Coatings Word June 2016
Coatings Word June 2016
Coatings Word June 2016
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27
Industrial Coatings
31
34
36
34
DEPARTMENTS
COLUMNS
Editorial ................................................................. 6
As We Go to Press ................................................. 8
Fresh Paint ........................................................... 10
Market Reports .................................................... 18
New Products ...................................................... 20
Industry News ...................................................... 42
Suppliers Corner .................................................. 45
People.................................................................. 46
Meetings .............................................................. 47
Final Coat............................................................. 50
ADVERTISING SECTIONS
Classified Ads....................................................... 48
Advertising Index................................................. 49
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4 | Coatings World
www.coatingsworld.com
June 2016
Editors Page
Industrial
Coatings Market
he industrial coatings market is quite diverse owing to its varied applications. It encompasses protective coatings for architectural steel, transportation and oil and offshore structures, just to name a few segments.
Industrial coatings must protect substrates in some of the harshest conditions. Environmental legislation has added to the challenge, by forcing
coatings manufacturers to develop durable coatings that both meet environmental regulations and deliver outstanding performance.
We interviewed leaders in the industrial coatings market including Axalta,
Hempel, Sherwin-Williams, AkzoNobel and Hempel to see how they remain
competitive in such a challenging market. Across the board these market
leaders stressed the importance of understanding customers goals and letting that be the guide to new innovation, products and services.
According to market research firm IRL, general industrial coatings is estimated to have reached almost 7.6 million metric tons in 2015, with sales expected to reach more
than 8.9 million metric
tons by 2020. In terms
of value, global sales of
general industrial coatings reached $23 billion
in 2015. Asia accounted for the largest share
of the market despite
having a substantially
lower average price
compared to Western economies. Europe followed Asia closely in terms of the
revenue generated, although with a substantially lower volume sold.
Correction: The Lab and Testing Equipment Directory in the May issue
had an error in it. The correct listing for Atlas Material Testing is as follows:
Atlas Material Testing Technology, LLC
Mount Prospect, IL, USA
773-327-5787 /Fax: 773-327-4520
Email: atlas.info@ametek.com / Web: www.atlas-mts.com
Low-Temperature EMMAQUA Device
Atlas Low-Temperature EMMAQUA device performs natural exposure testing on materials at significantly cooler temperatures. With its
patented cool mirror technology, the LT-EMMAQUA is ideal for materials that require a long service life, coatings applied to metal panels,
and temperature-sensitive materials.
kpianoforte@rodmanmedia.com
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June 2016
As We Go To Press
he Sherwin-Williams Company
and The Valspar Corporation
announced that, as expected,
the companies have each received a request for additional information and
documentary materia from the United
States Federal Trade Commission (FTC)
in connection with Sherwin-Williams
pending acquisition of Valspar. The
Second Request was issued under notification requirements of the Hart-ScottRodino Antitrust Improvements Act of
1976, as amended (the HSR Act). This
Second Request is a common part of the
regulatory process in connection with
the FTCs review.
The transaction, which was announced
on March 20, 2016, is subject to approval
of Valspars shareholders and satisfaction
of other customary closing conditions, including expiration or termination of the
waiting period under the HSR Act. The
effect of the Second Request is to extend
the waiting period imposed by the HSR
Act until 30 days after Sherwin-Williams
and Valspar have substantially complied
with the request, unless that period is extended voluntarily by the parties or terminated sooner by the FTC.
Sherwin-Williams and Valspar are
cooperating fully with the FTC staff
and continue to expect the transaction
will close by the end of Q1 calendar
year 2017. Given the complementary
nature of the businesses and the benefits
this transaction will provide to customers, Sherwin-Williams and Valspar
continue to believe that no or minimal
divestitures should be required to complete the transaction.
acquired the remaining 51 percent interest in its Chinese joint venture, Carboline
Dalian Paint Production Co., Ltd.
(Carboline Dalian), bringing its total
ownership to 100 percent.
Terms of the transaction, which is expected to be accretive to earnings within
one year, were not disclosed. Carboline
acquired its initial 49 percent interest
in the company in 2009. UniChemical
Company, originally a Carboline licensee,
has been Carbolines long-standing partner in the joint venture. Carboline Dalian,
with sales of approximately $11 million,
manufactures corrosion control coatings
and linings for oil and gas, power and
petrochemical related projects.
Headquartered in Dalian, China, the
company also has operations in Shanghai,
Tianjin, Guangzhou and Hong Kong.
