver must traverse a fl at curve of radius 150 m and coefficient of friction 0.6 to avoid skidding is (a) 60 (b) 30 (c) 15 (d) 25 19. A cylinder of height 20 m is completely filled with water. The velocity o f efflux of water (in ms-1) through a small hole on the side wall of the cylinder near its bottom is (a) 10 (b) 20 (c) 25.5 (d) 5 20. A spring of force constant 800 N/m has an extension of 5 cm. The work do ne is extending it from 5 cm to 15 cm is (a) 16 J (b) 8 J (c) 32 J (d) 24 J 21. Two identical particles move towards each other with velocity 2v and v re spectively. The velocity of centre of mass is 1 1 (b) m 1 (c) M+ 4m 1 M+ m M

(a) v (d) zero 22. 23.

(b) v/3

(c) v/2

If a current is passed through a spring then the spring will (a) expand (b) compress (c) remains same (d) none of these Heat given to a body which raises its temperature by 10C is (a) water equivalent (b) thermal capacity (d) temperature gradient (c) specific heat

24.

At absolute zero, Si acts as (a) non metal (b) metal (d) none of these 2

(c) insulator

----------------------- Page 3----------------------25. Electromagnetic waves are transverse in nature is evident by (a) polarization (b) interference (c) reflection (d) diffraction Wires 1 and 2 carrying currents i and i respectively are inclined at an 1 2

26.

1 angle to each other. What is the force on a small element dI of wire 2 a 2

a distance of r from wire 1 (as shown in the figure) due to the magnetic field i1 i2 of wire 1? < 0 dI (A) i i dItan 2r 1 2 0 (c) i i dIcos 2r 1 2 (d) (b) 0 i i dIsin 2r 1 2 0 i i dIsin 4r 1 2 r

27. At a specific instant emission of radioactive compound is deflected in a magnetic field. The compound can emit (i) electrons (iv) neutrons (ii) protons (iii) He2+

The emission at instant can be (a) i, ii, iii (b) i, ii, iii, iv (d) ii, iii

(c) iv

28. Sodium and copper have work functions 2.3 eV and 4.5 eV respectively. The n the ratio of the wave lengths is nearest to (a) 1 : 2 (b) 4 : 1 (d) 1 : 4 Formation of covalent bonds in compounds exhibits (c) 2 : 1

29.

(a) wave nature of electron (b) particle natur e of electron (c) both wave and particle nature of electron (d) none of these 30. + ++ ++ + + A conducting square loop of side L and resistance R moves in its plane + ++ ++ + + + ++ ++ + + with a uniform velocity v perpendicular to one of its sides. A magnetic + ++ ++ + + L >

V induction B constant in time and space, pointing perpendicular and into ++ ++ + + + ++ ++ + + the plane at the loop exists everywhere with half the loop outside the + ++ ++ + + field, as shown in figure. The induced emf is + ++ ++ + + (a) zero (d) VBL (b) RvB (c) VBL/R

31.

Infra red radiation is detected by (a) spectrometer (b) pyrometer (d) photometer

(c) nanometer

32. If N0 is the original mass of the substance of half- life period t1/2 = 5 years, then the amount of substance left after 15 years is (a) N /8 (d)N /4 0 0 (b) N /16 0 (c) N /2 0

33. By increasing the temperature, the specific resistance of a conductor and a semiconductor (a) increases for both th (c) increases, decreases ases 34. If there are n capacitors in parallel connected to V volt source, then th e energy stored is equal to 1 2 (d) decreases, incre (b) decreases for bo

1 (a) CV (d) 35. CV

2 (b) nCV (c) CV2

2 2n Which of the following is more closed to a black body? (a) black board paint (b) green leaves (c) black holes (d) red roses 3

----------------------- Page 4----------------------36. The inductance between A and D is (a) 3.66 H (b) 9 H (c) 0.66 H D (d) 1 H A

3 3H 3H 37. A ball whose kinetic energy is E, is projected at an angle of 450 to the horizontal. The kinetic energy of the ball at the hig hest point of its flight will be H (a) E (d) zero (b) E/ 2 (c) E/2

38. From a building two balls A and B are thrown such that A is thrown upward s A and B downwards (both vertically). If v and v are their respective velocities on reachi ng the ground, then A B (a) v > v B A (c) v > v epend on their masses A B (b) v = v A B (d) their velocities d

39. If a body looses half of its velocity on penetrating 3 cm in a wooden blo ck, then how much will it penetrate more before coming to rest? (a) 1 cm (b) 2 cm (d) 4 cm (c) 3 cm

40. If suddenly the gravitational force of attraction between Earth and a sat ellite revolving around it becomes zero, then the satellite will (a) continue to move in its orbit with same velocity (b) move tangentially to the originally orbit in the same velocity (c) become stationary in its orbit (d) move towards the e arth. 41. Cooking gas containers are kept in a lorry moving with uniform speed. The temperature of the gas molecules inside will

(a) increase

(b) decrease

(c) remain same (d) decrease for some, while increase for others 42. When temperature increases, the frequency of a tuning fork (a) increases (c) remains same ases depending on the material (b) decreases (d) increases or decre

43. If mass-energy equivalence is taken into account, when water is cooled to form ice, the mass of water should (a) increase (c) decrease n decrease 44. The energy band gap is maximum in (a) metals (b) superconductors (d) semiconductors (b) remain unchanged (d) first increase the

