Flat Products

Coated Steel Sheets

Hot-dip Galvanized Sheets, Electrogalvanized Sheets
and Precoated Sheets

http://www.nssmc.com/

2-6-1 Marunouchi, Chiyoda-ku,Tokyo 100-8071 Japan

Tel: +81-3-6867-4111
Coated Steel Sheets
U008en_01_201211f
2012 NIPPON STEEL & SUMITOMO METAL CORPORATION
Coated Steel Sheets of Nippon Steel & Sumitomo Metal Corporation
Steel sheets are applied throughout a broad spectrum of weldability, paintability, and various other properties as
life and industryincluding automobiles, home electric well. In addition to metallurgy, a growing diversity of other
appliances, building materials, housing, beverage cans, technologies is indispensable for meeting these needs.
and transformers. Economic growth in the emerging They include electro-chemistry, thin-lm engineering, paint
countries and other parts of the world has spurred an engineering, interface engineering, corrosion science,
expansion in steel sheet use. thermal technology, and alloying control (dif fusion)
By its speedy response to a wide range of needs and technology. In the case of coated steel sheets, if any of
its rich line-up of products, Nippon Steel & Sumitomo these technologies is lacking, customer needs cannot be
Metal Corporation is renowned for its coated steel sheets. fullled.
Nippon Steel & Sumitomo Metal develops and markets Nippon Steel & Sumitomo Metal has outstanding
high-performance steel materials capable of responding to command of these various elemental technologies and
increasingly stringent needs, such as growing concern for continues to develop products that precisely meet the Hot-dip galvanizing line Electrogalvanizing line
the environment and energy conservation. performance requirements of its customers.
Coated steel sheets, in particular, are required to
possess not only rust resistance but press formability,

Building Civil
structural engineering Road fence Heater Microwave oven Kitchen stove
member structure

DURGRIPTM
Hot-dip galvannealed steel sheet and strip
Housing
DURGRIPTM Roof, wall structural Duct Air conditioner Washing Refrigerator
Hot-dip galvanized steel sheet and strip member (outdoor unit) machine
SuperDymaTM
Hot-dip zinc-aluminum-magnesium-silicon alloy coated steel sheet and strip

Hot-dip galvanized steel sheets GALVALUME STEEL SHEETTM

Hot-dip 55% aluminum-zinc alloy-coated steel sheet and strip
Advanced control over the coating atmo- ALSHEETTM
sphere secures adhesion of the zinc to the Hot-dip aluminum-coated steel sheet and strip Automatic
base metal, thereby ensuring good workabil- ECOKOTETM-S Automobile Deck plate Greenhouse Steel furniture vending Tank roof
Sn-Zn coated steel sheet and strip machine
ity. These products are used mainly in home
Building Housing
electric appliances and building materials. Washing Refrigerator Air conditioner structural structural
machine (outdoor unit) member member

ZINKOTETM COLOR
Pre-Coating Steel Sheet and Strip
Precoated Sheets VIEWKOTETM
Pre-Coating Steel Sheet and Strip

ZINKOTETM
Electrolytic zinc-coated steel sheet and strip
DURZINKLITETM Ofce AV equipment Copying Steel furniture
Electrolytic zinc-nickel AV equipment Precision equipment machine
alloy-coated steel sheet and strip machine
Electrogalvanized steel sheets ECOTRIOTM
Zn-Si-Ni alloy coated steel sheet and strip
The surface texture is uniform and beautiful. SUPERNICKELTM
The lack of heat treatment during the coat- Nickel Coated Steel Sheet and strip
ing process helps to retain the properties of
the base metal. These products are used Copying Ofce Washing Refrigerator Air conditioner
mainly in home electric appliances for machine equipment machine (outdoor unit)
indoor use.

Notice: While ever y ef for t has been made to ensure the accuracy of the Please refrain from unauthorized reproduction or copying of the contents of this
information contained within this publication, the use of the information is at the publication.
readers risk and no warranty is implied or expressed by Nippon Steel & Sumitomo The names of our products and services shown in this publication are trademarks
Metal Corporation with respect to the use of the information contained herein. The or registered trademarks of Nippon Steel & Sumitomo Metal Corporation, afliat-
information in this publication is subject to change or modication without notice. ed companies, or third parties granting rights to Nippon Steel & Sumitomo Metal
Battery cell Heater Kitchen stove Automobile
Please contact the Nippon Steel & Sumitomo Metal Corporation ofce for the latest Corporation or afliated companies. Other product or service names shown may
information. be trademarks or registered trademarks of their respective owners.

1
 Lineup of Coated Steel Sheets of Nippon Steel & Sumitomo Metal
Available sizes Post treatment
Chromate-free treatment Intro-
Type Brand name Coating structure Main applications duction
(representative example) Coating mass Plate thickness Features No
Widthmm
g/m2 (mm) treatment General Lubricating Other special page
treatments
Automobile outer and inner panels
Zn-Fe alloyed 30 0.5 610 Corrosion resistance home appliance
Hot-dip galvannealed Base Press formability
5

Structural member (shutter)
steel sheet and strip DURGRIPTM 45g/m2(6m)
metal Weldability

Steel furniture, automatic vending
120 4.5 1,850 Paint adhesion machine

Structural member (house, civil

Hot-dip galvanized Zn 60 0.23 580 engineering structure, road member)
Base
6

TM
steel sheet and strip DURGRIP 120g/m2(17m) metal Corrosion resistance Automobile outer and inner panels
home appliance
Hot-dip galvanized sheet

600 6.0 1,840 Automatic vending machine

Corrosion resistance Structural member (house,

Hot-dip zinc-aluminum- Zn-Al (11%) 60 0.27 580 (30 times higher than common galvanized sheet) agriculture/stockbreeding structure,
Base solar panel supporting structure, civil
7

magnesium-silicon alloy coated SuperDymaTM -Mg (3%) metal Cut-edge surface corrosion resistance engineering/road structure),
steel sheet and strip -Si (0.2%) 275 9.0 1,700 Alkaline resistance home appliance, automobile parts
Scratch resistance Automatic vending machine

