Latent Heat, Latent Heat of Vaporization - Physics@TutorVista
Latent Heat, Latent Heat of Vaporization - Physics@TutorVista
Latent Heat, Latent Heat of Vaporization - Physics@TutorVista
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LatentHeat
LatentHeatDefinition
LatentHeatFormula
LatentHeatof
Vaporization
LatentHeatof
Condensation
LatentHeatofFreezing
LatentHeatofFusion
LatentHeatofMelting
LatentHeat
Whenweboilwatertoevaporateitthenwhatweobserve.Weobservethatwhenwe
LatentHeatofSublimation
boilwatertoevaporateitat100C,thenallthegivenheatisabsorbedbytheliquid.
LatentHeatFlux
This absorbed heat is called latent heat of vaporization and taken by vapour
LatentHeatvsSensible
Heat
LatentHeatsof
Substances
molecules. Similarly, when we melt ice then it is converted into water because ice
moleculesabsorbthisheat.Thisiscalledlatentheatoffusion.
Thus,wecansaythattheamountofabsorbedorreleasedheatiscalled latent heat.
Thisheatisreleasedorabsorbedduringphysicalchange.Itisnamedaccordingtothe
process of physical change. It is expressed as per mole amount of released or
RelatedConcepts
definelatentheat
LatentHeatAnimation
ChangeofStateandSpecific
LatentHeatAnimation
LMUCaptivePortal
Username
LatentHeatDefinition
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LatentHyperopia
HeatAnimation
HeatEngines
But there are scenarios during which energy transfer between system and its
HeatLoss
surroundingsdoesnotresultinthechangeintemperatureofthesystem.Thisoccurs
whenever system changes from one of its phase to the another or we can say that
when the transfer of energy results in the change in the physical properties of the
RelatedFormulas
system. This change is termed as Phase Change or Phase Transition. Two main
Phasetransitionsare,
LatentHeatofVaporization
Equation
EquationforHeat
1. SolidtoLiquid
2. LiquidtoGas
EquationforHeatofFusion
Other phase transition is when change takes place in the crystalline structure of the
EquationforHeatTransfer
changeintheinternalenergyofthesystemtakesplace.
solid.WhenphaseTransitionoccurstemperatureofthesystemdoesnotchangebut
Attheboilingpointofthewaterwhenheatistransferredtothewateritresultsinthe
RelatedCalculators
breakingofmolecularbondsinwater.Asaresult,themoleculesbecomeapartastheir
potentialandkineticenergiesgetincreasedandwatergetsconvertedtothegaseous
HeatCalculator
HeatCapacityCalculator
HeatTransferCalculator
state.Everysubstancehasdifferentmolecularandatomicstructure.So,forthephase
transition to occur every substance requires different amount of energy depending on
their internal structure. It also depends on the mass of substance involved for the
phase transition. The substance of a particular type with larger quantity and mass
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HowtoCalculateSpecificHeat
1. PhasechangeNature
2. Properties(atomic,molecularstructureofthesubstance)
LatentHeatFormula
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Fromthedefinition,itisclearthattheamountofheatrequiredforaphasetransitionis
latentheat.Themathematicalrepresentationofthegivenstatementis,
Q = mL
L=
Q
m
Where,
L=Latentheatofthesubstance
Q=AmountofenergytransferredforthePhasechange
m=Massofthesubstance
LatentHeatofVaporization
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Latent heat of Vaporization is the Latent heat (explained above) when phase of the
substance changes from Liquid to gaseous state. Latent heat of vaporization is
denotedbyLV.
LatentHeatofCondensation
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LatentHeatofCondensationisdefinedasthequantityofheatneedstobetransferred
to convert a unit mass of a substance in gaseous phase into liquid phase at its
condensationpointatoneatmospherepressure.
L=
Q
m
KCal/Kg
LatentHeatofFreezing
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Q
m
KCalorie/Kg
LatentHeatofFusion
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LatentHeatofFusionisthelatentheat(explainedabove)whenphaseofthe
substancechangesfromSolidtoLiquidphase.LatentheatofFusionisdenotedbyLF.
