Thermal Conductivity of FRP Composites

Thermal Conductivity Characterization of Composite Materials
Bhyrav Mutnuri
Thesis Submitted to the

College of Engineering and Mineral Resources
at West Virginia University
in partial fulfillment of the requirements
for the degree of
Master of Science
in
Mechanical Engineering
Dr. Kenneth Means, Ph.D., Chair

Dr. Gangarao Hota, Ph.D.
Dr. Eric Johnson, Ph.D.
Dr. Ruifeng Liang, Ph.D.
Department of Mechanical Engineering

Morgantown, West Virginia
2006
Keywords: Thermal conductivity, Three Dimensional Thermal Conductivity,

Composite materials, E-glass, Carbon Fibers, Additives
ABSTRACT
Thermal Conductivity Characterization of Composite Materials

Bhyrav Mutnuri
Thermal conductivity of a polymer composite is a function of resin type, fiber type and
architecture, fiber volume fraction, direction of heat flow, and service temperature. Recognizing
the thermal responses in Fiber Reinforced Polymer (FRP) composite decks play a critical role in
their performance, accurate thermal measurements of FRP decks are essential.
The objective of the research is to attain better understanding of global and local thermal
behavior of a composite structural system through fundamental understanding of thermal
conductivity properties. The literature reveals that a major focus has been placed on
measurements of thermal conductivity in through-the-thickness direction of a FRP composite.
Therefore, current research focus has been on characterization of thermal conductivity in the
planar direction (along the direction of fiber and transverse direction of fiber) of a composite
laminate. The characterization has been carried out using Guarded heat flow meter method in
accordance with ASTM E 1530. The results obtained from this study are useful for the prediction
of thermal conductivity of E-glass and Carbon fiber composites with vinyl ester.
Results showed that E-glass/Vinyl ester samples exhibited in-plane and through-thethickness thermal conductivity of 0.35 0.05 W/m K. Thermal conductivity of Carbon/Vinyl
ester composite is almost twice the conductivity in transverse and four times greater than
through-the-thickness direction. Addition of 10 wt%, 12.5 wt% of graphite powder additive in
neat vinyl ester resin increased the conductivity by nearly 88%, 170% respectively. The
experimental values from this research correlated well with results from rule of mixtures in inplane direction and also correlated with other theoretical methods. The results of this research
would also be useful for in situ non-destructive testing of composite structures using Infrared
thermography.
ACKNOWLEDGEMENTS
First I would like to thank god for giving me this wonderful opportunity to enhance my
knowledge and thinking ability through pursing this masters degree. I wish to express my sincere
gratitude to Dr. Liang and Dr. Hota for introducing me to the field of research and guiding me
through out this work. I would like to thank Dr. Means for serving as committee chair and for his
support during this work and I extend my thanks to Dr. Johnson for his valuable advises as a
committee member.
I wish to thank Jim Hall, Dave Turner, Paul Porter, Jerry Nestor and Bill Comstock for
their help in preparing samples. I wish to thank Linda Rogers, Lynne Jacobs, Debbie Willis and
the staff of CFC for their support during the course of work.
I thank Federal Highway Administration / Department of Transportation for funding this
project, Bedford Reinforced Plastics, Inc. for donating FRP bridge deck samples and Anter
Corporation, Pittsburgh, Pa for providing latest model instrument for testing the samples for
thermal conductivity.
I wish to express my appreciation to Suneetha Burla for her help during experimental
work and thesis write-up. I would like to extend my thanks to Amarnath, Deepika for helping me
in preparing carbon fiber composite blocks and Sandilya Hota for his support as an officemate
during this study.
Last but not the least, I am very much thankful to my mom, family, relatives and friends
for their loving support and encouragement which made all this possible.
iii
TABLE OF CONTENTS
ABSTRACT ------------------------------------------------------------------------------------------------- ii
ACKNOWLEDGEMENTS ----------------------------------------------------------------------------- iii
TABLE OF CONTENTS -------------------------------------------------------------------------------- iv
LIST OF FIGURES --------------------------------------------------------------------------------------- vi
LIST OF TABLES ----------------------------------------------------------------------------------------vii
CHAPTER 1------------------------------------------------------------------------------------------------- 1
INTRODUCTION..................................................................................1
1.1 Introduction................................................................................................................... 1
1.2 Objective ....................................................................................................................... 1
1.3 Scope............................................................................................................................. 2
CHAPTER 2------------------------------------------------------------------------------------------------- 4
LITERATURE REVIEW......................................................................4
2.1 Introduction................................................................................................................... 4
2.2 Theory of thermal conductivity .................................................................................... 4
2.3 Factors affecting thermal conductivity of composite materials.................................... 5
2.4 Experimental approach for thermal conductivity measurements................................ 10
2.5 Theoretical approach for thermal conductivity predictions ........................................ 14
CHAPTER 3------------------------------------------------------------------------------------------------20
TESTING METHODS.........................................................................20
3.1 Introduction................................................................................................................. 20
3.2 Experimental setup...................................................................................................... 20
3.3 Operation principle of Unitherm 2022........................................................................ 22
3.4 Sample requirement and test procedure...................................................................... 23
3.5 Determination of fiber volume fraction ...................................................................... 24
CHAPTER 4------------------------------------------------------------------------------------------------26
MATERIALS AND SAMPLE PREPARATION ..............................26

4.1 Introduction................................................................................................................. 26
4.2 Thermal conductivity test matrix ................................................................................ 26
4.3 Resin casting with or without additives ...................................................................... 28
iv
4.4 E-glass/vinyl ester laminates with or without stitching .............................................. 31

4.5 Epoxy based wearing surface...................................................................................... 31
4.6 Natural fiber /vinyl ester composites .......................................................................... 32
4.7 FRP garage door panel................................................................................................ 32
4.8 E-Glass Vinyl ester composite block.......................................................................... 32
4.9 Carbon fiber/ vinyl ester composite sheet and block .................................................. 33
4.10 Prodeck 4 and Prodeck 8 bridge decks ..................................................................... 34
CHAPTER 5------------------------------------------------------------------------------------------------37
EXPERIMENTAL RESULTS AND DISCUSSION .........................37

5.1 Introduction................................................................................................................. 37
5.2 Neat resin castings and resin castings with additives ................................................. 37
5.3 E-glass /vinyl ester laminates with or without stitching ............................................. 42
5.4 Miscellaneous composite samples .............................................................................. 43
5.7 E-glass/vinyl ester composite block............................................................................ 45
5.8 Carbon fiber /vinyl ester composites .......................................................................... 46
5.9 Prodeck 4 and Prodeck 8 bridge deck samples........................................................... 49
CHAPTER 6------------------------------------------------------------------------------------------------53
VALIDATION OF MODEL PREDICTIONS ..................................53

6.1 Introduction................................................................................................................. 53
6.2 Analytical models and validation................................................................................ 53
6.3 Discussion ................................................................................................................... 57
CHAPTER 7------------------------------------------------------------------------------------------------58
CONCLUSIONS AND RECOMMENDATIONS .............................58

7.1 Introduction................................................................................................................. 58
7.2 Conclusions................................................................................................................. 58
7.3 Recommendations for future work ............................................................................. 59
BIBLIOGRAPHY -----------------------------------------------------------------------------------------61
LIST OF FIGURES
Figure 2.1 Schematic of Resin Transfer Molding........................................................................... 9
Figure 2.2 Schematic of Pultrusion Process ................................................................................. 10
Figure 2.3 Schematic representation of transient pulse method ................................................... 12
Figure 2.4 Schematic representation of Laser Pulse Operator...................................................... 13
Figure 3.1 Experimental set up of Unitherm 2022 ....................................................................... 20
Figure 3.2 Schematic model showing the system arrangement in Unitherm 2022 ...................... 21
Figure 3.3 SEM pictures showing the number of layers and their alignment............................... 25
Figure 4.1 Samples of Epoxy, Vinyl ester and Polyester resins on top row; samples with different
particulate sizes of graphite powder additive, chopped carbon fiber additives in bottom two rows
....................................................................................................................................................... 29
Figure 4.2 Samples of Derakane 8084 vinyl ester resin with or without additives ...................... 30
Figure 4.3 Sonicator and Teflon mold ...................................................................................... 30
Figure 4.4 Miscellaneous FRP composite samples tested ............................................................ 31
Figure 4.5 Samples of bridge deck, natural fiber, deck with epoxy wearing surface................... 32
Figure 4.6 E-glass/vinyl ester block and three dimensional samples, carbon tow and carbon/vinyl
ester sheet sample ......................................................................................................................... 33
Figure 4.7 Carbon fiber /vinyl ester composite block and specimens along fiber direction
(marked X), in transverse direction (Y) and through the thickness direction (Z)......................... 34
Figure 4.8 Samples prepared from web and flange sections of Prodeck 4 ................................... 36
Figure 4.9 Samples prepared from web and flange sections of Prodeck 8 ................................... 36
Figure 5.2 Thermal conductivity variations with graphite additives, with carbon nano-tubes in
Derakane 8084 vinyl ester resin.................................................................................................... 41
Figure 5.3 Thermal conductivity variations with change in particulate size of............................ 41
graphite additives in Hetron 922 vinyl ester resin ........................................................................ 41
Figure 5.4 Thermal conductivity variations with chopped carbon fiber additives in Hetron 922 L
vinyl ester resin ............................................................................................................................. 42
Figure 5.5 Thermal conductivity variations for Carbon/Vinyl ester composites.......................... 49
vi
LIST OF TABLES
Table 4.1 Thermal Conductivity Test Matrix ............................................................................... 27

Table 5.1 Thermal conductivity values of different resins ........................................................... 38
Table 5.2 Thermal conductivity values of vinyl ester resins with different additives and
particulate size of additive ............................................................................................................ 39
Table 5.3 Thermal conductivity of E-glass /vinyl ester laminates................................................ 43
Table 5.4 Thermal conductivity of miscellaneous composites..................................................... 44
Table 5.5 Thermal conductivities of E-glass/vinyl ester composite block samples ..................... 46
Table 5.6 Thermal conductivities of carbon fiber/vinyl ester composite blocks I, II................... 48
Table 5.7 Thermal conductivity of FRP bridge deck samples in three directions........................ 50
Table 5.8 Thermal conductivity values of 4-inch deck web section samples............................... 51
Table 5.9 Thermal conductivity values of 4-inch deck flange section samples ........................... 51
Table 5.10 Thermal conductivity values of 8-inch deck web section samples............................. 52
Table 5.11 Thermal conductivity values of 8-inch deck flange section samples ......................... 52
Table 6.1 Theoretical models for transverse effective thermal conductivity................................ 54
Table 6.2 Parameters of the samples verified using theoretical methods ..................................... 55
Table 6.3 Comparison of experimental and theoretical values in (through the thickness effective
thermal conductivity) for E glass/Vinyl ester sample and Carbon/Vinyl ester samples............... 56
vii
CHAPTER 1
INTRODUCTION
1.1 Introduction
Composites are engineered materials made out of two or more components. Most of the
composites can be tailored to obtain properties better than individual constituents. A polymer
composite reinforced with fiber is called FRP composite. Considering a composite, which
involves two or more macro constituent phases, the matrix is referred to as continuous phase and
the fibers are called the reinforcing phase (Mirmira, 1999). The fibers increase the strength and
stiffness, increase thermal and fatigue properties, provide better dimensional stability and
electrical resistivity. Whereas the primary function of the resin is to transfer load, to hold the
fibers, protect fibers from environment and mechanical abrasion. Matrix also carries transverse
loads and interlaminar shear stresses (Barbero, 1998). The advantages of composites include
high strength to weight ratio, non-corrosiveness, less maintenance, high electrical resistance,
wear resistance, electromagnetic transparency, appeasing appearance etc. Composites can be
manufactured in different ways depending upon matrix, reinforcement and application. Different
manufacturing methods include Hand-lay up, Compression molding, Resin Transfer Molding
(RTM), Pultrusion, Autoclave and Filament molding etc.
Considering the mechanical and thermal properties of composites, they are anisotropic in
nature (i.e. the properties vary with orientation), but most of the composites can be considered as
orthotropic (i.e. nine different constants are required to describe an orthotropic material). This
behavior of the material also causes the development of large values of thermal stresses due to
temperature gradient across the section. This problem emphasizes the necessity of knowledge on
thermal behavior of composites.
1.2 Objective
The long-term vision of this research is to develop composites with reduced thermal
stresses to avoid catastrophic failures and to develop FRP composite bridges with self-deicing
capacity creating environmental friendly atmosphere. To achieve these goals, research was
required in the fields of thermal expansion, thermal conductive behavior and design of composite
structure. Knowledge about the thermal conductivity can be utilized in finding the optimum heat
source required to conduct Infrared testing (non-destructive) on composite components in service
1
as well as in designing of composite materials with reduced thermal stresses. The objective of
this present work is to understand the thermal behavior of FRP composites by developing a
database of thermal conductivity for different FRP composite materials. Different composite
samples are to be distinguished based upon the following parameters:
Different resin
Different fibers
Effect of heat flow direction
Fiber volume fraction
Effect of additive materials and particle size of additive
Different manufacturing methods
1.3 Scope
The structure of this report is as follows. Chapter 2 contains a brief description of
published literature on prediction and determination of thermal conductivity of composite
materials. Most of the literature deals with analytical determination of thermal conductivity, with
few published papers dealing with the experimental methods determining thermal conductivity
of composite materials. Those papers on experimental methods mainly focused on thermal
conductivity of FRP materials in a single direction.
Chapter 3 deals with test method to determine thermal conductivity. The measurements
of thermal conductivity of composite materials were carried out on a guarded heat flow meter
entitled Anter system model Unitherm 2022. This model is
fully computerized and equipped
with a mid range flux module covering the thermal conductivity of materials in the range of 0.1
to 40 W/m-K in terms of test standard ASTM E 1530.
Chapter 4 presents details on constituent materials and manufacturing techniques of test
samples. Fiber reinforcements include E-Glass, Carbon fiber, and natural fiber, while resin types
range from vinyl ester, polyester, and epoxy. Most samples were manufactured in CFC-WVU
laboratories using conventional manufacturing techniques like Hand-lay up, Compression
molding, Resin Transfer Molding. However, two types of bridge decks i.e. Prodeck 4 and
Prodeck 8 were manufactured through pultrusion process by Bedford Reinforced Plastics Inc.
Bedford, PA, and were supplied to CFC-WVU for experimental evaluation.
Chapter 5 presents thermal conductivity values obtained for a variety of composite
materials. This chapter also includes discussions on the influence of various parameters on the
2
thermal conductivity of FRP composites. Chapter 6 compares experimental thermal conductivity

