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1 2 The Mole and Molar Mass

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The Mole & Molar Mass

The mole is the standard method in chemistry for communicating how much of a
substance is present.
Here is how the International Union of Pure and Applied Chemistry (IUPAC) defines
"mole:"
The mole is the amount of substance of a system which contains as many elementary
entities as there are atoms in 0.012 kilogram of carbon-12. When the mole is used, the
elementary entities must be specified and may be atoms, molecules, ions, electrons,
other particles, or specified groups of such particles.
This is the fundamental definition of what one mole is. One mole contains as many
entities as there are in 12 grams of carbon-12 (or 0.012 kilogram).
In one mole, there are 6.022 x 1023 atoms. Here's another way: there are 6.022 x
1023 atoms of carbon in 12 grams of carbon-12.

Let's say that real clearly: one mole of ANYTHING contains 6.022 x 10 23 entities.

The word "entities" is simply a generic word. For example, if we were discussing
atoms, then we would use "atoms" and if molecules were the subject of discussion, the
word entities would be replaced in actual use by "molecules."
Avogadro's Number has been very carefully measured in a number of ways over many
decades. The symbol for mole is "mol." Why does a four-letter word have a threeletter symbol? That's really the wrong question.
Here it is again: one mole of ANY specified entity contains 6.022 x 10 23 of that entity.
For example:
One mole of donuts contains 6.022 x 1023 donuts
One mole of H2O contains 6.022 x 1023 molecules

One mole of nails contains 6.022 x 1023 nails


One mole of Fe contains 6.022 x 1023 atoms
One mole of dogs contains 6.022 x 1023 dogs
One mole of electrons contains 6.022 x 1023 electrons
One mole of IB Chemistry students contains 6.022 x 10 23 poor, suffering (I
mean happy, joyful) high school students
Get the idea?
6.022 x 1023 is so important in chemistry that it has a name. It is called Avogadro's
Number and has the symbol N. It is so named in honor of Amedeo Avogadro, an
Italian chemist, who, in 1811, made a critical contribution (recognized only in 1860
after his death) which helped greatly with the measurement of atomic weights.

Avogadro's Number has a unit associated with it. It is mol 1, as in 6.022 x 1023 mol1.
The superscripted minus one means the unit mol is in the denominator. There is an
understood numerator of one, as in 1/mol.
Why is there no unit in the numerator? There could be, but it would vary based on the
entity involved. If we were discussing an element, we might write atoms/mol. If we
were discussing a compound, we would say "molecules per mol." What is in the
numerator depends on what "entity" (atom, molecule, ion, electron, etc.) is being used
in the problem.
Consequently, units names in the numerator are not used and a one is used instead.

Getting back to Avogadro's Number role in chemistry; please note that counting atoms
or molecules is very difficult since they are so small. However, we can "count" atoms
or molecules by weighing large amounts of them on a balance.
When we weigh one mole of a substance on a balance, this is called a "molar mass"
and has the units g/mol (grams per mole). This idea is very critical because it is used
all the time.

A molar mass is the weight in grams of one mole.


One mole contains 6.022 x 1023 entities.
Therefore, a molar mass is the mass in grams of 6.022 x 10 23 entities.
OK. How does one calculate a molar mass? Get ready, because you already know how
to calculate a molar mass.
The molar mass of a substance is the molecular weight in grams.
All you need to do is calculate the molecular weight and stick the unit "g/mol" after
the number and that is the molar mass for the substance in question.

Calculate the molar mass of Al(NO3)3


(1 x 26.98) + (3 x 14.007) + (9 x 16.00) = 213.00 g/mol
213.00 grams is the mass of one mole of aluminum nitrate.
213.00 grams of aluminum nitrate contains 6.022 x 10 23 entities of Al(NO3)3

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