K.R.

MANGALAM WORLD SCHOOL, GURGAON

HOLIDAY HOMEWORK (WORKSHEET-1)
CLASS- XII SUBJECT- CHEMISTRY
Chapter -1 (Solution)
Note: Practice these given questions and submit in chemistry notebook.
1.Which one of the following pairs will form an ideal solution?
(a) Chloroform and acetone. (b) Ethanol and acetone.
(c) n-hexane and n-heptane. (d) Phenol and aniline
2. Which of the following formula represents Raoult's law for a solution containing
non-volatile solute?
(a) Psolute = Posolute · Xsolute. (b) P = KH.X.
(c) Ptotal = Psolvent. (d) Psolute = P0solvent Xsolvent
3. An azeotropic solution of two liquids has a boiling point lower than either of the
two when it
(a) shows a positive deviation from Raoult's law.
(b) shows a negative deviation from Raoult's law.
(c) shows no deviation from Raoult's law.
(d) is saturated.
4. The mole fraction of a solvent in aqueous solution of a solute is 0.8. The
molality (in mol kg - 1 ) of the aqueous solution is
(a) 13.88 X 10-2 (b) 13.88 X 10-1
(c) 13.88 (d)13.88 X 10-3
5. Which of the following aqueous solutions should have the highest boiling point?
(a) 1.0 M NaOH (b) 1.0 M Na2SO4
(c) 1.0 M NH4NO3 (d) 1.0 M KNO3
6. What would be the molality of 20% (mass/mass) aqueous solution of KI ?
(Molar mass of KI = 166 g mol– 1
(a) 1.48 (b) 1.51
(c) 1.35 (d) 1.08
7. Low concentration of oxygen in the blood and tissues of people living at high
altitude is due to……….
(a) low temperature (b) low atmospheric pressure
(c) high atmospheric pressure (d) both low temp & high atmospheric pressure
8. If we place the blood cells in a solution containing less than 0.9% (m/V) sodium
chloride. They would swell. This is because
(a) the solution is hypotonic (b) the solution is isotonic
(c) the solution is hypertonic (d) none of these
9. Which of the following colligative property is used to calculate the molar mass
of biomolecules?
(a) Relative lowering of vapour pressure (b) Elevation in boiling point
(c) Depression in freezing point (d) Osmotic pressure
10. On mixing 20 mL of acetone with 30 mL of chloroform, the total volume of the
solution is
(a) < 50 mL. (b) = 50 mL
(c) > 50 mL. (d) = 10 mL
11. Elevation of boiling point is inversely proportional to
(a) molal elevation constant (Kb). (b) molality (m).
(c) molar mass of solute (M). (d) weight of solute (W)
12. An unknown gas 'X' is dissolved in water at 2.5 bar pressure and has mole
fraction 0.04 in solution. The mole fraction of 'X' gas when the pressure of gas is
doubled at the same temperature is
(a) 0.08. (b) 0.04.
(c) 0.02. (d) 0.92
13. The boiling point of a 0.2 m solution of a non-electrolyte in water is (Kb for
water = 0.52 K kg mol–1)
(a) 100 °C (b) 100.52 °C
(c) 100.104 °C (d) 100.26 °C
14. In the following diagram point, 'X' represents
(a) Boiling point of solution (b) Freezing point of solvent
(c)Boiling point of solvent (d) Freezing point of solution
The question consists of two statements –
Select the most appropriate answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A.
(b) Both A and R are true but R is not the correct explanation of A.
(c) A is true but R is false.
(d) A is false but R is true.
15.Assertion (A): A raw mango placed in a saline solution loses water and shrivel
into pickle.
Reason (R): Through the process of reverse osmosis, raw mango shrivel into
pickle.
16. Assertion (A) : 0.1 M solution of KCl has greater osmotic pressure than 0.1 M
solution of glucose at same temperature.
Reason (R) : In solution, KCI dissociates to produce more number of particles.
17. Assertion (A) : Elevation in boiling point is a colligative property.
Reason (R) : Elevation in boiling point is directly proportional to molarity.
18.Assertion (A) : When NaCl is added to water a depression in freezing point is
observed.
Reason (R) : The lowering of vapour pressure of a solution causes depression in
the freezing point.
Passage based questions:
19.Boiling point or freezing point of liquid solution would be affected by the
dissolved solids in the liquid phase. A soluble solid in solution has the effect of
raising its boiling point and depressing its freezing point.
The addition of non-volatile substances to a solvent decreases the vapor pressure
and the added solute particles affect the formation of pure solvent crystals.
According to many researches the decrease in freezing point directly correlated to
the concentration of solutes dissolved in the solvent. This phenomenon is
expressed as freezing point depression and it is useful for several applications such
as freeze concentration of liquid food and to find the molar mass of an unknown
solute in the solution. Freeze concentration is a high quality liquid food
concentration method where water is removed by forming ice crystals. This is done
by cooling the liquid food below the freezing point of the solution. The freezing
point depression is referred as a colligative property and it is proportional to the
molar concentration of the solution (m), along with vapor pressure lowering,
boiling point elevation, and osmotic pressure.
(i) When a non volatile solid is added to pure water it will:
(a) boil above 100oC and freeze above 0oC
(b) boil below 100oC and freeze above 0oC
(c) boil above 100oC and freeze below 0oC
(d) boil below 100oC and freeze below 0oC
(ii) Colligative properties are:
(a) dependent only on the concentration of the solute and independent of the
solvent’s and solute’s identity.
(b) dependent only on the identity of the solute and the concentration of the solute
and independent of the solvent’s identity.
(c) dependent on the identity of the solvent and solute and thus on the
concentration of the solute.
(d) dependent only on the identity of the solvent and the concentration of the solute
and independent of the solute’s identity.
(iii). Assume three samples of juices A, B and C have glucose as the only sugar
present in them. The concentration of sample A, B and C are 0.1M, .5M and 0.2 M
respectively. Freezing point will be highest for the fruit juice:
(a) A (b) B
(c) C (d) All have same freezing point
(iv) Identify which of the following is a colligative property :
(a) Freezing point (b) Boiling point
(c) Osmotic pressure (d) all of the above
20. A solution which obeys Raoult’s law strictly is called an ideal solution, while a
solution which shows deviations from Raoult’s law is called a non-ideal solution or
real solution. Suppose the molecules of the solvent and solute are represented by A
and B respectively, and let AB, AA and BB are the attractive forces between A—
B, A—A and B—B respectively. An ideal solution of the components A and B is
defined as the solution in which the intermolecular interactions between the
components A—B are of the same magnitude as the intermolecular interactions
found in the pure components A—A and B—B. Similarly,a non- ideal solution of
the components A and B is defined as the solution in which the intermolecular
interactions between the components A—B are of the different magnitude as the
intermolecular interactions found in the pure components A—A and B—B.
(i). What type of liquids form the ideal solution?
(ii). Give one example of an ideal solution.
(iii). Write two characteristics of non-ideal solution.
(iv). On mixing liquid A and liquid B, volume of the resulting solution decreases,
what type of deviation from Raoult’s law is shown by?
21. A 5% solution of Na2SO4.10H2O (MW = 322) is isotonic with 2% solution of
non- electrolytic, non volatile substance X. Find out the molecular weight of X.
22. Given alongside is the sketch of a plant for carrying out a process.
(a) Name the process occurring in the given plant.
(b) To which container does the net flow of solvent take place?
(c) Name one SPM which can be used in this plant, Give one practical use of the
plant.