Index to Companies
This index gives the starting page for a department or feature with a significant reference to a manufacturer of paint, coatings, adhesives and sealants
Subsidiaries are indexed under their own names.
AkzoNobel................................................................................................. 10, 27
Arizona Polymer.............................................................................................. 10
Axalta Coating Systems.............................................................................. 10, 27
BASF Coatings................................................................................................. 10
Hempel...................................................................................................... 10, 27
HMG Paints............................................................................................... 10, 20
PPG.......................................................................................................10, 27, 50
RPM.................................................................................................................. 8
Sherwin-Williams..............................................................................8, 10, 20, 27
Valspar......................................................................................................... 8, 20
June 2016
Fresh Paint
Foundation grant will support chemical refills for teachers test kits, travel to
schools and stream sites, and a student
research symposium.
By supporting Allegheny College and
the Creek Connections programs unique
approach to science education, PPG aims
to continue to spark students interest in
scientific areas, said Sue Sloan, executive
director, PPG Foundation. Memorable
hands-on programs like these are what
inspire students to pursue careers in
math, engineering and technology.
ISO 9001
Fresh Paint
Americas, Inc. This project focuses on improving the fuel efficiency of truck and bus radial
tires using PPGs AGILON performance silica platform. The goal of the
project is to deliver prototype tires to
DOE that help trucks and buses achieve
fuel-efficiency improvements of 4 to 6
percent while maintaining or improving
tear strength and tread wear. Research
and development work for the project
will be completed at PPGs Monroeville,
Pennsylvania, facility.
Anup Jain, PPG vice president, specialty coatings and materials, said PPGs
collaboration with Bridgestone has the
potential to significantly change the truck
tire industry. We are excited to partner
with Bridgestone on this important project, he said. The DOE funding validates
what our preliminary research already
has shown that Agilon performance
silica has significant potential as a nextgeneration filler to help increase truck tire
fuel efficiency.
Improving the fuel efficiency of trucks
and buses would provide significant
economic and environmental benefits.
According to DOE reports, heavy-duty
vehicles comprise only 4 percent of all
vehicles on U.S. roads but consume approximately 20 percent of all fuel. PPG
estimates that if even 25 percent of all
tractor-trailers on the road improved fuel
efficiency by 4 percent, they would consume 750 million fewer gallons of diesel
fuel annually, saving nearly $2 billion and
reducing carbon-dioxide emissions by
nearly 8 million metric tons.
According to Kurt Danielson, president, Bridgestone Commercial Group,
Bridgestone has a long-standing commitment to environmental sustainability. The
companys environmental mission is to
help ensure a healthy environment for
current and future generations, and as
the worlds largest tire and rubber company, Danielson said Bridgestone believes
it has a corporate responsibility to produce sustainable products in the most
sustainable way. Using 2005 data as a
baseline, the companys midterm target is
to achieve a 35 percent reduction in CO2
emissions by 2020.
Our partnership with PPG was
created for our customers, Danielson
said. We are constantly working to deliver innovative solutions that not only
align with our companys environmental mission but will also carry cost saving benefits for our truck and bus radial
tire customers.
Jain added that Agilon performance
silica is part of PPGs global commitment
to helping the transportation industry
and its suppliers manufacture more sustainable products. From coatings that
contribute to lighter, more fuel-efficient
undercoat to classic coach enamel, results from a highly developed and close technical partnership between Craftmaster and
HMG Paints that dates back nearly two decades. HMG manufactures exclusive formulations to Craftmasters specifications,
using pigments and components of the highest quality.
June 2016
American Chemistry
Council Launches Website
on Chemistry in Building &
Construction Materials
The American Chemistry Council
(ACC)
has
launched
www.
BuildingWithChemistry.org, to provide
architects, material specifiers, interior
designers and other building and construction professionals with tools and
information about green building codes
and standards, materials selection, and
the role of chemistry in developing innovative, sustainable building materials.
Many of the materials and products
used to build the homes, schools and office buildings where we live and work
every day rely on the safety, energy savings, durability and other sustainability
and performance benefits that the products of chemistry provide, said Richard
Skorpenske, director of advocacy and
sustainability at Covestro, and chair
of ACCs Building and Construction
Subcommittee. We created this new
website to contribute to thoughtful, informed decisions about the materials in
todays innovative, modern and sustainable building applications.
The website includes an interactive graphic of a mixed use residential
building which highlights how chemical
ingredients are used in materials, from
polycarbonate panels in skylights, to
plastics in piping, to nylon and polyester fibers in carpeting. Individual pages
feature specific chemicals used in a range
of B&C applications, with information
on where the chemicals are used and the
functionality they provide.
