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    P Block Reactions

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    arch360
    This document contains 50 chemical reaction equations involving elements in the p-block of the periodic table. The reactions are divided into 10 cards with 5 reactions each. The reactions cover oxidation-reduction, acid-base, substitution, elimination, and other reaction types of common p-block elements such as halogens, chalcogens, pnictogens and noble gases.

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    P Block Reactions

    Uploaded by

    arch360
    807 views3 pages
    This document contains 50 chemical reaction equations involving elements in the p-block of the periodic table. The reactions are divided into 10 cards with 5 reactions each. The reactions cover oxidation-reduction, acid-base, substitution, elimination, and other reaction types of common p-block elements such as halogens, chalcogens, pnictogens and noble gases.

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    chemistry class xii p-block notes

    Original Title

    p Block Reactions

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    This document contains 50 chemical reaction equations involving elements in the p-block of the periodic table. The reactions are divided into 10 cards with 5 reactions each. The reactions cover oxidation-reduction, acid-base, substitution, elimination, and other reaction types of common p-block elements such as halogens, chalcogens, pnictogens and noble gases.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    807 views3 pages

    P Block Reactions

    Uploaded by

    arch360
    This document contains 50 chemical reaction equations involving elements in the p-block of the periodic table. The reactions are divided into 10 cards with 5 reactions each. The reactions cover oxidation-reduction, acid-base, substitution, elimination, and other reaction types of common p-block elements such as halogens, chalcogens, pnictogens and noble gases.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 3

    CLASS- XII

    P- BLOCK ELEMENTS
    MASTER THE REACTION PREVIOUS YEAR BOARD QUESTIONS (P-Block)2M
    SN Complete the following chemical reaction
    SN Complete the following chemical reaction
    equations:
    equations:
    P-BLOCK REACTION CARD-1
    P-BLOCK REACTION CARD-6
    1
    Cu + HNO3 (CONC.)
    26
    P4 + Conc. HNO3
    2
    NaOH (hot and conc.) + Cl2
    27
    Sn + 2PCl5 (heating)
    3
    XeF2 (s) + H2O(l)
    28
    AgCl(s) + NH3(aq)
    4
    HgCl2 +2PH3
    29
    NH3 + Cl2 ( excess)
    5
    P4 + NaOH + H2O
    30
    Cu (s) + H 2SO 4 (conc.)
    6
    7
    8
    9
    10

    P-BLOCK REACTION CARD-2


    Cu + HNO3 (DIL.)
    NaOH (cold and dil.) + Cl2
    XeF4(s) + H2O(l)
    CuSO4+2PH3
    Ca3P2 + H2O

    31
    32
    33
    34
    35

    P-BLOCK REACTION CARD-7


    PCl5 + H2O (excess)
    I (aq ) +H2O(aq) + O3(g)
    XeF4 + O2F2
    XeF6 (s) + H2O(l)
    AgNO3 +H3PO2+ H2O

    11
    12
    13
    14
    15

    P-BLOCK REACTION CARD-3


    P4 + SO2Cl2
    SO2 + MnO 4- + H2O
    Xe (g) (in excess) + F2(g) , 673K 1Bar
    H3PO3 + (Heat)
    XeF2 + PF5

    36
    37
    38
    39
    40

    P-BLOCK REACTION CARD-8


    PCl3 + H2O
    Br2 (g) + F2(g) (excess)
    SO3 + H 2SO 4 (conc.)
    XeF6 (s) + 2H2O(l)
    CaF2 + H2SO4

    16
    17
    18
    19
    20

    P-BLOCK REACTION CARD-4


    P4 + SOCl2
    SO2 + Fe3+ + H2O
    Cl2 (g) + F2(g) (excess)(3000C)
    F2(g) + H2O
    PCl5 + Heat

    41
    42
    43
    44
    45

    P-BLOCK REACTION CARD-9


    KClO3 + Heat( in presence of MnO2)
    SiO2 + HF
    XeF6 (s) + H2O(excess)
    NaF + XeF6
    (NH4)2 Cr2O7 + Heat

    21
    22
    23
    24
    25

    P-BLOCK REACTION CARD-5


    I2 + HNO3 (conc.)
    Ag + 2PCl5 (heating)
    Cu (aq) + NH 3(excess (aq)
    NH4Cl(aq) + NaNO2 (aq)
    C + H 2SO 4 (conc.)

    46
    47
    48
    49
    50

    P-BLOCK REACTION CARD-10


    Ca(OH)2 + Cl2 (g)
    Cl2 (g) + H2O
    NH3 (excess) + Cl2
    NaN3 + Heat
    Na2SO3 + Cl2 + H2O

    P-BLOCK REACTIONS
    1(a)# Cu + 8 HNO3(Dil. ) Cu(NO3)2 + 2NO +4 H2O
    1(b)# Cu + 4 HNO3( conc.) Cu(NO3)2 + 2NO2 +2H2O
    2(a)# 2NaOH (cold and dilute) + Cl2 NaCl +NaOCl +H2O
    2(b)# 6NaOH (hot and conc.) + 3Cl2 5NaCl +NaClO3 +H2O
    3(a)# 8NH3 (excess) + 3 Cl2 6NH4Cl + N2