Hot-dip 55% aluminum-zinc 90 0.25 610 Corrosion resistance

Zn-55%Al alloy Structural member
GALVALUME Base (3~6 times higher than common galvanized sheet)
8

alloy-coated 78g/m2 (21m)
metal Thermal resistance, heat reectivity (civil engineering/
steel sheet and strip STEEL SHEETTM 170 1.6 1,230 road structure)
Decorativeness (spangle)

Al-Si alloy 40 0.3 610 Corrosion resistance

Hot-dip aluminum-coated steel Automobile exhaust system parts
Base Thermal resistance, heat reectivity
9

sheet and strip ALSHEETTM 50g/m2 (18.5m)
metal Chemical resistance Heating equipment
Toaster, hot-water system
160 2.5 1,250 Decorativeness (aluminum)

30 0.3 610 Corrosion resistance (bio fuel)

Base
10

Sn-Zn coated steel sheet and strip ECOKOTETM-S Sn-Zn layer
metal Fuel non-permeable property Fuel tank
Special lm 50 2.0 1,250

Corrosion resistance Conductivity

Electrolytic zinc-coated Zn 10 0.4 600 Lubricity, formability Fingerprint resistance
AV equipment, electronic device
Base home appliance
11

TM
steel sheet and strip ZINKOTE 20g/m2 (2.8m) metal Scratch resistance Paint adhesion OA equipment
Electrogalvanized sheet

40 3.2 1,650 *Diverse post-treatment menu Automobile outer and inner panels

Electrolytic zinc-nickel alloy-coated Zn-Ni alloy 10 0.4 600 Corrosion resistance Automobile outer and inner panels
Base
13

steel sheet and strip DURZINKLITETM 20g/m2 (2.8m) metal
Weldability home appliance
Paint adhesion Housing equipment
40 2.3 1,650

Zn-Si-Ni alloy coated 4 0.15 580 Whisker resistance

Base AV equipment, electronic device
14

steel sheet and strip ECOTRIOTM Zn-Sn-Ni alloy metal Solder wettability OA equipment
Special lm 15 1.0 1,024

Corrosion resistance (particularly after forming)

Nickel Coated 1 0.15 25 Coating adhesion
Fe-Ni alloy Base Battery
15

TM
Steel Sheet and strip SUPERNICKEL Ni layer metal Thermal resistance, heat reectivity Heating equipment
4m 0.8 1,000 Decorativeness (luster)
Precoated sheet

home appliance
10 0.4 600 Decorativeness, corrosion resistance, elimination
AV equipment, electronic device
Base of coating process at user plant
12

TM
ZINKOTE COLOR Topcoat metal (reduction of production process, cost cutting) OA equipment
Housing equipment (interior,
Zn 40 0.8 1,650 *Different properties depending on the type steel furniture)

20g/m2(2.8m) EG type Decorativeness, corrosion resistance, elimination home appliance, AV equipment,

0.3 25 of coating process at user plant electronic device
10 40
Polyester, etc. Base
16

VIEWKOTETM (25m) metal *Preparation of a variety of product types: high heat Fuel cell
CG type absorption, high reection, self cleaning, deep-drawable Housing equipment (steel
Zn 1.2 1,300 furniture, door, kitchen, bath)
60 150 metallic, antistatic, grainy, orange-peel-surfaced

Information about environmental load chemical substances contained in the products

of Nippon Steel & Sumitomo Metal Corporation is supplied in the form shown below:
1) Material Safety Data Sheet (MSDS)
2) Information about specified chemical substance content (supplementary MSDS)
3) Specified Chemical Substances Data Sheet (SSDS)
For more details, please confirm by accessing our website: http://www.nssmc.com/.

2 3
 DURGRIPTM
Production Process Hot-dip galvannealed steel sheet and strip
Limestone
Oxygen
Main Characteristics
blowing Excellent paint adhesion and weldabilityprovided by reheating
Iron ore Sintering plant Zn-Fe alloy layer
the zinc-iron alloyed layer produced by heating
Base metal
Exceptional post-painting corrosion resistance Lubricative film

Excellent press-formability, ranging from bending to deep Zn-Fe alloy layer

Basic-oxygen Non-treatment type
Molten iron drawing Base metal
furnace Continuous casting
Blast furnace Availability of sheet with highly lubricative film treatment
Coal Coking plant
Secondary refining Lubricative
Coating structure lm-treated type
(representative example)

Typical Properties
Press Formability Paint Adhesion

Reheating Pickling line The application of lubricative film treatment imparts good press form- DURGRIP has a finely textured yet rugged surface, ensuring good
Continuous hot-rolling mill
ability. paint adhesion.

GA (Lubricative film treatment) Examples of Paint Adhesion (Primary Adhesion)

Temper rolling mill
Forming tolerance Galvanized sheet DURGRIP (Galvannealed) Cold-rolled sheet

25kN 20kN 15kN 10kN 7kN

: Split : Pass : Pass : Pass : Creased

: Split : Split : Pass : Creased

Cold-rolling mill Cold-rolled coil
25kN 15kN 10kN 7kN
Treatment condition : Dip-type phosphate treatment
Forming tolerance Cation ED 20 baking
GA (no treatment) (blank folding force) Assessment test : After drawing grid pattern
Pickled coil 3mm
Stretching
Erichsen stretch forming, cellophane
5mm
tape peeling off
Weldability
Examples of Surface Appearance of Base Substrate Sheet before
The resistance weldability of galvanized steel sheet, in contrast to that Coating (Scanning Electron Microscope 1,000)
Hot-dip galvanizing line Post of cold-rolled steel sheet, generally requires appropriate welding con- DURGRIP (galvanized) DURGRIP (Galvannealed) Cold-rolled sheet
treatment
Welder Skin pass ditions in the region of high heat input. This is because zinc is a soft
equipment
metal that easily conforms to the partner metal and because zincs low
melting point causes it to melt and spread out during the initial welding
Tension leveler Tension reel stage, thereby resulting in lower current density. Consequently, less
Pay-off reel Heat Galvanizing
treatment bath heat is generated in the overlapped areas.

