Naphthenic Base Lube Oil Manufactured Via Hydrogenation Process Naphthenic Base Lube Oil Manufactured Via Hydrogenation Process

Naphthenic Base Lube Oil Manufactured
Via Hydrogenation Process
Reporter ZHEN Xinping ,ZHANG Hong

Written byZHEN Xinping, ZHANG Hong, QIN Benji, LI Rong
CONTENTS
1
Foreword
2
3
4
5
Characteristics of naphthenic heavy oil from Karamay

To manufacture transformer oils via hydrotreating
combined process
To manufacture rubber oil and bright stock oil via highpressure hydrogenation process
Commercialized
1.FOREWORD
In 1980s, about 0.6 billion tons of

reserves of naphthenic base heavy
oil was been discovered in
Karamay.
Naphtenic base heavy oil and

paraffinic base oil distribute
crossly under ground, and lack of
efficient way to separate them.
How to get pure naphthenic base

heavy oil is the most important
precondition for process these two
kinds of crude oil efficiently.
1.FOREWORD
Naphthenic base heavy oil is high in Acid number, low in yield of its light fraction , and
makes equipment corrosive so bad, makes refinery long time operation not safe, lower
economic benefit, even make lower percentage in refined crude oil.
Pure naphthenic heavy oil is low in solidifying point, is high in cycle-alkane content, is
suitable to manufacture special lube oil. To process naphthenic heavy oil at local field is
easier to make resource utilization effectively.
Naphthen
ic Heavy
Oil
Da Qing
Crude
Oil
Density at 20, kg/L
0.939
0.861
Acid Value ,mgKOH/g
9.33
0.03
CCR, m%
5.78
3.2
Colloid, m%
19.11
10.22
Wax, m%
2.38
26.14
Ca, g/g
212
<1
Solidifying Point,
-20
30
Properties
Karamay Naphthenic
High-end
1.FOREWORD
In Karamay Oil Field, about two thousands sets of mining system
and 6 sets of transporting system to ensure naphthenic base
crude oil mined, transported and refined separately in large scale.
Naphthenic
base crude oil
Storing
separately
Collect
crude
Mining
separately
Paraffinic
Collect
crude
For paraffin
Paraffinic
base crude
Transporting
separately
For Naphthenic
Refining
separately
High-end
special lube oil
CONTENTS
1
Foreword
2
3
4
5

combined process
Commercialized
Karamay
From 9th
Properties
district in
Karamay
Heavy
Oil classification
naphthenic
Density at 20,
928.8
kg/m3
Viscosity at
229.1
50, mm2/s
Solidifying point,
-21
Acid value,
4.72
mgKOH/g
No. 3 Crude oil Huan Xiling From Suizhong

in Karamay
heavy crude
361
Merey Crude
oil in
Venezuela
Heavy
naphthenic
Medium
naphthenic
Heavy
naphthenic
Heavy
naphthenic
883.4
943.4
943.4
959.3
33.01
679
560
206.8
-54
-20
-2
-12
1.82
3.71
3.33
1.24
Sulfur, %
0.1
0.12
0.26
0.39
2.49
Nitrogen, %
0.1
0.41
0.53
0.5
CCR, %
5.5
3.8
4.8
9.1
11.5
Wax, %
1.42
1.05
2.2
1.32
2.4
Colloid, %
23.5
13.3
20.5
21.8
2. Characteristics of Naphthenic Heavy Oil from Karamay
Karamay naphthenic crude oil is very typically, a kind of

heavy oil with low sulfur content, high viscosity, high acid
value, and special in low asphaltene content.
Distillations from Karamay naphthenic crude oil compared with Huan Xinling
and Suzhong 361 heavy crude oil in viscosity and solidifying point
Distillations from Karamay naphthenic crude oil compared with Huan Xinling
and Suzhong 361 heavy crude oil in CA
Aromatic Hydrocarbons in Karamay naphthenic heavy crude oil is
lower, equal to the half of the two others, and is suitable to manufacture
CONTENTS
1
Foreword
2
3
4
5

combined process
Commercialized
3.To Manufacture Transformer Oils via Hydrotreating

Combined Process
PCA is transformed to ideal component via Hydrotreating
Combined Process

Combined Process
1. Variation Law about how hydrocarbons generate hydrogen and
effects oxidation resistance in high voltage electric field, that work
as important guideline to design catalyst and combined process
H2 evolutionL/min
oxidation stability (RBOT)

min
alkane
+40emit
300
alkane+10% mono-aromatic
+30emit
200
alkane+1% di-aromatics
-10absorb
280
alkane+1% tri-aromatics
+35emit
180
alkane+1% tetra-aromatics
+34emit
150

Combined Process
ooling, Insulation,
limate adaptation, Long
eriod operation,
formation carrier, HSE
alkanes
yclane
ono-aromatics
-aromatics
CA
Low
High
Moderate
Moderate
Low

Combined Process
2. Modified catalyst used under medium pressure, select Alumina
with suitable pore size as carrier, use Ni-W active component,
increase acidity in catalytic, to improve transformed yield about
aromatics.
Ideal component

Combined Process
3. Hydrotreating combined process to manufacture transformer oil, by means
of opertimizing process condition, controlling hydrotreating reaction extent to
improve mono-aromatics and di-aromatics contents about 2 times to solvent
refining process.
Compared data about Aromatic contents and hydrogen evolution in
transformer oil made by different process
properties
Mono-aromatic%
Di-aromatics%
H2 evolutionL/min
Hydrotreating
combined process
Solvent refining
process
improvement%
22.6
8.5
+166
7.0
1.6
+338
-25absorb
+20emit
+225