values to values computed from available empirical models. Chapter 7 gives a summary and
directions for future work.
CHAPTER 2
LITERATURE REVIEW
2.1 Introduction
Increasing
use
of
composites
for
various
applications
emphasizes
its
importance/significance in the thermal property analysis of an engineering system. Thermal

conductivity of a composite (combination of two or more constituents) can be measured by
experimental methods. Analytical equations are essential to predict thermal conductivities of a
composite material. Information on the thermal properties of composite materials would
facilitate the design of an engineering system made of FRPs.
Published literature is rich with investigations of mechanical properties of composites
(Gowayed, 1995). Fewer publications focused on thermal properties. Several publications like
Hashin (1979), Caruso et al (1986), Muralidhar (1989), Springer and Tsai (1967) addressing
different theoretical approaches for predicting thermal conductivity of composite materials have
been noted. However, one of the publications (Gowayed, 1995) has discussed both transverse
and axial thermal conductivity of a carbon fiber composite. A non-linear increase in the thermal
conductivity was reported with the increase of fiber volume fraction of plain weaves and no
theoretical models are able to predict this non-linearity. The result of literature search even
further identified the necessity and importance of carrying out the proposed research.
This review is focused on: 1) the concept of thermal conductivity, 2) experimental
methods for measuring thermal conductivity of a composite material, and 3) analytical/numerical
methods for predicting thermal conductivity of composite materials.
2.2 Theory of thermal conductivity
The theory of thermal conductivity was proposed by Fourier in 1822. According to
Fourier, the fundamental heat conduction equation can be stated as For a homogeneous solid,
the local heat flux is proportional to the negative local temperature gradient. For one
dimensional steady state heat transfer, this statement can be represented by Equation 2.1:
q = K
dT
dx
2.1
Where q is the heat flux, K is the thermal conductivity of the material, which is a positive 2nd
order tensor quantity, dT
dx
represents change in temperature across the thickness and negative
sign indicates the temperature reduction from hotter surface to cooler surface.
According to Equation 2.1, conductivity can be given as (under the assumption, that heat
is not lost in its plane)
K = (Q/A)/ (T/L)
2.2
where K is the thermal conductivity (W /m-K), Q is the Heat Flux (W), A is the cross sectional
area of the specimen (m2), T is the Temperature difference (K), L is the over all distance (m).
Thus, the thermal conductivity of a material can be defined as a rate at which heat is transferred
by conduction through a given unit area of a given material, when the temperature gradient is
normal to the cross sectional area. The thermal conductivity of a composite material depends on
the fiber, resin materials, fiber volume fraction, orientation of the fiber, direction of heat flow
and operating temperature.
2.3 Factors affecting thermal conductivity of composite materials
Thermal conductivity of composites is anisotropic in nature. The knowledge of thermal
conductivity of composites is needed for accurate design. Data about thermal conductivity of
resin facilitates to reduce stresses related to shrinkage of composites during cure and mismatch in
thermal expansion coefficients. Before conducting experiments to determine thermal
conductivity of various composites, knowledge about effect of different parameters influencing
thermal conductivity is essential.
2.3.1 Fibers
Fiber is the reinforcing phase of a composite material. Thermal conductivity of a
composite depends upon the thermal conductive nature of the fiber and matrix. Commonly used
fibers for composites include Glass, Carbon, and Aramid etc.
Glass fibers are commonly used for engineering composites. Their uses include the
manufacturing of automotive parts, pipes, structural members etc. Glass fiber is available
economically in abundance with good mechanical properties; thus widely used in composite
structures (Barbero, 1998). Basing upon different applications glass fiber (silicaoxygen
network) is classified into E glass, C glass, and S glass fibers (Barbero, 1998). E glass is used as
5
an insulator and mostly used in electrical industry, hence got the name E before the word glass.
E-glass also has good mechanical properties in addition to low cost and ease of usability. The
letter S in S-glass stands for structural applications. S-glass got different chemical formulation
and it has higher strength to weight ratio, and higher elongation strain percentage. S glass is a bit
expensive and mostly used in structural application, and C-glass fibers are advantageous in
resisting chemical corrosion. Glass fibers are available in different forms like continuous,
chopped and woven fabrics.
The microstructure of any fiber plays vital role in carrying heat. The glass fiber has an
amorphous structure. It consists of SiO2 molecules and forms a three dimensional silica
polyhedral network along the length of the fiber. It behaves nearly isotropic, resulting in nearly
same conductivity properties in any direction of the fiber.
Carbon fibers are manufactured using precursor materials like rayon, petroleum or coal
tar pitches and polyacrylonitrile (PAN) (ASM Handbook, 2001). The conversion of pitch or
PAN precursor to carbon fibers involves manufacturing steps like fiber formation by spinning,
stabilization to thermoset the fiber, carbonization, graphitization, surface treatment and sizing
(Mirmira, 1999). During graphitization stage at higher temperatures the crystallites are properly
ordered and oriented along the axis direction of the fiber. In PAN based carbon fibers, during the
graphitization stage the linear structure of carbon atoms transforms into a planar structure called
as basal planes and are oriented or stacked along the axis of the fiber. These basal planes are
closely packed and are responsible for the high modulus and higher electrical and thermal
conductivities along the axis of the fiber.
Natural fibers are becoming potential alternatives for glass fiber reinforced composites in
many applications (Joshi et al 2004). Usage of natural fibers like hemp, jute, flax, cotton etc.
instead of synthetic fibers leads to increase in specific properties like impact strength, crash
behavior, sound absorption, thermal insulation and reduction in components weight, pollutants,
and greenhouse gas emissions making the composite more environmental friendly. Natural fiber
composites have many applications including automobile parts like door trim panels, headliners
or back panels. Natural fiber is filled with cellulose material, which acts as an insulator, thus a
natural fiber composite shows much lesser thermal conductivity when compared to a glass fiber
reinforced polymer (GFRP) composite.
2.3.2 Resins
Matrix materials are of different types like metal matrix, ceramic matrix and polymer
matrix. Polymer matrices are most commonly used because of cost efficiency, ease of fabricating
complex parts with less tooling cost and they also have excellent room temperature properties
when compared to metal, ceramic matrices.
Polymer matrices can be either thermoplastic or thermoset. Thermoplastic materials are
formed by addition polymerization. Thermoplastics soften or fuse when heated, harden and
become rigid after cooling. Unlike thermosets, thermoplastics can be modified or reused upon
the need. Thermoplastics have longer shelf life and higher fracture toughness than thermoset
resins. Thermoplastic resins have high viscosity and less creep resistance when compared to
thermosets (Barbero, 1998).
Thermoset matrices are formed due to an irreversible chemical transformation of a resin
into an amorphous cross-linked polymer matrix. Due to huge molecular structures, thermoset
resins provide good electrical and thermal insulation. Thermosets have low viscosity, which
allow proper fiber wet out, excellent thermal stability and better creep resistance. The most
commonly used thermoset resins are epoxy, polyester, vinyl ester and phenolics. Mostly
thermoset resins can be formulated to give a wide range of properties upon the requirement.
Epoxy resin has excellent adhesion property compared to other resins. In addition to that
it has low shrinkage upon curing, good chemical resistance, excellent mechanical properties.
Epoxies have been used for advanced composites due to their adhesion to wide variety of fibers,
with superior mechanical and electrical properties, good performance at elevated temperatures.
Epoxies are expensive compared to polyester and less resistant to moisture. Polyester has the
advantages of low cost, ease of handling, good chemical resistance with reasonable mechanical
properties. Polyester and epoxy makes approximately 85% of the fiber reinforced polymer
composites.
Vinyl ester has the chemical backbone of epoxy and curing mechanism of polyester, so it
got improved resistance to chemical attack and ease of fabrication. Vinyl ester is stronger than
polyester and less expensive than epoxy. Vinyl ester has better resistance to moisture absorption
than polyester and the bonding capability is not good when compared to epoxy to all kinds of
fibers. Vinyl ester offers good mechanical properties and excellent corrosion resistance. The
bonding ability of vinyl ester is good to glass fiber but less efficient with carbon or Kevlar.
Phenolic resin cures through condensation reaction, which produces water during the reaction. It
7
has excellent properties like high temperature and creep resistance, good thermal insulation and
sound damping properties in addition to first-rate fire properties.
2.3.3 Fillers
The primary advantage of using filler material in composites is to reduce the overall cost
of the composite. In addition to reduction of cost, filler materials also serve as major ingredient,
which improves the performance of the composite by enhancing crack resistance, reducing
shrinkage, influencing mechanical strength, improving fire resistance etc. Major filler materials
used in composite manufacturing are calcium carbonate, kaolin (clay), Aluminum-trihydrate etc.
2.3.4 Additives
Additive materials are primarily used to modify and tailor material properties of the
composite. By introducing additives into resin system it enhances the processability or durability
of the composite. Additives help in increasing the performance or a specific property as well it
increases the overall cost of the product. Various additives widely used to boost the thermal and
electrical conductivity of the resin are graphite powder, chopped carbon fiber, carbon nano-tubes
etc.
2.3.5 Manufacturing Methods
As the thermal conductivity of a polymer composite is based upon the conductivity of
fiber and resin, being a polymer, resins are usually insulating and the conductivity is dominated
by fiber material. The compactness of fibers per unit area influences the conductivity of the
composite. Fiber packing in a composite depends on the method of manufacturing. The various
composites manufacturing techniques are Hand lay-up, Compression molding, Resin Transfer
Molding, Pultrusion etc (Barbero, 1998).
2.3.5.1 Hand lay-up
Hand lay-up is the oldest and simplest method of manufacturing composites. The tools
required for the process are a mold to accommodate dry manufacturing according to the desired
shape and a roller to facilitate uniform distribution of resin. Virtually any sized composites can
be manufactured using this method. This method is the cheapest method of manufacturing but it
has some disadvantages such as long curing time, low production rate, and further the quality of
the composite depends on the skill of the worker.
2.3.5.2 Compression molding process

This method is commonly used to manufacture sheet molding or bulk molding.
Compression molding machine consists of a male and female dies or platens to form the mold.
The reinforcement combined with resin is placed in the mold and a hydraulic press is used to
apply high pressure by closing male and female halves of the mold. After the material is cured,
the pressure is released and the part is removed from the mold. Exterior body panels for
structural members such as automobile bumpers are widely manufactured using this method.
2.3.5.3 Resin Transfer Molding (RTM)
This manufacturing method uses a mold with an inlet to introduce resin/catalyst mixture
and vent ports to allow air to escape. In this method, resin and catalysts are mixed proportionally
in an injection head and then pumped into the mold. Dry reinforcement is placed inside the mold
and is closed. Resin is pumped into the mold till the mold is full. After the resin is cured, the part
is removed from the mold. RTM has been further modified by using vacuum to suck resin
catalyst mixture inside. In this case, vacuum bags are used along with molds and hence this
method is called as Vacuum Assisted Resin Transfer Molding (VARTM). VARTM process
enhances resin flow and reduces void fraction. RTM process is cleaner with less emissions of
volatiles. The applications of this process includes manufacturing of auto body panels, swim
pool panels, sandwich panels etc. A schematic of Resin Transfer Molding is shown in Figure 2.1
Figure 2.1 Schematic of Resin Transfer Molding

