SOLUTIONS
SOLUTIONS
SOLUTIONS
The ratio of the value of any colligative property for KCl solution to that of sugar solution is
1.
1
a)
0.5
b)
2
c)
4
d)
2.
What would be the freezing point of aqueous solution containing 17 g of C 2 H 5 OH in 1000 g
of water. K f H O=1.86 K m
−1
2
a)
−0.69 ℃
b)
−0.34 ℃
c)
0.0 ℃
d)
0.34 ℃
3.
The osmotic pressure of a solution (density is 1 g m L−1) containing 3 g of glucose (molecular
weight = 180) in 60 g of water at 15 ℃ is
a)
0.34 atm
b)
0.65 atm
c)
6.25 atm
d)
5.57 atm
4.
The molal freezing point constant of water is 1.86 K m−1, If 342 g of cane sugar (C 12 H 22 O 11 ¿ is
dissolved in 1000 g of water, the solution will freeze at
Page|1
a)
−1.86 ℃
b)
1.86 °
c)
−3.92 ℃
d)
2.42 ℃
a)
¿ 50 mL
b)
¿ 50 mL
c)
¿ 50 mL
Cannot be predicted
d)
a)
NaCl− H 2 O
b)
C 2 H 5 OH −C6 H 6
c)
C 6 H 16 ( l )−H 2 O
d)
C 6 H 5 OH −H 2 O
7.
FeCl3 on reaction with K 4 ¿ in aqueous solution gives blue colour. These are separated by a
semi-permeable membrane AB as shown. Due to osmosis, there is
Page|2
Blue colour formation in both of sides X and Y
c)
A mixture of volatile components A and B has total vapour pressure (in torr)
8.
P=254−119 χ A
Where χ A is the mole fraction of A in mixture. Hence, P A ° and PB ° are (in torr)
254, 119
a)
119, 254
b)
135, 254
c)
154, 119
d)
An azeotropic solution of two liquids has boiling point lower than either of them when it
9.
Is saturated
d)
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A 5% solution of cane sugar (molecular weight = 342) is isotonic with 1% solution of
11.
171.2
a)
68.4
b)
34.2
c)
136.2
d)
A teacher one day pointed out to his students the peculiar fact that water is a unique liquid
12.
which freezes exactly at 0 ° C and boils exactly at 100 ℃ . He asked the students to find the
correct statement based on this fact
Boiling and freezing temperatures of water were used to define a temperature scale
c)
The vapour pressure (VP) of a dilute solution of non-volatile solute is P and the VP of a pure
13.
a)
+ ve
b)
−ve
c)
P/ P °
d)
P ° /P
Temperature is lowered
a)
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Volume is increased
b)
solution is
a)
¿ 20 mL
b)
¿ 20 m L
c)
¿ 20 mL
Cannot be predicted
d)
A solution containing 4 g of a non-volatile organic solute, per 100 mL was found to have an
17.
14.97
a)
149.7
b)
1697
c)
Page|5
1.497
d)
18.
When 20 g of naphthoic acid (C 11 H 8 O2) is dissolved in 50 g of benzene (k f =1.72 K kg mo l ), a
−1
0.5
a)
1
b)
2
c)
3
d)
Osmosis
a)
Diffusion
b)
Solubility
c)
None
d)
An ideal solution
a)
Non-ideal solution
b)
Suspension
c)
Emulsion
d)
Additive property
a)
Constitutive property
b)
Page|6
Colligative property
c)
1/2
a)
2
b)
1
c)
3
d)
1% glucose in water
a)
1% sucrose in water
b)
1% NaCl in water
c)
d)
1 % CaCl2 in water
24.
The osmotic pressure of equimolar solutions of BaC l 2 , NaCl , and glucose follow the order
a)
BaC l 2> NaCl> Glucose
b)
Glucose> NaCl> BaC l 2
c)
NaCl> BaC l 2> Glucose
d)
NaCl>Glucose> BaC l 2
Camphor
a)
Naphthalene
b)
Page|7
Benzene
c)
Water
d)
If a 6.84% (weight/volume ) solution of cane sugar (molecular weight = 342) is isotonic with
26.
152
a)
760
b)
60
c)
180
d)
12.2 g of benzoic acid (Mw=122) in 100 g benzene has depression in freezing point
27.
2. 6 ° : K f =5.2 °=kg mol . If there is 100% polymerzation, the number of molecules of benzoic
−1
1
a)
2
b)
3
c)
4
d)
Assuming each salt to be 90 % dissociated which of the following will have the highest
28.
osmotic pressure?
a)
Decinormal Al2 ¿
b)
Decinormal BaCl 2
c)
Decinormal Na2 SO 4
A solution obtained by mixing equal volumes of (b) and (c) and filtering
d)
Page|8
a)
, if T is constant
1
π∝
V
π ∝ T , if V is constant
b)
π ∝V , if T is constant
c)
a)
0℃
Above 0 ℃
b)
c)
1℃
Below 0 ℃
d)
31.
The molal elevation constant of water ¿ 0.52 K m−1. The boiling point of 1.0 molal aqueous KCl
solution (assuming complete dissociation of KCl ) should be
100.52℃
a)
101.04℃
b)
99.48℃
c)
98.96℃
d)
The freezing point of 1 m NaCl solution assuming NaCl to be 100% dissociated in water is (
32.
K f =1.86 K m−1)
a)
−1.86 ℃
b)
−3.72 ℃
c)
+1.86 ℃
d)
+3.72 ℃
Page|9
−1
(K f =1.86 K m )
a)
−1.86 ℃
b)
−0.93 ℃
c)
−0.093 ℃
d)
0.093 ℃
34.
An aqueous solution freezes at −0.186 ℃ (K ¿ ¿ f =1.86 ° ; K b=0.512 °)¿. What is the elevation in
boiling point?
0.186
a)
0.512
b)
c)
0.512
1.86
0.0512
d)
The lowering of vapour pressure is equal to the mole fraction of the solute
a)
The relative lowering of vapour pressure is equal to the mole fraction of the solute
b)
The relative lowering of vapour pressure is proportional to the amount of solute in the
c)
solution
The vapour pressure of the solution is equal to the mole fraction of the solvent
d)
Based on the given diagram, which of the following statements regarding the solutions of
36.