(c) insulators

45. The part of a transistor which is most heavily doped to produce large num ber of majority carriers is (a) emmiter (b) base (c) collector (d) can be any of the above three 46. Energy required to move a body of mass m from an orbit of radius 2R to 3R is (a) GMm/12R2 (b) GMm/3R2 (c) GMm/8R (d) GMm/6R 47. If a spring has time period T, and is cut into n equal parts, then the ti me period of each part will be (a) T E (d) T D 48. C A charged particle q is placed at the centre O of cube of length L O q q (A B C D E F G H). Another same charge q is placed at a distance H G L from O. Then the electric flux through ABCD is A B (a) q/ 4 < L 0 L (b) zero (c) q/ 2 0 L (d) q/ 3 0 L n (b) T / n F (c) nT

4 ----------------------- Page 5----------------------49. If in the circuit, power dissipation is 150 W, then R is R (a) 2 2 (c) 5 15 V 0 0 Wavelength of light used in an optical instrument are 1 = 4000A and 2 = 5000A , then ratio of their respective resolving powers (corresponding to 1 and 2 ) is (d) 4 (b) 6

50.

(a) 16 : 25 (b) 9 : 1 (c) 4 : 5 (d) 5 : 4 51. A child swinging on a swing in sitting position, stands up, then the tim e period of the swing will (a) increase (b) decrease (c) remains same (d) increases if the child is tall and decreases if the child is short 52. A lift is moving down with acceleration a. A man in the lift drops a bal l inside the lift. The acceleration of the ball as observed by the man in the lift and a man standing stationary on the ground are respectively (a) g, g 53. s on (b) g - a, g - a (c) g - a, g (d) a, g The mass of product liberated on anode in an electrochemical cell depend (a) (It)1/2 2 (b) IT (c) I/t (d) I t (where t is the time period, for which the current is passed) 54. At what temperature is the r.m.s. velocity of a hydrogen molecule equal to that of an oxygen molecule at 470 C? (b) - 73 K (c) 3 K (d) 20 K 55. The time period of a charged particle undergoing a circular motion in a uniform magnetic field is independent of its (a) speed (b) mass (c) charge (d) magnetic induction 56. A solid sphere, a hallow sphere and a ring are released from top of an i nclined plane (frictionless) so that they slide down the plane. Then maximum acceleration down the pl ane is for (no rolling) (a) solid sphere (b) hollow sphere (c) ring (d) all same (a) 80 K

57. In a transformer , number of turns in the primary coil are 140 and that in the secondary coil are 280. If current in primary coil is 4A, then that in the secondary coil i s (a) 4 A (b) 2 A (c) 6 A (d) 10 A 58. Even Carnot engine cannot give 100% efficiency because we cannot (a) prevent radiation (b) find ideal sou rces (c) reach absolute zero temperature (d) eliminate fric tion 59. Moment of inertia of a circular wire of mass M and radius R about its di ameter is 2 2 (a) MR /2 (b) MR (c) 2MR (d) MR /4 60. When forces F , F , F are acting on a particle of mass m such that F a nd F are mutually 1 2 3 2 3 perpendicular, then the particle remains stationary. If the force F1 is now removed then the acceleration of the particle is (a) F /m (d) F /m 1 2 61. Two forces are such that the sum of their magnitudes is 18 N and their r esultant is 12 N which is perpendicular to the smaller force. Then the magnitudes of the forces are (a) 12 N, 6 N (d) 16 N, 2 N 62. (b) 13 N, 5 N (c) 10 N, 8 N 2 3 1 2 3 (b) F F /mF (c) (F - F )/m 2 2

Speeds of two identical cars are u and 4u at the specific instant. The ratio of the respective distances in which the two cars are stopped from that instant is (a) 1 : 1 (d) 1 : 16 (b) 1 : 4 (c) 1 : 8

5 ----------------------- Page 6----------------------63. 1 mole of a gas with = 7 / 5 is mixed with 1 mole of a gas with = 5 / 3 , then the value of for the resulting mixture is (a) 7/5 (d) 12/7 64. (b) 2/5 (c) 24/16

If a charge q is placed at the centre of the line joining two equal charg

es Q such that the system is in equilibrium then the value of q is (a) Q/2 65. (b) -Q/2 (c) Q/4 (d) -Q/4 Capacitance (in F) of a spherical conductor with radius 1 m is -10 -3 -6 -9

(a) 1.1 10 (b) 10 (c) 9 10 (d) 10 66. A light string passing over a smooth light pulley connects two blocks of masses m and m 1 2

(vertically). If the acceleration of the system is g/8, then the ratio of the masses is (a) 8 : 1 (b) 9 : 7 (c) 4 : 3 (d) 5 : 3 67. Two spheres of the same material have radii 1 m and 4m and temperatures 4 000 K and 2000 K respectively. The ratio of the energy radiated per second by the first sp here to that by the second is (a) 1 : 1 (d) 1 : 9 68. (b) 16 : 1 (c) 4 : 1

Three identical blocks of masses m = 2kg are drawn by a force F = 10.2 N with an acceleration of 0.6 ms-2 on a frictions surface, C B A F then what is the tension (in N) in the string between the blocks B and C ? (a) 9.2 (b) 7.8 (c) 4 (d) 9.8 One end of a massless rope, which passes over a massless and frictionless P pulley P is tied to a hook C while the other end is free. Maximum tension C the rope can bear is 360 N. With what value of maximum safe acceleration

69.

that (in

ms-2) can a man of 60 kg climb on the rope? (a) 16 70. (b) 6 (c) 4 (d) 8 A particle of mass m moves along line PC with velocity v as shown. What is the angular momentum of the particle about P? C (a) mvL (c) mvr (b) mvl (d) zero

71.