Fresh Paint
Coatings World | 13
Fresh Paint
June 2016
Sherwin-Williams Among
First in North America to
Achieve QUALICOAT Class
1 Certification
Sherwin-Williams
has
achieved
QUALICOAT Class 1 Normal Durable
Certification for polyester-TGIC based
powder coatings manufactured at
Sherwin-Williams Arlington Powder
Plant. These gloss powder coatings include a wide array of colors and include
many RAL colors.
A QUALICOAT Class 1 Certification
Fresh Paint
The PPG Colorful Communities initiative aims to enhance, protect and beautify
the neighborhoods where the company
operates around the world. Together with
community partners and PPG employees
who volunteer, the program supports projects that transform community assets using donated PPG products. In 2015, PPG
completed 11 Colorful Communities projects, and it expects to complete about 30
more this year.
Coatings World | 15
Fresh Paint
Little Joe Industries offers the ADM Automatic Draw-Down Machine for use with
grind gages. The ADM automates the draw down process controlling scraper
angle, speed, and force. Since these aspects are no longer operator dependent your grind gage draw-downs will be more consistent while requiring less
operator training and supervision.
Uses existing grind gages and scrapers from your current supplier.
US and foreign patents apply.
Little Joe Industries
10 Ilene Court, Suite 4, Hillsborough, NJ 08844-1922
Phone: (908) 359-5213 Fax: (908) 359-5724
Web: www.littlejoe.com Email: info@littlejoe.com
16 | Coatings World www.coatingsworld.com
Instructor-led
classroom
programs are offered at three
Development
Centers
in
Canada and at eight centers
in the United States, virtually in the users own office or shop, online through
AxaltaLearningCampus.com
and
through customized, blended learning
methods. CW
Cenomic full-volume
bead mill maximum
economic efficiency at
an attractive price.
The wet grinding solution with
up to
20% better pigment utilization*
20% lower production costs*
20% higher throughput*
20% reduction of required
specific energy*
* Compared with the standard solutions on
the market.
Fresh Paint
Coatings World | 17
5/6/2016 9:59:13 AM
Market Reports
2009
2014 2019
13060
2839
2600
5739
599
710
573
16145
3102
2738
8010
701
840
754
20150
3570
3090
10650
838
1025
977
20092014
4.3
1.8
1.0
6.9
3.2
3.4
5.6
20142019
4.5
2.9
2.4
5.9
3.6
4.1
5.3
June 2016
Group.
The Asia/Pacific region accounts for
the largest share of the global specialty
silicas market, representing 48 percent of
the total in 2015. China alone accounted
for over half of regional demand. The
Asia/Pacific region dominates global rubber production, and as a result many
countries in the region are major consumers of specialty silicas, notes analyst
Elliott Woo. Increased demand for silica
in tires will drive growth in demand in
developed nations like Japan and South
Korea. Broader manufacturing growth
will support strong gains in demand for
specialty silicas in developing countries
throughout the region.
Demand for specialty silicas in North
America and Western Europe is projected to advance at below average rates
through 2020. Sluggish manufacturing
growth and market maturity will constrain advances for specialty silicas in
many applications. However, the tire
rubber market will provide some gains in
these regions. Consumption of specialty
silicas in Eastern Europe, Central and
South America, and the Africa/Mideast
region is modest, with these regions collectively accounting for 16 percent of the
global total in 2015. Of these regions, the
Africa/Mideast region is expected to post
the fastest growth, but it will remain the
smallest regional market.
Market Reports
New Products
Sherwin-Williams Introduces
KEM Aqua 3001 for HeatSensitive Substrates
Sherwin-Williams, through its Product
Finishes Division, has introduced KEM
Aqua 3001, a waterborne acrylic topcoat
for application on vinyl windows, trim,
shutters and doors.
Available in satin and semi-gloss
sheens, KEM Aqua 3001 can be used
on heat-sensitive vinyl building products such as windows, shutters, doors,
and trim in multifamily and residential
new construction projects as well as the
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For companies
with worldwide
operations, the
final stage of
market launches
can be more
difficult in Europe
than in North
America and Asia
Pacific.
by Sean Milmo
European Correspondent
milmocw@rodmanmedia.com
have to be taken into account when commercializing new products and technologies.
For PPG, which claims to hold number one
global position in coatings with AkzoNobel,
Sherwin Williams, Valspar, Axalta and BASF
being the other worldwide leaders, the introduction of innovative products can be particularly challenging in Europe, especially in the
architectural sector.