Plots AD and BC show that Raoult''s law is obeyed for the solution in which B is a
solvent and A is the solute and as well as for that in which. A is solvent and B is solute
Plot CD shows that Dalton''s law of partial pressures is observed by the binary solutions of
components A and B
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EF+ EG =EH ; and AC and BD corresponds to the vapour pressures of the pure
solvents A and B, respectively
Select the correct answer using the codes given below: Codes:
1 and 2
a)
2 and 3
b)
1 and 3
c)
1, 2, and 3
d)
Amorphous
a)
Azeotropic mixture
b)
c)
P a g e | 11
Ideal solution
a)
4 atm
b)
3.4 atm
c)
5.078 atm
d)
2.45 atm
13.44 torr
a)
14.12 torr
b)
312 torr
c)
352 torr
d)
42.
Two solutions of KNO3 and CH 3COOH are prepared separately. The molarity of both is 0.1 M
and osmotic pressure P1 and P2 respectively
P a g e | 12
a)
P2 > P1
b)
P1=P2
c)
P1 > P2
d)
P1 P2
=
P 1+ P 2 P 1 + P2
Ionic concentration
b)
Boiling point
c)
a)
C 2 H 5 Br andC 2 H 5 I
b)
C 6 H 5 ClandC 6 H 5 Br
c)
C 6 H 6 andC 6 H 5 ∙CH 3
d)
C 2 H 6 I andC 2 H 5 OH
45.
The Henry’s law constant for the solubility of N 2 gas in water at 298 K is 1.0 ×105 atm . The
mole fraction of N 2 In air is 0.8 The number of moles of N 2 from air dissolved in 10 moles
of water of 298 K and 5 atm pressure is
a)
−4
4 ×10
b)
−5
4.0 × 10
c)
−4
5.0 ×10
P a g e | 13
d)
−6
4.0 × 10
46.
The use of common salts, e.g NaCl orCaCl 2 anhydrous is made to clear snow on the rods. This
causes:
The relative decrease in the vapour pressure of an aqueous solution containing 2 mol ¿ in 3
47.
a)
1 mol AgCl
b)
0.25 mol AgCl
c)
2 mol AgCl
d)
0.40 mol AgCl
Which of the following 0.1 M aqueous solutions will have the lowest freezing point?
48.
Potassium sulphate
a)
Sodium chloride
b)
Urea
c)
Glucose
d)
84% of HCl
a)
22.2% HCl
b)
63% of HCl
c)
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20.2% HCl
d)
50.
25 mL of an aqueous solution of KCl was found to require 20 mL of 1 M AgNO3 solution when
titrated using a K 2 CrO 4 as indicator. The depression in freezing point of KCl solution with
100% ionization will be:
a)
5.0 °
b)
3.2 °
c)
1.6 °
d)
0.8 °
a)
∆ mix H=0
b)
∆ mix V =0
c)
∆ mix S=0
52.
When 0.004 M N a2 S O4 is an isotonic acid with 0.01 M glucose, the degree of dissociation of
N a2 S O4 is
75%
a)
50%
b)
25%
c)
85%
d)
53.
The correct relationship between the boiling points of very dilute solutions of AlCl3 (t 1) and
CaCl2(t 2 ¿ , having the same molar concentration, is
a)
t 1=t 2
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b)
t 1> t 2
c)
t 2> t 1
d)
t 2 ≥ t1
The osmotic pressure of a sugar solution at 24 ℃ is 2.5 atm. The concentration of the
54.
10.25
a)
1.025
b)
1025
c)
0.1025
d)
The boiling point of an azeotropic mixture of water and ethyl alcohol is less than that of the
55.
theoretical value of water and alcohol mixture. Hence the mixture shows
The freezing point among the following equimolal aqueous solutions will be highest for
56.
C 6 H 5 N H 3 Cl (aniline hydrochloride)
a)
b)
Ca ( N O3 ) 2
c)
La ( N O3 )3
C 6 H 12 O6 (glucose)
d)
P a g e | 16
0.0 1M NaCl
a)
b)
0.005 M C 2 H 5 OH
c)
0.005 M Mg I 2
d)
0.005 M Mg SO 4
The osmotic pressure of blood is 7.40 atm at 27 ℃ . The number of mol of glucose to be used
58.
per liter for an intravenous injection that is to have the same osmotic pressure as blood is
0.3
a)
0.2
b)
0.1
c)
0.4
d)
Freezing point
b)
Osmotic pressure
c)
Copper ferrocyanide
a)
Copper ferricyanide
b)
Copper sulphate
c)
Potassium ferrocyanide
d)
61.
P a g e | 17
A pressure cooker reduces cooking time because
Same molarity
b)
Same density
c)
Same normality
d)
63.
The depression in freezing point of 0.01 m aqueous CH 3 COOH solution is 0.02046 ° . 1 m urea
solution freezes at −1.86 ℃ . Assuming molality equal to molarity. pH of CH 3 COOH solution is
2
a)
3
b)
3.2
c)
4.2
d)
P a g e | 18
The solvent from a solution of lower concentration to one of higher concentration
b)
None
d)
1000 g of solvent
a)
1 L of solvent
b)
1 L of solution
c)
22.4 L of solution
d)
Pfeffer's method
b)
Townend's method
d)
The solutions in which the blood cells retain their normal shape, with regard to the blood, are
67.
Isotonic
a)
Hypertonic
b)
Hypotonic
c)
None
d)
a)
P a g e | 19
Freezing point
Boiling point
b)
Vapour pressure
c)
Osmotic pressure
d)
a)
P=P 0 × N 1
b)
πV =nRT
c)
∆ P=P0 N 2
d)
∆ P P °−P S
=
P° P°
The osmotic pressure of a solution containing 0.1 mol of solute per liter at 273 K is
70.
a)
0.1
×0.08205 × 273 atm
1
b)
0.1 ×2 ×0.08205 × 273 atm
c)
1
×0.08205 × 273 atm
0.1
d)
0.1 273
× atm
1 0.08205
The freezing point of a solution prepared from 1.25 g of non-electrolyte and 20 g of water is
71.
271.9K. If the molar depression constant is 1.86 K mol−1 , then molar mass of the solute will
be
105.7
a)
106.7
b)
115.3
c)
93.9
d)
72.