P Which of the following is used in optical fibres ? I r > (a) total internal reflection (b) scattering O (d) refraction (c) diffraction

72.

The escape velocity of a body depends upon mass as (a) m0 (b) m1 (d) m3 Which of the following are not electromagnetic waves? (a) cosmic rays (d) X- rays (b) gamma rays

(c) m2

73.

(c) rays

74.

Identify the pair whose dimensions are equal (a) torque and work (b) stress and energy(c) force and stress (d) force and work is t

75. If , is the inversion temperature , is the neutral temperature, he temperature of the i n c cold junction, then (a) + d) = 2 i = c c n i n 6 ----------------------- Page 7----------------------76. When H S is passed through Hg S we get 2 (a) HgS (d) Hg S 2 2 2 77. Alum helps in purifying water by (a) forming Si complex with clay particles (b) sulphate part which combines with the dirt and removes it (c) coagulating the mud particles 78. als ? (d) making mud water soluble A square planar complex is formed by hybridisation of which atomic orbit (a) s, p , p , d (b) s, p ,p ,d 2 (d) s, p ,p ,d 2 (c) s, p ,p ,d 2 (b) HgS + Hg S 2 (c) Hg S (b) i c = 2 n (c) + i C = n 2

x z2 79.

yz y z xy

x y

Polymer formation from monomers starts by (a) condensation reaction between monomers (b) coordinate reaction between monomers (c) conversion of monomer to monomer ions by protons (d) hydrolysis of monomers

80. is

The type of isomerism present in nitropentamine chromium (III) chloride (a) optical (b) linkage (d) polymerisation (c) ionization

81. Arrangement of (CH ) - C-, (CH ) - CH-, CH - CH - when attached to b enzyl or an unsaturated 3 3 3 2 3 2 group in increasing order of inductive effect is (a) (CH ) -C - < (CH ) - CH - < CH - CH - < (CH ) - < CH - < (CH ) - C 3 3 3 2 2 3 2 3 3 (b) CH - CH 3 2 3

(c) (CH ) - CH - < (CH ) - C - < CH , - CH (d) (CH ) -C - < CH - CH - (CH ) - CH3 2 3 3 3 2 3 3 3 2 3 2 82. CH3 - Mg - Br is an organo metallic compound due to (a) Mg - Br bond (b) C - Mg bond (d) C - H bond (c) C - Br bond

83.

1 M NaCl and 1 M HCl are present in an aqueous solution. The solution is (b) not a buffe (d) a buffer so (c) NH 3

(a) not a buffer solution with pH < 7 r solution with pH > 7 (c) a buffer solution with pH < 7 lution with pH > 7 84. Species acting as both Bronsted acid and base is (a) (HSO )-1 (b) Na CO (d) OH-1 4 2 3 85.

Let the solubility of an aqueous solution of Mg(OH) be x then its k is 2 sp (a) 4x3 (b) 108x5 (c) 27x4 (d) 9x

86. Units of rate constant of first and zero order reactions in terms of mol arity M unit are respectively -1 -1 -1 -1 -1 -1

87.

(a) sec , Msec (b) sec , M (c) Msec , sec (d) M, sec In XeF , XeF , XeF the numebr of lone pairs of Xe are respectively 2 4 6 (a) 2, 3, 1 (b) 1, 2, 3 (c) 4, 1, 2 (d) 3, 2, 1 In which of the folloiwng species the interatomic bond angle is 0 ? 109 28 -1 -1 (a) NH , (BF ) (b) (NH ) , BF (d) (NH ) , BF 3 4 4 2 3 (c) NH , BF 3 3 +

88.

2 89. For the reaction A + 2B the reaction is (a) 3 90.

C, rate is given by R = [A] [B] then the order of (c) 5

(b) 6 (d) 7 RNA is different from DNA because RNA contains

(a) ribose sugar and thymine r and uracil (c) deoxyribose sugar and thymine sugar and uracil 7 ----------------------- Page 8-----------------------

(b) ribose suga (d) deoxyribose

91. Which of the following are arranged in an increasing order of their bond strengths ? (a) O O+ 2 2 (c) 2 O O 2 < O 2 2 2 2 2 2 2 < O < O < O O < O < 2 2 + (d) + 2 2 2 2 2 < O < O+ < O2 (b) O2 < O < O <

92. If an endothermic reaction is non- spantaneous at freezing point of wate r and becomes feasible at its boiling point, then (a) H is ve, S is + ve ve (b) H and S both are +

(c) H and S both are ve

(d) H is + ve, S is ve

93. A heat engine absorbs heat Q at temperature T and heat Q at temperatu re T . Work done by 1 1 2 2 the engine is J(Q + Q ). This data 1 2 (a) violates 1st st law of thermodynamics law of thermodynamics if Q is -ve 1 (c) violates 1st law of thermodynamics if Q is -ve 2 (d) does not violate 1st law of thermodynamics 94. Most common oxidation states of Ce (cerium) are (a) +2, +3 (b) +2, +4 (c) +3, +4 (d) +3, +5 Arrange Ce+3, La+3, Pm+3 and Yb+3 in increasing order of their ionic rad (b) Ce+3 < Yb+3 (d) Pm+3 < La+3 < (b) violates 1

95. ii

(a) Yb+3 < Pm+3 < Ce+3 < La+3 < Pm+3 < La+3 (c) Yb+3 < Pm+3 < La+3 < Ce+3 Ce+3 < Yb+3