(Photo Courtesy: http://www.esi-group.com)
2.3.5.4 Pultrusion
Pultrusion is a continuous and highly automated molding process used in fabrication of
composite parts that have a constant cross section. Reinforcement materials are arranged in such
a pattern so that they match the profile of the die. The fibers are pulled through a resin bath and
9
then to the heated metal pultrusion die. The die is maintained at a prcised temperature so that it
can transfer heat to the fiber and liquid resin. The heat energy is used to carry on the
polymerization of the resin to matrix. The cooled solid part is then pulled from the die and cut to
desired length. Pultrusion is a low cost process for a large volume production. Applications of
this process are in the fields like construction, transportation, electrical etc. A schematic of
pultrusion process is shown in Figure 2.2
Figure 2.2 Schematic of Pultrusion Process

(Photo Courtesy: www.pulwellpultrusions.com)
2.4 Experimental approach for thermal conductivity measurements

There are various test methods available for thermal conductivity measurement and each
method depends mainly on configuration of a material and job requirement. Some principal
experimental methods for determinations of thermal conductivity are discussed below:
2.4.1 Guarded heat flow meter
This method is based on two dimensional steady state techniques and is used to measure
and compare thermal properties of materials under controlled conditions and their ability to
maintain required thermal conductance levels (ANTER, 2003).
The specimen and a heat flux transducer (HFT) are sandwiched between two flat plates
controlled at different temperatures, to produce a heat flow through the stack. A cylindrical guard
surrounds the test stack and is maintained at a uniform mean temperature of the two plates, in
order to minimize the lateral leak of heat. At steady state, the difference in temperature between
the surfaces contacting the specimen is measured with temperature sensors embedded in the
10
surfaces, together with the electrical output of the HFT. The output voltage is proportional to the
heat flow through the specimen, HFT and the interfaces between the specimen and the apparatus.
The coefficient of thermal conductivity can be obtained by prior calibration of system with the
specimens of know thermal conductivity.
At equilibrium, the thermal conductivity of material can be given as
K= ( x) / Rs
2.3
Rs =(N(T)/Q) Ro
2.4
where K is the thermal conductivity (W/ m-K), Rs is the resistance of unknown specimen (m2.
K/W), N is the HFT calibration constant, T is the temperature difference between one surface
of the specimen and the other surface (K), x is the specimen thickness (m), and R0 is the contact
thermal resistance.
Other methods also based on two dimensional steady state techniques for wide range of
operating temperatures include Heat Flow Meter, Guarded Hotplate, Hot Wire, and Laser Flash.
2.4.2 Surface probe method
The surface probe (also called Mathis probe) is demonstrated as a non-intrusive indirect
method of obtaining thermal conductivity (Rouison et.al, 2002) for heat flux parallel (i.e., axial
or transverse) to the plane of a sample. This transient-state probe consists of three parallel nickel
ribbons connected to electrical circuitry providing a constant rate of heating with time, with the
outer strips acting as thermal guards, forcing the heat flux vector to be perpendicular to the probe
surface. The circuitry is designed to monitor the temperature of the central strip, and computer
control and data acquisition allows the recording of temperature rise of the central strip and the
time lapse after the start of heating. When placed against a flat sample surface, this temperature
rise depends on the thermal properties of the sample.
T (Q t1/2)/ (k Cp)
2.5
where T is surface temperature, Q is center strip constant heating source intensity in W/m2, t is
time elapsed after the onset of heating, k, , and Cp are thermal conductivity, density, and heat
capacity of the sample. This gives K for the heat flux vector normal to the plane of the surface.
11
2.4.3 Transient pulse method

This method deals with the usage of electrical model, which detects the dissipations of
thermal system (Zmeskal et.al 2003). A thermo physical transient tester is used to detect the
pulse heat responses. In this method, the sample is placed in the isothermal chamber, consisted of
the three parts of cylindrical shape. Between the first and the second part the heat source was
placed (nickel folium 20 m thick and radius R2 = 2 cm). Between the second and third part one
connection of differentially connected thermocouple (Ni Cr-Ni) was placed. The second
connection was placed on heat exchanger where the constant temperature was kept with the help
of thermostat. The temperature is measured in terms of the platinum resistance. Heat is supplied
as a rectangular current pulse from the software directed source and the responses are computed
from the parameters of pulse. The change of temperature was measured by nano voltmeter. This
method is schematically illustrated in Figure 2.3.
Figure 2.3 Schematic representation of transient pulse method

The thermal conductivity equation can be given as
2.6
where h is sample thickness, is density of material and Tm is maximal temperature response
for applicated thermal pulse; it will occurs in the time tm after start of heating.
12
2.4.4 Flash pulse measurement system

Flash Pulse technique is a direct method of measuring the off axis thermal conductivity of
a composite and was first developed by Parker and Jenkins (Parker et al, 1961). A face of the
FRP sample will be exposed to the short pulse of radiant energy and the thermal diffusivity of
the sample is determined by considering the travel time of heat pulse through the section of the
sample. The thermal diffusivity was given as
=
1.38 L2
2 t1 / 2
2.7
where L is the thickness of the sample, is the thermal diffusivity, and t1/2 is the time required to
reach one half of the maximum back surface temperatures. Thermal conductivity is given by
K = Cp
2.8
where K is the thermal conductivity, is the density of the material and Cp is the specific heat of
the sample. So the thermal conductivity can be given as
K=
1.38 C p L2
2 t1 / 2
2.9
An experimental set up is schematically represented in Figure 2.4.
Figure 2.4 Schematic representation of Laser Pulse Operator
13
2.5 Theoretical approach for thermal conductivity predictions

The theoretical approach brings more generalized equation for a two dimensional steady
state heat flow. Various theoretical approaches are used to yield the thermal conductivity of a
composite material so that the heat flow in anisotropic composite material in any direction can be
estimated.
2.5.1 The rule of mixture and finite difference method
For homogeneous fibers of thermal conductivity Kf embedded in a resin matrix of
thermal conductivity Km, the thermal conductivity Kp parallel to the axis of the fiber is given by
(Barbero, 1998)
Kp = Kf Vf + (1-Vf) Km
2.10
where Vf is the fiber volume fraction while the thermal conductivity in transverse direction (Kt)
can be given as
1/Kt = Vf /Kf + (1-Vf)/Km
2.11
However, Equation 2.11 developed by rule of mixtures gives the lower limit value of the
transverse thermal conductivity. The upper limit value can be give as (James et.al, 1987)
Kt = BKm (1-Vf) + (Vf + (1-B)(1-Vf) Kf Km)/(Vf Km+(1-B)(1-Vf) Kf)
2.12
In finite difference method the body in which the heat flow occurs is divided into equal
increments in both x, y directions creating nodal points in both the directions. According to the
finite difference method the temperature around a nodal point is related to the thermal
conductivity for the material link between nodes as
Ti = ( j=1,4 Kj Tj)/ ( j=1,4 Kj)
2.13
Where Kj is the thermal conductivity between the nodes. Equation (2.13) is applied sequentially
to all nodes of a body using the latest calculated values and the process is repeated until a steady
state equation is obtained by Gauss-Seidel iteration.
14
2.5.2 Caruso model

A general finite element analysis method was proposed by Caruso et al (1986) to predict
thermal conductivity of a composite. This method is based on integrating Advanced Finite
Element Methods with simplified micromechanics equations. The boundary conditions and
loading conditions i.e. change in temperature and thermal expansions were considered in the
derivation of equation to predict thermal conductivity.
The longitudinal and transverse conductivity equations were given as
KL = Vf * K fl + Vm K ml
KT=1- V f Km +
2.23
Vf * K m
K
1 Vf (1 m )
K fl
2.24
Where KL is the thermal conductivity in longitudinal direction, KT is the thermal conductivity in

transverse direction, Vf is the fiber volume fraction, Vm is the matrix volume fraction, K
fl
and
Kml are thermal conductivity in longitudinal direction of fiber and matrix, respectively.
2.5.3 Muralidhar model
Muralidhar (1989) proposed an analytical model using FE modeling and analytical
formulation to predict thermal conductivity as a function of fiber volume fraction. The author
considered the fibers in the composite materials as inhomogeneous insulating layers and thus the
thermal conductivity of the fiber to be zero along with the sidewalls between the reinforcements
in the composite material. Herein, only the transverse thermal conductivity of the composite
material was modeled while the longitudinal thermal conductivity can be obtained by rule of
mixtures effectively.
In this method the formulation was given by considering the transient heat conduction.
The steady heat conduction was given by the Laplace equation
2 T =Txx + Tyy =0
2.25
and the unsteady case was given as
2 T = (
) Tt
2.26
15
Where T is the temperature, Tt is the partial differential of temperature with respect to time, and
is thermal diffusivity of matrix. The above equations were solved considering the boundary
conditions and the transient temperature distribution through Laplace inversion method.
A best fit between classical rule of mixtures and empirical correlation for transverse
conductivity to determine the transverse thermal conductivity was given as
K = 1-1.63 V
2.27
Where K is thermal conductivity and V is the fiber volume fraction in the range from 0 to 0.2. It
was found that the pattern of distribution of fibers and fineness of their size showed very little
effect on thermal conductivity of composites.
2.5.4 Cylinder assemblage model
Cylinder Assemblage model was developed by Hashin (1979) who considered a
transversely isotropic fiber reinforced cylinder in which the phases are transversely isotropic
with material axes of symmetry in cylindrical axis direction. The transverse thermal conductivity
was given as:
(K V + K TF (1 + Vf ))
KT = KTM TM M
(K TM (1 + Vf ) + K TF VM )
2.28
Where KT is the transverse thermal conductivity, KTM is the thermal conductivity of the matrix in
transverse direction VM is the matrix volume fraction, Vf is the fiber volume fraction, and KTF is
the thermal conductivity of fiber in transverse direction.
The above equation was derived using the expressions for finding elastic moduli and
thermal expansion coefficients of unidirectional fiber composites consisting of transversely
isotropic phases.
2.5.5 Shear loading analogy
A shear loading analogy method was proposed by Springer and Tsai (1967) to estimate
thermal conductivity of a composite. Herein, a numerical approach was presented based on
analogy between the response of the unidirectional composite to shear loading and to heat
transfer along with a thermal model. This model was developed under some assumptions
regarding the placement of fibers and packing patterns like elliptical, cylindrical and square
16
shapes. In particular, the matrix and fibers were assumed as parallel and series as in electrical
circuits depending on the heat flow direction i.e., longitudinal or transverse, respectively.
The longitudinal conductivity was given as
K11 = Vf Kf + Vm Km
2.29
and the transverse thermal conductivity was given as
4
Vf 1
K22 = Km 1 2
+
B
B 2V f
tan 1
1+
B 2V f

B 2V f
2.30
K
where B 2 m 1 , K11 and K22 are the longitudinal and transverse thermal conductivities
f
respectively, Vf, and Vm are the fiber volume fraction and matrix volume fraction respectively,
Km and Kf are the thermal conductivities of matrix and fiber respectively. The shear loading
analogy approach under predicted thermal conductivity by about 10% depending on fiber volume
fraction.
2.5.6 Effective transverse thermal conductivity
Mirmira (1999) defined the effective transverse thermal conductivity of a composite by

considering the transverse anisotropy of the fiber (in cylindrical coordinates), interfacial thermal
conductance between matrix and fiber, radius of fiber along with the volume fractions of the
matrix, fiber and their thermal conductivities. Mori and Tanaka micromechanics model for heat
conduction in composite material was used in order to derive the equation for calculating
effective thermal conductivity. The other important parameters considered included effect of
composite porosity and interaction between the fibers. In this approach the temperature profile
for a single fiber was first considered and the analysis was extended to the entire composite.
The conventional rule of mixtures was considered for estimating the longitudinal
effective thermal conductivity but the effective transverse thermal conductivity was given as
17

ke = k m

+ 1 + V f
km
ahc
k r k
k r k
+
+ 1 + V f
km
ahc
k r k
k r k
km
ahc
(1 V )2 2.31
k r k
k r k
+ 1
ahc
km
K r K
k r k
where k e is the effective thermal conductivity in transverse direction, k m is the thermal

conductivity of matrix, kr is the thermal conductivity of fiber in radial direction, K is the
thermal conductivity of fiber in tangential direction, V f is the fiber volume fraction, a is the
fiber radius, hc is the interfacial thermal conductance between fiber and matrix, V p is the
porosity volume fraction.
2.5.7 Bounding solution approach
In order to determine effective thermal conductivity value of a composite with unknown

phase geometry parameter, Lim (2002) developed a boundary solution method. In this method a
lower and upper bounds were concluded for the effective thermal conductivity of a composite
material.
The bounds were determined by considering a representative volume element and
considering its geometry in three directions X, Y, Z. This bounding solution technique has
considered various geometrical assumptions in the reinforcements like unidirectional both in
longitudinal and transverse, particulate, in plane and out of plane laminae etc. The bounds were
given as
k c1
1
1 R

