Prism Experiment
Prism Experiment
Prism Experiment
Spectrometer
1.1
Optical spectrometer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1.2
Mass spectrometer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1.3
Time-of-ight spectrometer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1.4
Magnetic spectrometer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1.5
Resolution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1.6
References
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Prism
2.1
2.1.1
2.2
2.3
Types of prisms . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.3.1
Dispersive prisms . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.3.2
Reective prisms . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.3.3
Polarizing prisms . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.3.4
Deecting prisms . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.4
In optometry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.5
See also . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.6
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.7
Further reading . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.8
External links . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Minimum deviation
3.1
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Angle of incidence
4.1
Optics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.1.1
Grazing angle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.2
4.3
See also . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.4
Notes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4.5
External links . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
ii
5
CONTENTS
Refractive index
10
5.1
Denition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
10
5.2
History . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
11
5.3
Typical values . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
11
5.3.1
11
5.3.2
12
5.4
Microscopic explanation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
12
5.5
Dispersion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
12
5.6
13
5.7
14
5.7.1
14
5.7.2
Refraction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
15
5.7.3
15
5.7.4
Reectivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
15
5.7.5
Lenses . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
15
5.7.6
Microscope resolution . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
16
5.7.7
16
5.7.8
Density . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
16
5.7.9
Group index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
17
17
17
5.7.12 Refractivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
17
17
5.8.1
Birefringence . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
17
5.8.2
Nonlinearity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
18
5.8.3
Inhomogeneity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
18
18
5.9.1
Homogeneous media . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
19
5.9.2
19
5.10 Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
20
20
5.12 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
20
22
Prism spectrometer
23
6.1
Theory . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
23
6.2
Usage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
23
6.2.1
Spectroscopy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
23
6.2.2
23
6.3
External links . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
24
6.4
25
6.4.1
25
5.8
5.9
Text . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
CONTENTS
iii
6.4.2
Images . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
26
6.4.3
Content license . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
27
Chapter 1
Spectrometer
In physics, a spectrometer is an apparatus to measure a
spectrum.[1] Generally, a spectrum is a graph that shows
intensity as a function of wavelength, of frequency, of
energy, of momentum, or of mass.
F
+
Optical spectrometers (often simply called spectrometers), in particular, show the intensity of light as a function of wavelength or of frequency. The deection is produced either by refraction in a prism or by diraction in
a diraction grating.
CHAPTER 1. SPECTROMETER
Since Danysz' time, many types of magnetic spectrometers more complicated than the semicircular type have
been devised.[1]
1.5 Resolution
Generally, the resolution of an instrument tells us how
well two close-lying energies (or wavelengths, or frequencies, or masses) can be resolved. Generally, for an instrument with mechanical slits, higher resolution will mean
lower intensity.[1]
1.6 References
[1] K. Siegbahn, Alpha-, Beta- and Gamma-Ray Spectroscopy, North-Holland Publishing Co. Amsterdam
(1966)
[2] mass
spectrometer
doi:10.1351/goldbook.M03732.
(PDF).
2009.
Chapter 2
Prism
This article is about a prism in optics. For a prism in ge- light into components with dierent polarizations.
ometry, see Prism (geometry). For other uses, see Prism
(disambiguation).
Prismatic redirects here. For other uses, see Prismatic 2.1 How prisms work
(disambiguation).
In optics, a prism is a transparent optical element with
Light changes speed as it moves from one medium to another (for example, from air into the glass of the prism).
This speed change causes the light to be refracted and
to enter the new medium at a dierent angle (Huygens
principle). The degree of bending of the lights path depends on the angle that the incident beam of light makes
with the surface, and on the ratio between the refractive
indices of the two media (Snells law). The refractive
index of many materials (such as glass) varies with the
wavelength or color of the light used, a phenomenon
known as dispersion. This causes light of dierent colors to be refracted dierently and to leave the prism at
dierent angles, creating an eect similar to a rainbow.
