Introduction To Iron Ore
Introduction To Iron Ore
Introduction To Iron Ore
Overview
Introduction to Iron Ore
Top Iron Ore Producing Countries Iron Ore Mining Iron Ore Processing
Direct Shipping Ore Hematite Magnetite
Iron Ore Stockyards & Transportation Iron Ore Export/Transportation Supporting Infrastructure Supporting Slides Protective Coatings Cube systems References
Hematite (Fe2O3)
-
(70% Fe)
(63% Fe)
Siderite (FeCO3)
Hematite and Magnetite are the most common types of iron ores extracted by mining companies, the latter being a variant of another iron deposit called Taconite
(Taconite = BIFs (Banded Iron Formations))
Iron is indispensable to modern civilization and people have been skilled in its use for more than 3000 years
However, its use only became widespread in the 14th century, when smelting furnaces (the forerunner of blast furnaces) began to replace forges
About 98% of world iron ore production is used to make iron in the form of steel
In many instances they are mined as iron ores, but most importantly they are the source rocks for most of the large high-grade concentrations of iron ore currently mined throughout the world
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
Example of BIFs
Natural ore/Direct shipping ore is the name for ores carrying very high quantities of iron (usually Hematite)
Means they can be fed directly into iron making blast furnaces Most reserves already depleted Magnetite and taconite ores experience a longer, more effortful separation process
Iron ore is the raw material used to make pig iron, which is one of the main raw materials to make steel
98% of the mined iron ore is used to make steel
Magnetite I
Magnetite is an iron oxide mineral generally black in colour and highly magnetic, the latter property aiding which helps in the beneficiation of magnetite ores Magnetite mineral contains 72.4% iron, which is higher than hematite but the presence of impurities results in lower ore grade, making it more costly to produce the concentrates used in steel smelters Magnetite mining is an emerging industry in Australia with large deposits in the Pilbara region of WA being developed
Like hematite ores, magnetite ores require initial crushing and screening, but undergo a second stage of processing that relies on the magnetic properties of the ore and involves magnetic separators to extract the magnetite and produce a concentrate.
Magnetite is increasing its presence in world production
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
Magnetite II
The key economic parameters for magnetite ore being economic are the crystallinity of the magnetite;
the grade of the iron within the banded iron formation host rock and the contaminant elements which exist within the magnetite concentrate
Magnetite
Hematite
Hematite iron ore deposits are currently exploited on all continents except Antarctica, with the largest intensity in South America, Australia and Asia Hematite is an iron oxide mineral
It is non-magnetic and has colour variations ranging from steel silver to reddish brown. Pure hematite mineral contains 69.9% iron The word comes from the Greek world Haematite, meaning 'blood-stone
Been the dominant IO mined in Australia since the early 1960s and approximately 96% of Australia's iron ore exports are high grade hematite High grade hematite ore is referred to as direct shipping ore (DSO) because it is mined and the ores go through a relatively simple crushing and screening process before being exported for use in steel making. Australia's hematite DSO from the Hamersley region in WA averages from 56% to 62% iron Hematite ores dominate the world production of iron ores and are sourced mainly in Australia and Brazil
Hematite
The predominant minerals in DSO are usually the ferric iron oxides hematite (Fe2O3), goethite (FeO(OH) and/or limonite (FeO(OH).nH2O)
Most large hematite iron ore deposits are sourced from altered banded iron formations and rarely igneous accumulations
DSO deposits are typically rarer than the magnetite-bearing BIF or other rocks which form its main source or protolith rock, but are considerably cheaper to mine and process as they require less beneficiation due to the higher iron content
DSO ores can however contain significantly higher concentrations of penalty elements, typically being higher in phosphorus, water content (especially pisolite sedimentary accumulations) and aluminum (clays within pisolites)
Iron Properties
Iron is unusual in being magnetic (magnetite)
if you dangle a piece it will turn to face north-south
Iron is a silver-grey metal which quickly corrodes or rusts (it forms a red powder called iron oxide) when exposed to air and water. Iron is quite soft and easily worked, but when made into steel iron is very strong Iron has the symbol Fe from the Roman word ferrum Iron has a very high melting point of 1535oC
3.Iron ore is smelted in by the customers in blast furnaces, by feeding the furnace ore and coke and very hot air is blasted in