= 1 V f 1
k
km
R
1 V f 1 f
k m
and
kc 2
1
R
= 1 V f 1
km

k
1 R
m
1 V f 1
k f
2.32
+1
2.33
18
where, k c1 , k c 2 are the lower and upper bounds of the thermal conductivity in a composite V f ,
is the volume fraction of fiber and k m , k f are the thermal conductivity of matrix and fiber
respectively. R corresponds the reinforcement parameter such that R =1, 2/3, 0 for unidirectional
fiber, particulate and laminae reinforcements respectively for thermal conductivity in parallel to
reinforcement axis of symmetry and R=1/2, 2/3 and 1 for unidirectional fiber, particulate and
laminae reinforcements respectively, for transverse to the reinforcement axis of symmetry.
19
CHAPTER 3
TESTING METHODS
3.1 Introduction
This chapter presents the development of an experimental method for thermal
conductivity measurements of composite materials in transverse, longitudinal and through the

thickness directions. After a brief description on the test equipment, the operation principle of the
unit is discussed and followed by sample requirement and testing procedure. This chapter also
includes the methods to find fiber volume fractions of the samples tested for determining the
thermal conductivity values.
3.2 Experimental setup
A guarded heat flow meter method has been developed for thermal conductivity
measurements. This is achieved by using a thermal conductivity testing system Unitherm model
2022 from ANTER Corp., Pittsburgh, PA. The experimental set up of this instrument in CFCWVU laboratory is shown in Figure 3.1.
Figure 3.1 Experimental set up of Unitherm 2022
20
This unit is supplied with a mid range flux module covering a thermal resistance range
from 0.002 to 0.02 m2 K/W and is able to measure the thermal conductivity of materials in the
range of 0.1 to 40 W/m-K in terms of test standard ASTM E 1530. The materials that can be
tested include metals, ceramics, polymers, composites, glass etc. The test samples need to be
prepared in a form of two-inch diameter circular discs with their thickness depending on the
materials thermal conductivity. The thermal conductivity machine was supplied with three sets
of calibration samples span the Rs range from 0.0005 to 0.05 m2K/W. These samples were tested
for conductivity values and compared with the given values by the manufacturer for calibration
purpose. The relationship among the thermal conductivity of a material, its thermal resistance
and sample thickness is discussed in detail under Section 3.3.
This equipment requires compressed air to raise and lower the upper stack assembly. It
also needs either city water or a chiller to cool the heat sink, giving an operation temperature
range from 200C to 3000C. ANTER model Unitherm 2022 is a computerized system. The
computer automatically controls the equipment for testing and data processing through a latest
version of electronics and operating software once a test program is designed and initiated.
Figure 3.2 Schematic model showing the system arrangement in Unitherm 2022
A schematic picture shown in Figure 3.2 represents the system functioning in detail. The
assembly is a stack of parts with different functionalities. The heater on top and bottom helps to
maintain steady state heat transfer through the sample, two polished surfaces on top and bottom
of the sample transfer heat from top and bottom heaters with reduced thermal resistance through
21
surface. A reference calorimeter is placed under the lower plate, which acts as a heat flux
transducer. The heat sink at the bottom avoids excessive temperature from the system. The
sample is compressed in between the polished surfaces, each controlled at different temperatures,
using pneumatic load. The pressure is maintained at 10 psi using pressurized air supply. As an
option, coolant water is circulated through heat sink. A circular low temperature heat insulation
ring is wrapped around the lower stack of the assembly to restrain heat flow to outside
atmosphere. The entire system is maintained in a thermally insulated glass chamber. Unitherm is
completely automatic while testing as the apparatus is completely controlled by a computer. The
test system is hooked to the computer by means of an USB cable.
Considering the operation of the system, the sample to be tested is prepared into a flat
surface on both sides and thermal compound is applied on the sample to reduce thermal
resistance caused due to surface roughness. Then the prepared sample is placed in between two
polished surfaces and a pneumatic pressure of 10 psi is applied on the top portion of the stack.
The sample can be tested in the temperature range from 200 C to 3000 C. For steady state heat
transfer, the user can divide the testing into different zones, called as set point temperatures. In
this thesis the testing was divided into three temperature zones i.e. 60, 80, 1000 C. For higher
thermal conductivity materials, a difference of 50 degrees is recommended for the machine. At
every set point temperature, the system checks for steady state heat flow through the sample and
thermal conductivity is measured.
3.3 Operation principle of Unitherm 2022
By definition thermal conductivity means The material property that describes the rate
at which heat flows with in a body for a given temperature change. For one-dimensional heat
conduction the formula can be given as Equation 3.1
Q = KA
T1 T2
x
3.1
Where Q is the heat flux (W), K is the thermal conductivity (W/m-K), A is the cross- sectional
area (m2), T1-T2 is the difference in temperature (K), x is the thickness of the sample (m).
The thermal resistance of a sample can be given as Equation 3.2
R=
T1 T2
Q/ A
3.2
22
Where R is the resistance of the sample between hot and cold surfaces (m2-K/W).
From Equations 3.1 and 3.2 we can derive that
K=
x
R
3.3
In Unitherm 2022 the heat flux transducer measures the Q value and the temperature
difference can be obtained between the upper plate and lower plate. Thus the thermal resistance
can be calculated between the upper and lower surfaces. Giving the input value of thickness and
taking the known cross sectional area, the thermal conductivity of the samples can be calculated
using Equation 3.3.
3.4 Sample requirement and test procedure
Preparation of test sample is a challenging task. One accurate measurement requires a

sample of dimensional precision of 0.005 inch both in diameter and thickness. A core drill is
employed to cut a two-inch diameter disk and then the disk is machine-milled to appropriate
thickness.
A sample thickness is determined by the relationship between thickness, resistance and
thermal conductivity as defined by Equation 3.3. By assigning an estimated thermal conductivity
value to the testing material specimen with a given thickness, the calculated thermal resistance
should fall into the working window of the equipment, which is 0.002-0.02 m2 K/W for ANTER
Unitherm model 2022. The thickness usually can be considered any value between 50* K to 0.5*
K (mm) with 25mm being the maximum thickness for Unitherm model 2022.
A test begins from sample preparation. Major operation procedures include: 1)
application of thermal compound onto sample surface to reduce the interfacial resistance; 2)
proper loading of sample into the stack assembly so that it completely occupies the gap between
upper and lower stacks; 3) closing the furnace chamber and mounting on protective glass shield;
4) switch on air and water supply; 5) designing of a test program that need input of sample
thickness and temperature segments; 6) switching on heaters before starting a test; 7) after
testing, allowing the unit to cool down to room temperature before removing the protective
shield; 8) cleaning the upper and lower stacks; and 9) data processing. Typically a three-segment
test lasts for three hours.
23
3.5 Determination of fiber volume fraction
Fiber volume fraction of a composite can be calculated using two methods.

1) Burn out method, and 2) Areal method.
3.5.1 Burn-out method
The fiber volume fraction for composites with inorganic fibers such as glass can be
determined by using the standard test method for Ignition loss of cured resins, ASTM D 2584.
Using this method, samples with dimensions 1 x 1 are placed in a crucible and weighed, which
are then placed in a furnace to attain a temperature of 5650 C for three hours, which is sufficient
to burn off the matrix material. After the matrix is burned off, the remaining fiber is weighed.
Using the fiber, resin densities and fiber weight fraction the fiber volume fraction can be
determined.
3.5.2 Areal Method
Areal method is used where organic fibers like carbon burns along with the resin. In this
method the volume of the specimen is calculated using the mass and density of the specimen or
by determining the dimensions of the specimen. The mass of the fiber is calculated by
determining the number of layers of fabric in the specimen and weight of each layer. The fiber
volume can be calculated by using mass of fiber and density of fiber. Finally the fiber volume
fraction is determined by using fiber volume divided by volume of specimen.
For samples like carbon composites, determining the number of layers per unit thickness
after burning may not be accurate as there is a possibility of burning some of the layers while
burning off the matrix. To avoid this problem, the specimen was observed under Scanning
Electron Microscope (SEM) to count the number of layers per unit thickness of 1x 1. Three
different samples were considered as representative volume elements from three different
locations of the sample and observed under SEM. To observe a sample under SEM, the sample
has to be surface finished using different ranges of polishing papers to obtain a clear image of the
sample. In the present study, a total of 18 different pictures were taken using SEM and counted
for number of layers. Typical pictures taken for two different samples were shown in Figure 3.3.
24
Figure 3.3 SEM pictures showing the number of layers and their alignment
25
CHAPTER 4
MATERIALS AND SAMPLE PREPARATION
4.1 Introduction
The objective of this investigation is to determine conductivity properties of FRP

composites in three different directions (i.e. longitudinal, transverse, and through-the-thickness).
The properties are function of composition parameters and process parameters. Herein, the
thermal conductivity measurement in the transverse direction means that a sample is prepared in
such a way that heat flow direction is transverse to primary fiber orientation of the sample;
similarly, the thermal conductivity measurement in the longitudinal direction means heat flowing
along the fiber direction; and the thermal conductivity measurement in the thickness direction
means heat flowing through the thickness direction. The thermal conductivity of an anisotropic
composite material depends on the resin nature, fiber type and architecture, fiber volume
fraction, manufacturing technique, direction of heat flow and operating temperature, leading to a
high degree of complexity.
4.2 Thermal conductivity test matrix
The research proceeded as outlined in Table 4.1, Thermal Conductivity Test Matrix. The
test matrix has included various material parameters and process parameters, leading to a
spectrum of composite samples for their thermal conductivities along 00 and 900 fiber
orientations and through the thickness direction. It should be noted that sample preparation was
the most challenging part of the entire process. Many tools were used specially for sample
preparation such as carbide grit, carbide tipped hole-saw, and diamond tipped hole-saw. In
addition, attention to environmental and health safety issues were also needed.
26
Table 4.1 Thermal Conductivity Test Matrix

Effect of different materials and manufacturing methods
Pultrusion
Compression Molding/Hand lay-up/RTM
Vinyl
Polyester Epoxy
4
8
Glass
Carbon
ester
Tr/ Th/
L T
Th
L T
Th
Th
Th
Th
Th/F,W
L/F
F
F,W
Vinyl ester,
Vinyl ester, 0
Neat Resin
Vinyl ester, Multi-axial glass fabric
0/90
44
Effect of additives and particulate size of additive