P a g e | 20
The mole fraction of component A in vapour phase is χ 1 and mole fraction of component A
in liquid mixture is χ 2 ( P A ° = vapour pressure of pure A; PB ° = vapour pressure of pure B).
Then total vapour pressure of the liquid mixture is
a)
P A ° χ2
χ1
b)
P A ° χ1
χ2
c)
P A ° χ1
χ2
d)
PB ° χ 2
χ1
Dissolving 120 g of urea (mol. Wt. 60) in1000 g of water gave a solution of density 1.15
73.
1.78M
a)
2.00M
b)
2.05M
c)
2.22M
d)
c)
1 molal CaC l 2 solution
75.
If P ° and Ps are vapour pressures of solvent and its solution, respectively, χ 1 and χ 2 are mole
fractions of solvent and solute, respectively, then
a)
P a g e | 21
Ps =P° / χ 2
b)
0
P −P s=P ° χ 2
c)
Ps =P° χ 2
d)
P ° −P s χ1
=
Ps χ 1+ χ 2
added to the solvent. The mole fraction of solute in solution is 0.2, what would be the mole
fraction of solvent if the decrease in vapour pressure is 20 mm of Hg
0.8
a)
0.6
b)
0.4
c)
0.2
d)
c)
1 molar of CaC l 2 solution
If Raoult's law is obeyed, the vapour pressure of the solvent in a solution is directly
79.
proportional to
P a g e | 22
The mole fraction of the solvent
a)
80.
The vapour pressure of pure benzene C 6 H 6 at 50 ℃ is 268 torr. How many moles of non-
volatile solute per mole of benzene is required to prepare a solution of benzene having a
vapour pressure of 167 torr at 50 ℃ ?
0.377
a)
0.605
b)
0.623
c)
0.395
d)
81.
The value of K f for water is 1.86 ° , calculated from glucose solution. The value of K f for water
calculated for NaCl solution will be
a)
¿ 1.86
b)
¿ 1.86
c)
¿ 1.86
Zero
d)
Which of the following solutions (1 molal) will have the maximum freezing point, assuming
82.
a)
¿
b)
¿
c)
¿
d)
¿
P a g e | 23
The mole fraction of toluene in the vapour phase which is in equilibrium with a solution of
83.
benzene (P¿¿ B °=120 torr)¿ and toluene ( PT °=80torr ¿ having 2.0 mol of each is
0.50
a)
0.25
b)
0.60
c)
0.40
d)
What will be the molecular weight of NaCl determined experimentally following elevation in the
85.
a)
¿ 58.5
b)
¿ 58.5
c)
¿ 58.5
None
d)
86.
0.004 M N a2 S O4 is isotonic with 0.01 M glucose.Degree of dissociation of N a2 S O4 is
75%
a)
50%
b)
25%
c)
P a g e | 24
85%
d)
The molecular weight of benzoic acid in benzene as determined by depression in the freezing
87.
PtCl 4 . 6 H 2 O can exist as a hydrated complex; 1 m aqueous solution has the depression in
88.
freezing point of 3.72 °. Assume 100% ionization and K f ( H 2 O ) =1.86 °mol kg, then the
−1
complex is
a)
¿
b)
¿
c)
¿
d)
¿
The molal depression constant for water in 1.86 ℃ . The freezing point of a 0.05-molal
89.
a)
−1.86 ℃
b)
−0.93 ℃
c)
−0.093 ℃
d)
0.93 ℃
Which of the following will have the highest boiling point at 1 atm pressure?
90.
0.1 M NaCl
a)
0.1 M sucrose
b)
P a g e | 25
c)
0.1 M BaC l 2
0.1 M glucose
d)
Dry air was passed successively through a solution of 5 g of a solute in 180 g of water and
92.
then through pure water. The loss in the weight of solution was 2.50 g and that of pure
solvent 0.04 g. The molecular weight of the solute is
31.25
a)
3.125
b)
312.5
c)
None
d)
93.
The factor ∆ T f / K f represents
Molarity
a)
Formality
b)
Normality
c)
Molality
d)
94.
The elevation in boiling point of a solution of13.44 g of CuC l 2in 1 kg of water using the
following information will be (molecular weight of CuC l 2=134.4 and k b=0.52 K m ¿
−1
0.16
a)
P a g e | 26
0.05
b)
0.1
c)
0.2
d)
A perfectly semi-permeable membrane when use to separate a solution from its solvent
95.
Solute only
a)
Solvent only
b)
None
d)
Which of the following substances will lose its whose solubility with increase in
96.
temperature?
a)
NaOH
b)
Na2 CO 3
c)
Na2 SO 4
All
d)
The relative lowering of vapour pressure is equal to the mole fraction of the non- volatile
97.
Raoult
a)
Henry
b)
Joule
c)
Dalton
d)
98.
The total vapour pressure of a mixture of 1 mol A ( P A ° =150 torr) and 2 mol B ¿ ¿ 240 torr ¿ is
200 mm. In this case
a)
P a g e | 27
There is positive deviation from Raoult’s law
1
a)
2
b)
3
c)
4
d)
0.2 m urea
a)
0.1 m glucose
b)
c)
0.1 m Mg SO 4
d)
0.1 m BaCl 2
a)
AgNO3
b)
Na2 SO 4
c)
¿¿
d)
MgCl 2
The osmotic pressure of 40% (weight/volume) urea solution is 1.64 atm and that of 3.42%
102.
(weight/volume) cane sugar is 2.46 atm. When equal volumes of the above two solutions are
mixed, the osmotic pressure of the resulting solution is
a)
P a g e | 28
1.64 atm
b)
2.46 atm
c)
4.10 atm
d)
2.05 atm
0.1 M KCl
a)
b)
0.1 M BaCl 2
c)
0.1 MFeCl 3
d)
0.1 M Fe2 ¿ ¿
An ideal solution was obtained by mixing methanol and ethanol. If the partial vapour
104.
pressure of methanol and ethanol are 2.619 kPa and 4.556 kPa, respectively, the composition
of vapour (in terms of mole fraction) will be
a)
0.635 MeOH , 0.365 EtOH
b)
0.365 MeOH , 0.635 EtOH
c)
0.574 MeOH , 0.326 EtOH
d)
0.173 MeOH , 0.827 EtOH
P a g e | 29
None
d)
At 40 ℃ , the vapour pressures of pure liquids, benzene and toluene are 160 mm Hg and 60
106.