The company pursues a marketing policy
in Europe based on its numerous local brands
now totalling around 30, the majority of
which are in architectural coatings. They
have been accumulated from a series of acquisitions, including those of SigmaKalon
and Johnstones.
The introduction of new products have to
match the strategies of local brands, although
some have an international presence, such as
Sigma, Johnstones and Seigneurie, which have
spread outside Europe, particularly into Africa.
June 2016
The growth in
new markets,
including high
speed train,
passenger
car, consumer
electronics, clean
energy, aircrafts
and packaging,
provide growth
potentials for
adhesives.
by Arnold Wang
China Correspondent
DIFFERENTIATION:
The Anecdote to a Disruptive Threat Part 2
by Phil Phillips, PhD
Contributing Editor
phillips@chemarkconsulting.net
STARTING POINTS:
Differentiation Flow
Diagram
Historic diagnosing evaluations of past
successes/failures, are not much fun but
it is an exercise, properly addressed, that
can make a great deal of sense in building
a differentiation model.
Take the past 5-10 (the more the better) growth investments and ascertain
what they have in common. Determine
your most important differentiators in
these growth initiatives by screening your
judgments through these sets of fundamental questions:
Are they truly distinctive?
Are they measurable (quantifiable)
vs. competitors?
Are they pertinent to your core customer deliverable?
Are they mutually reinforce able?
Are they obvious to all levels of the
organization?
Once this very difficult process is complete and thoroughly tested at all levels of
the company, one has a formula for focusing on innovation. Innovation in this case
refers to the complete spectrum of business
activity . . . not just technical innovation.
Additionally, it is very important not
only to recognize your differentiation but
also to test the sources of competitive innovation and its potential affect on your
FEATURE
The Industrial
Coatings Market
The market for industrial and protective coatings has potential for growth in a number of
key markets including construction, transportation and oil and gas.
Kerry Pianoforte, Editor
ccording to market research firm IRL, general industrial coatings is estimated to have reached almost 7.6 million metric tons in 2015, with sales expected to reach
more than 8.9 million metric tons by 2020. In terms of value,
global sales of general industrial coatings reached $23 billion
in 2015. Asia accounted for the largest share of the market
despite having a substantially lower average price compared
to Western economies. Europe followed Asia closely in terms
June 2016
www.coatingsworld.com
Coatings World | 27
June 2016
direct maintenance cost and interruptions that result in expensive downtime of their operations.
Coatings World | 29
New Products
AkzoNobel recently launched a range of Chartek fire protection
coatings for the oil and gas sector that offer self-reinforced fire
protection. This provides weight-savings advantages coupled
with faster application.
Axalta Coating Systems recently launched AquaEC 6100
electrocoat coatings designed to improve customers productivity and reduce application costs. The AquaEC range of electrocoat primers use patented epoxy-based technology to provide
superior corrosion resistance with excellent throw power and
improved edge protection, said Cash. This tin-free technology
used in AquaEC 6100, now available globally, also helps meet
environmental goals. The U.S.-made AquaEC 6100 E-Coat also
received Caterpillar approval to their specification 1E2732F.
Towards the end of last year, we introduced a non-acidic and
formaldehyde-free Voltatex electrical steel varnish formulated
to reduce costly shutdown periods during maintenance inspections, increasing our customers efficiency. In the architectural
segment weve experienced great success in the launch of our
Alesta Anti-Graffiti outdoor powder coatings, where our customers experienced outstanding exterior durability due to the
excellent chemical resistance, UV weathering and film hardness
of the coating. Its weather and chemical resistance makes it an
ideal protective coating for finishes exposed to graffiti as well as
extreme conditions such as dirt and smog. Axalta is also pleased
to announce the release of the Nap-Gard 7-2500 series, which
brings industry recognized FBE powder coatings into one group
and expands the benefits of our thermosetting epoxy powder for
onshore and offshore oil and gas pipelines.
Sherwin-Williasm recently launched KEM NISO 8510 system, a high-durability isocyanate-free topcoat system with an
ambient cure of 15 minutes and Polane D 8700 coating, which
provides the high durability of a urethane in a single direct-tometal step. Our newest powder offering is our patent pending introduction of the Powdura OneCuresystem, a two-coat
powder system, applied in a single bake cycle, allowing for the
June 2016
FEATURE
Latin America
2016
Regional demand is likely to exceed GDP in the region.