Graphite powder
Chopped carbon fiber
10 Wt%
12.5 Wt%
0.15 Wt%
0.4 Wt%
55 75
150
Th
Th
Th
Vinyl ester
Vinyl ester
Carbon nano-tubes
0.25 Wt%
Note:
L
Tr
Th
Longitudinal
Transverse
Through the thickness
F
W
Flange
Web
27
The test samples were prepared in the form of two-inch diameter circular discs
using compression molding and hand lay-up methods. Ideally all samples for threedimensional measurements should be cut from same block. Since one layer of fabric of
density 27 oz/yd2 approximately gives a laminate of thickness 0.04, 100 layers of fabric
would be required to manufacture a three-inch thick block. Technically this poses a great
difficulty in manufacturing such a block in terms of proper alignment of fabric and wet
out.
Typically, FRP laminate has a thickness of 1/8 to . A two-inch diameter disc
was cut from this type of laminate to measure its thermal conductivity with heat flowing
through the thickness direction. In order to prepare samples for the measurements of
thermal conductivity along the 0 degree and 90-degree fiber orientation, 5 to 20 layers of
laminates need to be joined together with Pliogrip to arrive at an overall thickness of 2.5
inch. To ensure the quality of test sample and measurement accuracy, CSM was removed
from the surface of laminates during sample preparation.
Both the above discussed approaches were used to prepare samples in the present
study. As a result, we have successfully prepared a couple of samples that allow for
thermal conductivity measurements in transverse, longitudinal, and through the thickness
directions.
4.3 Resin casting with or without additives
The resins used for this study were vinyl ester, polyester and epoxy. Hetron 922 L
25 Vinyl ester resin was obtained from Ashland and Derakane 8084 was obtained from
Dow chemicals. To prepare vinyl ester neat resin sample, 2% Methyl Ethyl Ketone
Peroxide (MEKP) was used as a catalyst. The epoxy used was Tyfo S Saturant epoxy
consisting of components A and B obtained from FYFE Co. LLC. Part A is epoxy resin
and part B is hardener. To prepare epoxy neat resin sample, part A and part B were mixed
in the proportion of 100:44.5 ratio by weight. For polyester sample, the polyester resin
was mixed with 2% MEKP (catalyst) and 6% Cobalt Napthanate (promoter). The
promoter was mixed in the resin thoroughly before adding the initiator. The reaction
between initiator and promoter caused the resin to become gel. Since the reaction
between initiator and promoter is very fast, an inhibitor was added to increase the gel
28
time. 10% Hydroquinone in menthol was used as inhibitor. Derakane 8084, polyester,
epoxy neat resins were set to cure in 2 inch diameter Teflon molds where as Hetron 922
L 25 vinyl ester was prepared using Resin Transfer Molding (RTM) machine. This
sample was cut into 2-inch diameter disc using hole-saw. Neat resin samples of Vinyl
ester, polyester and epoxy are shown in Figure 4.1.
To determine the influence of additives on the thermal conductivity, graphite
powder GP 55 -B (UCAR Carbon Company, Clarksburg, WV) was added into 8084 vinyl
ester resin at two different proportions, i.e. 10 wt% and 12.5 wt% respectively. The
additive was thoroughly mixed in the resin and molded into 2 inch diameter discs of a
thickness approximately 16 mm using Teflon molds. Carbon nano tubes (CNT) were also
used as additives to prepare 0.25 wt% CNT/8084 vinyl ester samples for thermal
conductivity measurements. Figure 4.2 shows those Derakane 8084 vinyl ester samples
with or without additives.
Figure 4.1 Samples of Epoxy, Vinyl ester and Polyester resins on top row; samples
with different particulate sizes of graphite powder additive, chopped carbon fiber
additives in bottom two rows
29
Figure 4.2 Samples of Derakane 8084 vinyl ester resin with or without additives
In addition to these, chopped carbon fiber was also added as additive to prepare
samples with 0.15 wt% and 0.3 wt% of vinyl ester. To investigate the effect of particulate
size of an additive material, 44micron, 55 micron, 75 micron and 150 micron sized
graphite powders were used to prepare samples. All these additives were thoroughly
dispersed in the resin system using Branson 2510 Sonicator, a machine which uses
ultrasound waves for dispersion. All these samples were molded in the same 2-inch
diameter Teflon mold. These samples with mold and Sonicator are shown in Figure 4.3
Figure 4.3 Sonicator and Teflon mold
30
4.4 E-glass/vinyl ester laminates with or without stitching
5 layers of 24oz 0/90 bi-axial FGI fabric infused with Hetron 922 vinyl ester
samples were prepared by using hand-lay up and compression molding procedures at a
compressive pressure of 100 psi. The molded sample was cut into 2-inch diameter discs
using hole-saw. For stitched samples, 5 layers of 24oz 0/90 bi-axial FGI fabric were
stitched together using 4 ply polyester thread with a pitch of 4 mm and at a spacing of 8
mm along the thickness and then used to prepare samples along with Hetron 922 vinyl
ester resin. To examine the possible effect of surface resin rich layer, samples were also
tested after removal of the surface layer. Figure 4.4 shows a group of FRP composite
samples tested, including stitched and non-stitched laminate samples.
Figure 4.4 Miscellaneous FRP composite samples tested

Left to right: garage door panel, stitched and non-stitched laminate,
Neat 922 Vinyl ester, and bridge deck samples.
4.5 Epoxy based wearing surface
A wearing surface is used to provide friction enabling easy transit of vehicles and
protection for composite bridge decks. The wearing surface consists of fine aggregates or
sand bonded together with a polymer resin. A thin layer (about 3/8) of polymer concrete
wearing surface is usually used for FRP bridge decks. In this study, a wearing surface
made of Transpo T-48 epoxy resin binder was cast using a compact rolling technique and
cut into two- inch circular disks. The rough surface of the samples was sanded to arrive at
31
acceptable smooth surface level for thermal conductivity measurements. One wearing
surface sample is shown in Figure 4.5.
Figure 4.5 Samples of bridge deck, natural fiber, deck with epoxy wearing surface
4.6 Natural fiber /vinyl ester composites
In this study, a natural fiber composite material was tested for its thermal
conductivity in a limited manner because of its growing importance (Colton 2005). This
natural fiber composite plate was made of four layers of natural fiber mat wet out with
vinyl ester by hand-lay up process and cut into two-inch diameter disks for thermal
conductivity measurement in the thickness direction. A photographic view of the sample
is also shown in Figure 4.5.
4.7 FRP garage door panel
Samples were cut from a quarter inch thick pultruded FRP garage door panel.
This panel was made of unidirectional rovings impregnated with polyester resin. Both
samples (with and without removal of surface resin rich layer) were tested, as shown in
Figure 4.4.
4.8 E-Glass Vinyl ester composite block
An E-glass /vinyl ester composite block was prepared and used as a control
sample for thermal conductivity measurements. This block was prepared in the shape of a
cube of 2.5 inch each side. The cube was made by joining two smaller plates using a very
32
thin layer of adhesive (Pliogrip), each plate consisting of 55 layers of 24 oz E- glass bi

axial FGI fabric. Sheets of about 0.2 inch thickness were cut from this cube in
longitudinal, transverse and through the thickness directions. Discs of 2 inch diameter
were cut from those sheets using a hole-saw. The specimens along with the remaining
block were shown in Figure 4.6. In this case, the amount of adhesive (Pliogrip) was
minimized for joining two parts into a block in order to avoid its possible effect on the
resulting thermal conductivity values.
Figure 4.6 E-glass/vinyl ester block and three dimensional samples, carbon tow and
carbon/vinyl ester sheet sample
4.9 Carbon fiber/ vinyl ester composite sheet and block
Both carbon fiber/vinyl ester composite sheet and composite block were made for
thermal conductivity measurements. A tow of carbon fiber was cut into 5-inch squares
and 6 layers of these squares were used for sheet preparation. The carbon fiber /vinyl
ester composite sheet was hand-laid up and then compressed. The sheet was cut into a
circular disc using a hole-saw. The carbon fiber tow and resulting specimen are also
shown in Figure 4.6.
A carbon/vinyl ester composite block was prepared to generate all test specimens
in three directions, i.e. through the thickness, longitudinal and transverse directions. The
block was made in the shape of cuboids of dimensions 6x6x3, consisting of nearly
260 layers of carbon fiber tow sheets of density 0.056 lbs/in3. The tow sheet (tape) was
made of unidirectional fiber (00) and the fibers were supported on a glass fiber scrim. A
33
rectangular wooden mold was used to hold those carbon fiber tow sheets. Hence, the tow
sheets were hand-laid, wetted with vinyl ester and then compression molded into the
block. Three plates of a quarter inch in thickness were cut from the block from each
direction and two-inch diameter circular disks were cut from each plate using a 2-inch
diameter carbide or diamond tipped hole-saw. Thus, six disks for each direction were
prepared giving a total of 18 specimens. Three typical specimens along with the block are
shown in Figure 4.7.
Figure 4.7 Carbon fiber /vinyl ester composite block and specimens along fiber
direction (marked X), in transverse direction (Y) and through the thickness
direction (Z)
To verify the effect of fiber volume fraction on thermal conductivity of

composites, another carbon/vinyl ester composite block with around 300 layers was
prepared. In order to squeeze out the excess resin a compressive force of 410 psi was
applied using compression molding machine. This method resulted in higher volume
fraction and good alignment of fabric through out the composite.
4.10 Prodeck 4 and Prodeck 8 bridge decks
Prodeck 4 is 4 inches in depth, while Prodeck 8 is 8 inches in depth. Both bridge

decks were developed by CFC-WVU researchers and mass-produced through pultrusion
by BRP Inc. These two types of FRP bridge decks were tested extensively for their
thermal conductivities.
Through-the-thickness: Both bridge deck samples were tested for their thermal
conductivity through the thickness direction. For example, half inch thick bridge deck
panel samples from Prodeck 8 with a fabric configuration of 8 layers of 0/+-45 tri-axial
34
fabric TV4000 and 60 glass fiber roving impregnated with vinyl ester were tested with
the surface CSM removed when mill-grinding to the required thickness. One of these
samples is also shown in Figure 4.2. However, a 4 bridge deck sample was tested for its
thermal conductivity through the thickness direction without removing surface CSM in
order to reflect the situation similar to field applications. This sample is also shown in
Figure 4.4.
3-D Evaluation: The thermal conductivity measurements in the longitudinal
direction (i.e. parallel to 0 degree fiber orientation) and transverse direction (i.e. parallel
to 90 degree fiber orientation) as well as through the thickness direction were carried out
using 8 inch depth FRP bridge deck. A section of the bridge deck flange panel was cut
across the width into required number of small pieces with an optimum dimension (about
0.7 inch in width). Then these little pieces were flipped by 90 degrees so as to get the 0
degree fibers in vertical direction and were glued together using Pliogrip, an adhesive
used to join FRP modules. The glued plate was then mill-grinded to a required thickness
of about 0.18 inch. The plate was cut using a hole-saw into two-inch diameter disks and
used for thermal conductivity measurement along the longitudinal direction. Similarly,
specimens were prepared for thermal conductivity measurement along the transverse
direction by cutting the deck panel into little pieces across the length.
Flange and Web Sections: Samples cut from different portions of the bridge
decks were tested along the thickness direction for their thermal conductivity properties.
The samples were prepared from both the web section and flange section of the four-inch
and eight-inch FRP bridge decks. In order to be accommodated with the heat flow meter
model Unitherm 2022, each entire section was ripped across the thickness into three
equal pieces, i.e. top, middle and bottom parts from either web or flange of both 4-inch
and 8-inch decks. The thermal conductivity was determined for each part and then
compared to the value obtained from testing the entire section. Figures 4.8 and 4.9 show
the samples from the 4 inch and 8 inch decks respectively.
35
Figure 4.8 Samples prepared from web and flange sections of Prodeck 4
Figure 4.9 Samples prepared from web and flange sections of Prodeck 8
36
CHAPTER 5
EXPERIMENTAL RESULTS AND DISCUSSION
5.1 Introduction
The objective of the experimental investigation is to determine longitudinal,

transverse and through-the-thickness thermal conductivity of composite materials with
known material compositions and fiber configurations. In addition the thermal
conductivity variation was examined as a function of fiber type, fiber volume fraction,
and other parameters, such as additives and fillers. This chapter presents the results and
discusses thermal conductivity variations as a function of composite material parameters.
5.2 Neat resin castings and resin castings with additives
The thermal conductivity of a composite depends on many parameters including

1) Direction of fiber; 2) Specific gravity of fiber; 3) Moisture content; 4) Distribution of
moisture; 5) Voids or cross fibers; 6) Resin type. The parameters of major influence on
thermal conductivity are fiber volume percentage and conductivity properties of both
resin and fiber. In this present study, thermal conductivities of different resins like Hetron
922 L 25 vinyl ester, Derakane 8084 vinyl ester, polyester, and epoxy were determined
and the results are in agreement with the literature (Callister, 1990). One sample with
Hetron 922 L 25 vinyl ester resin samples was prepared using RTM and other neat resin
samples were prepared using a 2 inch diameter Teflon mold. The results are listed in
Table 5.1 and graphically presented in Figure 5.1.
Additives like graphite powder, carbon nano-tubes and chopped carbon fibers
were directly mixed with the resin and the effect of addition of these additives on thermal
conductivity was determined. Different samples with 10 wt%, 12.5 wt% of graphite
powder, 0.25 wt% of carbon nano-tubes, 0.15 wt% and 0.3 wt% of chopped carbon fibers
were mixed in the resin for testing and results are listed in Table 5.2 and graphically
plotted in Figures 5.2 and 5.3. In addition to the above tests, the effect of particulate size
of additives in Hetron 922 L 25 vinyl ester resin was investigated. Samples with 10-wt %
37
graphite additive with vinyl ester were prepared with particulate sizes 44, 55 , 75
and 150 . The results were listed in Table 5.2.
Table 5.1 Thermal conductivity values of different resins
Thickness
mm
(inch)
Sample
Neat resin Hetron
922 Vinyl ester
(RTM)
Thermal conductivity, W/m K

Segment 1
at 1400 F (600C)
Segment 2
at 1400 F (800C)
Segment 3
at 2120F (1000C)
0.188
0.197
0.201
0.211
0.218
0.221
0.215
0.230
0.235
0.213
0.224
0.228
0.178
0.184
0.192
0.214
0.219
0.224
0.204
0.216
0.219
0.209
0.218
0.222
0.229
0.249
0.256
2.006
(0.079)
Neat resin Hetron

922 Vinyl ester
Derakane 8084 neat
resin
Neat Polyester resin
Neat Epoxy
7.106
(0.2797)
9.15
(0.3602)
Average
4.594
(0.18085)
7.569
(0.298)
6.769
(0.2665)
Average
8.052
(0.317)
0.3
0.25
0.2
0.15
Hetron 922 Vinyl ester(RTM)