140 mm Hg
a)
110 mm Hg
b)
220 mm Hg
c)
100 mm Hg
d)
temperature T K is
a)
0.1 RT
b)
0.11 RT
c)
1.1 RT
d)
0.01 RT
Equimolal solutions A and B show depression in freezing point in the ratio 2:1. A remains in the
108.
Normal in solution
a)
Dissociated in solution
b)
Associated in solution
c)
Hydrolysed in solution
d)
348.9
a)
34.89
b)
c)
P a g e | 30
3489
861.2
d)
110.
If P0 and Ps are the V.P. of solvent and solution respectively and N 1 and N 2 are the mole of
solute and solvent then :
a)
( P0 −P s ) N1
=
P0 ( N 1+ N 2)
b)
( P ¿ ¿ 0−Ps ) N 1
= ¿
Ps N2
c)
(P0 −P s ) N 1
=
P0 N2
None of these
d)
Molarity
a)
Molality
b)
Normality
c)
Mole fraction
d)
permeable membrane
on both sides
In osmosis only the solvent moves while in diffusion both solute and solvent move
c)
113.
P a g e | 31
Consider the two solutions:
I: 0.5 M NaCl aqueous solution at 25 ℃ ; NaCl is complete ionized
II: 2.0 M C 6 H 5 COOH in benzene at 25 ℃ , C 6 H 5 COOH dimerizes to the full extent
Which of the following statement(s) is (are) correct?
Solution II is hypertonic
c)
a)
N a2 S O 4
b)
NaOH
c)
CaC l 2
d)
LiBr
115.
2 L of 1 molar solution of a complex salt CrC l 3 .6 H 2 O(Mw=266.5) shows an osmotic pressure
of 98.52 atm. The solution is now treated with 1 L of 6 M AgN O3, which of the following are
correct?
d)
2 mol of [ Cr ( H 2 O )6 ] ( N O 3 )3 will be present in solution
a)
P a g e | 32
The vapour pressure of a solute is zero
117.
Two miscible liquids A and B having vapour pressure in pure state P A ° and PB ° are mixed in
mole fraction χ A and χ B to get a mixture having total vapour pressure of mixture P M . Which
of the following relations are correct?
a)
PM −PB °
χ A=
P A °−PB °
b)
χ A (l) PM
'
=
χ A (v)
PA °
c)
χ A (l) PM
'
=
χ A (v)
PB °
All of these
d)
Chloroform + Benzene
c)
Benzene + Toluene
d)
Temperature of solution
a)
c)
P a g e | 33
Melting point of solute
The following is a graph plotted between the vapour pressure of two volatile liquids against
120.
a)
When χ A =1 and χ B=0 , then P=P A °
b)
When χ B=1 and χ A =0, then P=P B °
c)
When χ A =1 and χ B=0 , then P< P B °
d)
When χ B=1 and χ A =0, then P> P A °
An azeotropic mixture
c)
A eutectic formation
d)
P a g e | 34
To decrease its osmotic pressure
d)
Which pair(s) of liquids on mixing is/are expected to show no net volume change and no heat
123.
effect?
124.
The processes of getting fresh water from sea water is/are known as :
125.
Osmosis
a)
Filtration
b)
Desaltation
c)
Reverse osmosis
d)
Which statement (s) is/are correct about osmotic pressure (P), volume (V ) and temperature
126.
(T ) ?
P a g e | 35
P ∝1/V if T is constant
a)
b)
P ∝T if V is constant
P ∝V if T is constant
c)
PV is constant if T is constant
d)
The solution (s) which will boil at the highest temperature is/are
127.
0.1 M urea
a)
b)
0.1 M HN O3
c)
0.1 M Ca ( N O3 )2
d)
0.1 M BaC l 2
Which of the following statements is/are false for a solution of chloroform and acetone?
128.
The solution formed is a non-ideal solution with positive deviation from Raoult’s law
b)
The solution formed is a non-ideal solution with negative deviation from Raoult’s law
c)
An azeotropic solution of two liquids has a boiling point lower than that of either of them
c)
d)
P a g e | 36
An azetropic solution of two liquids has a boiling point higher than that of either of them if it
shows positive deviation from Raoult’s law
A mixture of two immiscible liquids A and B, having vapour pressure in pure state obeys the
130.
following relationship if χ A and χ B are mole fractions of A and B in vapour phase over the
solution
a)
' '
P A =PM χ A
b)
'
PA W A × M wB
'
=
P B
M w A ×W B
c)
If P A > P B then χ A < χ B
' ' ' '
d)
If P A > P B then n A >n B
' '
For a given value of degree of dissociation, which of the following have correct Van’t Hoff
131.
factor?
a)
NaCl , i=2+α
b)
Ca ( N O3 ) 2 , i=1+2 α
c)
K 4 [ F e3 ( CN )6 ] ,i=1+ 4 α
d)
( N H 3 )3 P O 4 ,i=3+ α
P a g e | 37
Inversely proportional to the moles of non-volatile solution
a)
Energy is released when a substance dissolves in water provided that the hydration energy
c)
If two liquids that form an ideal solution are mixed, the change in entropy is positive
d)
The vapour pressure and freezing point are the lowest for urea
a)
The vapour pressure and boiling point are the lowest for urea
b)
a)
P a g e | 38
b)
c)
d)
Minimum boiling azeotropic mixture boils at temperature lower than either of the two pure
a)
components
Maximum boiling azeotropic mixture boils at temperature higher than either of the two pure
b)
components
∝molality
a)
∝ 1/molecular weight
b)
P a g e | 39
Proportional to each other
c)
Molecular weight of urea is 60. A solution of urea containing 6 g of urea in one litre is a
139.
1N
a)
0.1 M
b)
0.1 N
c)
1M
d)
140.
If P0 and Ps are the V.P. of solvent and its solution respectively and N 1 and N 2 are the mole
fraction of solvent and solute respectively then :
a)
Ps =P0 N 2
b)
P0−P s=P0 N 2
c)
Ps =P0 N 1
d)
(P0−P s )/P s=N 1 /(N 1+ N 2)
a)
P a g e | 40
The vapour pressure of the solution is less than that of pure solvent
The vapour pressure of the solution is more than that of pure solvent
b)
24.88 atm
a)
2.488 atm
b)
0.248 atm
c)
189.09 cm
d)
Concentration increases
b)
Concentration decreases
d)
145.