96. KO (potassium super oxide) is used in oxygen cylinders in space and sub marines because it 2 (a) absorbs CO and increases O content oisture 2 (c) absorbs CO2 ne. 97. 2 (d) produces ozo (b) eliminates m

A similarity between optical and geometrical isomerism is that (a) each forms equal number of isomers for a given compound (b) If in a compound one is present then so is the other

(c) both are included in stereoisomerism (d) they have no similarity 98. Which of the following does not show geometrical isomerism? (a) 1, 2-dichloro - 1- pentene ro - 2- pentene (c) 1, 1- dichloro - 1- pentene ro - 2- pentene (b) 1, 3 - dichlo (d) 1, 4 - dichlo

99. In case of nitrogen, NCl is possible but not NCl while in case of phos phorous, PCl as well as 3 5 3

PCl5 are possible. It is due to (a) availability of vacant d orbitals in P but not in N (b) lower electronegativity of P than N (c) lower tendency of H - bond formation in P than N (d) occurrence of P in solid while N in gaseous state at room temperatur e 100. re P, For an ideal gas, number of moles per litre gas contant R and temperature T is (a) PT/R in terms of its pressu

(b) PRT (c) P/RT (d) RT/P 101. The formation of gas at the surface of tungsten due to adsorption is the reaction of order (b) 1 (c) 2 (d) insufficient data 102. The solubility of Mg(OH)2 is S moles/litre. The solubility product under the same condition is (a) 4S3 (b) 3S4 (c) 4S2 (d) S3 8 ----------------------- Page 9----------------------103. How do we differentiate between Fe3+ and Cr3+ in group III? (a) by taking excess of NH4OH solution (b) by increasing NH4+ ion concentration (c) by decreasing OH- ion concentration (d) both (b) and (c) (a) 0

104. In a compound C, H and N atoms are present in 9 : 1 : 35 by weight. Molec ular weight of compound is 108. Molecular formula of compound is (a) C H N (d) C H N 2 6 2 9 12 3 (b) C H N 3 4 (c) C H N 6 8 2

105. The functional group, which is found in amino acid is (a) -COOH group (d) both (a) and (b) (b) - NH group 2 (c) - CH group 3

106. Conductivity (unit Siemens S) is directly proportional to area of the vess el and the concentration of the solution in it and is inversely proportional to the length of the vessel then the unit of the constant of proportionality is -1 2 2 -2 2 -1 -2 2

(a) Sm mol (b) Sm mol (c) S m mol (d) S m mol 107. In a hydrogen atom, if energy of an electron in ground state is 13.6 eV, then that in the 2nd excited state is (a) 1.51 eV (d) 13.6 eV (b) 3.4 eV (c) 6.04 eV

108. Which of the following statements is true ? (a) HF is less polar than HBr (b) absolutely pure water does not contain any ions (c) chemical bond formation take place when forces of attraction overcome the forces of repulsion (d) in covalency transference of electron takes place 109. Which of the following compounds has wrong IUPAC name ? (a) CH CH CH COO CH CH 3 2 2 (b) CH3 CH CH2 CHO CH (c) CH3 CH CH CH3 OH CH3 O (d) CH3 CH C CH2 CH3 110. CH CH COOH 3 2 Cl2 A red P (b) alc. KOH B. What is B? CH CH CHO 3 2 (c) CH = CHCOOH 2 CH3 2 methyl3 pentanone 2 - methyl3 butanol ethyl butanoate 2 3

3-methylutana

(a) CH CH COCl (d) ClCH CH COOH 3 2 2 2

111. Aluminium is extracted by the electrolysis of (a) bauxite (b) alumina molten cryolite (d) molten cryolite 112. The metal extracted by leaching with a cyanide is (a) Mg (b) Ag (d) Na 113. Value of gas constant R is (a) 0.082 litre atm (b) 0.987 cal mol-1 -1 -1 K (d) 83 erg mol K

(c) alumina mixed with

(c) Cu -1 (c) 8.3 J mol -1 -1 K

9 ----------------------- Page 10----------------------0 114. Freezing point of an aqueous solution is (-0.186) C. Elevation of boilin g point of the same solution is K = 0.512 0C, K = 1.86 0C, find the increase in boiling point. b f (a) 0.186 0C (b) 0.0512 0C (c) 0.092 0C (d) 0.2372 0C 115. EMF of a cell in terms of reduction potental of its left and right elect rodes is Eleft 116. 0 (a) E = Eleft - Eright (b) E = Eleft + Eright (d) E = -(Eright + Eleft) (c) E = Eright -

-5 m. What is the uncertainity Uncertainity in position of a minute particle of mass 25 g in space is 1 in its velocity (in ms-1) ? (h = 6.6 10-34 Js) -34 -34 -23 (b) 0.5 10 (c) 2.1 10 -2

8 (a) 2.1 10 (d) 0.5 10 117.