Charles W. Thurston, Latin America Correspondent
Coatings World | 31
Argentina
In Argentina, the expectation for paint and coatings growth
beyond the predicted GDP increase of 0.8 percent this year
is low. However, HSBC predicts that potential growth in
GDP for 2017 could reach 3.5 percent. We expect slightly
positive growth in Argentina, said Knavish. Others agreed:
Despite macro-economic headwinds in the region, our performance was solid inArgentina, Akzo-Nobels 2015 annual report stated.
Majors are continuing investment in Argentina. We are
nearing completion of a new manufacturing facility in Argentina
which will produce coatings for OEMs, refinish and industrial
customers, says Winocur.
In November 2015, Fabin Gil, the new president of Dow
Latin America, suggested that Argentinas Bahia Blanca complex
could become Dows third major polyethylene project, globally.
Growth in Argentinas gas and oil industry led to the award
of a $55 million dollar contract for ShawCor, which expected
to complete work earlier this year on anti-corrosion pipeline
coatings for Tenaris, for its part in the Argentina Northeast Gas
Pipeline (GNEA) project.
Brazil
In contrast, in Brazil, the expectation for paint and coatings
growth is minimal, given the expected GDP decrease of -2.0 percent this year, at least until recovery from impeachment takes
place. Brazils paint and coatings industry is going through a
third very tough year, unprecedented in recent history, reckons
Dilson Ferreira, the executive president of the national manufacturers association Associacao das Fabricantes de Tintas, or
Abrafati, in Sao Paulo. Building and construction expects no
recovery this year. The automotive industry anticipates that
sales will remain the same as in 2015, far below the average for
the past several years, he reckoned.
The total volume of paint sold in Brazil was down 5.6 percent in 2015, with associated net revenues of $3.05 billion, significantly lower than 2014 value, due in substantial part to the
depreciation of the Brazils currency, the real, which has plummeted 40 percent over the recent past.
Over the past year, AkzoNobel opened a new Expancel microsphere production line within its paint and coatings complex
in Jundia, Sao Paulo State, with the aim of serving both the
Brazilian and regional market demand.
Similarly, In 2015, PPG completed a $40 million plant for
on-site resin production at its Sumar, So Paulo State, coatings
manufacturing facility, which will help PPG to meet the demand
of automotive and industrial customers with locally produced
material, said Knavish.
June 2016
From left to right: Francisco X. Gonzalez, President Axalta Mexico; Undersecretary of Industrial Development of the State of Mexico, Laura Gonzalez; Charles
W. Shaver, Axalta Chairman and CEO; Tatjana Heinrich, Managing Partner of
the German-Mexican Chamber of Commerce and Industry; Aurora Denisse
Ugalde, President of the Municipality of Tlalnepantla; Ana Lopez, Executive
Vice President and General Director of the American Chamber; Jorge Cossio,
President Axalta Latin America.
Another encouraging note for Brazilian industry is that during the coming year Abrafatis annual paint and coatings show
will move to a new, larger, more modern venue in 2017, supported by large investments by new show developer GL Events.
Colombia
Colombias economy expanded by 3.1 percent last year, following 4.0 percent results for many years. Still, We anticipate that
activity in Colombia will likely be flat, said Knavish.
Among other new developments in the market, Axalta
launched the second edition of the Axalta Colors Partners Club
in Colombia, which it calls the first loyalty program in Latin
America, Winocur said. This program is intended to share innovative techniques with hundreds of automotive refinishers in
Colombia through training designed to help them strengthen
their skills and capabilities.
On the company stores front, Pintuco set a goal of adding 35
Tienda Pintacasa Pintuco stores during 2015, increasing coverage to 57 cities in Colombia. The goal up to 2018 is to increase
the store count to 300, according to statements by Jean Jeaques
Thiriez, the general manager of Pintuco.
Similarly, DIY chain Sodimac Colombia, the countrys largest, is also investing in new stores. The company issued $160
million worth of shares in July 2015 to finance new investments. Among new facilities is a $25 million distribution center
in Colombia, the companys third. Sodimac now has 35 stores
across the country.
Mexico
In Mexico, the expectation for paint and coatings growth is
beyond the expected GDP increase of 2.6 percent this year.
Investments there are heating up.
In April 2016, we opened an expanded resin production
facility in Tlalnepantla, just outside of Mexico City, from which
we will supply many of the leading automotive OEMs in Mexico
among other customers, noted Winocur. At the manufacturing
facility in Apodaca, Nuevo Leon State, we inaugurated a newly
refurbished technology and R&D center for powder coatings in
2015, he adds.