4.The chemical reactions that take place form a mixture of molten iron and slag 5.The dense iron sinks to the bottom of the furnace and is tapped of once cooled its called pig iron 6.Pig iron is used to produce steel or is further refined to produce commercially pure iron
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
Wrought iron
Nearly pure iron mixed with a glass-like material Is softer than cast iron and does not rust Used in outdoor furniture, railings and other decorations
Steel
The most common form of iron Contains around 1% carbon
Stainless steel
Contains chromium, making it very rust restistent Is ideal for vehicle parts, hospital equipment and cooking utensils
Tool steel
Extremely hard, heat treated steel that is used in metalworking tools
Note: The mine production estimate for China is based on crude ore, rather than usable ore, which is reported for the other countries
Mining iron ore is a high volume low margin business, as the value of iron is significantly lower than base metals
It is highly capital intensive, and requires significant investment in infrastructure such as rail in order to transport the ore from the mine to a freight ship
For these reasons, iron ore production is concentrated in the hands of a few major players
Chinese demand for iron ore whether imported or domestically produced is the key determinant of the outlook for the global iron ore market in the short run
Australias Economic Demonstrated Resources (EDR) of iron ore are around 28 billion tonnes with Western Australia accounting for about 98 per cent. Dominated by 3 main players:
BHP Billiton
7 mines, 1 port and rail network
Rio Tinto
13 mines, 3 shipping terminals at 2 ports and almost 1400km of rail network
Brazils reserves are known for their high metal content, which frequently exceeds 60%
Known for being an unstable exporter of IO Export bans (due to environmental issues like illegal logging) Estimated that India will end 2013 as a net importer of IO The largest steel producers, TATA Steel & Steel Authority of India Ltd (SAIL), have their own IO mines
However, in contrast to Australia and Brazil, the average iron content in the Russian iron ores is relatively low, less than 36%, and Russias reserves of rich iron ores are insignificant
Also extremely uneven distribution of iron-ore reserves within the country
IO deposits are located in the Urals and Siberia regions with the Kursk Magnetic Anomaly (KMA) being Russia 's major iron ore mining region
Production of crude iron ore in the country :
Central Federal District (CFD) accounts for 44-47% Northwest Federal District (NWFD) is responsible for 21-23% Urals Federal District (UFD) for 22-23%
Most of Russia 's iron ore mining companies form part of large steel enterprises that are vertically integrated
Worlds IO Consumers
The top consumer of all countries is China
Being the largest importer and largest producer of IO in the world China imported 687 Mt of iron ore in 2011, accounting for 61% of global imports
Australia was Chinas top source of iron ore, with 296 Mt or 43% of its iron ore imports coming from Australia
Australia is also the dominant supplier to Japan and South Korea, supplying 62% and 68% of those countries iron ore imports respectively
Brazil supplies around a quarter of total iron ore imports to China, Japan and South Korea
Todays system has moved away from the traditional ways to market-based pricing
Index-based quarterly pricing by the worlds 3 largest IO miners; Vale, Rio Tinto and BHP Billiton
Global prices declined steadily since 2011, and in September 2012, they reached the lowest benchmark prices since 2009 at US $86
Mixed expectations to IO prices:
Different scenarios: high vs low prices
Extraction Methods
The decision to employ underground or surface mining techniques is dependent on the proximity of the ore body to the surface Historically, underground mining methods, including caving and stopping, were commonly used to extract iron ores Underground methods are very expensive compared to open-pit and open-cut methods
Cant compete with high volume surface mines (like those in WA), and even if they can compete on cost, its very difficult to extract the high volumes required to make the development economically viable Open-pit and open-cut mining are considered to be the least expensive extraction techniques
IO Surface Mining
Surface mining methods are designed to extract ore from surface deposits
Overburden, the soil and rock material that overlies the mine area, is removed to expose the ore deposit
The ore bench is drilled, blasted, and hauled to a plant for beneficiation Overburden may be continually removed during the life of the mine as the highwall is cut back to permit deepening of the pit
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
The data from the exploration activities are logged, mapped, analyzed and interpreted through models
A detailed plan of which ore bodies to mine in what sequence, to deliver the required product quality at an appropriate cost, is developed
The process of mine planning commence many years before a mine is developed and continues on a day-to-day basis once the mine is operational
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
3. 4.