Direct Spot Weldability

Electrogalvanizing line
The appropriate welding conditions for coated steel sheets are shown
Cleaning Post Drying Shear in the figure below. Adequate welding current regions for coated steel
tank treatment
sheets are higher than those for cold-rolled steel sheets.
Main Applications
Electric appliances
Galvanizing Example of Appropriate Welding Conditions for Galvanized Sheet Washing machine, refrigerator, air conditioner, automatic vending machine (outer
Continuous annealing line Welder bath
t=0.8mm plate, side plate, back plate, bottom plate, parts)
13 Electrode: Circular type, 5.0 mm
Weld time: 10 Building and furniture
12 Signboard, door, sash, shutter, cabinet, steel furniture, ofce equipment
Occurrence of expulsion

Welding current (kA)

DURGRIP
11 Automobile (outer, inner, parts)
(galvanized)(90/90)
10 Pillar outer
Appropriate range (base metal fracture) Trunk lid outer, inner
9 DURGRIP Hood outer, inner Cowl panel
(Galvannealed)(90/90)
8
Cold-rolled sheet
Coil 7 Quarter panel

6 Wheel house Outer

Shortage of strength
200 250 300 400
Welding pressure (Kg) Locker outer,
inner
t=0.8mm
Front floor

Front fender Door outer

Door inner

4 5
 DURGRIPTM SuperDymaTM
Hot-dip galvanized steel sheet and strip Hot-dip zinc-aluminum-magnesium-silicon alloy coated steel sheet and strip

Main Characteristics Main Characteristics

High corrosion, and rust resistance similar to that of With remarkably high corrosion resistance compared to hot-dip galvanized Zn-Al-Mg-Si
Zn
Zn-Fe alloy layer
conventional chromate-treated sheet even with chromate- steel sheet, inhibits corrosion resistance in cut-end surfaces
Base metal
Base metal Chromate-free special film
free treatment Lubricative film Strong alkaline resistance even in direct contact with mortar and concrete Base metal
Chromate-free special film
Excellent zinc adhesion and responsiveness to severe Zn
Zn-Fe alloy layer Superior substitute for stainless steel (weak in chlorine resistance) and
Hot-dip galvanized sheet Zn-Al-Mg-Si
fabrication conditions Base
Base metal
metal aluminum (weak in alkaline resistance)
Product lineup with excellent tribological properties by Availability of chromate-free sheet having properties similar to those of Base metal
means of chromate-free treatment Coating structure Chromate-free hot-dip chromate-treated sheet Coating structure
(representative example) galvanized sheet (representative example)

Typical Properties Main Applications Typical Properties

Corrosion Resistance Mechanism of Conventional Chromate Treatment Civil engineering structure and building Coating Layer Composition and Corrosion Resistance Acid and Alkaline Resistance of Various Coated Sheets
and Chromate-free Coating Film construction (Salt Spray Tests)
Guard rail, corrugated pipe, spiral pipe, deck plate, 120 (5% NaCl solution, 24 hours)
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Hot-dip zinc-coated sheet 100

Corrosion loss (g/m2/side)

Chromate Coating Film Chromate-free Coating Film Zn 1.02 pH9~14 : Cattle and compost shed environment
wall, scaffolding pipe, light-gauge shape, shutter,
pH12.5 : Mortar and concrete environment
Shutting out of
corrosion factors Coating lm Corrosion factor Coating film sash, door, housing structural member (column, SuperDyma 80
H2O O2 Zn-11%Al-3%Mg-0.2%Si 0.034 GALVALUME STEEL SHEET AZ150
Shutting out of beam)
(Reference) 60
Coating corrosion factors Coating
adhesiveness adhesiveness Automobile In case of no addition of Si 0.060
Zn-11%Al-3%Mg
Floor, various parts 40
Corrosion- GALVALUME STEEL SHEET Surface treatment: No treatment SuperDyma K18
Self-restorative suppression Shipbuilding Zn-55%Al 0.028
Zinc coating layer Processed/ Zinc coating layer
function function injured section 20
Duct, panel 0.000 0.100 0.200 0.300 0.400 Hot-dip Zn-coated
sheet Z27
Electric appliance Corrosion loss rate (g/m2/hr) 0
Steel sheet Steel sheet 12.5
Chromate coating lm Special coating lm R e f r i g e r a t o r, w a s h i n g m a c h i n e , h e a t i n g 0 2 4 6 8 10 12 14
(containing corrosion-suppression agent) Corrosion Resistance of Flat Surfaces
equipment, air conditioner, automatic vending pH
When this film is injured, soluble hexavalent chromium Corrosion Resistance Mechanism of Chromate-free The corrosion resistance of SuperDyma (assessed by salt-spray tests to
leaches out to offer a self-restorative function that repairs machine, showcase parts
Coating Film : Chromate-free film uses substances selected determine corrosion rate) is extremely high about 30 times that of hot-dip
the film. because they provide the characteristic features of chromate Industrial machinery
film such as its barrier effect, self-restorative function and Zn-coated sheets. Scratch Resistance
paint adhesiveness. Chromate-free coated sheet has been Container for transporting agricultural product,
realized by use of this special coating film. various parts requiring corrosion resistance The coating layer of SuperDyma is hard, thus offering high scratch
Function of Chromate Coating Film Corrosion Protection Mechanism on Cut-end Surfaces and
r#BSSJFS
Fffect
Effects similar to those offered by
at Welded Sections resistance.
r4FMG
restoration function special coating lm containing corrosion-suppression agent
Corrosion Protection Mechanism at Cut-end Surfaces
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SuperDyma