This can be used to separate a beam of white light into
its constituent spectrum of colors. Prisms will generally
disperse light over a much larger frequency bandwidth
than diraction gratings, making them useful for broadspectrum spectroscopy. Furthermore, prisms do not suffer from complications arising from overlapping spectral
orders, which all gratings have.
A plastic prism
CHAPTER 2. PRISM
prism hits one of the surfaces at a suciently steep angle, total internal reection occurs and all of the light is
reected. This makes a prism a useful substitute for a
mirror in some situations.
2.1.1
0
1
0
0
2
1
= 0
(n
)
1
= arcsin
sin 1
n2
= 1
2.3.1
Dispersive prisms
AbbeKoenig prism
SchmidtPechan prism
Bauernfeind prism
Dove prism
2
Comparison of the spectra obtained from a diraction grating
by diraction (1), and a prism by refraction (2). Longer wavelengths (red) are diracted more, but refracted less than shorter
wavelengths (violet).
Retroreector prism
Beam-splitting prisms
Some reective prisms are used for splitting a beam into
two or more beams:
Beam splitter cube
Dichroic prism
Dispersive prisms are used to break up light into its con- There are also polarizing prisms which can split a beam
stituent spectral colors because the refractive index de- of light into components of varying polarization. These
pends on frequency; the white light entering the prism is a are typically made of a birefringent crystalline material.
mixture of dierent frequencies, each of which gets bent
slightly dierently. Blue light is slowed down more than
Nicol prism
red light and will therefore be bent more than red light.
Wollaston prism
Triangular prism
Nomarski prism a variant of the Wollaston prism
with advantages in microscopy
Abbe prism
PellinBroca prism
Amici prism
Compound prism
Grism, a dispersive prism with a diraction grating
on its surface
Rochon prism
Snarmont prism
GlanFoucault prism
GlanTaylor prism
GlanThompson prism
CHAPTER 2. PRISM
2.3.4
Deecting prisms
2.4 In optometry
By shifting corrective lenses o axis, images seen through
them can be displaced in the same way that a prism displaces images. Eye care professionals use prisms, as well
as lenses o axis, to treat various orthoptics problems:
Diplopia (double vision)
Positive and negative fusion problems
Positive relative accommodation and negative relative accommodation problems.
Prism spectacles with a single prism perform a relative
displacement of the two eyes, thereby correcting eso-,
exo, hyper- or hypotropia.
In contrast, spectacles with prisms of equal power for
both eyes, called yoked prisms (also: conjugate prisms,
ambient lenses or performance glasses) shift the visual
eld of both eyes to the same extent.[5]
2.6 References
[1] I. Newton (1704). Opticks. London: Royal Society. ISBN
0-486-60205-2.
[2] The Discovery of the Spectrum of Light. Retrieved 19
December 2009.
[3] F. J. Duarte and J. A. Piper (1982). Dispersion
theory of multiple-prism beam expanders for pulsed
dye lasers.
Opt.
Commun.
43 (5): 303
307. Bibcode:1982OptCo..43..303D. doi:10.1016/00304018(82)90216-4.
[4] B.D. Duncan; et al. (2003). Wide-angle achromatic prism beam steering for infrared countermeasure applications.
Opt.
Eng.
42 (4):
10381047.
Bibcode:2003OptEn..42.1038D.
doi:10.1117/1.1556393.
[5] Kaplan, M; Carmody, D. P.; Gaydos, A (1996). Postural
orientation modications in autism in response to ambient
lenses. Child Psychiatry and Human Development 27 (2):
8191. PMID 8936794.
Chapter 3
Minimum deviation
prism or water drop is deected twice: once entering, and
again when exiting. The sum of these two deections is
called the deviation angle.
The deviation angle in a prism depends upon:
Refractive index of the prism: The refractive index depends on the material and the wavelength of the light. The
larger the refractive index, the larger the deviation angle.