Identified areas are tagged Holes are drilled in an appropriate pattern by rigs
5.
6.
The resulting blast breaks the material to a size required for digging
Video: http://www.minesurveyor.net/ssblast.php
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
Historically, much of the iron ore utilized by industrialized societies has been mined from predominantly hematite deposits with grades in excess of 70% Fe
These deposits are commonly referred to as "direct shipping ores" or "natural ores
Increasing iron ore demand, coupled with the depletion of high-grade hematite ores WW and led to development of lower-grade iron ore sources, principally the utilization of magnetite and taconite(BIFs)
Iron ore is being beneficiated all round the world to meet the quality requirement of Iron and Steel industries. However, each source of Iron ore has its own peculiar mineralogical characteristics and requires the specific beneficiation and metallurgical treatment to get the best product out of it
Choice of the beneficiation treatment depends on the nature of the gangue present and its association with the ore structure Several techniques such as washing, jigging, magnetic separation, advanced gravity separation and flotation are being used to enhance the quality of the Iron ore
The process the ore goes through depends on the grade of ore being mined!
Beneficiation or upgrade is done by physical processes, which remove impurities by differences in particle density or size gravity or size separation
Implications of this is that the lower quality of ore the more rigorous the processing will be more expensive To reach the specified grind size the ore material goes through several processes
The smaller the size, the longer the process!
Beneficiation
Beneficiation is defined as a variety of processes whereby extracted ore from mining is reduced to particles that can be separated into mineral and waste, the former suitable for further processing or direct use Beneficiation means the following as applied to iron ore: milling (crushing and grinding); washing; filtration; sorting; sizing; gravity concentration; magnetic separation; flotation; and agglomeration (pelletizing, sintering, briquetting, or nodulizing)
Milling and magnetic separation are the most common methods used Flotation is primarily used to upgrade concentrates from magnetic separation by reducing the silica content of the concentrate
The ore must be ground to a particle size sufficiently close to the grain size of the iron-bearing mineral to allow for a high degree of mineral liberation
ref. required size for pellent plant feed for the different types of ore
Prior to grinding, the ore is crushed in up to six stages, depending on the hardness of the ore
One or two stages of crushing might be done at the mine before being shipped to the processing facility(primary & secondary crushing)
Crushers
Gyratory Crusher
Crushers II
Primary crushing plant with gyratory crusher for iron ore and overburden
The crusher is directly fed from two sides by means of dump/haul trucks
Crushers III
Jaw Crushers
Primary crushing machine used for coarse crushing plant in mine ore mining process
Cone Crusher
Mainly used in secondary or tertiary stone crushing process
Feeders
Feeders are in charge of feeding material to the different units in the processing of iron ore:
Crushers Screens
Vibrating feeder
Screens are basically box frames into which sheets of screen meshes of the required apertures are inserted, clamped and tensioned
Screens are usually "multi-deck", i.e. two or more screen meshes are stacked vertically within the screen frame The whole screen is coupled to its support frame by springs or resilient rubber mountings and are made to vibrate by a rotating transverse shaft. The shaft is machined to be unbalanced, and when driven by an electric motor by v-belts, the required vibratory motion to agitate the aggregate is imparted.