Cold-rolled
Hot-dip Zn-coated
Corrosion loss(g/m2)

sheet Repaired section

300 Coating layer sheet

(5 days~6 months)
Phosphate-treated sheet Coating layer
GALVALUME

Initial period
200 STEEL SHEET Load: 0.098 N
ZINKOTE Red rust
Iron Iron Iron
100 0 20 40 60 80 100 120 140
DURGRIP Vichers hardness (Hv)
(galvanized)

1 2 3 4
Period (years) Main Applications
Coating layer Lapping of
Moisture composition coating layer
Zinc Coating Mass and Corrosion Resistance

(6 months~several years)
composition
Coating layer
As the zinc coating mass increases, the corrosion resistance of the hot-dip galvanized sheet is Moisture

Middle period
Sacrificed corro-
sion-protection effect
extended.
Iron Iron
Iron Lapping of coating
Zinc Coating Mass and Time up to Occurrence of Red Rust (Example) (Salt Spray Test) layer composition
Testing condition (JIS Z 2371)
Time up to occurrence of red rust (Hrs)

Room temperature : 35C

Saline solution : 5% Bridge (cable rack)
300
Automobile parts
(Several years~Until zinc around

Protection film
the cut-end surface is lost)

200
Coating layer
Latter period

100 Iron Iron

Iron
Air-conditioner
outer unit
(bottom plate)
50 100 150 200
Coating mass (one side:g/m2) Compost house (roof, frame)

6 7
 GALVALUME STEEL SHEETTM ALSHEETTM
Hot-dip 55% aluminum-zinc alloy-coated steel sheet and strip Hot-dip aluminum-coated steel sheet and strip

Main Characteristics Main Characteristics

Excellent durability and corrosion resistance Outstanding weather resistance and corrosion resistance
Zn-55%Al Al-Si
Beautiful silvery white appearance with a finely spangled Discoloration and high thermal resistance in high-temperature
pattern Base metal application Base metal
Chromate-free special film
Chromate-free special film
Excellent thermal resistance and high heat reflectivity due to Excellent high-temperature heat reflectivity, compared to hot- Al-Si
Zn-55%Al
aluminum contained in the coating dip galvanized steel sheets
Base metal
Available with chromate-free film Base metal

Coating structure Coating structure

(representative example) (representative example)

Typical Properties Typical Properties

Thermal Resistance Heat Reectivity Thermal Resistance Corrosion resistance
GALVALUME STEEL SHEET has high aluminum content, 55% of The surfaces of GALVALUME STEEL SHEET exhibit excellent heat The surface appearance of ALSHEET at high temperatures is far Because ALSHEET, like aluminum, easily generates fine yet stable
mass and 80% of capacity, and shows better thermal resistance than reflectivity, showing no substantial deterioration after long-term superior to that of hot-dip galvanized steel sheet or that of cold- oxide and hydroxide films in the atmosphere and in water, its corrosion
ordinary hot-dip galvanized steel sheets. Even when exposed to high exposure to high temperatures. Materials with high heat reflectivity rolled steel sheet. No surface discoloration occurs at 350C or under. resistance under various conditions is superior to that of galvanized
air temperatures, it shows neither significant increase of mass due to show a minimal rise in temperature. The use of materials with high At temperatures above that, the surface becomes an Al-Fe alloy, steel sheets. In application, however, it should be borne in mind that,
oxidization nor any surface discoloration due to progressive alloying. heat reflectivity particularly in roofing subjected to large thermal loads causing a discoloration. However, this conversion to an alloy prevents contrary to galvanized steel sheet, galvanic action (sacrificial action)
When used for many hours under temperatures around 350C, it is highly effective in preventing increases in indoor temperature. oxidization of the base metal, helping to retain the steel sheets thermal cannot be expected of ALSHEET.
undergoes little change. B e c a u s e o f t h e c o m b i n a t i o n o f t h i s p ro p e r t y w i t h t h e resistance.
Cyclic wetting and drying tests (Resistance to exhaust gas corrosion)
The figure below shows the change in mass when steel sheets are aforementioned excellent heat reflectivity, GALVALUME STEEL SHEET
An example of surface conditions after heating (300C 200 hours) As a result of corrosion tests using automobile exhaust gas-condensed
continuously heated in the atmosphere. It is evident that GALVALUME is suitable for such applications as the heat shields and the heat simulated fluids, ALSHEET demonstrates better corrosion resistance than do
When heated at temperatures below 350C, ALSHEET undergoes no surface
STEEL SHEET undergoes less change due to oxidization than hot-dip reflectors for toasters and microwave ovens. discoloration, retaining its beautiful appearance. electrogalvanized steel sheets and cold-rolled steel sheets.
galvanized steel sheet.
Example of Comparison of Heat Reectivity between GALVALUME Example of Mufer Test Result (Chrysler's Spec 461H-83)
Example of Oxidation Amount due to Continuous Heating STEEL SHEET and Hot-dip Galvanized Sheet (3 years after construction) Cold-rolled sheet set as 100
GALVALUME STEEL SHEET Hot-dip galvanized sheet
Corrosion rate (%)
10 Type
Hot-dip galvanized sheet [Z 25](400C) Solar radiation Solar radiation 50 100
850W/m2 850W/m2
9 (no wind) (no wind)
0 0 18%Cr stainless steel 22.9%
8
13%Cr stainless steel 27.5%
Oxidation amountg/cm2