Alsofusemeansmelting.
ForaparticularsubstanceLatentheatofVaporizationisgenerally
greaterthanitsLatentheatofFusion.
LatentHeatofMelting
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Q
m
Calorie/gmorKCalorie/Kg
LatentHeatofSublimation
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LatentHeatofSublimationisdefinedasthequantityofheatneedstobetransferredto
convertaunitmassofasubstanceinsolidphaseintogasphasewithoutpassingthe
substancethroughtheintermediatestateofLiquid,anddirectlytothegaseousphase
atitssublimationpointandatoneatmospherepressure.
LatentHeatFlux
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LatentHeatFluxisdenotedbyQewhenwaterevaporates,itremovessignificant
amountsofheat.Theenergythatisaddedtobreakthehydrogenbondstoallow
evaporationisremovedbythewatervapor.ItcanbecalculatedwiththehelpofBulk
Formula,
Qe
= a LE C L U10 (qa
qs )
Where,
a
=DensityOfair(1.2kg/m3)
LE
=LatentHeatofvaporization(2260kJ/kg)
CL
=Bulktransfercoefficient(StantonNumber)
U10
=Windspeedat10m
qa
=specificHumidityatsaturation
qs
=specificHumidityofoverlyingair
LatentHeatvsSensibleHeat
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LatentHeatistheheatwhichisrequiredtochangethephaseof
substancefromonestatetoother.Andintheotherhand,
SensibleHeatistheheatwhichisaddedortheheatwhichis
removedanditistheheatwhichchangesthetemperature.
SensibleHeat
Whenenergyorheatistransferredtothesubstance,itresultsinincreaseinits
temperature.Theincreaseintheheatofthesubstanceiscalledsensibleheat.
Similarly,whenheatistransferredfromthesubstancetoitssurroundings,heatis
removedfromthesubstanceandresultsindecreaseinthetemperatureofthesystem.
Theheatremovedfromthesubstanceisalsosensibleheat.Heat,becauseofwhich
changeintemperatureofthesubstancetakesplace,iscalledsensibleheat.
LatentHeat
IncontrasttoSensibleHeat,Latentheatdoesnotchangethetemperatureofthe
systembutitresultsintransitionofthephaseofthesubstancefromonephaseinto
other.
LatentHeatsofSubstances
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LatentHeatofWater,LatentHeatofIceandLatentHeatofSteamaregiveninthe
tablesbelow.LatentHeatofFusionandLatentHeatofVaporizationfordifferent
substancesaregiveninthebelowtables.
Table1:
Substance
Melting
LatentHeatOf
Boiling
LatentheatOf
Point(C)
Fusion(J/kg)
Point(C)
Vaporization(J\kg)
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269.65
5.23103
268.93
2.09104
Nitrogen
209.97
2.5510
195.81
2.01105
Oxygen
218.79
1.38104
182.97
2.13105
114
1.04105
78
8.54105
0.00
3.33105
100.00
2.26106
119
3.8110
444.60
3.26105
327.3
2.4510
1750
8.70105
660
3.97105
2450
1.14107
Silver
960.80
8.8210
2193
2.33106
Gold
1063.00
6.4410
2660
1.58106
1083
1.34105
1187
5.06106
Ethyl
Alcohol
Water
Sulphur
Lead
Aluminum
Copper
Table2:
Substance
LatentHeatof MeltingPoint
LatentheatOf
Vaporization(J\kg)
Fusion(kJ/kg)
(C)
Alcohol,Ethyl
108
114
855
78.3
Ammonia
339
75
1369
33.34
Carbondioxide
184
78
574
57
21
268.93
253
Helium
Hydrogen(2)
58
259
455
Lead[6]
24.5
327.5
871
1750
Nitrogen
25.7
210
200
196
Oxygen
13.9
219
213
183
R134a
101
215.9
26.6
Toluene
93
351
110.6
Turpentine
Water
293
334
2260
SpecificHeat
100
HeatTransfer
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