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CONCEPTUAL QUESTIONS
(i) less than the rate of crystallization
(ii) greater than the rate of crystallisation (iii) equal to the rate of crystallization (iv) zero 3. Maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid solvent does not depend upon ____________. (i) Temperature (ii) Nature of solute (iii) Pressure (iv) Nature of solvent 4. Low concentration of oxygen in the blood and tissues of people living at high altitude is due to----(i) low temperature (ii) low atmospheric pressure (iii) high atmospheric pressure (iv) both low temperature and high atmospheric pressure 5. Considering the formation, breaking and strength of hydrogen bond, predict which of the following mixtures will show a positive deviation from Raoults law? (i) Methanol and acetone. (ii) Chloroform and acetone. (iii) Nitric acid and water. (iv) Phenol and aniline. 6. Colligative properties depend on ____________. (i) the nature of the solute particles dissolved in solution. (ii) the number of solute particles in solution. (iii) the physical properties of the solute particles dissolved in solution. (iv) the nature of solvent particles. 7. Which of the following aqueous solutions should have the highest boiling point? (i) 1.0 M NaOH (ii) 1.0 M Na2SO4 (iii) 1.0 M NH4NO3 (iv) 1.0 M KNO3 8. The unit of ebulioscopic constant is _______________. (i) K kg mol 1 or K (molality)1 (ii) mol kg K1 or 1 K (molality) (iii) kg mol 1 K1 or K1(molality)1 (iv) K mol kg 1 or K (molality)
9. In comparison to a 0.01 M solution of glucose, the
depression in freezing point of a 0.01 M MgCl2 solution is _____________. (i) the same (ii) about twice (iii) about three times (iv) about six times 10. An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because --(i) it gains water due to osmosis. (ii) it loses water due to reverse osmosis. (iii) it gains water due to reverse osmosis. (iv) it loses water due to osmosis. 11. At a given temperature, osmotic pressure of a concentrated solution of a substance -----(i) is higher than that at a dilute solution. (ii) is lower than that of a dilute solution. (iii) is same as that of a dilute solution. (iv) cannot be compared with osmotic pressure of dilute solution. 12. Which of the following statements is false? (i) Two different solutions of sucrose of same molality prepared in different solvents will have the same depression in freezing point. (ii) The osmotic pressure of a solution is given by the equation = CRT ( where C is the molarity of the solution). (iii) Decreasing order of osmotic pressure for 0.01 M aqueous solutions of barium chloride, potassium chloride, acetic acid and sucrose is BaCl2 > KCl > CH3COOH > sucrose. (iv) According to Raoults law, the vapour pressure exerted by a volatile component of a solution is directly proportional to its mole fraction in the solution. 13. The values of Vant Hoff factors for KCl, NaCl and K2SO4, respectively, are _____________.