    3(b)# NH3 + Cl2 ( excess) NCl3 (explosive ) + 3 HCl

    4(a)# PCl3 + H2O H3PO3 + 3 HCl


    4(b)# PCl5 + H2O POCl3 + 2 HCl
    > + H2O H3PO4 + 3 HCl
    5(a)# F2 + H2O HF + O2
    5(b)# X2(g) + H2O(l) HX(aq) + HOX (aq) ] 1/3
    ClF + H2O HF + HOCl X2(Hydrated) ] 2/3
    6(a) # 2XeF2 (s) + 2H2O(l) 2Xe (g) + 4 HF(aq) + O2(g)
    6(b) # 6XeF4 + 12 H2O 4Xe + 2Xe03 + 24 HF + 3 O2
    [Hydrolysis of XeF4 and XeF6 with water gives Xe03.]
    7(a)# # C + 2H2SO4 (Conc.) CO2 + 2 SO2 +2H2O
    7(b)# # Cu + 2H2SO4 (Conc.) CuSO4 + SO2 +2H2O
    8(a)# # 4 H3PO3 3 H3PO4 + PH3
    8(b)# (NH4)2Cr2O7
    (Heat ) - N2 + Cr2O3 +H2O
    8(c)# HNO2 --(Heat) HNO3 + H2O + 2NO
    8(d)# PCl5 + Heat PCl3 + Cl2
    9(a)# Cu + 2H2SO4 (Conc.) CuSO4 + SO2 +2H2O
    9(b)# Cu + 4 HNO3( conc.) Cu(NO3)2 + 2NO2 +2H2O
    10(a)# XeF6 + 3 H2O XeO3 + 6 HF
    10(b)# XeF6 + H2O XeOF4 + 2 HF [Partial hydrolysis of XeF6 gives oxyfluorides, XeOF4 and
    XeO2F2]
    10(c)# XeF6 + 2 H2O XeO2F2 + 4HF
    11(a)# XeF2 + PF5[XeF]+ [PF6] ;
    11(b)# XeF4 + SbF5[XeF3]+ [SbF6]
    11(c)# XeF6 + MF M+ [XeF7] (M = Na, K, Rb or Cs)
    12(a)# Ca3P2 + 6H2O 3 Ca(OH)2 + 2 PH3
    12(b)# P4 + 3NaOH + 3 H2O PH3 + 3 NaH2PO2

    P-BLOCK REACTIONS
    13(a)# 2 Fe3+ + SO2 + 2H2O 2 Fe2+ + SO42 + 4 H+
    13(b)# 5 SO2 + 2 MnO4 + 2 H2O 5 SO42 + 4 H+ + 2 Mn2+
    14(a)# P4 + 8 SOCl2 4 PCl3 +4 SO2 + 2 S2Cl2
    15(a)# 3CuSO4 +2PH3 Cu3P2 + 3 H2SO4

    14(c)# P4 + SO2Cl2 4 PCl5 + 10 SO2


    15(b)# 3HgCl2 +2 PH3 Hg3P2 + 6 HCl

    16(a)# Cu2+ (aq) + 4 NH3(aq) [Cu(NH3)4]2+(aq)


    (blue)
    (deep blue)
    16(b)# AgCl (s) + 2 NH3(aq) [Ag(NH3)2] Cl (aq) {colourless soluble complex}
    17(a)# NH4Cl(aq) + NaNO2 (aq) N2(g) +2H2O (l) + NaCl (aq)
    17(b)# (NH4)2Cr2O7+Heat N2 + 4H2O + Cr2O3
    17(c)# Ba(N3)2 Ba + N2
    18(a)# PCl3 + H2O H3PO3 + 3 HCl
    18(b)# PCl5 + H2O POCl3 + 2 HCl
    > + H2O H3PO4 + 3 HCl
    19(a)# C2 H5 OH + PCl5C2 H 5Cl + POCl3 + HCl
    19(a)# CH 3COOH + PCl5CH3 COCl + POCl3 +HCl
    20(a)# 2Ag (Finely divided )+ PCl5 2AgCl + PCl3
    20(b)# Sn(Finely divided ) + 2PCl5 SnCl4 + 2PCl3
    21(a)# NCl3 + H2O NH3 + 3 HOCl

    21(b)# PCl3 + H2O H3PO3 + 3 HCl

    22(a)# 2FeSO4 + H2SO4 + Cl2 Fe2(SO4)3 + 2HCl


    22(b)# Na2SO3 + Cl2 + H2O Na2SO4 + 2HCl
    22(c)# SO2 + 2H2O + Cl2 H2SO4 + 2HCl
    23(a)# Cl2+F2 [437K]2ClF;
    (equal volume)

    23(b)# Cl2 + 3F2 (excess) [573K ]2ClF3 ;

    24(a)# I2 +3Cl2 [437K]2ICl3;


    24(b)# I2 +Cl2 (equimolar)2ICl
    25(a)# Br2 + 3F2 2BrF3
    (Diluted with water)

    25(b)# Br2 + 5F2 2BrF5


    (excess)

    26(a)# 2 Na2S2O3 + I2 Na2S4O6 + 2 NaI


    26(a)# Na2S2O3 + 4 Cl2 +5 H2O 2 NaHSO4 + 8 HCl

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