Angle of the prism: The larger the prism angle, the
larger the deviation angle.
n =
sin( 2 )
sin( A
2 )
3.1 References
Chapter 4
Angle of incidence
for nearly 50 years until a closed-form result was derived
by mathematicians Allen R Miller and Emanuel Vegh in
1991.[1]
ed
ct
Total internal
reection
Re
f
y
t ra
en
Inc
id
n1
Critical angle
ra
n2
ra
Air
Water
When dealing with a beam that is nearly parallel to a surface, it is sometimes more useful to refer to the angle beAngle of incidence is a measure of deviation of some- tween the beam and the surface, rather than that between
thing from straight on, for example:
the beam and the surface normal, in other words 90 minus the angle of incidence. This small angle is called a
in the approach of a ray to a surface, or
glancing angle or grazing angle. Incidence at grazing
angles is called grazing incidence.
the angle at which the wing or horizontal tail of an
airplane is installed on the fuselage, measured rela- Grazing incidence diraction is used in X-ray spectroscopy and atom optics, where signicant reection can
tive to the axis of the fuselage.
be achieved only at small values of the grazing angle.
Ridged mirrors are designed for reection of atoms coming at small grazing angle. This angle is usually measured
4.1 Optics
in milliradians. In optics, there is Lloyds mirror.
In geometric optics, the angle of incidence is the angle
between a ray incident on a surface and the line perpendicular to the surface at the point of incidence, called the
normal. The ray can be formed by any wave: optical,
acoustic, microwave, X-ray and so on. In the gure above,
the red line representing a ray makes an angle with the
normal (dotted line). The angle of incidence at which
light is rst totally internally reected is known as the
critical angle. The angle of reection and angle of refraction are other angles related to beams.
4.4 Notes
[1] Allen R Miller and Emanuel Vegh (1993).
Exact Result for the Grazing Angle of Specular Reection from a Sphere. SIAM Review 35: 472480.
doi:10.1137/1035091.
[2] Phillips, Warren F. (2010). Mechanics of Flight (2nd ed.).
Wiley & Sons. ISBN 978-0-470-53975-0.
Angle of incidence,
Chapter 5
Refractive index
torically rst use of refractive indices and is described by
Snells law of refraction, n1 sin 1 = n2 sin 2 , where 1
and 2 are the angles of incidence and refraction, respectively, of a ray crossing the interface between two media
with refractive indices n1 and n2 . The refractive indices
also determine the amount of light that is reected when
reaching the interface, as well as the critical angle for total
internal reection and Brewsters angle.[1]
The refractive index can be seen as the factor by which
the speed and the wavelength of the radiation are reduced
with respect to their vacuum values: the phase velocity of
light in a medium is v = c/n, and similarly the wavelength
in that medium is = 0 /n, where 0 is the wavelength
A ray of light being refracted in a plastic block.
of that light in vacuum. This implies that vacuum has a
In optics the refractive index or index of refraction refractive index of 1, and that the frequency (f = v/) of
n of an optical medium is a dimensionless number that the wave is not aected by the refractive index.
describes how light, or any other radiation, propagates The refractive index varies with the wavelength of light.
through that medium. It is dened as
This is called dispersion and causes the splitting of white
light into its constituent colors in prisms and rainbows,
and chromatic aberration in lenses. Light propagation in
c
n= ,
absorbing materials can be described using a complexv
valued refractive index.[2] The imaginary part then hanwhere c is the speed of light in vacuum and v is the phase
dles the attenuation, while the real part accounts for revelocity of light in the medium.
fraction.
refractive index
n1 n2
interface
normal
5.1 Denition
The refractive index n of an optical medium is dened as
the ratio of the speed of light in vacuum, c = 299792458
m/s, and the phase velocity v of light in the medium,[1]
n=
c
.
v
The refractive index determines how much light is bent, The phase velocity is the speed at which the crests or the
or refracted, when entering a material. This is the his- phase of the wave moves, which may be dierent from
10
11
5.2 History
12
ple, water has a refractive index of 0.99999974 = 1 radiated in other directions or even at other frequencies
2.6107 for X-ray radiation at a photon energy of 30 (see scattering).