For PPG, Mexico continues to be a strong market. In the
first quarter, PPG sales were up approximately 5.0 percent in
Mexico, in pesos, he said. We also completed a $27 million
expansion of its San Juan del Rio, Queretaro State manufacturing facility in 2015. The additional capacity enables PPG to
meet increasing demand for OEMs, packaging and industrial
coatings customers in Mexico, notes Knavish.
PPG-Comex last year added 190 paint stores in Mexico.
Today, we have more than 4,100 stores and we plan to add
more than 160 stores this year. The PPG-Comex team has its
highest store density in Central Mexico, while we are enhancing
our presence in Southern and Northern Mexico with new store
concepts, Knavish explained. CW
Coatings World | 33
FEATURE
Diversified trends in automotive colors and increased consumer competition are driving
this market forward.
Green trends
As consumers and manufacturers become more focused on
the environment, suppliers are challenged with meeting sophisticated technical demands while utilizing green methods.
Thomas Hughes, head of key account management and automotive coatings, ECKART America Corporation, said that
both environmental regulations and cost are the major factors
impacting this industry.
Our development efforts are aligned with the market and
our customer needs in order to provide increased value with
our technical solution offerings, Hughes said. The demand
for environmentally-friendly coatings continues and we support
this with our technical leadership position with stabilized and
encapsulated pigments for water based coatings systems and
pigments for powder coatings.
Silberlines Nataro said that stricter environmental regulations have forced metallic pigment suppliers to modify their
processes and materials in order to provide pigments that can
pass all regulatory testing and offer low to zero VOC.
There is also a push for further reduction of aromatic
content in the carrier solvent in some metallic pigments,
along with more and more pressure to test and ensure that
PAH levels are within regulations for the different markets,
he said. Silberline is continuing to see more efficient coating
applications, imparting thinner film builds and less overall
paint being required to paint a vehicle, while retaining excellent color and performance. Finer and brighter continues to
be the message.
June 2016
Emerging markets
Metallic pigments are versatile, eye-catching and increasingly
utilized to differentiate products in competitive markets. Strong
markets have historically included industrial and automotive
markets. According to Silberlines Nataro, there is also demand
in protective coatings markets, automotive OEM and refinish
coatings. Metallic printing inks are also adding flash and pizzazz to packaging and paper, creating new effects that catch the
eye, he said.
Hughes, of ECKART, said that there is steady demand in the
automotive and the electronics segments in spite of the decline
in pure silver in the automotive sector.
However, we continue to see an increase in the use of metallic and special effects in designed colors, he said. For example more metallic blues, reds and other colors. We expect
this to increase in the future along with the use of more pure
silver metallic based on the development of the new pigments
we are developing.
The automotive segment, which has been the key driver for
global metallic pigment demand, has remained steady in North
America and is showing modest gains in Europe, according to
Hollman of Sun Chemical.
Sun Chemical has seen strong demand for Benda-Lutz
SPLENDAL vacuum metallized pigments for high end automotive interiors. We are also seeing increased usage of our new high
performance stain resistant metallics for wheel coatings. For
topcoats, new color trends emerge every year, Hollman said.
Coatings World | 35
FEATURE
Unique Solutions to
Regulatory Concerns
Affecting Cobalt and MEKO
Richard Najdusak, Borchers, USA; Dr. Franjo Gol, Borchers, Germany
Introduction
Coatings World | 37
Cobalt Replacement
Strategies
Few viable options exist to replace cobalt
in alkyd and other air drying systems. As
noted above, only manganese and iron
complexes can approach cobalts activity level. Conventional iron, vanadium
and cerium carboxylate driers are not
effective replacements. Accelerated
manganese driers improve the activity
somewhat but may affect the color of
light tinted coatings over time and generate brittle films. However, a new ironcomplex drier has been developed to
equal or exceed the drying performance
of cobalt and at reduced levels. The catalytic reaction mechanisms of cobalt and
the iron-complex driers have been shown
to be the same, however the efficiency of
the iron-complex drier is so high that less
oxygen is needed to promote oxidative
cure throughout the film, not just on the
surface as do the cobalt carboxylates.
oxidative crosslinking from the higher activity of the iron-complex drier. However,
as with cobalt, coordinative driers like
zirconium may still be needed to promote
faster hardness values.
Summary of Cobalt
Replacement Driers
No other metal carboxylate drier can approach the oxidative activity of cobalt.