Combined Process
Aromatic content in transformer base oil will be controlled effectively
via combining this two process; 12 types of products were passed
SIEMENSABB examination and got their certification.
CONTENTS
1
Foreword
2
3
4
5

combined process
Commercialized
high-pressure hydrogenation process
RHW process is a kind of all hydrogen type high pressure

hydrogenation technique to manufacture naphthenic base lube oil w
low aromatic, which can be used to control aromatics saturated and
hydrogenation extent flexiblely.
1.RHW process integrate advantages from combined catalytic to

process different raw materials. Its turn round period is more than 3
years.
H2
1. Invent catalyst RDW-1 used to hydrotreating de-wax, design Molecular

Sieve Pretreatment process to remove alkanes with large molecule, develop
catalyst formed technique to improve its strength, add active metal in catalyst to
enhance its carbon deposition resistance.
0.51-0.57nm
D=0.54nm

2. Based on reaction chemical mechanism, saturate aromatics at suitable
reaction condition, to get rubber oil and maximum yield.
Vacuum Dist
line 2
KN4006
Vacuum Dist
line 3
KN4010
25
-43
40mm2/s
51.41
45.88
301.6
143.6
100mm2/s
5.648
5.549
13.58
9.866
Flash point
192
195
214
220
Pour point
-21
<-33.0
-7
-24
Nitrogeng/g
267.8
12.9
733.6
7.1
52
<5
623.6
<5
Saturated
hydrocarbons,%
70.62
98.02
71.31
97.51
Aromatics,%
29.38
1.98
28.68
2.49
4.5
Properties
VI
Sulfurg/g
colour

2. More than 20 kinds of rubber oil have been developed successfully,
which PCA is lower than the most strict limitation of I grade (< 0.2mg/kg)
from EU. And Karamay Petrochemical Co. become famous long-term
appointed rubber oil supplier for rubber manufacturer.
SN
Products
SN
Products
SN
Products
K6H
KNH4008
17
KGN3510
K10H
10
KNH4010
18
KFN3506
YT-6
11
KPH6006
19
KFN3508
YT-10
12
KPH6008
20
KFN3510
KN4006
13
KPH6010
21
KJN360
KN4010
14
KP6030
22
KZ50
KN4012
15
KP6035
23
KZ160
3. Based on reaction chemical mechanism, control the extent of reaction, make

aromatic saturated and rings opened to get 150 BS with high viscosity and
viscosity index at same time.
properties
DAO
150BS
54
83
74.19
32.25
288
281
Pour point
-12.5
Nitrogeng/g
948.8
5.6
sulfurg/g
1144
5.7
Saturated
hydrocarbons,%
66.84
92.86
Aromatics,%
33.16
7.14
360
VI
100mm2/s
Flash point (O)
Rotating bomb/min

3. In 2010 year, 119 thousands tons of Bright Stock (API II) was
manufactured and salt out to produce high grade lube oil as important
mixture .
CONTENTS
1
Foreword
2
3
4
5

combined process
Commercialized
5.COMMERCIALIZED
Transformer
oil
Rubber
oil
Bright
stock
Hydrogenate
Hydrotreating combine
distillate
SDA
A complete industrial chain has been formed in Karamay , from
asphalt
Mix &
modified
5.COMMERCIALIZED
Got CHINA PRODUCT QUALITY

ASSOCIATION awards!
In 2003 year, got Quality prize

medal for naphthenic rubber oil
In 2005 year, got the Quality

for prize medal road asphalt
5.COMMERCIALIZED
Outputs of 2010
Global
thousands ton ranking
1
White naphthenic rubber oil
340
Nynas
Transformer oil
Doble in USA
SN
High-end special lube oil
174
Data from
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Naphthenic Base Lube Oil Manufactured

Via Hydrogenation Process

Reporter ZHEN Xinping ,ZHANG Hong

Characteristics of naphthenic heavy oil from Karamay

In 1980s, about 0.6 billion tons of

Naphtenic base heavy oil and

How to get pure naphthenic base

Density at 20, kg/L

Acid Value ,mgKOH/g

Characteristics of naphthenic heavy oil from Karamay

No. 3 Crude oil Huan Xiling From Suizhong

2. Characteristics of Naphthenic Heavy Oil from Karamay

Karamay naphthenic crude oil is very typically, a kind of

2. Characteristics of Naphthenic Heavy Oil from Karamay

2. Characteristics of Naphthenic Heavy Oil from Karamay

Characteristics of naphthenic heavy oil from Karamay

3.To Manufacture Transformer Oils via Hydrotreating

3.To Manufacture Transformer Oils via Hydrotreating

oxidation stability (RBOT)

3.To Manufacture Transformer Oils via Hydrotreating

3.To Manufacture Transformer Oils via Hydrotreating

3.To Manufacture Transformer Oils via Hydrotreating

3.To Manufacture Transformer Oils via Hydrotreating

Characteristics of naphthenic heavy oil from Karamay

high-pressure hydrogenation process

RHW process is a kind of all hydrogen type high pressure

high-pressure hydrogenation process

1.RHW process integrate advantages from combined catalytic to

high-pressure hydrogenation process

1. Invent catalyst RDW-1 used to hydrotreating de-wax, design Molecular

high-pressure hydrogenation process

high-pressure hydrogenation process

high-pressure hydrogenation process

3. Based on reaction chemical mechanism, control the extent of reaction, make

high-pressure hydrogenation process

Characteristics of naphthenic heavy oil from Karamay

A complete industrial chain has been formed in Karamay , from

Got CHINA PRODUCT QUALITY

In 2003 year, got Quality prize

In 2005 year, got the Quality

High-end special lube oil

Give Our Respective

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