keV (0.04 nm wavelength).[16]
Depending on the relative phase of the original driving
wave and the waves radiated by the charge motion, there
are several possibilities:
5.3.2
materials with a negative refractive index, which can occur if permittivity and permeability have simultaneous
negative values.[17] This can be achieved with periodically
constructed metamaterials. The resulting negative refraction (i.e., a reversal of Snells law) oers the possibility
of the superlens and other exotic phenomena.[18]
5.5 Dispersion
Main article: Dispersion (optics)
The refractive index of materials varies with the wavelength (and frequency) of light.[20] This is called dispersion and causes prisms and rainbows to divide white light
into its constituent spectral colors.[21] As the refractive
index varies with wavelength, so will the refraction angle as light goes from one material to another. Dispersion also causes the focal length of lenses to be wavelength dependent. This is a type of chromatic aberration, which often needs to be corrected for in imaging
systems. In regions of the spectrum where the material
13
V =
nyellow 1
.
nblue nred
For a more accurate description of the wavelength dependence of the refractive index, the Sellmeier equation
can be used.[22] It is an empirical formula that works well
in describing dispersion. Sellmeier coecients are often
quoted instead of the refractive index in tables.
Because of dispersion, it is usually important to specify
the vacuum wavelength of light for which a refractive index is measured. Typically, measurements are done at
various well-dened spectral emission lines; for example,
nD usually denotes the refractive index at the Fraunhofer
D line, the centre of the yellow sodium double emission
at 589.29 nm wavelength.[11]
n = n + i.
does not absorb light, the refractive index tends to decrease with increasing wavelength, and thus increase with
frequency. This is called normal dispersion, in contrast
to anomalous dispersion, where the refractive index increases with wavelength.[20] For visible light normal dispersion means that the refractive index is higher for blue
light than for red.
14
quantities
Both n and are dependent on the frequency. In most circumstances > 0 (light is absorbed) or = 0 (light travels
forever without loss). In special situations, especially in
the gain medium of lasers, it is also possible that < 0,
corresponding to an amplication of the light.
An alternative convention uses n = n i instead of n = n
+ i, but where > 0 still corresponds to loss. Therefore
these two conventions are inconsistent and should not be
confused. The dierence is related to dening sinusoidal
time dependence as Re[exp(it)] versus Re[exp(+it)]. The colors of a soap bubble are determined by the optical path
See Mathematical descriptions of opacity.
length through the thin soap lm in a phenomenon called thinDielectric loss and non-zero DC conductivity in materials cause absorption. Good dielectric materials such as
glass have extremely low DC conductivity, and at low
frequencies the dielectric loss is also negligible, resulting
in almost no absorption. However, at higher frequencies
(such as visible light), dielectric loss may increase absorp-
lm interference.
15
OPL = nd.
This is an important concept in optics because it determines the phase of the light and governs interference
and diraction of light as it propagates. According to
Fermats principle, light rays can be characterized as
those curves that optimize the optical path length.[1]:6869
5.7.2
Refraction
n1
v1
n2 index
v2 velocity
normal
interface
n1 sin 1 = n2 sin 2 .
When light enters a material with higher refractive index,
the angle of refraction will be smaller than the angle of incidence and the light will be refracted towards the normal
of the surface. The higher the refractive index, the closer
to the normal direction the light will travel. When passing into a medium with lower refractive index, the light
will instead be refracted away from the normal, towards
the surface.
5.7.3
)
n2
c = arcsin
.
n1
5.7.4 Reectivity
Apart from the transmitted light there is also a reected
part. The reection angle is equal to the incidence angle,
and the amount of light that is reected is determined by
the reectivity of the surface. The reectivity can be calculated from the refractive index and the incidence angle
with the Fresnel equations, which for normal incidence
reduces to[26]:44
n1 n2 2
.