Hetron 922 vinyl ester
Derakane 8084 Vinyl ester
Epoxy
Polyester
0.1
0.05
0
40
50
60
70
80
90
100
110
Temperature, degree C
Figure 5.1 Thermal conductivity variations of different resins
38
Table 5.2 Thermal conductivity values of vinyl ester resins with different additives
and particulate size of additive
Sample
Derakane 8084 neat
resin
10 wt% graphite
powder/8084
12.5 wt% graphite
powder/8084
0.25 wt% carbon nano
tubes/8084
0.15wt% chopped
carbon fiber/Hetron
Vinyl ester resin
0.3wt% chopped
carbon fiber/ Hetron
Vinyl ester resin
44 size 10wt%
graphite
powder/Hetron Vinyl
ester resin
55 size 10wt%
graphite
powder/Hetron Vinyl
ester resin
75 size 10wt%
graphite
powder/Hetron Vinyl
ester resin
150 size 10wt%
graphite
powder/Hetron Vinyl
ester resin
Thickness
mm
(inch)
4.594
(0.18085)
16.021
(0.6307)
16.186
(0.6372)
8.528
(0.3357)
6.985
(0.275)
5.709
(0.2247)
Average
6.896
(0.2715)
7.7128
(0.3042)
Average
10.528
(0.4145)
12.605
(0.4962)
Average
9.646
(0.3797)
11.911
(0.4689)
Average
7.683
(0.3025)
4.807
(0.1892)
Average
9.106
(0.3585)
4.54
(0.1787)
Average

Segment 1
at 1400 F (600C)
Segment 2
at 1400 F (800C)
Segment 3
at 2120F (1000C)
0.178
0.184
0.192
0.358
0.368
0.361
0.496
0.536
0.515
0.239
0.198
0.192
0.225
0.226
0.229
0.209
0.214
0.224
0.217
0.220
0.227
0.224
0.228
0.236
0.224
0.231
0.243
0.224
0.230
0.234
0.414
0.432
0.428
0.394
0.408
0.42
0.404
0.420
0.424
0.423
0.438
0.448
0.384
0.398
0.397
0.404
0.418
0.423
0.351
0.362
0.374
0.341
0.366
0.38
0.346
0.364
0.377
0.352
0.354
0.358
0.318
0.338
0.355
0.335
0.346
0.357
39
The results show that the thermal conductivity values of vinyl ester, polyester,
and epoxy have nearly the same values. As the RTM made Hetron 922 vinyl ester sample
has little air voids, it is showing lower thermal conductivity than the one made in Teflon
mold. Addition of graphite powder significantly increases the thermal conductivity. For
example, 10 wt% and 12.5 wt% respectively result in 80% and 170% increase in thermal
conductivity over neat resin for temperatures ranging from 60-1000 C. However, for
carbon nano-tubes with vinyl ester 8084 samples, slight increase in thermal conductivity
is noted at the temperature segment of 600C when compared to the neat vinyl ester resin;
but the thermal conductivity almost remains unchanged at the temperature range of 800C
to 1000C. This could have happened because addition of carbon nano-tubes makes the
sample brittle and hairline cracks were formed in the sample under heat and pressure.
These cracks create air voids thus reducing the heat capacity and corresponding thermal
conductivity. These results are tabulated in Table 5.2 and plotted in Figure 5.2.
Vinyl ester resin samples with 10 wt% of graphite powder were tested for
different graphite particulate sizes 44, 55 , 75 and 150 ; the test results are given in
Table 5.2. Figure 5.3 shows the graphical representation of variation in thermal
conductivity values for varying particle size for same weight fraction of the additive. Two
samples of each kind were tested for replication and the data were repetitive. The
addition of finer grade additives increases the thermal conductivity of a sample than that
of coarse grade additives. The reason is that the finer particles tend to get in contact with
more resin molecules i.e. higher surface area in case of finer particles than the coarser
particles in the resin.
Addition of chopped carbon fiber at 0.15 wt% and 0.3 wt% increased the thermal
conductivity by nearly 12.5 % and 19% respectively, but further increase in wt% (say
after 0.3 wt%) of this additive increases the viscosity of the resin. As a result, sample
preparation to a required shape with this resin system becomes much more difficult and
also there is a possibility of getting micro cracks in the sample.
40
0.6
0.55
0.5
0.45
Neat Derakane 8084 Vinyl ester
10 wt% graphite powder
12.5 wt% graphite powder
0.25 wt% carbon nanotubes
0.4
0.35
0.3
0.25
0.2
0.15
40
60
80
100
120
Temperature, degrees C
Figure 5.2 Thermal conductivity variations with graphite additives, with carbon
nano-tubes in Derakane 8084 vinyl ester resin
0.6
0.55
0.5
0.45
0.4
0.35
0.3
0.25
0.2
44 micron sized particles

55 micron sized particulte
75 micron sized particulate size
150 micron sized particulates
0.15
0.1
0.05
0
40
50
60
70
80
90
100
110
Temperature, Degrees C
Figure 5.3 Thermal conductivity variations with change in particulate size of

graphite additives in Hetron 922 vinyl ester resin
41
0.25
0.24
0.23
0.22
Neat Hetron 922 Vinyl ester

0.15 wt% chopped carbon fiber
0.3 wt% chopped carbon fiber
0.21
0.2
0.19
0.18
40
60
80
100
120
Temperature, degrees C
Figure 5.4 Thermal conductivity variations with chopped carbon fiber additives in
Hetron 922 L vinyl ester resin
5.3 E-glass /vinyl ester laminates with or without stitching
Thermal conductivity measurements of E-glass/Vinyl ester samples with third

dimensional reinforcement (i.e. introducing fiber along the thickness direction by
stitching the fabric) and without third dimensional reinforcement are reported in Table
5.3. Thermal conductivity data for these samples were obtained by testing in through-thethickness direction. For glass/vinyl ester composites, manufacturing method has little
effect on thermal conductivity. Experimental results show that non- stitched samples have
higher thermal conductivity than stitched samples. The potential cause for this variation
in thermal conductivity might be due to air voids. Two potential reasons are suggested for
formation of air voids: 1) stitching closely packs the fabric layers, leaving small air
pockets between the layers, and applied resin might not seep through the air gaps fully,
these air pockets hinder full conductivity; and 2) stitching forms holes and may even
form a thin interfacial gap between the thread and resin due to inadequate interfacial
compatibility acting like air void and in turn reducing the thermal conductivity. These
factors potentially change thermal conductivity by around 0.05 W/ m-K. The removal
of the top resin rich layer of the samples improved thermal conduction as it allows the
fabric layers of the sample to get in direct contact with the heating plates of the testing
42
facility. For all samples thermal conductivity increases slightly with test increased
temperature.
Table 5.3 Thermal conductivity of E-glass /vinyl ester laminates
Sample
Non stitched
laminate, asmolded
Non stitched
laminate with
surface removal
Stitched
laminate, asmolded
Stitched laminate
with surface
removal

Segment 1 Segment 2 Segment 3
at 1400 F
at 1760 F
at 2120F
0
0
(60 C)
(80 C)
(1000C)
Manufacturing
method/ fabric
configuration
Thickness,
mm
Compression/
0/90 fabric
2.7432
0.372
0.390
0.413
Compression/
0/90 fabric
2.4892
0.386
0.406
0.421
Compression/
0/90 fabric
2.6670
0.302
0.336
0.378
Compression/
0/90 fabric
2.4892
0.328
0.347
0.369
5.4 Miscellaneous composite samples
Thermal conductivities were determined for composite samples including epoxywearing surface, natural fiber/vinyl ester composite, FRP garage door panel, urethane/
glass fiber pultruded sample, carbon/vinyl ester pultruded samples. These results are
tabulated in Table 5.4.
The epoxy-wearing surface facilitates better heat conduction at the top surface of
FRP bridge deck. The surfaces of the epoxy-wearing surface samples are coated with a
thin layer of sand aggregate and that sand layer is responsible for increase in heat
conductivity. As a result, epoxy-wearing surface showed nearly twice the thermal
conductivity of the FRP deck. This information is also needed to promote the field
application of infrared thermography as a NDE tool leading for better quantitative
interpretation of the results.
43
The results indicate that natural fiber composites have an extremely low thermal
conductivity, much lower than neat vinyl ester, demonstrating excellent thermal
insulation characteristics..
Urethane pultruded panels are showing more promising characteristics like fire
retardance compared to other economically available pultruded products. A sample of a
pultruded urethane/ glass fiber composite from BRP Inc. was tested and the result
represents the high thermal conductivity of urethane compared to vinyl ester.
A carbon/vinyl ester unidirectional pultruded sample from Creative Pultrusions
Inc. was also tested to check the effect of manufacturing method on thermal conductivity
across the thickness of the sample. It shows that the pultruded sample is more conductive
than hand laid /compression molded samples. This might be because of pultrusion
process where fiber being straight, well aligned and the additives in the resin (data not
available) etc. Furthermore pultrusion results in better fiber packing than hand lay-up,
which attributes to higher conductivity.
Table 5.4 Thermal conductivity of miscellaneous composites

Thickness
mm
Sample
information
5.6388
Natural fiber
composite
FRP door panel,
as-pultruded
Sample
Epoxy based
wearing surface
Pultruded
Carbon sample
Pultruded
Urethane sample
Segment 1
at 1400 F
(600C)
Segment 2
at 1760 F
(800C)
Segment 3
at 2120F
(1000C)
T-48 epoxy
resin
0.630
0.689
0.737
2.3114
Compression
natural fiber
mat
0.123
0.128
0.136
2.9464
Pultrusion
uniroving
0.331
0.356
0.373
Pultrusion
uniroving
0.41
0.441
0.485
0.392
0.417
0.442
0.392
0.420
0.446
0.392
0.419
0.444
4.75
(0.187)
6.337
(0.2495)
6.337
(0.2495)
Average
Pultrusion
Multi axial
glass fiber
44
5.7 E-glass/vinyl ester composite block
The thermal conductivity values of E-glass/vinyl ester composite blocks in

longitudinal, transverse and through-the-thickness directions are listed in Table 5.5. It is
observed that the thermal conductivity in through-the-thickness direction is higher than
that in the transverse direction, which in turn is higher than the conductivity in
longitudinal direction. The conductivity value is supposed to be higher in longitudinal
direction. However, in this case, bi-axial fabric might have led to this anomaly. Further
more, the sample preparation also influences the results. After cutting the sample in 0 and
90 directions the fiber would be in the direction of heat flow and these fibers form a
corrugated shape on the top and bottom surfaces. According to the sample requirements
of the test facility, these surfaces are supposed to be smooth with a tolerance of 0.005
inch, which was difficult to achieve with the available resources. However, the thermal
conductivity value of the E-glass/vinyl ester block showed no significant change with
respect to the direction of fiber. The fiber volume fraction for this block was determined
as 49.8%. The low thermal conductivity of balanced biaxial E-glass fabric in 0 and 90
directions (i.e. in horizontal plane) resulted in heat conduction to be nearly uniform in
both longitudinal and transverse directions.
45
Table 5.5 Thermal conductivities of E-glass/vinyl ester composite block samples
Heat Flow Direction

Through the thickness
Transverse
( 0 fiber)
Longitudinal
(// 0 fiber)
Thickness
mm
(inch)
5.023
(0.1977)
5.855
(0.2305)
5.467
(0.2152)
5.81
(0.2287)
Average
5.156
(0.203)
5.512
(0.217)
5.156
(0.203)
Average