Vibrating screens
Screening in operation
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
General Processing 3:
Further Crushing/Grinding/Milling
After crushing and screening the material is further reduced by wet grinding in rod mills or ball/pebble mills
The rod and ball mills are in closed-circuit with classification systems such as cyclones
An alternative to crushing (after primary crushing) is to feed some coarse ore directly to a wet or dry semi-autogenous or autogenous grinding mills
Followed by pebble/ball mills, rod mills or tower mills
The liberated particles should be removed from the grinding circuits as soon as they are formed/freed, with larger particles returned for further grinding/milling It should be noted that the grinding/milling solutions available are numerous, dependent on what is most economical and beneficial for the ore being processed
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
Semi-autogenous grinding mills (SAG) are essentially autogenous mills, but utilize grinding balls to aid in grinding like in a ball mill A SAG or AG mill is generally used as a primary or first stage grinding solution
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
Ball mills:
A slightly inclined or horizontal rotating cylinder is partially filled with balls, usually stone or metal, which grinds material to the necessary fineness by friction and impact with the tumbling balls
Rod mills:
A rotating drum causes friction and gradual reduction of particle size between steel rods and ore particles
Tower Mills
As with ball and rod mills, tower mills can be used for dry or wet grinding applications
often called vertical mills, stirred mills or regrind mills
Are a more efficient means of grinding material at smaller particle sizes, and can be used after ball mills in a grinding process Like ball mills, grinding (steel) balls or pebbles are often added to stirred mills to help grind ore, however these mills contain a large screw mounted vertically to lift and grind material
In tower mills, there is no cascading action as in standard grinding mills
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
At an iron ore mine, the ore going into the blast furnaces must be blended so that the process can be controlled and the required minimum quality of iron produced
It is impossible to get an even quality of any mined ore if you simply use it as it comes out of the mine As a result, the blending process is a key function of most stacker/reclaimer stockyard systems
To achieve the required level of blending from a particular mine for a particular process, one must first determine the most appropriate combination of stacking system and reclaiming system
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
Combination:
Bucket wheel reclaimers Bridge bucket wheel reclaimers Halfbridge bucket wheel reclaimers Combination stacker/bucket wheel reclaimers
Reclaimers:
Multi-directional:
Circular stackers Uni- and bidirectional reclaimers
Further Processing
To maximize the recovery of iron-bearing minerals sometimes additional gravity separation processes are used: Jigging Dense Media Separation (DMS)
Depends on bottom size Near density material Optimize yield and recovery Lower tailings grades
Density Separation
Jigging
Low operating cost
Less efficient separation
DMS is a process where a suspension of dense powder in water is used to form a type of heavier liquid to separate mineral particles in a sink-float process
Many modern dense media plants use this technology because it is both flexible and allows upgrading of resources thereby increasing overall profitability of the resource
The correct application of the DMS technology can increase the recovery of iron ore and increase the separation efficiency of the scrap metal recycling process
Jigging
Main purpose of jigging is to separate particles within the ore body, based on their specific gravity (relative density)
The particles would usually be of a similar size, often crushed and screened prior to being fed over the jig bed
There are many variations in design; however the basic principles are constant:
The particles are introduced to the jig bed (usually a screen) where they are thrust upward by a pulsing water column or body, resulting in the particles being suspended within the water As the pulse dissipates, the water level returns to its lower starting position and the particles once again settle on the jig bed As the particles are exposed to gravitational energy whilst in suspension within the water, those with a higher specific gravity (density) settle faster than those with a lower count, resulting in a concentration of material with higher density at the bottom, on the jig bed The particles are now concentrated according to density and can be extracted from the jig bed separately
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
Dewatering
The main processes that are used in dewatering include dewatering screens, sedimentation, filtering, and thermal drying
These processes increase in difficulty and cost as the particle size decreases
Dewatering screens operate by passing particles over a screen. The particles pass over the screen while the water passes through the apertures in the screen
Only viable for coarse ores that have a close size distribution as the apertures can allow small particles to pass though and are not able to be produced for small particles
Direct shipping ores, when mined, typically have iron (Fe) content of between 56% Fe and 64% Fe
The predominant minerals in DSO are usually the ferric iron oxides hematite (Fe2O3), goethite (FeO(OH) and/or limonite (FeO(OH).nH2O)
As they require less beneficiation due to the higher iron content, DSOs are considerably cheaper to mine and process compare to Hematite and Magnetite
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
Processing of Hematite
Processing of Hematite
Due to the high density of hematite relative to silicates, ore separating line usually involves a combination of crushing and milling as well as heavy liquid separation