Which of these will not react with acetylene ? (a) NaOH (b) ammonical AgNO3 (d) HCl

(c) Na

118 Change in volume of the system does not alter the number of moles in whi ch of the following equilibria ? (a) N (g)+ O (g) PCl (g) + Cl (g) 2 2 3 2 (c) N (g) + 3H (g) SO (g) + Cl (g) 2 2 2 2 119. For the reactions, C+ O2 CO2 ; H = 393J 2Zn+ O 2ZnO ; H = 412J 2 (a) carbon can oxidise Zn carbon is not feasible (b) oxidation of 2 NO(g) (b) PCl (g) 5 2NH (g) 3 (d) SO Cl (g) 2 2

(c) oxidation of Zn is not feasible (d) Zn can oxidis e carbon 120. Which of the following ions has the maximum magnetic moment ? (a) Mn+2 (b) Fe+2 (c) Ti+2

(d) Cr+2 3 121. In which of the following species is the underlined carbon having sp hy bridisation? (a) 3 122. nds (c) meso compounds rs 123. The differential rate law for the reaction H + I 2 d[H ] [I ] 2 (a) dt 2 = = dt d[HI] (d) 2 dt is 4 (a) 6 125. (b) 7 (d) 16 Kinetic theory of gases proves 10 (c) 17 dt (b) dt d[H ] 2 = 2 = = dt dt dt 1 d[H ] 1 d[I ] d[I ] d[HI] (c) 2 = 2 = 2 = 2 dt 2 dt dt dt 124. Number of sigma bonds in P O 1 d[HI] 2 2 2 d[I ] d[HI] 2 d[H ] d 2HI is (d) optical isome CH COOH (b) (d) CH = CH - CH 3 2 CH CH OH 3 3 2 (c)CH COCH 3

Racemic mixture is formed by mixing two (a) isomeric compounds (b) chiral compou

(a) only Boyles law (b) only Charles law (c) only Avogadros law (d) all of these 126. A metal M readily forms its sulphate MSO which is water - soluble. It f orms its oxide MO which 4 becomes inert on heating. It forms an insoluble hydroxide M(OH)2 which is soluble in NaOH solution. Then M is (a) Mg (d) Be 127. If denotes reduction potential, then which is true ? E0 0 = E0 + E0 (b) Ba (c) Ca

(a) (d) Ecell

cell = riht et (b) cell = et + riht (c) ( left right ) 10

cell = et riht

----------------------- Page 11----------------------128. What is the product when acetylene reacts with hypochlorous acid ? (a) CH COCI (b) ClCH CHO (c) Cl CHCHO (d) ClCHCOOH 3 2 2 On vigorous oxidation by permanganate solution (CH ) C = CH - CH - CHO gives 3 2 2 CH OH OH + CH CH COOH (a) CH C CH CH CH 3 2 3 2 CH CH3 CH CH CHO (c) 2 2 CH3 OCOCH3 COOH 130. The compound is used as (c) analgesic Pt | H 2 2 (a) 2 RT P RT P log 1 (b) log 1 (d) none of these f P 2f P 2 2 RT (c) f log P 1 P 2 + (P ) | H (aq) | 1 (a) antiseptic (b) antibiotic (d) pesticide What will be the emf for the given cell CH3 C = O + CH OH + CH CH CH OH (d) 2 2 2 CH3 CH3 CO (b) 3 CH3

129.

131.

| H (P ) | Pt

132. t is

When primary amine reacts with chloroform in ethanoic KOH then the produc (a) an isocyanide (d) an alcohol (b) an aldehyde (c) a cyanide

133.

Which of the following reaction is possible at anode? (a) 2Cr 3+ + 7H O Cr O2 + 14H+ 2 2 7 (c) (1/ 2) O + 2H 2 + H O 2 H O 2 (b) F 2F 2 (d) none of these

134.

The reaction : (CH ) C Br 3 3 (a) elimination reaction

(CH ) C OH 3 3 (b) substitution re

action (c) free radical reaction (d) displacement re action 135. If half-life of a substance is 5 yrs, then the total amount of substance left after 15 years, when initial amount is 64 grams is (a) 16 grams (b) 2 grams (d) 8 grams 136. Cyanide process is used for the extraction of (a) barium (b) aluminium (d) silver (c) 32 grams

(c) boron

137.

Which is the correct order of ionic sizes ? (a) Ce > Sn > Yb > Lu (b) Sn > Ce > Lu > Yb (c) Lu > Yb > Sn > Ce (d) Sn > Yb > Ce > Lu (Atomic Number : Ce = 58, Sn = 50, Yb = 70 and Lu = 71) With increase of temperature, which of these changes? (b) weight fraction (d) mole fraction

138.

(a) molality of solute (c) fraction of solute present in water 11 ----------------------- Page 12----------------------139. The integrated rate equation ight line graph is obtained by plotting 1 1 1 (a) time vs log Ct (b) time vs Ct (d) time vs Ct

is Rt = log C - log C . The stra 0 t

(c) time vs Ct

140. In which of the following reactions, increase in the volume at constant temperature does not affect the number of moles at equilibrium

(a) 2NH g) CO(g) 3 2

N + 3H 2 2

(b) C(g) + (1/ 2)O (

(c) H (g) + O (g) H O (g) 2 2 2

(d) none of these 2

141. When the sample of copper with zinc impurity is to be purified by electro lysis, the appropriate electrodes are cathode anode (a) pure zinc pure copper (c) impure zinc impure sample anode pure copper impure sample cathode (b) impure sample (d) pure copper

142. The most stable ion is (a) [Fe(OH) ]3(b) [Fe(Cl) ]3(d) [Fe(H O) ]3+ 3 6 2 6 143. - particle is emitted in radioactivity by (a) conversion of proton to neutron orbit (c) conversion of neutron to proton ot emitted 144. In mixture A and B component show -ve deviation as (a) V mix > 0

(c)

