1 2 The Mole and Molar Mass
1 2 The Mole and Molar Mass
1 2 The Mole and Molar Mass
The mole is the standard method in chemistry for communicating how much of a
substance is present.
Here is how the International Union of Pure and Applied Chemistry (IUPAC) defines
"mole:"
The mole is the amount of substance of a system which contains as many elementary
entities as there are atoms in 0.012 kilogram of carbon-12. When the mole is used, the
elementary entities must be specified and may be atoms, molecules, ions, electrons,
other particles, or specified groups of such particles.
This is the fundamental definition of what one mole is. One mole contains as many
entities as there are in 12 grams of carbon-12 (or 0.012 kilogram).
In one mole, there are 6.022 x 1023 atoms. Here's another way: there are 6.022 x
1023 atoms of carbon in 12 grams of carbon-12.
Let's say that real clearly: one mole of ANYTHING contains 6.022 x 10 23 entities.
The word "entities" is simply a generic word. For example, if we were discussing
atoms, then we would use "atoms" and if molecules were the subject of discussion, the
word entities would be replaced in actual use by "molecules."
Avogadro's Number has been very carefully measured in a number of ways over many
decades. The symbol for mole is "mol." Why does a four-letter word have a threeletter symbol? That's really the wrong question.
Here it is again: one mole of ANY specified entity contains 6.022 x 10 23 of that entity.
For example:
One mole of donuts contains 6.022 x 1023 donuts
One mole of H2O contains 6.022 x 1023 molecules
Avogadro's Number has a unit associated with it. It is mol 1, as in 6.022 x 1023 mol1.
The superscripted minus one means the unit mol is in the denominator. There is an
understood numerator of one, as in 1/mol.
Why is there no unit in the numerator? There could be, but it would vary based on the
entity involved. If we were discussing an element, we might write atoms/mol. If we
were discussing a compound, we would say "molecules per mol." What is in the
numerator depends on what "entity" (atom, molecule, ion, electron, etc.) is being used
in the problem.
Consequently, units names in the numerator are not used and a one is used instead.
Getting back to Avogadro's Number role in chemistry; please note that counting atoms
or molecules is very difficult since they are so small. However, we can "count" atoms
or molecules by weighing large amounts of them on a balance.
When we weigh one mole of a substance on a balance, this is called a "molar mass"
and has the units g/mol (grams per mole). This idea is very critical because it is used
all the time.