Heavy liquid separation is achieved by passing the finely crushed ore over a bath of solution containing bentonite or other agent which increases the density of the solution
When the density of the solution is properly calibrated, the hematite will sink and the silicate mineral fragments will float and can be removed
Grinding equipment: processing mill, energy-saving ball mill fine sieve grading equipment, vibrating screen, spiral classifier
Processing of Hematite:
One method of processing hematite relies on passing the finely crushed ore over a bath of solution containing bentonite or other agent which increases the density of the solution
When the density of the solution is properly calibrated, the hematite will sink and the silicate mineral fragments will float and can be removed
Floatation
Types of floatation:
Flash floatation Conventional floatation Tank cells Column cells Reagent Plants
Processing of Magnetite
Processing/Beneficiation of Magnetite
Compared to Hematite, Magnetite goes through a more rigorous processing
This to ensure the iron ore reaches the quality required by the end users
The beneficiation of magnetite typically involves grinding to a particle size where magnetite is liberated form its silicate matrix The typical grade of iron at which a magnetite-bearing banded iron formation becomes economic is roughly 25% iron, which can generally yield a 33% to 40% recovery of magnetite by weight to produce a concentrate grading in excess of 64% iron by weight The typical magnetite iron ore concentrate has less than 0.1% phosphorus, 37% silica and less than 3% aluminium
Processing/Beneficiation of Magnetite
Magnetite is magnetic, and as a result:
Easily separated from the gangue minerals Capable of producing a high-grade concentrate with very low levels of impurities
The grain size of the magnetite and its degree of commingling with the silica groundmass determine the grind size to which the rock must be comminuted to enable efficient magnetic separation to provide a high purity magnetite concentrate
This again determines the energy inputs required to run a milling operation
Mining of magnetite bearing BIFs involves coarse crushing and screening, followed by rough crushing and fine grinding to pulverize the ore to the point where the crystallized magnetite and quartz are fine enough that the quartz is left behind when the resultant powder is passed under a magnetic separator
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
Processing/Beneficiation of Magnetite II
After the coarse and fine crushing, milling and screening the next step is to concentrate
Only around 30-35% of the crude magnetite becomes a shippable produce for iron making and a large amount of gangue is created
The magnetite ore usually goes through several stages of magnetic separation (mostly 1 & 2)
1. Rougher Magnetic Separation 2. Cleaner Magnetic Separation 3. Second Cleaner Magnetic Separation
Floatation
Flotation in iron ore beneficiation sometimes happen in addition to the magnetic separation, in order to clean the magnetite it from the silica
This to meet the silica and alumina specifications of the end product In some cases, siderite, an iron carbonate may occur in the magnetite-bearing BIFs and could warrant recovery by flotation if present in high enough amounts
Flotation systems for removing silica from magnetite ores have to be designed differently compared to the systems for treatment of hematite ore. There are several reasons for this but in all magnetite flotation, the collector must have the capability to float mixed magnetite-silica grains
In hematite flotation, the most normal case is to float fully liberated quartz from hematite
Example: The flotation phases for magnetite can employ conventional large-size mechanical cells, in addition to flotation columns
This process uses starch (depressant) and amine (quartz collector) as reagents to promote the separation of the contaminant mineral (quartz) from the iron-bearing mineral
Example of process flow for Samarcos Alegria and Fazendao mines ore produce, Brazil
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
3. The ore stream enters the magnetic separators to become concentrate 4. The concentrate will be then be thickened and stored before being pumped 25km to the port 5. Arriving the port the concentrate is filtered to reduce moisture and stacked before loaded for export
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
Jotuns supply to the Sino Iron project is ca. 1,8 mill USD. Supplied by Jotun China and Jotun Australia
Additionally, when compared to hematite DSO, the magnetite pellets contain lower levels of impurities, particularly phosphorous, sulphur and aluminium
These pellets are premium products which attract higher prices from steel makers, offsetting the higher costs of producing magnetite pellets
NOTE: Further processing of io will not be covered as this is not part of the concept
Stockyards are used to store, separate/blend the different sizes and qualities of material before export Machinery found:
Stackers Reclaimers Stacker reclaimers Conveyor belts
Stockyards are fed iron ore by either conveyors or trains dependent on where the stockyard is located (crushing, processing plant or port)
A typical rail train for iron ore export in Australia can consist of:
9 locomotives 230 ore cars Over 2,4 km long!
Once the train arrives the port the ore cars go through the car-dumper:
The ore cars are rotated and the ore flows into bins and then is discharged onto conveyors
Slurry Transportation
The port is often purpose built for the exportation of iron ore
SUPPORTING INFRASTRUCTURE
AW / Introduction to Iron Ore & Iron Ore Mining / 2013
Supporting Infrastructure
Supporting infrastructure found in iron ore mines depends greatly on the set-up and demand form the mine itself and the processing process Examples of supporting infra:
Accommodation facilities Storage facilities Airport Desalination plant Dewatering plant Power plant Pelletizing plant
Note: pelletizing plant is not in focus for the concept unless part of the total mining project
Desalination plant
SUPPORTING SLIDES