[Fe(CN) ]36

(b) from outermost (d) -particle is n

(b) H mix

< 0

(c) A - B interaction is weaker than A - A and B - B interaction (d) A - B interaction is stronger than A - A and B - B interaction 145. The heat required to raise the temperature of body by 1 K is called (a) specific heat (b) thermal capacity (c) water equivale (d) none of these 146. Na and Mg crystallize in BCC and FCC type crystals respectively, then th e number of atoms of nt Na and Mg present in the unit cell of their respective crystal is (a) 4 and 2 (b) 9 and 14 (c) 14 and 9 (d) 2 and 4 147. Number of atoms in 558.5 gram Fe (at.wt. of Fe = 55.85 g mol-1) is (a) twice that in 60 g carbon (b) 6.023 1022 (c) half that in 8g He (d) 558.5 6.023 1023 148. When KMnO acts as an oxidising agent and ultimately forms [MnO ]-1 , MnO , Mn O , Mn+2 4

2 3

then the number of electrons transferred in each case respectively is (a) 4, 3, 1, 5 (b) 1, 5, 3, 7 (c) 1, 3, 4, 5 (d) 3, 5, 7, 1 149. Which of the following is a redox reaction ? (a) NaCl+ KNO l CaCl + H C O 4 2 NaNO + KCl 3 2 2 3 4 (b) CaC O + 2HC 2

(c) Mg(OH) + 2NH Cl MgCl + 2NH OH (d) Zn+ 2AgCN 2Ag + Zn(CN)2 2 4 2 4 150. For the reaction CO(g) + (1/ 2)O (g) = CO (g), K / K 2 2 (a) RT (d) (RT)1/2 12 ----------------------- Page 13----------------------AIEEE - 2002 Mathematics 1. If but 2 nd / as its roots is = 5 3 and 2 (a) 3x - 19 x + 3 = 0 0 (c) 3x2 - 19 x - 3 = 0 2 (d) x - 5x + 3 = 0 2 = 5 3 2 (b) 3x + 19x - 3 = then the equation having / a (b) (RT)-1 (c) is p c (RT)-1/2

2.

2 2 n 2 d y dy If y = (x + 1+ x ) , then (1+ x ) 2 + x is dx dx (a) n2 2 2

3.

y (b) -n y (c) -y (d) 2x y If 1, log 1-x x (3 + 2), log (4.3 -1) are in A.P. then x equals 9 3 (a) log 4 (d) log 3 3 4 (b) 1+ log 4 3 (c) 1 - log 3 4

4. A problem in mathematics is given to three students A, B, C and their re spective probability of

1 solving the problem is is solved is 2 3 1 (a) (d) 4 3 5. The period of sin2 is (a) 2 (d) / 2 log l logm 6. logn p q 1 (b) (b) 2 1 ,

1 and 3

1 . Probability that the problem 4 2 (c) 3

(c) 2

th th th 1 l, m, n are the p , q and r term of a G.P. all positive, then equals r 1 (b) 2 (c) 1

(a) -1 (d) 0 1 cos2x 7. Lim x 0 is 2x

(a) 1 (d) does not exist 8.

(b) -1

(c) zero

A triangle with vertices (4, 0), (-1, -1), (3, 5) is (a) isosceles and right angled (b) isosceles but no t right angled (c) right angled but not isosceles (d) neither right an gled nor isoceles 9. In a class of 100 students there are 70 boys whose average marks in a su bject are 75. If the average marks of the complete class is 72, then what is the average of the girls? (a) 73 (b) 65 (c) 68 (d) 74 10. cot 1( cos ) = tan 1( 2 tan 2 2 2 cos ) = x, then sinx = (c) tan

(a) (d) cot

(b) cot2

13 ----------------------- Page 14----------------------2 / 3 dy 11. dx 2 (a) (1, 3 x 4 y 7 z 4 A plane which passes through the point (3, 2, 0) and the line = = is 1 z = 1 5 4 (c) x + 2y ) (d) (1, 2) (b) (3, 1) (c) (3, 3) 3 1+ 3 = 4 d y are The order and degree of the differential equation 3 dx

12.

(a) x - y + z = 1 (b) x + y + z = 5 (d) 2x - y + z = 5 2 d y 2x 2 = e dx e2x 1 (a) e2x (d) 4 4 1 2 x + 5x + 3 2 x (a) e4 (d) 1 + x + 3 (b) e2 x (b) e4x + cx + d 4 + cx + d

13.

The solution of the equation

1 (c) 4 e2x +

cx2 + d

14.

Lim x

(c) e3

15.

-1 The domain of sin [log (x/3)] is 3 (a) [1, 9] (b) [-1,9] (d) [-9, -1] The value of 21/4, 41/8, 81/6 + ..... (c) [-9, 1] is

16.

(a) 1 (d) 4 17.

(b) 2

(c) 3/2

Fifth term of a GP is 2, then the product of its 9 terms is (a) 256 (b) 512 (c) 1024 (d) none of these 10

18.

| sin x | dx is 0 (a) 20 (d) 18 / 4 n (b) 8 (c) 10

19.

l = n 1 (a)

tan 0

x dx then Lim n [ln n

+ ln 2 ] equals

(b) 1 (d) zero 2

(c)

2 20. 2 [x ]dx is 0 (a) 2 2 (d) (b) 2 + 2 2 dx is 2 (c) 2 1

21.