On mixing 1 mole of C 6 H 6 ( P0 = 42 mm) and 2 mole of C 7 H 8 ( P0 = 36 mm), one can conclude :
b)
P a g e | 41
Consider the following solutions
146.
I. 1 M sucrose
II. 1 M KCl
IV. 1 M ( N H 3 )3 P O 4
148.
1 mol benzene (Pbenzene =42 mm) and 2 mol toluene (P ° toluene =36 mm) will have
°
149.
P a g e | 42
Consider the following graph pertaining to distillation. The distillate to residue ratio is
a)
l
12+l 2
b)
l x1
l x2
c)
ll 1
ll 2
d)
ll 2
ll 1
Boiling point
a)
Osmotic pressure
b)
151.
Which relations are not correct for an aqueous dilute solution of K 3 PO 4 if its degree of
dissociation is α ?
a)
∆ P Molality ×18 ×(1+3 α )
=
P° 1000
b)
∆ P π obs ×18 ×(1+3 α )
=
P° RT × 1000
c)
∆ P ∆ T f obs × 18
=
P° K f ×1000
P a g e | 43
d)
Mw of K 3 PO 4=M w obs ×(1+ 3 α )
152.
Among 0.1 M solutions of N H 2 CON H 2 , N a2 P O 4 and A l 2 ( S O 4 )3 :
The vapour pressure and freezing point are the lowest for urea
a)
The vapour pressure and freezing point are the highest for urea
b)
c)
The elevation in boiling point is the highest for A l 2 ( S O 4 )3
d)
The depression in freezing point is the highest for Al2 ( SO 4 )3
Which of the following combinations are correct for a binary solution, in which the solute as
154.
a)
C 6 H 6 andC 6 H 5 C H 3 ; ∆ sol H >0 ; ∆ sol V =0
b)
||
O
c)
H 2 Oand HCl ; ∆ sol H >0 ; ∆ sol V <0
d)
H 2 Oand C H 2 OH ; ∆ sol H >0 ; ∆sol V < 0
When acetone and chloroform are mixed, hydrogen bonding takes place between them. Such
155.
P a g e | 44
a liquid pair will cause
Cannot be predicted
d)
157.
To 10 mL of 1 M BaC l 2 solution of 5 mL of 0.5 M K 2 S O 4 is added. BaS O 4 is precipitated out.
What will happen?
Calcium phosphate
a)
Barium oxalate
b)
Nickel phosphate
c)
P a g e | 45
Copper ferrocyanide
d)
For the same solution, elevation in boiling point = depression in freezing point
a)
b)
The Van’t Hoff factor for a dilute solution of BaC l 2 is 3
a)
C 6 H 5 Cl — C6 H 5 Br
b)
C 6 H 6 — C6 H 5 C H 3
Hexane-heptane
c)
None of these
d)
of 7 atm?
33.94 K
a)
306.94 K
b)
273 K
c)
33.94ͦ C
d)
0.1 M urea
a)
b)
P a g e | 46
0.1 M sodium nitrate
Nature of solute
a)
Nature of solvent
b)
Temperature
c)
a)
∆ H mix=0
b)
∆ V mix=0
c)
∆ Gmix >0
d)
∆ S mix >0
166.
1.2575 g sample of [ Cr ( N H 3) 6 ] S O 4 Cl (Mw=251.5) is dissolved to prepare 250 mL solution
showing an osmotic pressure of 1.478 atm of Hg at27 ℃ . Which of the following statements
is/are correct about this solution?
P a g e | 47
Each molecule furnishes three ions in solution
a)
c)
The equilibrium molarity of [ Cr ( N H 3) 6 ] S O 4 Cl=0
d)
The equilibrium molarity of [ Cr ( N H 3) 6 ]
3+¿=0.02 M ¿
215.
217.
219.
220.
222.
223.
224.
225.
P a g e | 48
226.
When a non-volatile solute is dissolved in a solvent, the relative lowering of vapour pressure
227.
is equal to
The phase diagram for the pure solvent and solution are recorded below. The quantity
228.
a)
∆p
b)
k b∙ m
c)
kf m
d)
m
0.322
a)
0.222
b)
P a g e | 49
0.413
c)
0.5
d)
0.0229
a)
0.4
b)
0.6
c)
0.9
d)
Hypotonic solution
a)
Hypertonic solution
b)
Isotonic solution
c)
Pure water
d)
Are supersaturated
c)
P a g e | 50
Paragraph for Question Nos. 233 to - 233
17.89
a)
27.89
b)
37.89
c)
47.89
d)
Benzoic acid undergoes dimerization in benzene solution. The Van’t Hoff factor i is related to
234.
a)
i=2−α
b)
i=1+ ( α /3 )
c)
i=1− ( α /2 )
d)
i=1+ ( α /2 )
1 only
a)
3 only
b)
4 only
c)
2 only
d)
Which of the following is a better reagent for depression in freezing point but not for
236.
P a g e | 51
elevation in boiling point?
a)
C H 3 OH
b)
c)
d)
C 6 H 12 O6
268.7 K
a)
268.5 K
b)
150.9 K
c)
268.7 K
d)
238.
0.001 m NaCl
0.001 m urea
0.001 m MgC l 2
0.001 m C H 3 COOH
(ii)<(iv)<(i)<(iii)
a)
(iv)<(i)<(ii)<(iii)
b)
(iii)<(ii)<(i)<(iv)
c)
(i)<(ii)<(iii)<(iv)
d)
P a g e | 52
Paragraph for Question Nos. 239 to - 240
239.
Pressure of H 2 O(g) in X at 320 K
0.1
a)
0.2
b)
1.0
c)
2.0
d)
A decrease of entropy
a)
241.
What is the result of distilling a mixture of 50% HN O3 and50 % H 2 O?
b)
Pure H 2 O and pure HN O3 can be separated
c)
Pure HN O3 and azeotropic mixture can be separated
2, 3, 4
a)
1, 2, 4
b)
1, 2, 3
c)
3, 4
d)
An aqueous solution of 0.1 molal concentration of sucrose should have freezing point of
243.