Segment
Segment
Segment 3
1
2
at 2120F
0
0
at 140 F
at 140 F
(1000C)
(600C)
(800C)
0.322
0.343
0.353
0.256
0.280
0.319
0.307
0.326
0.348
0.276
0.292
0.323
0.280
0.299
0.330
0.255
0.281
0.310
0.235
0.256
0.302
0.247
0.267
0.288
0.246
0.268
0.300
5.8 Carbon fiber /vinyl ester composites
The thermal conductivity values of carbon fiber/vinyl ester composite materials in

longitudinal, transverse and through-the-thickness directions are listed in Table 5.6. Note
that carbon fibers are all unidirectional.
The following observations are made from the test results of carbon fiber/vinyl
ester composite material: 1) the thermal conductivities of carbon composites are the
highest along the fiber direction, medium in the transverse direction and lowest in
through-thethickness direction; 2) carbon composites have significantly different
thermal conductivity values in three directions strongly anisotropic. This is distinctively
different from E-glass composite materials for which thermal conductivities in three
directions are close - almost isotropic; 3) thermal conductivity of carbon composites
through the thickness direction is close to that of neat resin, indicating that thermal
property of the resin plays a major role in this direction; 4) Carbon composites result in
lower thermal conductivity values in through-the-thickness direction than glass fiber
46
composite. This observation is in accordance with the results published in the literature
(Gowayed, 1994); and 5) As shown in Table 5.6, through-the-thickness thermal
conductivity of carbon/vinyl ester composite block is consistent with that of carbon/ vinyl
ester composite sheet.
Carbon fiber is orthotropic in nature and the conductivity of the carbon fiber
along the axis would be higher than in other directions because of the basal plane
formation along the axis. These basal planes are closely packed in the order of angstrom
units, which helps in transferring heat quickly and by virtue of its property carbon fibers
contracts upon heat due to negative expansion coefficient further reducing the distance
between the basal planes. Thus thermal conductivity increased linearly in longitudinal
direction in the measured temperature range of 60-1000 C. In transverse direction,
conductivity would be much lower than that of in longitudinal direction due to lack of
basal planes. Moreover, carbon sheets would be sized to have good compatibility with the
resin, and this sizing causes an insulating layer and thus hinders heat flow in case of
through the thickness direction. This glossy sizing over the carbon tow might be the
reason for lower conductivity of carbon composite in through the thickness direction than
that of a glass fiber composite.
To test the effect of fiber volume fraction of a composite on thermal conductivity,
another carbon/vinyl ester block was made with higher fiber compactness and tested. The
results are also included in Table 5.6. During the sample preparation, sample for heat
flow in transverse direction in Carbon block II was damaged a little at the edges and
cracks were formed around the periphery. These issues lowered the conductivity of the
sample in transverse direction. The fiber volume fraction of second block (75%) was
more than the first block (60%) and hence, the thermal conductivity along zero (along the
fiber) direction was nearly double and the thermal conductivity through-the-thickness
direction increased by 13%. The results are compared graphically in Figure 5.5.
The fiber volume fractions of these samples were approximated using SEM and
areal method of finding fiber volume fraction. The fiber volume fractions for the first and
second block were found through SEM to be around 60%, 75% respectively. The pictures
representing number of layers and fiber alignment for each sample are shown in Figure
3.3.
47
Table 5.6 Thermal conductivities of carbon fiber/vinyl ester composite blocks I, II
Heat flow
direction
Thickness
mm
(inch)
Thickness
1.816
(0.0715)
Thickness
6.612
(0.2603)
5.639
(0.222)
Average
Longitudinal
(// 0 fiber)
7.163
(0.282)
6.764
(0.2663)
Average
Thickness
*
0.291
0.306
Carbon/Vinyl ester Composite Block I

6.934
0.232
0.270
(0.273)
6.934
0.245
0.262
(0.273)
Average
Transverse
( 0 fiber)

Segment 1
Segment 2
Segment 3
0
0
at 140 F
at 140 F
at 2120F
(600C)
(800C)
(1000C)
20.269
(0.798)
Longitudinal
(// 0 fiber)
20.073
(0.7903)
20.25
(0.7972)
Average
0.289
0.282
0.239
0.266
0.286
0.471
0.506
0.544
0.457
0.501
0.542
0.464
0.504
0.543
0.966
1.205
1.379
0.785
0.965
1.231
0.876
1.085
1.305
Carbon/Vinyl ester Composite Block II

19.964
0.296
0.297
(0.786)
20.129
0.313
0.323
(0.7925)
Average
0.305
0.310
Transverse
( 0 fiber)
0.323
0.312
0.334
0.323
0.426
0.442
0.453
1.904
2.146
2.603
1.367
1.643
2.211
1.636
1.895
2.407
*Sample damaged a little at the edges and cracks were formed around the periphery during sample
preparation
48
Thermal conductivity, W m/K
2.6
2.5
2.4
2.3
2.2
2.1
2
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
Carbon block II along the fiber direction

Carbon block II through the thickness
direction
Carbon block II in transverse direction
Carbon block I along the fiber
Carbon block I through the thickness
direction
Carbon block I in transverse direction
20
40
60
80
100
120
Temperature, Degrees C
Figure 5.5 Thermal conductivity variations for Carbon/Vinyl ester composites

5.9 Prodeck 4 and Prodeck 8 bridge deck samples
The thermal conductivities of FRP bridge deck samples are listed in Tables 5.7 5.11. 4-inch deep FRP bridge deck material shows slightly lower thermal conductivity
than that of an 8-inch deep FRP bridge deck (as seen in Table 5.6 in the thickness
direction). It is observed that the thermal conductivity of the bridge deck samples varied
from 0.34 W/m K to 0.42 W/m K. As these samples were fetched from the bridge deck
samples across the thickness from different locations, there would be a variation in fiber
volume fraction, fiber orientation, and fiber architecture. This explains the variation of
thermal conductivities at different sections of the bridge deck. The overall thermal
conductivity of the bridge deck could be calculated using these values. Considering an 8
inch bridge deck composite, it has a thermal conductivity value of 0.35 0.05 W/m K in
through-the-thickness and longitudinal directions.
49
Table 5.7 Thermal conductivity of FRP bridge deck samples in three directions
Sample
8 deck with CSM

removed
4 deck with CSM
Thickness
mm
(inch)
4.6228
(0.182)
4.5974
(0.183)
4.9784
(0.190)
5.1816
(0.190)

Heat flow
direction
Segment 1
at 1400 F
(600C)
Segment 2
at 1400 F
(800C)
Segment 3
at 2120F
(1000C)
Thickness
0.375
0.388
0.401
0.325
0.345
0.362
0.289
0.306
0.331
0.300
0.331
0.365
Transverse
(// 90 fiber)
Longitudinal
(// 0 fiber)
Thickness
Each reported value is an average of three or four runs of measurements; it is

shown that the longitudinal thermal conductivity is slightly lower than that along the
transverse direction. These results are consistent with the results obtained from section
5.7. This might be due to the presence of fibers in different directions in longitudinal
direction instead of having unidirectional fibers. The reason for higher conductivity
across the thickness and lower conductivity along the fiber direction in the case of Eglass/Vinyl ester has to be further researched.
However, the difference in thermal
conductivity value among three directions is not significant. Although there is a variation
in conductivity value for different directions, the thermal conductivity of E-glass/vinyl
ester composites shows a weak dependence on the fiber orientation. This observation is
attributed to the following reasons: 1) glass fiber has nearly the same thermal
conductivity along the transverse direction as that of longitudinal direction; 2) glass
fibers thermal conductivity is only slightly higher than that of vinyl ester; 3) pultruded
structural parts have a high fiber volume content; and 4) pultruded structural parts have a
balanced fiber content distribution both along the transverse and longitudinal directions.
50
Table 5.8 Thermal conductivity values of 4-inch deck web section samples
Sample
Bottom
Section
Middle
Section
Top
Section
Thickness
mm
(inch)
4.68
(0.1842)
4.997
(0.1967)
4.743
(0.1867)
Fiber
volume
fraction,
%
Segment 1
at 1400 F
(600C)
Segment 2
at 1400 F
(800C)
Segment 3
at 2120F
(1000C)
51.83
0.305
0.323
0.336
53.67
0.322
0.351
0.38
46.68
0.264
0.313
0.382
Table 5.9 Thermal conductivity values of 4-inch deck flange section samples
Sample
Thickness
mm
(inch)
Bottom
Section
Middle
Section *
Top
Section
5.194
(0.2045)
5.08
(0.2)
4.896
(0.1927)
Fiber
volume
fraction,
%
Segment 1
at 1400 F
(600C)
Segment 2
at 1400 F
(800C)
Segment 3
at 2120F
(1000C)
60.66
0.227
0.287
0.343
53.82
0.175
0.19
0.208
58.33
0.32
0.334
0.35
*indicates a problem while testing and to be tested again with a new sample
51
Table 5.10 Thermal conductivity values of 8-inch deck web section samples
Sample
Bottom
Section
Middle
Section
Top
Section
Thickness
mm
(inch)
4.534
(0.1784)
4.909
(0.1932)
4.813
(0.1895)
Fiber
volume
fraction,
%
Segment 1
at 1400 F
(600C)
Segment 2
at 1400 F
(800C)
Segment 3
at 2120F
(1000C)
53.46
0.304
0.340
0.36
54.20
0.395
0.417
0.427
59.08
0.312
0.348
0.381
Table 5.11 Thermal conductivity values of 8-inch deck flange section samples
Sample
Bottom
Section
Middle
Section
Top
Section
Thickness
mm
(inch)
5.023
(0.1978)
4.823
(0.1845)
5.093
(0.2005)
Fiber
volume
fraction,
%
Segment 1
at 1400 F
(600C)
Segment 2
at 1400 F
(800C)
Segment 3
at 2120F
(1000C)
57.27
0.335
0.368
0.396
61.23
0.335
0.368
0.391
55.36
0.376
0.395
0.421
52
CHAPTER 6
VALIDATION OF MODEL PREDICTIONS
6.1 Introduction
Analytical or numerical models help to predict the properties of a material without

conducting any experiments. However, these models have to be extensively validated
with experimental data before adopting them in practice on a large scale. Most of the
literature on composite materials (anisotropic) dealt with mechanical properties and very
few models were developed to predict thermal conductive properties in different
directions. Experimentally determined mechanical properties can be verified with the
previously published analytical models; however limited models on thermal conductivity
are available for cursory verification. Most of the literature predicts through-the-thickness
effective thermal conductivity, while thermal conductivity along the fiber direction in a
composite can be predicted using rule of mixtures. In this chapter, experimental results
obtained for the E-glass/vinyl ester samples are validated for through-the-thickness
effective thermal conductivity and longitudinal effective thermal conductivity.
6.2 Analytical models and validation
Thermal conductivities through-the-thickness and longitudinal directions are

verified using the theoretical models described in Chapter 2. The equations from these
models are tabulated again in Table 6.1 for a quick reference. In this study, thermal
conductivity considered for validation purpose is the value obtained at a temperature of
600 C. The thermal conductivity of the vinyl ester matrix was experimentally determined
as 0.213 W/m K and this value is repetitive and also in accordance with the data provided
by the manufacturers data sheet (www.ashland.com). The thermal conductivity of Eglass fiber was given as 0.5 W/m K and these data were provided by the manufacturer
(www.fgi.com). As the thermal conductivity value of the FORCA tow sheets used in
making Carbon/Vinyl ester block was not available, an approximate thermal conductivity
value for PAN based Carbon fiber was considered from the literature (Gowayed, 1995)
and the data from AMOCO Performance Products. Thermal conductivity along the axis
of the carbon (PAN) fiber was considered as 8 W/m-K. However, the thermal
53
conductivity in transverse direction will be 10 to 15 times less than that of the

conductivity value in along the fiber direction (Gowayed, 1995 and www.cytec.com). In
the present case thermal conductivity in transverse direction was taken as 15 times lower
than the conductivity in axial direction, which is 0.533 W/m K. These assumed values are
not for validation of the experimental data obtained in this study; but to verify how the
theoretical models perform at higher fiber volume fractions like 60 % or 75% as in case
of carbon/vinyl ester composite and at higher thermal conductivities like 8 W/m K.
Table 6.1 Theoretical models for transverse effective thermal conductivity