R0 =
n1 + n2
For common glass in air, n1 = 1 and n2 = 1.5, and thus
about 4% of the incident power is reected.[28] At other
incidence angles the reectivity will also depend on the
polarization of the incoming light. At a certain angle
called Brewsters angle, p-polarized light (light with the
electric eld in the plane of incidence) will be totally
transmitted. Brewsters angle can be calculated from the
two refractive indices of the interface as [1]:245
( )
n2
B = arctan
.
n1
n1
sin 1 > 1,
n2
5.7.5 Lenses
the light cannot be transmitted and will instead undergo The focal length of a lens is determined by its refractotal internal reection.[26]:4950 This occurs only when tive index n and the radii of curvature R1 and R2 of its
16
,
f
R1
R2
where f is the focal length of the lens.
5.7.6
Microscope resolution
r = 2n,
and:
n=
|r | + r
,
2
|r | r
.
2
5.7.8 Density
The resolution of a good optical microscope is mainly determined by the numerical aperture (NA) of its objective
lens. The numerical aperture in turn is determined by the
refractive index n of the medium lling the space between
the sample and the lens and the half collection angle of
light according to[30]:6
NA = n sin .
For this reason oil immersion is commonly used to obtain high resolution in microscopy. In this technique the
objective is dipped into a drop of high refractive index Relation between the refractive index and the density of silicate
immersion oil on the sample under study.[30]:14
and borosilicate glasses.[34]
5.7.7
Relative permittivity and permeabil- its density. However, there does not exist an overall linity
ear relation between the refractive index and the density
n=
r r ,
5.7.9
17
Group index
c
,
vg
n
.
1 + n dn
d
5.7.12 Refractivity
In atmospheric applications, the refractivity is taken as N
= n 1. Atmospheric refractivity is often expressed as
either[40] N = 106 (n 1)[41][42] or N = 108 (n 1)[43] The
multiplication factors are used because the refractive index for air, n deviates from unity by at most a few parts
per ten thousand.
Molar refractivity, on the other hand, is a measure of the
total polarizability of a mole of a substance and can be
calculated from the refractive index as
ng = n 0
5.7.10
M n2 1
,
n2 + 2
p=
A=
18
5.8.2 Nonlinearity
A calcite crystal laid upon a paper with some letters showing
double refraction.
5.8.3 Inhomogeneity
A gradient-index lens with a parabolic variation of refractive index (n) with radial distance (x). The lens focuses light in the
same way as a conventional lens.
5.9.1
Homogeneous media
19
chemical and pharmaceutical industry for process control.
ent under Bright-eld_microscopy as most cellular structures do not attenuate appreciable quantities of light.
Nevertheless, the variation in the materials that constitutes these structures also corresponds to a variation in
the refractive index. The following techniques convert
such variation into measurable amplitude dierences:
This type of devices are commonly used in chemical laboratories for identication of substances and for quality
control. Handheld variants are used in agriculture by,
e.g., wine makers to determine sugar content in grape
juice, and inline process refractometers are used in, e.g.,
20
Zernike phase-contrast microscopy introduces a phase
shift to the low spatial frequency components of the image
with a phase-shifting annulus in the Fourier plane of the
sample, so that high-spatial-frequency parts of the image can interfere with the low-frequency reference beam.
In DIC the illumination is split up into two beams that
are given dierent polarizations, are phase shifted dierently, and are shifted transversely with slightly dierent
amounts. After the specimen, the two parts are made to
interfere, giving an image of the derivative of the optical path length in the direction of the dierence in transverse shift.[30] In interferometry the illumination is split
up into two beams by a partially reective mirror. One of
the beams is let through the sample before they are combined to interfere and give a direct image of the phase
shifts. If the optical path length variations are more than
a wavelength the image will contain fringes.
There exist several phase-contrast X-ray imaging techniques to determine 2D or 3D spatial distribution of refractive index of samples in the X-ray regime.[48]
5.10 Applications
The refractive index is a very important property of the
components of any optical instrument that uses refraction.
It determines the focusing power of lenses, the dispersive
power of prisms, and generally the path of light through
the system. It is the increase in refractive index in the core
that guides the light in an optical ber, and the variations
in refractive index that reduces the reectivity of a surface
treated with an anti-reective coating.
5.12 References
[1] Hecht, Eugene (2002). Optics. Addison-Wesley. ISBN
0-321-18878-0.