( K f =1.86 ) :
a)
+0.186 ͦ C
b)
1.86 ͦ C
c)
−1.86 ͦ C
d)
−0.186 ͦ C
The osmotic pressure of a solution in atm obtained on mixing each 50 mL of 1.2% urea
244.
solution and 2.4% glucose solution at 300 K : ( R=0.08 litre atm K −1 mol−1 ) .
A mixture of two immiscible liquids nitrobenzene and water boiling at 99ͦ C has a partial
245.
pressure of water 733 mm and of nitrobenzene 27 mm. The ratio of weights of water and
nitrobenzene in mixture is ……….
How many g of glucose must be present in 0.5 litre of a solution for its osmotic pressure be
246.
lowering in vapour pressure of solvent by 20%. The ratio of moles of solvent and its solute is
…..
An aqueous solution of a substance mol. wt. 240 has osmotic pressure 0.2 atm at 300 K. The
248.
P a g e | 54
density of solution in g/d m 3 is : ( R = 0.08 litre atm K −1 mol −1 ¿ .
12.2 g of benzoic acid (Mw=122) in 100 g water has elevation in boiling point of 0.27.
249.
in associated state is
2
a)
1
b)
3
c)
4
d)
The Van’t Hoff factor for a solute which does not dissociate or associate in solution is
250.
0
a)
2
b)
3
c)
1
d)
251.
The ratio of the value of any colligative property for BaC l 2 solution of urea solution under
similar condition is
2
a)
3
b)
1
c)
4
d)
The osmotic pressure of a solute is 600 mm at 300 K. The solution is diluted and the
252.
temperature is raised to 400 K and the solution shows an osmotic pressure of 200 mm. the
solution was diluted to ……times.
253.
Compound PdC l 4 . 6 H 2 O is a hydrated complex; 1 m aqueous solution of it has freezing point
269.28 K. Assuming 100% ionization of complex, calculate number of ions furnished by
complex in the solution
a)
P a g e | 55
1
2
b)
4
c)
0
d)
254.
A solution of liquids A and B having vapour pressure in pure state P A and PB . The solution
0 0
contains 30% mole of A which is in equilibrium with 60% mole of A in vapour phase. If PB is
0
255.
A 0.4 molal aqueous solution of M X A has freezing point 3.72ͦ C . The K f of H 2 O is 1.86 K
molality . The value of X is ……….
−1
256.
A solution of 6.2 g ethylene glycol in 55 g H 2 O is cooled to −3.72 ͦ C . The ice separated from
solution is : (K f H 2 O=1.86 K molality )
−1
If for a sucrose, elevation in boiling point is 1.0 ℃ , then what will be the boiling point of NaCl
257.
a)
1.0 ℃
b)
2.0 ℃
c)
3.0 ℃
d)
4.0 ℃
The osmotic pressure of urea solution at 10 ℃ is 200 mm, becomes 105.3 mm when it is
258.
8 times
a)
5 times
b)
4 times
c)
2 times
d)
The osmotic pressure of a solution containing 40 g of solute (molecular mass 246) per liter at
259.
a)
3.0 atm
b)
P a g e | 56
4.0 atm
c)
2.0 atm
d)
1.0 atm
260.
A complex is represented as CoC l 3 . X N H 3 . Its 0.1 molal solution in water shows
∆ T F =0.558 ͦ C . K f of H 2 O is 1.86 Kmolality −1 . Assuming 100% ionisation, calculate the no. of
N H 3 molecules associated with Co.
1
a)
2
b)
3
c)
4
d)
3 mole of liquid A (V.P. = 60 mm) and a mole of B(V.P. = 40 mm) results in a solution having
262.
P a g e | 57
ACTIVE SITE TUTORIALS
Date : 20-08-2019 TEST ID: 493
Time : 15:39:00 CHEMISTRY
Marks : 928
2.SOLUTIONS
: ANSWER KEY :
1) c 2) a 3) c 4) a b,c
5) a 6) a 7) d 8) c 25) a,c,d 26) a, c, d 27) c 28)
9) c 10) d 11) b 12) c a,b,c,d
13) a 14) c 15) c 16) a 29) a, b, c 30) b,c 31) b, c 32)
17) b 18) a 19) a 20) a a, b, c
21) c 22) b 23) c 24) a 33) a,d 34) b, d 35) c, d 36)
25) a 26) b 27) b 28) a a, b, d
29) a 30) d 31) b 32) b 37) b,c,d 38) a, b, c 39) a,b 40) b
33) c 34) d 35) b 36) d 41) b, c, d 42) a,c,d 43) b, c, d 44)
37) c 38) b 39) c 40) a a, b, c, d
41) a 42) c 43) b 44) d 45) b,d 46) c 47) a, b 48)
45) a 46) d 47) a 48) a b,c
49) d 50) b 51) c 52) a 49) a, d 50) b,d 51) a, b, c 52)
53) b 54) d 55) b 56) d b, d
57) a 58) a 59) b 60) a 53) c, d 54) c,d 55) a, b, c 56)
61) b 62) a 63) b 64) b a, b
65) a 66) d 67) a 68) d 57) a,b,c,d 1) a 2) b 3) c
69) b 70) a 71) a 72) a 4) c
73) c 74) c 75) b 76) a 5) c 6) c 7) c 8) a
77) c 78) d 79) a 80) a 9) d 10) b 11) a 12) c
81) a 82) d 83) d 84) d 13) a 14) a 15) d 16) c
85) a 86) a 87) b 88) c 17) b 18) c 19) c 20) c
89) c 90) c 91) a 92) a 21) a 22) c 23) e 24) c
93) d 94) a 95) b 96) d 25) c 26) d 27) b 28) a
97) a 98) b 99) c 100) d 29) b 30) b 31) c 32) b
101) c 102) d 103) d 104) b 33) c 34) a 35) c 36) b
105) a 106) b 107) a 108) c 37) c 38) a 39) b 40) a
109) a 1) a, b 2) b,d 3) 41) b 42) a 43) a 44) c
a,b,c 4) a,d 45) b 46) a 47) a 48) c
5) a,b,c,d 6) a,c,d 7) a,c 8) 1) b 2) a 3) a 4) b
a,b 5) c 6) a 7) b 8) b
9) a,d 10) a, b, d 11) a,b 12) 9) c 10) d 11) a 12) a
a,c,d 1) b 2) b 3) a 4) a
13) a,c 14) b,d 15) a,b,c 16) 5) c 6) b 7) a 8) c
c, d 9) b 10) a 11) c 12) a
17) a, b, d 18) c,d 19) a, b, d 20) 13) a 14) d 15) a 16) b
a, c 17) d 1) 4 2) 4 3) 4