However, the iron-complex drier is a sustainable alternative to cobalt driers and
is not carboxylate-based. This product
is not CMR classified, can provide equal
or superior surface dry times to cobalt at
low levels under standard drying conditions, has improved efficiency in promoting surface curing under low temperature/
high humidity conditions and, due to its
additional through drying properties, can
June 2016
MEKO Replacement
Using Anti-Skinning
Additives in Paints
By adding driers to improve coating dry
times, we also increase the tendency of
the coating to cure prematurely whenever it comes in contact with air. This includes during the manufacturing, filtering
and filling processes. Adding driers also
means that less oxygen is needed to initiate surface curing which can affect longterm storage in the can. The coatings
industry developed additives to delay the
curing process to prevent skin formation.
The two main methods to prevent skinning are: (1) inhibit the catalytic activity
Aminic Complex
The health hazards associated with this
advanced antioxidant are minimal compared to MEKO as noted on its current
Coatings World | 39
Comparative Testing to
MEKO
These advanced antioxidants were
evaluated for in-can preservation, film
surface drying and film hardness development vs MEKO. MEKO is completely
volatile and does not interfere with curing while all antioxidants remain, at least
for a period of time, in the film to function properly. In these tests, we chose
a simple, clear alkyd formula based on
a long-oil alkyd resin and used a drier
package consisting of 0.04% cobalt and
0.1% calcium metal based on resin solids.
Results are shown in Figure 9.
Although not as effective as MEKO
with this drier package, the advanced antioxidants at low levels provide excellent
anti-skinning properties to this test system.
The overall hardness and integrity
of the dried film was not compromised
initially or after one week using the advanced antioxidant complex at any of the
levels tested (Figure 10). This confirms
that it does not remain in the film to interfere with crosslinking and final cure.
There is a slight loss of surface dry
using the advanced antioxidant complex
which is due to its lower volatility compared to MEKO and the different mechanism for inhibiting oxidation (Figure 11).
Excessive amounts should be avoided for
these reasons.
Summary MEKO
Replacement
These less toxic alternatives to phenolic
and oximic antioxidants require less than
half the level of MEKO in most coatings
systems to provide effective anti-skinning
properties. They perform independently
of the oxidative metal drier and are recommended in cobalt replacement strategies. These advanced antioxidants are
suitable for clear and pigmented coatings
with no discoloration. However, the optimum level should be experimentally determined as excessive amounts may lead
40 | Coatings World www.coatingsworld.com
June 2016
Conclusions
Additives manufacturers have developed
less toxic alternatives to cobalt and MEKO
which are both more effective and efficient.
Cobalt Replacement Iron-Complex
technology is an effective and sustainable
alternative to cobalt driers with the following advantages: no CMR classification
issues; improved film curing properties
under adverse conditions (high humidity/
low temperature) compared to cobalt; and
dried films develop less yellowing compared to films cured using cobalt driers.
MEKO Replacement Effective, less toxic, aminic-based anti-skinning alternatives
are available with minimal loss of properties
if used at the appropriate levels. CW
Coatings World | 41
Industry News
Industry News
Solvay to Increase
Production Capacity for
Hydroquinone & MEHQ
Solvay Aroma Performance plans to build
an additional production capacity of
Hydroquinone (HQ) in China starting-up
in 2018. This investment will be based on
an innovative and environmental friendly
technology.
In addition, the Global Business Unit
will extend its worldwide Methyl hydroquinone (MEHQ also referred as PMP
paramethoxyphenol) capacity. Both
projects will support Solvay captive needs
as well as the growth of HQ and MEHQ
markets, particularly in Asia.