S.No
6.1
Author
Springer and
Model
Vf
K22 = Km 1 2
+

Notes
1
4

B
B2Vf
1
1 B Vf
tan1
2
1 + B Vf
Tsai
K
m
where B 2 K 1
f
Hashin
6.2
(Cylindrical
assemblage model)
6.3
6.4
6.5
Caruso
Halpin Tsai
Inverse rule of
mixtures
K f V f + K m (1 + Vm )
Ke = K f
K f (1 + Vm ) + K mV f
KT = 1-
V f Km
Vf * K m
K
1 Vf (1 m )
K fl
Assumes matrix and fiber as

parallel and series as in
electrical circuits.
Assumes fiber patterns as
square,
cylindrical
and
elliptical shapes
Gives upper and lower
bound
for
transverse
conductivity
Considers phase geometry
Considered square lattice
Unidirectional fibers
k f
k 1
1 + V f
m
k2 = km
; =
k f
1 V f
k +
m
Widely
used
thermal
transport
formula
for
transverse conductivity
Useful for different shapes of
filaments, =1 for circular
fibers
Vf
V
1
=
+ m
KT K f Km
Derived from rule of

mixtures to calculate for
transverse
thermal
conductivity
Does not consider voids,
fabric overlap
54
The samples considered for validation are E-glass vinyl ester block, Carbon/Vinyl
ester blocks I and II as described in Chapter 5. The details about the samples are given in
Table 6.2. Kfl, Kft, Km represents thermal conductivity of fiber along the axis of the fiber,
transverse to the fiber and conductivity of the matrix respectively. Vf and Vm represent
the fiber and matrix volume fractions respectively.
Table 6.2 Parameters of the samples verified using theoretical methods
Kfl ,
Kft
Km
W/m K
W/m K
W/m K
E glass/Vinyl ester
0.5
0.5
Carbon/Vinyl ester I
Carbon/Vinyl ester II
Sample
Vf , %
Vm , %
0.213
53.55
46.45
0.533
0.213
60
40
0.533
0.213
75
25
55
Table 6.3 Comparison of experimental and theoretical values in (through the

thickness effective thermal conductivity) for E glass/Vinyl ester sample and
Carbon/Vinyl ester samples
E glass/Vinyl
ester , W/m k
Carbon/Vinylester I,
W/m k
Carbon/Vinylester II,
W/m k
Experimental
0.322
0.239
0.304
Springer Tsai
0.307
0.354
0.410
Cylindrical
assemblage model,
Hashin
0.330
0.360
0.415
Caruso model
0.326
0.356
0.412
Halpin Tsai
0.330
0.360
0.415
Inverse rule of
mixture
0.307
0.332
0.388
Method/Model
Note: The above data for Carbon composite is used for comparison purpose between models but
not between models and experimental results as the technical data for Carbon fiber is not
available.
The experimental results for longitudinal effective thermal conductivity were verified
using rule of mixtures. According to the rule of mixtures (ROM), the overall thermal
conductivity of a composite can be given by Equation 6.6
K 1 = K f V f + K m Vm
6.6
Where K 1 is the overall longitudinal thermal conductivity of the composite, K f , K m are
the individual thermal conductivities of the fiber and matrix respectively and V f , Vm are
the fiber volume fraction and matrix volume fraction of the composite. Comparison
between experimental and theoretical values are shown in Table 6.4
56
Table 6.4 Comparison of experimental and theoretical models for E glass/Vinyl ester sample and
Carbon/Vinyl ester samples for longitudinal effective thermal conductivity using rule of mixtures
Sample
E glass/
Vinyl ester
Carbon/
Vinyl ester I
Carbon/
Vinyl ester II
Kfl ,
Km
W/m K
W/m K
0.5
Vf , %
Vm , %
0.213
53.55
0.213
0.213
Experimental Theoretical
W/m K
W/m K
46.45
0.246
0.367
60
40
0.876
4.885
75
25
1.636
5.650
6.3 Discussion
The experimental results obtained from E glass/Vinyl ester sample in through-thethickness direction are in good agreement (~10%) with the theoretical models. Along
longitudinal direction, rule of mixtures was applied and that value is slightly more than
the experimental value. In general, rules of mixture over estimate the experimental value
and inverse rule of mixture under estimates (Barbero, 1998). This fact was proven with
this comparison.
In case of carbon composite, the assumed conductivity values of fiber in throughthe-thickness direction shows that the theoretical models are presenting reasonably close
values even for high volume fraction and high thermal conductivity (values obtained
from theoretical models were not compared with experimental data). The comparison
between experimental and theoretical values in both through-the-thickness and in
longitudinal direction reveals that the assumed value for thermal conductivity of carbon
fiber along the axis of the fiber and transverse to the fiber are not appropriate.
57
CHAPTER 7
CONCLUSIONS AND RECOMMENDATIONS
7.1 Introduction
In this chapter the conclusions are drawn from data obtained from literature and
our experimental results. Validation of experimental results with available models in
literature are being discussed along with the recommendations for future work
7.2 Conclusions
Chapter 2
1. In case of thermal characterization of composite materials, few theoretical and
limited experimental methods are available.
2. Some theoretical models available are of no good use for the validation of
experimental results, as they require various properties of fibers and matrix,
which are difficult to acquire for practical purpose.
3. Most of the models do not consider for thermal resistance, interaction between
fiber and matrix and fiber orientation.
Chapter 5
4. From section 5.2, thermal conductivity values of three different matrices
Polyester, Vinyl ester and Epoxy were given as 0.209, 0.213, and 0.229
respectively thus showing nearly the same thermal conductivity values.
5. From section 5.2, addition of 10 wt% and 12.5 wt% of graphite additive in neat
vinyl ester resin increased the conductivity by 88% and 170% respectively.
Addition of 0.15 wt% and 0.3 wt% of chopped carbon fibers in neat vinyl ester
resin resulted in increase of conductivity values by 12.5% and 19% respectively.
It was also observed that the finer particulates are better (by ~19%) in increasing
the conductivity than the coarser particulates in an additive at the same
concentration.
58
6. From section 5.7, in case of bi-axial E-glass/Vinyl ester composite, the

conductivity is nearly 18% more in through-the-thickness direction than in
transverse and longitudinal directions.
7. From section 5.8, thermal conductivity along longitudinal direction in case of
Carbon/Vinyl ester composite is almost twice the conductivity in transverse and
four times greater than through-the-thickness direction. Further more, increase in
fiber volume fraction from 60% to 75% almost doubled the conductivity (from
1.035W/m K-2.407 W/m K) along longitudinal direction and showed significant
increase of conductivity in through-the-thickness direction.
8. From section 5.9, in case of bridge deck samples, Prodeck 4 has lower
conductivity value (0.3 W/m K) when compared to Prodeck 8 (0.375 W/m K).
Chapter 6
9. From Tables 6.2 and 6.3, experimental results obtained from E-glass/Vinyl ester
sample in longitudinal and through-the-thickness direction are in good agreement
with the values obtained from theoretical models. In longitudinal direction, rules
of mixture showed an upper bound value and in through-the-thickness direction
inverse rule of mixture showed a lower bound experimental data.
7.3 Recommendations for future work
1. Determining three dimensional thermal conductivity behaviors of uni-directional

glass fiber composites so that it clarifies the confusion caused by the results
obtained from bi-axial glass fiber composites.
2. Testing the samples with wide range of volume fractions with adequate
knowledge about conductivity value of fiber and matrix.
3. Establishing thermal conductivity for a wide range of temperature from room
temperature to maximum service temperature.
4. Verification of effect of fiber orientation by testing composites with different
orientations along with uni-directional and cross-ply composites.
59
5. Control over manufacturing methods to reduce anomaly like fiber distortion, void
content and to attain required fiber volume fractions.
6. Usage of precision tools to maintain required surface finish of the sample to
acquire more accurate results.
60
BIBLIOGRAPHY
Alcaraz, D., J.A. Moreno and F.Alhama (2003) Thermal conductivity in continuous metal
matrix composites with random distributions, Material Science Forum, Vols. 426-432,
2169-2174
ANTER Corporation technical notes (2003) http://www.anter.com/tech_notes.htm
ASM Handbook, Volume 21, Composites, 2001
Barbero, Ever J. (1998) Introduction to Composite Materials Design, Taylor & Francis
Behrens, Ernest (1968) Thermal conductivities of composite materials, J. Composite
Materials, Vol.2, No.1, 2-17
Callister, D Williams Jr. (1990) Material Science and Engineering An Introduction, John
Wiley and Sons, Inc
Caruso, J. and Cristos C. Chamis (1986) Assessment of simplified composite
micromechanics using three dimensional finite element analysis, J. Composites
Technology and Research, Vol.8, No.3, 77-83
Colton, Jonathan (2005) Natural fiber-polyolefin composites (Presentation)
http://www.me.gatech.edu/jonathan.colton/me4793/natfiber.pdf
Donald, J. J and John. W. Walkinshaw (1988) Flash pulse measurement for off axis
thermal conductivity of carbon composite material, American Chemical Society.
Gowayed, Yasser and Jhy-Cherng Hwang (1995) Thermal conductivity of composite
materials made from plain weaves and 3-D weaves, Composites Engineering, Vol. 5(9),
1177-1186
Han, L.S. and A. A. Cosner (1981) Effective thermal conductivities of fibrous
composites, Journal of Heat Transfer, Vol.103, 387-392
Hashin, Z. (1979) Analysis of properties of fiber composites with anisotropic
constituents. ASME Applied Mechanics Vol. 46, 543-550
Hiroshi, Hatta and Minoru Taya (1985). Effective thermal conductivities of a misoriented
short fiber composite. Journal of Applied Physics, Vol. 58 (7), 2478-2486
James W.B, Wostenholm H.G, Keen S.G and McIvor D S (1987), Prediction and
Measurement of Thermal Conductivity of Composite Materials, Journal of Physics D,
Vol. 20, 261-268
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Joshi, V.S., Drzal, T.L., Mohanty, K.A, and Arora, S (2004), Are Natural Fiber
Composites Environmentally Superior to Glass Fiber Reinforced Composites?,
Composites Part A, Vol 35, 371-376
Lim, T. C. (2002) Unified practical bounds for the thermal conductivity of composite
materials, Materials Letters, 54, 152-157
Mirmira, Srinivas RangaRao (1999). Thermal conductivity of fibrous composites:
experimental and analytical study. Ph D Dissertation, Texas A&M, USA
Mottaram, J. T. and R. Taylor (1987). Thermal conductivity of fiber- phenolic resin
composites, Part II: numerical evaluation. Composite Science and Technology, Vol.29,
211-232
Muralidhar, K. (1989) Equivalent conduction of a heterogeneous medium, International
Journal of Heat Mass Transfer, Vol.33, No.8, 1759-1766
Parker, W.J., R.J. Jenkins, C.P. Butler, and G.L. Abbott (1961) A flash method of
determining thermal diffusivity, heat capacity, and thermal conductivity, Journal of
Applied Physics, 32 (9), 1679-1684
Rouison, David., Varejka, Milena and Picot, Jules (2002), Thermal Sensor to Monitor
Mechanical Properties in Polymer/Fiber Composite Molding, The Canadian Journal of
Chemical Engineering, Vol.80, 943-947
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2003, 84-88
62

Thermal Conductivity of FRP Composites

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Thermal Conductivity Characterization of Composite Materials

Thesis Submitted to the

Dr. Kenneth Means, Ph.D., Chair

Department of Mechanical Engineering

Keywords: Thermal conductivity, Three Dimensional Thermal Conductivity,

Thermal Conductivity Characterization of Composite Materials

MATERIALS AND SAMPLE PREPARATION ..............................26

4.4 E-glass/vinyl ester laminates with or without stitching .............................................. 31

EXPERIMENTAL RESULTS AND DISCUSSION .........................37

VALIDATION OF MODEL PREDICTIONS ..................................53

CONCLUSIONS AND RECOMMENDATIONS .............................58

Table 4.1 Thermal Conductivity Test Matrix ............................................................................... 27

Effect of heat flow direction

Fiber volume fraction

Effect of additive materials and particle size of additive

Different manufacturing methods

fully computerized and equipped

thermal conductivity of FRP composites. Chapter 6 compares experimental thermal conductivity

importance/significance in the thermal property analysis of an engineering system. Thermal

represents change in temperature across the thickness and negative

2.3.5.2 Compression molding process

Figure 2.1 Schematic of Resin Transfer Molding

Figure 2.2 Schematic of Pultrusion Process

2.4 Experimental approach for thermal conductivity measurements

2.4.3 Transient pulse method

Figure 2.3 Schematic representation of transient pulse method

2.4.4 Flash pulse measurement system

An experimental set up is schematically represented in Figure 2.4.

Figure 2.4 Schematic representation of Laser Pulse Operator

2.5 Theoretical approach for thermal conductivity predictions

2.5.2 Caruso model

Where KL is the thermal conductivity in longitudinal direction, KT is the thermal conductivity in

and the unsteady case was given as

and the transverse thermal conductivity was given as

Mirmira (1999) defined the effective transverse thermal conductivity of a composite by

where k e is the effective thermal conductivity in transverse direction, k m is the thermal

In order to determine effective thermal conductivity value of a composite with unknown

conductivity measurements of composite materials in transverse, longitudinal and through the

Figure 3.1 Experimental set up of Unitherm 2022

Preparation of test sample is a challenging task. One accurate measurement requires a

3.5 Determination of fiber volume fraction

Fiber volume fraction of a composite can be calculated using two methods.

The objective of this investigation is to determine conductivity properties of FRP

Table 4.1 Thermal Conductivity Test Matrix

Effect of additives and particulate size of additive

Figure 4.3 Sonicator and Teflon mold

4.4 E-glass/vinyl ester laminates with or without stitching

Figure 4.4 Miscellaneous FRP composite samples tested

thin layer of adhesive (Pliogrip), each plate consisting of 55 layers of 24 oz E- glass bi

To verify the effect of fiber volume fraction on thermal conductivity of

Prodeck 4 is 4 inches in depth, while Prodeck 8 is 8 inches in depth. Both bridge

The objective of the experimental investigation is to determine longitudinal,

The thermal conductivity of a composite depends on many parameters including

Thermal conductivity, W/m K

Neat resin Hetron

Thermal conductivity, W/m K

Hetron 922 Vinyl ester(RTM)

Figure 5.1 Thermal conductivity variations of different resins

Thermal conductivity, W/m K

Thermal conductivity, W/m K