2x(1+ sinx) 2 1+ cos x 2

2 (a) (d) 4 2 14 ----------------------- Page 15----------------------xf(2) 2f(x) 22. Let f(x) = 4 and (a) 2 . Then Lim f (x) = 4 x 2 (b) - 2 is given by x 2 (c) - 4 (b) (c) zero

(d) 3 23. z and w are two non zero complex no.s such that | z | = | w | and Arg z + Arg w = then z equals (a) w (d) - w 24. If | z-4 | < | z-2 |, its solution is given by (a) Re(z) > 0 (b) Re(z) < 0 (d) Re(z) > 2 (c) Re (z) > 3 (b) w (c) w

25. The locus of the centre of a circle which touches the circle | z - z | = a and | z - z | = b externally 1 2

(z, z and z are complex numbers) will be 1 2 (a) an ellipse (b) a hyperbola (c) a circle (d) none of these 26. Sum of infinite number of terms of GP is 20 and sum of their square is 10 0. The common ratio of GP is (a) 5 27. (b) 3/5 (d) 1/5 13 3 3 3 3 - 2 + 3 - 4 +.....+9 = (a) 425 (b) - 425 (d) - 475 (c) 8/5

(c) 475

2 2 28. Difference between the corresponding roots of x + ax + b = 0 and x + b x + a = 0 is same and a b, then (a) a + b + 4 = 0 (b) a + b - 4 = 0 (d) a - b + 4 = 0 Product of real roots of the equation t2 (a) is always positive tive 30. (c) does not exist (d) none of these If p and q are the roots of the equation x2 + px + q = 0, then (a) p =1, q = -2 (b) p = 0, q = 1 (d) p = -2, q = 1 (c) p = -2, q = 0 (c) a - b - 4 = 0 2 x + |x| + 9 = 0 (b) is always nega

29.

2 2 2 31. If a, b, c are distinct +ve real numbers and a + b + c =1 then ab + bc + ca is (a) less than 1 (b) equal to 1 (c) greater than 1 (d) any real no. 32. Total number of four digit odd numbers that can be formed using 0, 1, 2, 3, 5, 7 (using repetition

allowed) are (a) 216 (d) 720

(b) 375

(c) 400

33. Number greater than 1000 but less than 4000 is formed using the digits 0, 1, 2, 3, 4 (repetition allowed) is (b) 105 (c) 375 (d) 625 34. Five digit number divisible by 3 is formed using 0, 1, 2, 3, 4, 6 and 7 w ithout repetition. Total number of such numbers are (a) 312 (b) 3125 (d) 216 35. 36. re (a) equal osite signs (b) equal with opp (c) 120 (a) 125

The sum of integers from 1 to 100 that are divisible by 2 or 5 is (a) 3000 (b) 3050 (c) 3600 (d) 3250 The coefficients of xp q and x in the expansion of (1+x)

p+q a

(c) reciprocals of each other (d) none of these 37. If the sum of the coefficients in the expansion of (a + b)n is 4096, then the greatest coefficient in the expansion is (a) 1594 (d) 2924 (b) 792 (c) 924

15 ----------------------- Page 16----------------------38. The positive integer just greater than (1+0.0001)10000 is (a) 4 (d) 3 th th 39. r and n are positive integers r > 1, n > 2 and coefficient of (r + 2) term and 3r term in the expansion of (1+x)2n are equal, then n equals (a) 3r (d) 2r + 1 a b c 40. ax + b b bx + c If a > 0 discriminant of ax2 + 2bx + c is -ve, then is (b) 3r + 1 (c) 2r (b) 5 (c) 2

ax + b bx + c (a) +ve ve (d) 0 7 + ..... having n radical signs then by metho 41. If an = 7 + 7 + ds of mathematical induciton which is true (a) an > 7 n 1 (d) an < 3 n 1 (b) an > 7 n 1 (c) an < 4 n 1 0 2 2 (b) (ac - b ) (ax + 2bx + c) (c) -

42. The sides of a triangle are 3x + 4y, 4x+37 and 5x + 57 where x, y > 0 th en the triangle is (a) right angled (b) obtuse angled (c) equilateral (d) none of these 43. Locus of mid point of the portion between the axes of x cos + y sin = p wh ere p is constant is 4 2 2 + (a) x 2 p y (d) x 1 2 = + 2 2 p y p 2 1 = (b) x + y 2 = 4p (c) x 2 y 2 4 2 2 2 + = 1 1

2 2 44. If the pair of lines ax + 2hxy + by + 2gx + 2fy + c = 0 intersect on th e y - axis then (a) 2fgh = bg2 + ch2 (b) bg2 ch2 (c) abc = 2fgh (d) none of these 45. The point of lines represented by 3ax2 2 2 +5xy + (a -2)y = 0 and (c) for one value of 2 0 46. If the chord y = mx + 1 of the circle x + y = 1 subtends an angle of me asure 45 at the major segment of the circle then value of m is (a) 2 2 (d) none of these (b) 2 2 (c) 1 2 2

perpendicular to each other for a (a) two values of a (b) a (d) for no values of a

47.

2 2 The centres of a set of circles, each of radius 3, lie on the circle x +

y = 25. The locus of any point in the set is 2 2 2 2 2 2 2 2

(a) 4 < x + y < 64 (b) x + y < 25 (c) x + y > 25 (d) 3 < x + y < 9 48. The centre of the circle passing through (0, 0) and (1, 0) and touching t he circle x2 2 + y = 9 is 1 1 1 3 (a) , , 2 2 2 2 1 (b) 2 , 2 (c) 3 , 2 2 1

(d)

49. The equation of a circle with origin as a centre and passing through equi lateral triangle whose median is of length 3a is 2 2 2 2 2 2 2 2 2 2 (b) x + y =16a 2 (c) x + y 2 = 4a

(a) x + y = 9a (d) x + y = a

16 ----------------------- Page 17----------------------2 50. re 2 Two common tangents to the circle x + y = 2a (a) x = + (y + 2a) (b) y = + (x + 2a) (d) y = + (x + a) 51. then 2 2

and parabola y = 8ax a (c) x = + (y + a)

In a triangle with sides a, b, c, r > r > r (which are the ex- radii) 1 2 3 (c) a > b and b <

c 52.