Coatings World | 43
Industry News
www.technologylitigators.com
June 2016
Suppliers Corner
Coatings World | 45
People
June 5 - 8, 2016
2016 SSCT Annual Technical Meeting
Location: St Petersburg, FL
Venue: The Vinoy Renaissance Resort
Contact: Laura Fosselman
Phone: 601-310-7687
Website: www.ssct.org
Email: ssctorg@gmail.com
June 6 - 9, 2016
2016 EPCEd Workshop: Core-Shell
Latex Particles - Fundamental Aspects
of Morphology Control
Location: Durham, NH
Website: www.epced.com
June 7 - 8, 2016
Cleveland Coatings Society: Sink or
Swim Symposium
Location: Cleveland, OH
Phone: (216) 731-5213
Website: www.clevelandcoatingssociety.org
June 8 - 9, 2016
East African Coatings Conference
Location: Chicago, IL
Venue: DePaul University, OHare
Campus
October 6 - 7, 2016
CEPE Annual Meeting
October 7 - 9, 2016
2016 Greenbuild International
Conference & Expo
Location: Manchest, UK
Venue: Worsley Park Hotel & Country Club
Contact: British Coatings Federation
Website: www.coatings.org
Location: Philadelphia, PA
Meetings
December 6 - 9, 2016
The 16th International Paint, Resin,
Coating and Composites (IPCC) Fair
Location: Tehran, Iran
Venue: Tehran Permanent Fairground
Phone: +982 12200 1749-50
Website: www.ipcc.ir
Email: info@ipcc.ir
Classifieds
Blades
Classifieds
Wanted
Blades
Technical Sales Manager
STATIC
MIXERS
1-800-243-ROSS
www.StaticMixers.com
48 | Coatings World
June 2016
Classifieds
Advertising Index
Company Name
Page
Phone
Website
14
Buhler
17 512-466-8005 www.buhlergroup.com
11
478-552-2544
www.burgesspigment.com
203-265-2086
www.byk.com
Chemark Consulting
44
910-692-2492
www.chemarkconsulting.net
43
814-723-7980
www.connblade.com
Fineton
13 85224021782
602-539-2683
angus.com
www.blairgowrieassociates.com
www.fineton.com
Cover 4
540-980-7233
www.hoovercolor.com
16
908-359-5213
www.littlejoe.com
Lonza Inc.
41
www.lonza.com
44
512-472-8282
www.technologylitigators.com
PPG Industries
15
800-257-9365
www.recarroll.com
Sun Chemical
800-543-2323
www.sunchemical.com
Cover 2
973-443-4200
www.troycorp.com
Troy Corporation
www.ppg,com
Coatings World | 49
Final Coat
PG helped the California Science Center Foundation prepare the final space shuttle external tank for a six-week
ocean voyage by donating a military-grade paint matching the tanks foam covering to enhance appearance and protect against elements during its journey by barge from NASAs
Michoud Assembly Facility in New Orleans to Los Angeles.
Upon arrival in California, ET-94 the only existing flightqualified external tank will undergo cosmetic restoration for
display at the California Science Center along with the space
shuttle Endeavour.
DESOTHANE HS/CA 8211 series military and defense
topcoat manufactured at PPGs Mojave, California, plant was
tinted to match the burnt-orange foam by PPG aerospace coatings color experts. Loose foam was removed from ET-94 at
Michoud, and the PPG topcoat was applied by roller and brush
to cover gaps for a consistent appearance.
According to Duane Utter, PPG global segment manager for
space and defense coatings, PPG was asked to supply the paint
by Dennis R. Jenkins, project director overseeing the science
centers new Samuel Oschin Air and Space Center who was a
contract engineer for the shuttle program and knew PPG was
the original primer supplier.
PPG was a proud partner in the space shuttle program
as the supplier of the only primer qualified for the external
tanks, Utter said. This primer passed cryogenic and corrosion testing and met requirements for foam adhesion. After
accepting the opportunity to supply the topcoat for the historic ET-94 journey, we matched the color of the foam, and our
sample was approved by the science center. We recommended
Desothane HS/CA 8211 series topcoat because of its matte appearance and durability.
PPGs primer, applied to the metal tanks for corrosion resistance and enhanced topcoat adhesion, was DESOTO 515x346
epoxy primer, Utter said.
Jenkins said it was important for ET-94 to look as nice as
possible. We wanted ET-94 to be protected from water on its
voyage and to look good during its long journey to the Samuel
Oschin Air and Space Center. The California Science Center is
very grateful for the support provided by PPG, one of the original external tank suppliers, in helping us with our work that will
enable people to see an important part of the shuttle program.
The 65,000-pound, 154-foot-long ET-94 was loaded onto a
barge in New Orleans and transported through the Panama Canal
for delivery to Marina del Rey, California, riding its last leg through
the streets of Los Angeles to the California Science Center.
Lockheed Martin built the external tanks, which carried propellants to power the shuttles main engines. Lockheed Martin
delivered ET-94 in 2001 to NASA, where the tank was stored.
The original standard-weight tanks were replaced by lightweight tanks and then super-lightweight tanks.
For more information about the Endeavour exhibit and
California Science Center, visit www.californiasciencecenter.org. CW
PPG helped the California Science Center Foundation prepare ET-94, the
space shuttle programs only remaining external tank, for its final journey from
New Orleans to Los Angeles by donating a color-matched military and defense
topcoat to enhance aesthetics and provide protection. ET-94 will undergo cosmetic restoration for display alongside the shuttle Endeavour at the California
Science Center in Los Angeles. (Photos courtesy of Dennis R. Jenkins)
June 2016
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