7 50 50

6
ALSHEET 80g/m2 30.1%16m*
100 100
5
Electrogalvanized sheet
92.8%80m
4 20/20g/m2
150 150
ALSHEET Hot-dip galvanized sheet Electrogalvanized sheet Cold-rolled sheet
3 GALVALUME STEEL SHEET [AZ 150](400C)
W/m2 W/m2 Cold-rolled shee 100%87m
2
* ( ): Corrosion loss
Z 25
Hot-dip galvanized sheet 300C Heat reectivity
1
GALVALUME STEEL SHEET [AZ 150](300C) Note: Data of Bluescope Lysaght Because of its extremely beautiful surface, ALSHEET shows
0 100 200 300 400 500 600 700 800 900 Example of Heat Reectivity of Various Roong Materials Chemical resistance
exceptional heat reflectivitynearly 80% at temperatures of 450C or
Oxidation time (hours) Heat Reflectivity (%) below. Accordingly, ALSHEET is ideal for use in applications requiring Unlike zinc, aluminum has the property of being resistant to weak
Materials
heat reflectivity, including the inner heat shields for toasters and the acidity and vulnerable to alkalinity.
GALVALUME STEEL SHEET (no coating) 70 75
Corrosion Resistance upper reflectors for gas ovens and kerosene heaters.
Prepainted sheet (light color, brightness 6.0 8.5) 30 70
Example of Heat Reectivity of Various Materials
Example of Red Rust Occurrence Time Prepainted sheet (deep color, brightness 4.5 7.0) 15 40
(unit:%)
Main Applications
ZINKOTE Hot-dip galvanized sheet
Material
( )
Tile, slate (light color) 20 30 ALSHEET electrogalvanized Hot-water system
Test
Item condition sheet Spangled Non-spangled
GALVALUME STEEL SHEET Tile, slate (dark color) 10 20 Oven toaster
(AZ150) 100C24Hrs 90 95 95 95
Heat Bread machine
Concrete, cement 20 30
reectivity
Cut-end surface protection 400C24Hrs 80 30 20 20 Stove
Hot-dip galvanized sheet 30 40
Fan heater
Hot-dip galvanized sheet Measurement at room temperature after heating
Z27 Cloth dryer
D and S AERP emissivity meter (measurement wave 3 30m)
Main Applications Automobile
(muffler, manifold cover,
0 1,000 2,000 3,000
Building construction and civil
converter cover)
engineering structure
1% red rust occurrence time (hours)
Roong material, wall material, partition,
other structural metal ttings
Electric appliance
Refrigerator, washing machine, air
conditioner, automatic vending machine,
showcase, range, stove, microwave oven

8 9
 ECOKOTETM-S ZINKOTETM
Sn-Zn coated steel sheet and strip Electrolytic zinc-coated steel sheet and strip

Main Characteristics Main Characteristics

Chromate-free special film
Higher corrosion resistance than found in conventional fuel Demonstrates similar effects in application as chromate-treated sheet
tank metallic materials Sn-Zn alloy layer due to ZINKOTEs special film containing a corrosion inhibitor
Surface treatment
High corrosion resistance, even when used with bio fuels Availability of characteristic properties that conform to respective
Zn
Meets hydrocarbon permeation regulations; is free of Pretreatment customer needs thanks to ZINKOTEs diverse post-treatment lineup
environmental load substances Base metal
[Main Properties of ZINKOTE] Base metal
Highly recyclable Corrosion resistance Lubricity Conductivity Spot weldability
Thermal resistance Alkaline resistance Solvent resistance
Coating structure Coating structure
(representative example) Fingerprint resistance Paint adhesion (representative example)

Typical Properties Typical Properties Main Applications

TM
Responsiveness to Environmental Preservation: ECOKOTE -S is most suitable for use as an eco-friendly fuel Corrosion Resistance Mechanism of Chromate-free Coating Film ZINKOTE: Used for high-performance
tank material. electric appliances and OA equipment
Chromate-free Coating Film Function of Chromate Coating Film ZINKOTE is a chromate-free electrogalvanized
Emerging environmental r#BSSJFS
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needs facing fuel tank Corrosion factor r4FMG
restoration function sheet used for flat panel displays, copying
Coating film
H2O O2 When this film is injured, soluble hexavalent chromium leaches out
materials Shutting out machines, printers and other devices and
of crrosion to offer a self-restorative function that repairs the film.
factors Coating equipment.
Requirements of fuel tank adhesiveness
materials: total absence of Corrosion Resistance Mechanism of Chromate-free
Regulation for upper substances that add to Increasing use of Corrosion- Main End Products Employing ZINKOTE
ZEV regulations (US) Bio fuel Coating Film : Chromate-free film uses substances selected
limit for fuel permeation environmental burden, eco-friendly fuel suppression Processed/
function injured section Zinc coating because they provide the characteristic features of chromate Application (example) Application member
resistance to new fuels, no layer film such as its barrier effect, self-restorative function and
fuel permeation, paint adhesiveness. Chromate-free coated sheet has been Flat panel display Chassis, various parts
advantageous for recycling, Steel sheet realized by use of this special coating film.

and light-weight design Special coating lm Effects similar to those offered by special coating Copying machine, printer various parts
ELV regulations (Europe) (containing corrosion-suppression agent) lm containing corrosion-suppression agent
Regulation for Automobile Various Parts
environmental burden Promotion of recycling Recycling Law Film Required performance Audio equipment, etc
Voluntary regulations substance ECOKOTETM-S Importance on conductivity
of Japan Automobile High formability and lubricity due to Side Plate
Organic film Importance on corrosion resistance
Manufacturers surface film action Refrigerator, washing machine, etc
and scratch resistance
Association (Japan)
Excellent conductivity and adhesion Importance on conductivity, paintability
Lighter weight Inorganic film
because of thin film thickness and ironing property

Regulation for new

fuel efficiency
Corrosion Resistance

Salt Spray Test: Flat Surface Section and Formed Section (Erichsen 7 mm Extruded Section)
Characteristic Properties of Fuel Tank Material
Example of Corrosion Resistance of Flat Surface Section Example of Corrosion Resistance of Formed Section
TM TM
(A kind of typical surface treatments is shown)
ECOKOTE -S ALSHEET TERNESHEET

Rust occurrence area rate

Rust occurrence area rate

Resin 20 QS1 20 QS1
(Sn-Zn coating) (Aluminum coating) (Pb-Sn coating)
QF1T1N QF1T1N
Regulation for upper limit Inferior permeation shut-off QM QM
for fuel permeation No fuel permeation because of steel sheet performance