21) a,b,d 22) b,c 23) a,b 24) 4) 4
P a g e | 58
5) 2 6) a 7) a 8) b 13) 5 14) d 15) d 16) b
9) 4 10) b 11) 7 12) 4 17) 5 18) d 19) 3
P a g e | 59
ACTIVE SITE TUTORIALS
Date : 20-08-2019 TEST ID: 493
Time : 15:39:00 CHEMISTRY
Marks : 928
2.SOLUTIONS
1 Given eq .=254−119 χ A
Compare with the given equation,
Van’t Hoff factor
(c)
∴ PB °=254 , P B °−P A °=119
=1−α + xα+ yα ; For KCl it is 2 ∴ P A °=254−119=135
Experimental CP
¿
and for sugar it is 1
Calculated CP
9
P a g e | 60
The movement of solvent particles from dilute
π=RT (a)
14 dissociation
(c) 23
(c)
More is ∆ T b, more is boiling point
π ∝n
15
24
No changes in interparticle forces as both are (a)
(c)
17
(b) 26
m (benzoic acid)
(b)
C 11 H 8 O2)=172
1000 K b W 1
¿
Molecular mass (calculated)
∆ T bW 2
1000× k f × w ¿ 244 (twice of actual molecular weight)
¿ 28
W ×∆ T f
(a)
= =344 A l 2 ( S O4 )3 furnishes maximum number of ions
1000× 1.72× 20
50× 2
van’t Hoff factor (i) =
29
actual mol . wt . 172
= (a)
calculated mo . wt . 344
and not π ∝V
1
¿ 0.5 π∝
V
19
P a g e | 61
30 (at 100 ℃ , VP =760 torr)
∆ T f =1.86 ×0.05=0.093 ;
(c)
both
∴ T f =0−0.093=−0.093 ℃
34 45
(d) (a)
∆ T b=K b × Molality P N =K H × mole−fraction(N 2)
mole-fraction
2
∆ T f =K f × Molality
∆ Tb Kb ∆ T f × K b 0.186 × 0.512 1 −5 −1
∴ = ⇒ ∆ T b= = ( N2) 5
×0.8 × 5=4 ×10 mo l
10
In 10 mole solubility is 4 ×10−4 .
∆Tf Kf Kf 1.86
¿ 0.0512
35
46
The relative lowering of vapour pressure is
(b)
P a g e | 62
depression in freezing point Experimental value of vapour pressure of
49 mixture is more than calculated value
Azeotropic mixture of HCl conatins 20.4% Experimental value of boiling point of mixture
(d)
50 ∆ mixing H=+ ve
(b)
∆ mixing V =+ ve
25 × M (KCl)=20 × 1 M (AgN O )
3
∴ M (KCl )=0.8 56
'
∆ T f =M K f i (d)
¿ 0.8 ×2 ×2
51
of ions
¿ i× 0.004 × RT
For glucose, π 2=CRT
¿ 0.01 RT 0.01 ×2=0.02
π 1=π 2 (isotonic)
or 0.004 i=0.01
0.005 ×1=0.005
1 0
0.005 ×2=0.01
0
1−α 2α α
Total particles = 1−α +2 α + α
58
(a)
¿ 1+2 α n
π= RT
1+ 2α V
∴ i= =2.5
α =0.75 or 75 % dissociated
1 πV 7.40 ×1
n= = =0.3
RT 0.0821 ×300
53 59
AlC l 3 furnishes more ions than CaC l 2 and thus Elevation in boiling point, osmotic pressure,
(b) (b)
=0.974 K
(d) mL
First three methods involve use of C u 2 Fe ( CN )6
as semi-permeable membrane which will be ⇒Molarity = = 2.05 M
2.000
dissolved in non-aqueous solvent and thus
0.974
only Townend’s method having semi-
74
permeable membrane of powered glass and
(c)
More is ∆ T f , lesser is freezing point
clay can be used to determine the osmotic
pressure of non-aqueous solutions 75
(b)
20=P° × χ 2
∴ χ 2=0.4 ⇒ χ 1 ( solvent )=1−0.4=0.6 So,
2−¿ ¿
N a2 S O4 ⇌2 N a+¿+S O ¿
At t=0 1 0
4
78
(d) 0
More is ∆ T f , lesser is freezing point At equilibrium 1−α 2 α α
(where, α is the degree of dissociation of
79
N a2 S O 4 ¿
( π cal ¿ N a S O =C × S × T = 0.004 ×0.0821× T ---
(a)
(ii)
PS =P ° χ 2 2 4
%of∝= 75%
8
( i ) ,
point (d ) is a case of non-electrolytes, i=1
87
point of solution
85 88
osmotic pressures are equal to each other. Thus, freezing point ¿ 0−0.093=−0.093
Osmotic pressure of 0.01 M glucose ( π ¿glucose
=CST
90
Ca ( N O3 ) 2 → C a2 +¿+2 N O ¿
1 0 0
3
∴ M w2=31.25
0 1 2
93
∆ T f =K f × Molarity
(d)
Moles after dissociation 3
i= =
Moles before dissociation 1
94 100
(a) (d)
CuC l 2 is an electrolyte which ionise∈ solution P ° −P S
as follows . =Molality ×(1−α + xα+ yα )
P°
The value of P °−PS is maximum for BaC l 2
−¿¿
2 +¿+ 2C l ¿
CuC l 2 ⇌ C u
At t=0 1 mole 0
0
101
P a g e | 66
when the crystal dissolves. All the given
compounds have negative heat of solution
106
(b)
1 1 115
Pm=160× +60 × =110 mm
2 2 (a,c,d)
107 CrCl 3 . 6 H 2 O
(a) π=CRT (1−α + xα+ yα )
pH=2 98.52=1× 0.0821× 300 × ( x + y ) ( α =1 )
[ H ⊕ ]=0.01 M =Cx=0.1 x ∴ ( x+ y )=4
x=0.1 ∴ CrCl3 ⋅6 H 2 O can be written as:
i=1+ x=1.1
1 0
n
π=i RT =iMRT =1.1× 0.1 RT =0.11 RT 0
V
1−α α α
3 mol of AgNO3 will react with 1 mol of Cr ¿ ¿
108
(c)
Cr ¿ ¿
, i.e., B should associate to show moles 2 ×1=2 1 ×6=6 0
∆Tf 2 1
= =
A
∆ T f 1 1/2
higher ∆ T
B 0
0 0 2
109 6
∴ Moles of AgCl formed¿ 6
For two non-electrolyte solutions, if isotonic
(a)
Weight of AgCl formed ¿ 6 ×143.5=861 g
C 1=C2 ¿
2
8.6 5 ×1000 π=CRT ×(1+3 α )= × 0.0821 ×300 × 4=65.68 atm
∴ = ⇒ M w2=348.9 3
60 × 1 M w2 ×100
117
P M =P A °∙ χ A + PB ° ∙ χ B ; Also
111 (a,b)
a. π=C eff RT ⇒ π is same asC eff is same Experimental vapour pressure will be less
than calculated vapour pressure
b. Since both the solutions have different
solvents, vapor pressure will be different
122
132
(a,b)
n 2 RT W 2 RT 148
π=CRT ⇒ π= =
Benzene and toluene ⇒ Ideal solution
(a,b)
V Mw2 V
133
1 2
(b,c) Ptotal =P A ° χ A + P B ° χ B=42× +36 × =38 mm Hg
P a g e | 68
159 values of mol. wt.