23. (a) Define the following terms :

(i) Isotonic solution (ii)Osmotic pressure. (iii) Reverse Osmosis
(b) A 1.00 molal aqueous solution of trichloroacetic acid (CCl 3COOH) is heated to
its boiling point. The solution has the boiling point of 100.18°C. Determine the
van’t Hoff factor for trichloroacetic acid. (Kb for water = 0.512 Kkg mol −1)
24. (a)What is the effect of temperature on the solubility of glucose in water?
(b) Ibrahim collected a 10mL each of fresh water and ocean water. He observed
that one sample labeled "P" froze at 0°C while the other Q at -1.3°C. Ibrahim
forgot which of the two, " P " or " Q " was ocean water. Help him identify which
container contains ocean water, giving rationalization for your answer.
(c) Calculate Van't Hoff factor for an aqueous solution of K3 [Fe (CN) 6 ] if the
degree of dissociation is 0.852. What will be boiling point of this solution if its
concentration is 1 molal? (Kb =0.52 Kkg/mol).
25. 18 g of glucose, C6H12O6 (Molar Mass = 180 g mol−1) is dissolved in 1 kg of
water in a sauce pan. At what temperature will this solution boil? (Kb for water =
0.52 K kg mol−1, boiling point of pure water = 373.15 K)
26. Determine the osmotic pressure of a solution prepared by dissolving 2.5 × 10−2
g of K2SO4 in 2L of water at 25°C, assuming that it is completely dissociated. (R =
0.0821 L atm K−1 mol−1, Molar mass of K2SO4 = 174 g mol−1)
27. A 1.00 molal aqueous solution of trichloroacetic acid (CCl 3COOH) is heated to
its boiling point. The solution has the boiling point of 100.18°C. Determine the
van’t Hoff factor for trichloroacetic acid. (Kb for water = 0.512 kg mol −1)
28. Calculate the amount of KCl which must be added to 1 kg of water so that the
freezing point is depressed by 2K. (Kf for water = 1.86 K kg mol−1).
29. What is the effect of temperature on the solubility of gases in liquids?
30. Why does the solubility of gases in liquids decrease with rise in temperature?