(%)

(%)
10 10
Promotion of recycling High recyclability because of steel sheet Inferior recyclability
QS1
Lighter weight Lighter weight by use of steels rigidity instead of identical capacity
QS1
Regulation for environment Use of lead No inclusion of environment 0
burden substance No inclusion of environment burden substance burden substance 0
QM
QM 30 50 72
30 50 72 QF1
Increasing use of eco- Outstandingly high Concerns about corrosion resistance Growing concerns about QF1
friendly fuel corrosion resistance in case of using common bio fuel permeation and deterioration Test time (hr) T1N Test time (hr) T1N
T1N

Inner surface corrosion resistance

Outer surface
Press Conductivity (Grounding Property)
Degraded Degraded corrosion Weldability Paintability
Degraded formability
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gasoline
mixed gasoline gasoline
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-PSFTUB

1SPWF
5ZQF
ECOKOTETM-S (Sn-Zn coating) Excellent Excellent Excellent Excellent Excellent Fair Excellent
-PSFTUB

1SPWF
5ZQF

Measurement Loresta EP type made Constant current source TN

ALSHEETTM (aluminum coating) Excellent Excellent Fair Fair Fair Excellent device by Mitsubishi Chemical Corp.
Measurement 4 contact/4 probe method, i
TERNESHEET (Pb-Sn coating) Fair Fair Fair Fair Excellent Good Excellent system constant current application system V T1N
Measurement
range 10 10 -2 6

Probe ESP probe Test piece QS1

Main Applications Pin tip 2 mm 4 contacts, pin interval 5 mm
spring pressure 2.4 N/spring
10 20 30 40 50 60 70 80 90 100
Conducting cycle
Fuel tank Assessment Conducting rate% 100
20 cycles Conducting rate (%)
Conducting=Les than 1m

10 11
 ZINKOTETM COLOR DURZINKLITETM
Pre-Coating Steel Sheet and Strip Electrolytic zinc-nickel alloy-coated steel sheet and strip

Main Characteristics Main Characteristics

Excellent cost performance and reduced manufacturing term at user Topcoat Outstandingly high corrosion resistance even with conventional
plant by coating only one side of ZINKOTE with a beautiful topcoat Zn (electrogalvanizing)
electrolytic galvanizing mass
Available colors (3): black, silver and white, and preparation of Fine appearance and finishing after coating, similar to cold-rolled sheet
Base metal Zn-Ni alloy
improved scratch-resistant type Easy spot and seam welding
Zn (electrogalvanizing)
Black coated sheets (2): both-sided black coated type, and high- Base metal
conductivity/good heat-absorption type Conductive film

Coating structure Coating structure

(representative example) (representative example)

Product Lineup Typical Properties

Color Type Heat treatment symbol Surface finish Bare Corrosion Resistance Weldability
Excellent cost performance due to improved In commonly conducted salt spray testing, the bare corrosion resistance of Individual spot or seam welding of DURZINKLITE can be conducted using
topcoat performance; Preparation of two kinds of D (general)
Standard type surface roughness depending on appearance KJ1 DURZINKLITE coated surfaces is more than 3 times greater than galvanized low welding current, and because the welding current range is wide, welding
D5 (high roughness)
Black general roughness and high roughness sheets with equal coatings. This product shows favorable corrosion is easy.
resistance even with a thin coating mass, but the provision of a special Examples of single spot welding at a range of welding currents for
Improved Improved scratch resistance due to chromate treatment further improves corrosion resistance. both-side galvanized sheet are shown at right. In each case, adequate
KJ2 D
scratch-resistant type addition of large-diameter beads to film
nuggets are formed using a comparatively low welding current, and the
Example of Corrosion Resistance Assessment of DURZINKLITE
Excellent cost performance due to improved (Non-treated Sheet Salt Spray Test) recommended range of welding currents is wide to allow easy welding.
Standard type topcoat performance SJ1 D

Silver
300 Example of Welding Current Range for Single Sport Welding of Both-
Improved Improved scratch resistance due to
SJ2 D side Galvanized Sheet
scratch-resistant type addition of large-diameter beads to film
DURZINKLITE
Shortage of Appropriate welding Electrode welding

5% red rust occurrence time (hours)

Excellent cost performance due nugget diameter current range
White Standard type HJ1 D
to improved topcoat performance
DURGRIP
Standard D (general) 200 (galvanized) dn=4t
Excellent cost performance due
Black K1K1
both-sided black type to improved topcoat performance D5 (high roughness)
DURZINKLITE
(20g/m2)
Standard conductive, Standard black film (KJ1 film) on one side, and D (general)
K1KC
Conductive, heat-absorbing black type conductive heat-absorption black film on the other D5 (high roughness)
ZINKOTE
heat-absorbing
(20g/m2)
black Conductive, heat-absorbing Conductive clear film (QS film) on one side, and D (general) 100
KJC
type with conductive clear film conductive heat-absorption black film on the other D5 (high roughness)
DURGRIP(galvannealed)
(45g/m2)

Main Applications ZINKOTE Cold-rolled sheet

0
Home appliance 20 40 60 80 100 6 7 8 9
AV equipment, electronic device Type
Coating mass (g/m2) Welding current (KA)
OA equipment
Reference: Time required for the occurrence of red rust in the salt spray test JIS Z 2371
Housing equipment (interior, steel furniture)

12 13
 ECOTRIOTM SUPERNICKELTM
Zn-Si-Ni alloy coated steel sheet and strip Nickel Coated Steel Sheet and strip

Main Characteristics Main Characteristics

Lead-free and chromate-free, and conforms to RoHS (Restriction of Hazardous Substances) Directive High adhesion and corrosion resistance due to formation of Fe-Ni alloy layer
Greater suppression of whiskers compared to electrolytic tinplate Chromate-free special film Availability of material quality that conforms to the particular application and the degree of
Solderability and conductivity that are similar to electrolytic tinplate and higher than those Zn-Sn-Ni alloy layer fabrication Ni layer

of galvanized steel sheet Diverse surface nishes are available, from an outstandingly ne mirror nish to a rough dull nish. Fe-Ni alloy layer