(b,d) 173
BaCl 2 ⇌ Ba +2 Cl 2(after dissociation)
Explanation is correct reason for statement.
⊕
(c)
i=3
163 174
therefore, it depends upon the number of property, hence it depends upon the number
constituents of solution. It also depends of solute particles
upon temperature as π=CRT
175
178
cannot be read out accurately. A little error in same. Concentrations are same only when
measurement of ∆ T b will cause abnormal solute neither dissociates nor associates.
P a g e | 69
184 0
P −Ps n P
0
n+ N N
= ∨ 0 = =1+
Water boils at low temperature at mountains
(c) 0
n+ N P −P s n n
P
or 1−
Ps N
0
P −P s n Non-ideal solution with positive deviation ie, having
0
=1− ∨ 0
= more vapour pressure than expected, boil at lower
P n+ N P n+ N
temperature while those with negative deviation boil
186
at higher temperature, than those of the components.
K f is same for both solutions
(c)
194
of glucose solution
non-volatile solute to volatile solvent, the
freezing point of solution decreases 195
P a g e | 70
200 In benzene acetic dimerises but in water it does not
201 210
202 211
noticed.
of nonvolatile solute into solvent results into
depression of freezing point of solvent so both are true
and correct explanation. 212
achieved 213
Like dissolves like, i.e., non-polar solutes are Explanation is correct reason for statement.
(a) (c)
KCl is ionic salt and it dissociates in solution. (d →p, s) H 2 O+ H 2 SO 4=¿ Azeotropic mixture
(a)
(c→r)
221
(d→p)
experimentally by Berkeley and Hartley
(b→r) ∆ T b=T S −T °
226
(b→p¿ P=K H χ B (Henry’s law)
(a→s) Hypertonic solutions have higher
(a)
(c→s) Azeotropic mixture deviates from osmotic pressure than some other solutions
ideal solution
(b→q) Isotonic solutions have same osmotic
(d→r) For ideal solution ∆ mix V =0 ; ∆mix H=0 pressure than some other solutions
220 (c→r)
factor 227
(a→r) i is same for glucose, urea, fructose
The relative lowering of vapour pressure is
(b)
i.e., i=1
equal to the mole fraction of solute
P a g e | 72
Mol at eq 1−α
228 α
(b) 2
L represents ∆ T b=k b ∙m
Total moles ¿ 1−α + =1−
α α
229 2 2
Total moles at equilibrium α
Molarity of solution
(a)
∴ i= =1−
Initial moles 2
∆Tf 235
∆ T f =K f × m⇒ m=
Isotonic solution have same molarity
Kf (b)
−1
∆ T f =273−272.4=0.6 K , K f =0.86 K kg mol
Molarity of 18 g glucose = 276
18
0.6 /1000
∴ m= =0.322
1.86 =0.065
1000
230
or
0.023−P A 68.4 × 18 χB 1000
= ∆ T f =K f ∙ m=K f ∙ ×
0.023 342 ×100 1− χ B M w A
0.1 1000
or
0.023−P A ¿2× × =4.83 K
=0.0036 0.9 46
0.023 T f =T f °−∆ T f =155.7−4.83=150.87 K
or 0.023−P A=0.0036 ×0.023=0.000083 238
(a)
P A =0.023−0.00008=0.02292 atm Boiling point is higher if ∆ T b is higher
which in turn depends on
Vapor pressure of solution ¿ 0.02292 atm meffective (¿ ℑeffective )
231 ∴ 0.001 mUrea
¿ 0.001 mCH 3 COOH < 0.001m NaCl<0.001 m Mg Cl2
Hypertonic solutions have higher osmotic
(c)
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241 solution to urea solution is 3
(a)
The composition of 50% H 2 O and 50% HN O3
253
(b)
will lies in between the azeotropic mixture ∆ T =i K f m
and pure H 2 O. Therefore, distillation of such ( 273−269.28 )=i ×1.86 ×1
composition will give pure H 2 O and 3.72=i ×1.86
azeotropic mixture i=2
i−1
242 α= ; ( α=100 %=1 )
n−1
point. Now, π= RT
n
At T 2 , 50= …(ii)
243 n
(d) × R × 298
V2
Dividing (i) by (ii), we get
1000× K f × w
∆Tf= =K f × molality
= 1.86 ×0.1=0.186 ;
m× W
200 V 2 283
= × ⇒ V 2=2 V 1
Thus, f. p. = 0−0.186 ͦ C=−0.186 ͦ C
105.3 V 1 298
259
249
(b)
(a)
∆ T b=i K b m
0.27=i× 0.54 ×
12.2 1000
× π=CRT =
( )
W2
M w2
RT
V
or i=0.5 Given, W 2 =40 g
122 100
the ratios of any colligative property for BaC l 2 Total colligative properties are four
(d)
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