[2] Attwood, David (1999). Soft X-rays and extreme ultraviolet radiation: principles and applications. p. 60. ISBN
0-521-02997-X.
[3] Kinsler, Lawrence E. (2000). Fundamentals of Acoustics.
John Wiley. p. 136. ISBN 0-471-84789-5.
[4] Young, Thomas (1807). A course of lectures on natural
philosophy and the mechanical arts. p. 413.
[5] Newton, Isaac (1730). Opticks: Or, A Treatise of the Reections, Refractions, Inections and Colours of Light. p.
247.
[6] Hauksbee, Francis (1710). A Description of the Apparatus for Making Experiments on the Refractions of Fluids.
Philosophical Transactions of the Royal Society of London
27 (325336): 207. doi:10.1098/rstl.1710.0015.
[7] Hutton, Charles (1795). Philosophical and mathematical
dictionary. p. 299.
Since refractive index is a fundamental physical property [8] von Fraunhofer, Joseph (1817). Bestimmung des
of a substance, it is often used to identify a particular subBrechungs und Farbenzerstreuungs Vermogens verstance, conrm its purity, or measure its concentration.
schiedener Glasarten. Denkschriften der Kniglichen
Refractive index is used to measure solids, liquids, and
Akademie der Wissenschaften zu Mnchen 5: 208. Exgases. Most commonly it is used to measure the concenponent des Brechungsverhltnisses is index of refraction
tration of a solute in an aqueous solution. It can also be
used as a useful tool to dierentiate between dierent [9] Brewster, David (1815). On the structure of doubly
refracting crystals. Philosophical Magazine 45: 126.
types of gemstone, due to the unique chatoyance each indoi:10.1080/14786441508638398.
dividual stone displays. A refractometer is the instrument
used to measure refractive index. For a solution of sugar, [10] Herschel, John F.W. (1828). On the Theory of Light. p.
the refractive index can be used to determine the sugar
368.
content (see Brix).
[11] Forensic Science Communications, Glass Refractive In-
5.12. REFERENCES
[15] Als-Nielsen, J.; McMorrow, D. (2011). Elements of Modern X-ray Physics. Wiley-VCH. p. 25. ISBN 978-0-47097395-0. One consequence of the real part of n being less
than unity is that it implies that the phase velocity inside
the material, c/n, is larger than the velocity of light, c. This
does not, however, violate the law of relativity, which requires that only signals carrying information do not travel
faster than c. Such signals move with the group velocity,
not with the phase velocity, and it can be shown that the
group velocity is in fact less than c.
[16] X-Ray Interactions With Matter. The Center for X-Ray
Optics. Retrieved 2011-08-30.
[17] Veselago, V. G. (1968).
The electrodynamics of substances with simultaneously negative
values of and ".
Soviet Physics Uspekhi 10
(4):
509514.
Bibcode:1968SvPhU..10..509V.
doi:10.1070/PU1968v010n04ABEH003699.
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Chapter 6
Prism spectrometer
which in turn is slightly dependent on the wavelength of
light that is traveling through it.
6.1 Theory
Light is emitted from a source such as a vapor lamp. A
slit selects a thin strip of light which passes through the
collimator where it gets parallelized. The aligned light
then passes through the prism in which it is refracted
twice (once when entering and once when leaving). Due
to the nature of a dispersive element the angle with which
light is refracted depends on its wavelength. This leads to
a spectrum of thin lines of light, each being observable at
a dierent angle.
Replacing the prism with a diraction grating would result in a grating spectrometer. Optical gratings are less
expensive, provide much higher resolution, and are easier to calibrate, due to their linear diraction dependency.
A prisms refraction angle varies nonlinearly with wavelength. On the other hand, gratings have signicant intensity losses.
6.2 Usage
6.2.1 Spectroscopy
A prism spectrometer may be used to determine the composition of a material from its emitted spectral lines.
A prism spectrometer may be used to measure the refractive index of a material if the wavelengths of the light
used are known. The calibration of a prism spectrometer
is carried out with known spectral lines from vapor lamps
or laser light.
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