Availability of thin-gauge products with a minimum thickness of 0.15 mm Base metal Availability of coatings from thin to heavy and of differential coatings on front and rear surfaces Base metal

NEW ECOTRIO even in thin coating mass specications: Taking over the basic properties of ECOTRIO Same thermal resistance as that of stainless steel
High-strength ECOTRIO: Cost-cutting substitute for nickel silver and stainless steel sheets Coating structure Coating structure
(representative example) (representative example)

Typical Properties Main Applications Typical Properties Main Applications

Game console
Chromate-free Coating Film Surface gloss Post-fabrication Corrosion Resistance
Automobile AV equipment
t
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GPS
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PS
/P
0DDVSSFODF
PG
TV set Glossiness of surface nish External appearances of the top and body parts of size C and AA

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Personal computer batteries made of SUPERNICKEL steel sheets and Ni-coated sheets
200 [Test condition] 1000
Observed maximum whisker length (m)

Test piece: Electric and electronic parts without alloy layer, after subjected to 60 minutes of salt spray tests are
160 Plate thickness 0.3 mm, 900 BM nish shown below.
Audio system
cup forming
800 In both cases, batteries made of SUPERNICKEL steel sheet shows
Environment:60C 90%RH
120

Glossiness
Time:1000hrs 700 better post-fabrication corrosion resistance.
* The data shown here is an example 600 External appearances after SST (coating thickness: 2m)
80 of test results, which therefore does
not mean any quality guarantee.
500 BE nish Top Body
* In cases when the whisker resistance 400
40
under strict high-temperature condi-
tions (for example, high temperature 300
and high humidity surpassing 60C) Switch metal fitting Flow regulating valve
0 200 SUPERNICKEL
ECOTRIO ECOTRIO Electrolytic tinplate is required, the product with impor- B nish
tance on whisker resistance can be Fabricated
3X/3X 8/8 2.8g/m2 100
proposed. For details, please send into
1 2 3 4 5
inquiries.
size C
Coating thickness (m) batteries
Evaluation method Ni-coated sheet
Solder Wettability (Solder Wetting Time) Glossiness:Measured in transverse direction at an incidence angle without alloy
Condenser case of 60 degrees with Nihon Denshoku Model VGS-ID glossmeter. layer
t.FBTVSFNFOU
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GPS
4PMEFS
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5JNF
[Test condition]
Bad

10 Without acceleration
Test piece: Tuner cover SST: Pursuant to JIS Z 2371
After acceleration
8
0.3mm20mm7mm Coating Adhesion (workability)
(Zero crossing time) (sec)

Kind of solder: Corrosion Resistance of As-coated Flat Sheet Without

Solder wetting time

Sn-Ag-Cu An example of evaluation of coating adhesion (workability) Fabrication

6 Solder melting temperature Comparative example:
Flux applied: SUPERNICKEL Ni-coated sheet without alloy SUPERNICKEL steel sheet shows better corrosion resistance than
Rosin alcohol active type Heat sink metal layer (non-diffusion type)
4 Ni-coated steel sheet without alloy layer on both unfabricated and
accleleration conditions: fitting Bending test (No peeling found) (Peeling found)
100C (saturated humidity), Coating fabricated parts due to reduced pinholes on the coating layer,
2 (No peeling found)
8 hrs adhesion Erichsen test (No peeling found) formation of an Fe-Ni alloy layer having good adhesion, and
(tape peeling)
improved ductility due to recrystallization and softening of the Ni
Good

0 Cupping test (No peeling found) (Peeling

found)
ECOTRIO ECOTRIO Electrolytic tinplate Shield cover coating layer.
3X/3X 8/8 2.8g/m2 Work follow Bending test (Virtually no cracks found) (Many cracks found)
(SEM observation) Erichsen test (Virtually no cracks found) (Many cracks found)
Heat Resistance
Bending test A cellophane tape on the coating is peeled after 0T bend.
Corrosion Resistance A cellophane tape on the coating is peeled after a 7mm-
SUPERNICKEL steel sheet has heat resistance comparable to
Test Methods Erichsen test deep cup is formed. stainless steel (SUS) that is normally used as a heat-resistant material
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Cellophane tapes on the inside and outside are peeled after
Electrical equipment Cupping test a 30mm-deep cup is drawn. (heating temperature ~300C). As typical evaluation results of heat
[Test condition]
Bad

100
8hrs metal fitting
Corrosion resistance: resistance, changes in glossiness, changes in infrared-ray reflectance
24hrs (Salt spray test JIS Z2371)
80 and changes in color tone on heating are shown below.
occurrence area (%)

48hrs
Test piece:
Electrical equipment
Ratio of red rust

60
Flat sheet with edge seal
metal fitting Main Applications

40

Binder
20
Good

0
ECOTRIO ECOTRIO Electrolytic tinplate
3X/3X 8/8 2.8g/m2
Portable cooking stove

Stove reflection plate

High in whisker resistance, solder wettability and corrosion resistance Battery

Toaster

14 15
 VIEWKOTETM
Pre-Coating Steel Sheet and Strip
Self-Cleaning Type VIEWKOTE
Main Characteristics
Topcoat Hydrophilic coating vastly improves Coating Structure(Example) How self-cleaning works
Smooth and fine painted surface Outdoor exposure for
Primary coating
resistance against rain drop stains. Hydrophilic coating 1.5 years at Kimitsu City,
Selection of colors and material properties that meet specific needs, Offers high workability thanks to Water Chiba, Japan (industrial
through the combined use of diverse paints and base substrates Surface treatment optimal substrate design. Self-Cleaning Type Stain zone)