(a) a > b > c (b) a < b < c (d) a < b and b > c

The number of solution of tan x + sec x = 2cos x in [0, 2) is (a) 2 (d) 1 (b) 3 (c) 0

53. 2 x

Which one is not periodic 2 (a) | sin 3x | + sin x (b) cos (d) cos 2x + sin x x + cos x 2 (c) cos 4x + tan

p p p 1 + 2 + 3 + ....+ n 54. Lim n n 1 1 (a) (d) p + 1 p + 2 logxn [x] 55. Lim l to x) x 0 (b) p+ 1

p is 1 (c) 1 p p 1 p 1 1

, n N ([x] denotes greatest integer less than or equa [x] (c) has value 1

(a) has value -1 (b) has value 0 (d) does not exist f(x) 1 56. If f(1) = 1, , then Lim f (1) = 2 x 1 (a) 2 is x 1

(b) 4 (c) 1 (d) 1/2 57. f is defined in [-5, 5] as f(x) = x if x is rational and = -x is irratio nal. Then (a) f(x) is continuous at every x, except x = 0 (b) f(x) is discontinuous at every x, except x = 0 (c) f(x) is continuous everywhere (d) f(x) is discontinuous everywhere 58. f(x) and g(x) are two differentiable functions on [0, 2] such that f (x) g (x) = 0 f (1)= 2g (1) = 4f(2) = 3g(2) = 9 (a) 0 (d) 5 59. s (a) 0 (d) 2 at The maximum distance from origin of a point on the curve x = a sin t - b b at (b) 1 (c) 6 If f(x + y) = f(x) . f(y) x.y and f(5) =2, =3 then f (0) f (5)i (b) 2 then f(x) - g(x) at x = 3/2 is (c) 10

60. sin

y = a cos t - b cos b (a) a - b (d) a2 b2

, both a, b > 0 is (b) a + b (c) a2 + b2

2 61. If 2a + 3b + 6c = 0 (a,b,c R) then the quadratic equation ax + bx + c = 0 has (a) at least one root in [0, 1] root in [2, 3] (c) at least one root in [4, 5] (b) at least one (d) none of these

62. If y = f(x) makes +ve intercept of 2 and 0 unit on x and y axes and encl oses an area of 3/4 2 square unit with the axes then xf (x) dx is 0 (a) 3/2 (d) -3/4 17 ----------------------- Page 18----------------------63. The area bounded by the curves y = lnx, y = ln |x|, y = | ln x | and y = | ln | |x| is (a) 4 sq. units ne of these (b) 6 sq. units (c) 10 sq. units (d) no (b) 1 (c) 5/4

64. If and the angle between is 2 = 2 is equal to | a |= 4, | b |= 2 a and b / 6 then (a b) (a) 48 (b) 16 (c) (d) no ne of these a 65. If a,b,c (a) 16 (b) 64 are vectors such that [ ] a b c =4 then [ ] a b b c c a (c) 4 (d) 8 =

66. If are vectors such that =0 and the n angle between a,b,c a + b+ c | a | = 7, | b |= 5,| c |= 3 vector b and c is

(a) 60 0

(b) 300

(c) 450

(d) 90

67. If | a |=5, | b | = 4, | c | = 3 thus what will be the value of | a.b + b. c + c.a |, given that a+ b + c = 0 (a) 25 50 68. 3c + 2(a b) = 0 (a) 3 + 2 = 0 (b) 3 = 2 (c) = (d) + = 0 then (b) 50 (c) - 25 (d) -

69. a = 3 i 5j and b = 6 i + 3j are such that c = a b then

two

vectors

and c is

vector

| a |:| b |:| c | (a) 34 : 45 : 39 (b) : 35 : 34 70. If a b = b c = c a then a + b + c = (a) abc (b) -1 (c) 0 (d) 2 34 : 45 : 39 (c) 34 : 39 : 45 (d) 39

71. A and B are events such that P(A B) = 3 / 4 , P(A B) = 1/ 4, P(A) = 2 / 3 then P(A B) is (a) 5/12 (b) 3/8 (c) 5/8 (d) 1/ 4 72. A die is tossed 5 times. Getting an odd number is considered a success. Th en the variance of distribution of success is (a) 8/3 (b) 3/8 4 73. The d.r. of normal to the plane through (1, 0, 0) , (0, 1, 0) which makes an angle / 4 with plane x + y = 3 are (a) 1, 2,1 ,1, 1 74. The sum of two forces is 18 N and resultant whose direction is at right an gles to the smaller (b) 1, 1, 2 (c) 1, 1, 2 (d) 2 (c) 4/5 (d) 5/

force is 12 N. The magnitude of the two forces are (a) 13, 5 (b) 12, 6 (c) 14, 4 , 7

(d) 11

75. A bead of weight w can slide on smooth circular wire in a vertical plane. The bead is attached by a light thread to the highest point of the wire and in equilibrium, the thread is taut and make an angle with the vertical then tension of the thread and reaction of the wire on the bead are (a) T = w cos R = w tan (b) T = 2w cos R = w (c) T = w R = w sin (d)T = w sin R = w cot 18