Base metal
Coating
Improved such factors as process, space, energy and load savings at user plant Also offers excellent weatherability
Primer coating
Surface treatment and stain resistance in processed
[Paint type of VIEWKOTE] Chemical treatment
Rear surface coating areas.
Type/ Highly workable type Type / Balanced type in workability surface physical properties A wide range of color variations,
Galvanized steel sheet
Chemical treatment The hydrophilic
Type / Stain-resistance type Type / Highly workable, stain-resistant type(universal type) Coating structure including metallic tones. coating allows drops The stains are
Self- Conventional
Back coating of water to penetrate then washed
Type / Highly corrosion-resistant type Cleaning VIEWKOTE for
(representative example) Chromate-free and eco-friendly. under stains away
Type outdoor air-
conditioner
units

Typical Properties
Deep Drawable Metallic VIEWKOTE
Application parts/ VIEWKOTE Application parts/ VIEWKOTE
Application
materials recommended specifications
Application
materials recommended specifications Offers attractive appearances. Coating Structure(Example) Processing Examples of Deep Drawable Metallic Type
Suitable for processing applications Deep Drawable
Lighting Reflecting Front side VIEWKOTE Type Outdoor Top, outside Front side VIEWKOTE Type
equipment board air-conditioner unit panel
that require bending or drawing. Metallic Type Zn standards EGC
Back side VIEWKOTE Type Back side VIEWKOTE Type Coating
Add functions by selecting the Indicated thickness 0.55mm
Front side VIEWKOTE Type Refrigerator, Front side VIEWKOTE Type
Flat-panel TV Back panel Side panel appropriate back coating. Primer coating
Back side Electroconductivity Type washing machine Back side Rear surface coating Coating mass 20/20
Example: To discharge internal heat, Chemical treatment
Front side VIEWKOTE Type Front side VIEWKOTE Type C select high heat absorption Galvanized steel sheets Back coating
VIEWKOTE
Digital recorder Chassis Automobile parts Oil filter E type
Back side Electroconductivity type Back side Lubrication Type type coating. Chemical treatment
Silver metallic
Auto on-board Front side VIEWKOTE Type Chromate-free and eco-friendly. Back coating
Top coating (VIEWKOTE
Chassis Home appliance
equipment Back side Heat Absorption Type Type $ )
AV equipment, electronic device
Fuel Cell
Housing equipment (door, kitchen, bath) Antistatic Type VIEWKOTE
Prevents static electricity caused by Example: Comparison of charged voltage
Premium Series Coating Structure(Example)
0.3
friction from conveyors and rubber

Charged voltage (kV)

suction disks in the processing/ Antistatic Type
High Heat Absorption Type VIEWKOTE VIEWKOTE 0.2
production process. Coating
Heat absorption type VIEWKOTE Atmospheric thermometry result of the interior of the Reduces dust adhesion caused by
Coating Structure(Example) 0.1
discharges heat from devices/ Box (example) Primer coating 82
static electricity.
80 Galvanized steel sheet
equipment. Reduces electric shocks caused by 0

Heat absorption coating inside the ZINKOTE Chemical treatment Antistatic Type VIEWKOTE Conventional VIEWKOTE
Colored top coating static electricity. Chemical treatment
device enclosure facilitates heat Primer coating 70 Drop about Chromate-free and eco-friendly. Experiment conditions
10C Back coating Measurement of the charged voltage of the coating surface by non-contact type static
absorption and discharge. The Chemical treatment
Temperature (C)

electricity measuring apparatus immediately after VIEWKOTE sample (70150mm)

broad VIEWKOTE menu allows Galvanized steel sheet makes contact with a piece of neoprene resin (50100mm) and is then detached.
VIEWKOTE steel sheets are Chemical treatment 60 Heat Absorption
chromate-free and eco-friendly. Heat Absorption
Coating Grainy VIEWKOTE
Under these experimental conditions, steel
sheets with an endothermic film can reduce
50 the atmospheric temperature of the interior By adding beads with large particle Coating Structure(Example) Example:Appearance after embossing 1mm
of the Box by about 10C in comparison to diameters to the coating,this type of Grainy
the bare specifications of ZINKOTE.
VIEWKOTE features highly decora- VIEWKOTE
40
tive designs,much better than those Coating
0 20 40 60 80 100 120
Measurement time (min) of conventional prepainted steel Primer coating
sheets. Galvanized steel sheet
The decorative designs can be Chemical treatment
High Reection Type VIEWKOTE improved further by combining Chemical treatment

Diffuse reectivity of 92-98%. Measurement of diffuse reection factor (example) embossing and/or press forming. Back coating
Coating Structure(Example) Chromate-free and eco-friendly.
Can be deep drawn. Beige color Brick colored
Improved to diffuse reflectivity of 10% or more.
Has excellent basic properties General white
High Reflection PCM
including corrosion and chemical Coating
resistance.
Reflection film Orange-Peel-Surfaced VIEWKOTE
Primer coating
Both electromagnetic shielding and
VIEWKOTE
High Reflection Type

Galvanized steel sheet High Reflection A pebbled surface like that of an orange Coating Structure(Example) Example:Orange-Peel-Surfaced VIEWKOTE
temperature control can be achieved VIEWKOTE
peel is achieved by special beads in the
Chemical treatment (92% type) Orange-Peel-
by selecting heat absorption types Chemical treatment coating. These beads then melt during Surfaced
with good electroconductivity in the VIEWKOTE
Back coating heating when the coating is enameled. Coating
back coating. High Reflection This coating improves processing Primer coating
Chromate-free and eco-friendly. VIEWKOTE
(98% type)
yield by making handling scratches Galvanized steel sheet

less visible. Chemical treatment

80 82 84 86 88 90 92 94 96 98 100 Its workability, chemical resistance, Chemical treatment

Back coating
Diffuse Reflectivity (Wavelength 555nm) and other basic properties are the
Can be designed with reflectivity of 92 or 98%, same as conventional VIEWKOTE.
depending on the application.
(Can also include antistatic property.)
Chromate-free and eco-friendly.

16 17