HYDERABAD INSTITUTE OF EXCELLENCE

EAMCET PRACTICE PAPERS

PAPER-1

1. Kinetic energy of electron in the hydrogen atom is +1.51 eV. Number of waves made by the electron
in that orbit is
1) 1 2) 2 3) 3 4) 4
2. Ratio of number of Lyman spectral lines to Paschen spectral lines in an hydrogen atom, when
electron transition takes from 5th orbit to first orbit is
1) 4:3 2) 2:1 3) 1:2 4) 4:6
3. In which of the following reactions large amount of energy is released ?
O g 1e Og O g 1e Og2 S 1e S S 1e S 2
1) 2) 3) 4)
IP1 , IP2 , IP3 , IP4 IP5
4. and values of an element M are 28.2 eV, 46.8 eV, 82.1 eV, 276 eV and 305 eV
respectively. Its sulphate formula is

MSO4 M 2 SO4 3 M 3 SO4 2 M 2 S2O4

1) 2) 3) 4)
XeO3 XeO4
5. Hybridisation of Xe in and are respectively
sp 3 , sp 3 sp 2 , sp 2 sp 2 , sp 3 sp 3 , sp 2
1) 2) 3) 4)
6. Number of unit cells present in 29.25 grams of NaCl is
1) N/4 2) N/2 3) N/8 4) 2N
7. When pressure of a gas is increased by three times; RMS velocity of the molecules
1) increases by 3 times 2) decreases by 3 times 3) increases by 9 times 4) remains same
8. Assertion(A) : The solubility of NaCl is more in ordinary water than in heavy water
Reason(R) : The dielectric constant of ordinary water is more than heavy water
1) A & R true, and R is not the correct explanation to A
2) A & R true, and R is the correct explanation to A
3) A is true but R is false 4) A is false but R is true
0C H 2 SO4
Fe
CaC2 H 2O X /500
Y Z Y Z
9. . In the conversion of the electrophile is
SO3 NO2 H 2 SO4 SO3
1) 2) 3) 4)

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C
H
N3C
33H
CH 3 CH 2 CH 2 NH 2 ; CH 3 CH 2 NH CH 3
10. and are

1) Positional isomers 2) Chain isomers 3) Functional isomers 4) Both 1 & 3
11. Which of the following cannot give yellow precipitate when treated with iodine and alkali (hot) ?
C
H
CH
33
CH 3 CH 2 OH CH 3 CHO
1) 2) 3) HCHO 4)
12. Which of the following has more ionic strength ?
1) NaCl 2) KCl 3) RbCl 4) CsCl
Cu2 CN 2
HC CH HCN
X;
13. Formula of X and its use is

2
C
H2
C
HC
N
H 2C CH CN H 2C CH CN
1) ; soap industry 2)
N ; polymer industry

F
H 2C CH 2
3) ; insecticide
C
H
C
N
O2H
32C
H
O 4) ; Laundry

14. IUPAC Name of the compound is

1) 2-Flouro-2-Nitro butanal 2) 3-Flouro-3-Nitro butanol
3) 3-Flouro-3-Nitro butanal 4) 2-Flouro-2-Nitro butanol
CO2
15. The volume of liberated at (STP) when 12 g of 80% lime stone is completely
decomposed is
1) 22.42 litres 2) 12.24 litres 3) 2.152 litres 4) 44.8 litres
16. Four samples of water A,B,C and D of water have BOD values 20,80,120 and 160 ppm
respectively. Which is more polluted ?
1) A 2) B 3) C 4) D
17. Orbital over lapping of Banana bond in diborane is

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 sp 2 s sp 2 sp 3 s sp 2 sp 3 s sp 3 sp p sp
1) 2) 3) 4)
Na2CO3 NaHCO3
18. A mixture of solutions is titrated against standard HCl solution. The
results are given (a) Using methyl orange indicator, the titre value is x c.c HCl for 100 ml
mixture
(b) Using phenolphthalein indicator, the titre value is y c.c. of HCl for 100 ml mixture
NaHCO3
The volume of HCl required for in the mixture is
2 y x ml 2x y ml x 2 y ml x y ml
1) 2) 3) 4)

19. Match the following

List I (Name of the silicate) List II (Formula)
Be3 Al2 Si6O18
1) Thortveitite A)
Zn2 SiO4
2) Willemite B)
Ln2 Si2O7
3) Spodumene C)
LiAl SiO3 2
4) Beryl D)
1 A, 2 B,3 C , 4 D 1 D, 2 A,3 B, 4 C
1) 2)
1 C , 2 B,3 D, 4 A 1 C , 2 B,3 A, 4 D
3) 4)
XeF4
20. Number of lone pairs and bond pairs present on molecule are respectively
1) 2 & 3 2) 2 & 4 3) 4 & 2 4) 2 & 2
P4O6 & P4O10
21. Number of P-O-P bonds present in are respectively
1) 4 & 4 2) 6 & 6 3) 4 & 6 4) 6 & 4
22. Products formed when Hypo solution reacts with chlorine are

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 Na2 SO3 , HCl , S Na2 SO4 , HCl , S
1) 2)
Na2 S , HCl , S Na2 SO4 , HCl , H 2O
3) 4)
2 F2 2 NaOH 2 NaF ' X ' 2 H 2O
(Cold . Dilute)
23.
Hybridisation & Bond angle of X are respectively
sp3 ,1030 sp 2 ,1030 sp,1030 dsp 2 ,1030
1) 2) 3) 4)
NH 3
24. Which of the following Alloys is used to reduce Nitrites (or) Nitrates to ?
1) Duralumin 2) Devardas alloy 3) German silver 4) Brass
HCl dry Ag2O Hot C2 H 5COOAg
A
AlCl

B C ConHI D C2 H 5COOC2 H 5
3
25.
Where A and D respectively
C2 H 4 , C2 H 5 I C2 H 5OH , C2 H 5 O C2 H 5
1) 2)
C2 H 5OH , CH 3 3 COH CH 3 3 COH , CH 3 2 CHOH
3) 4)
pH
26. 50 ml of 0.2 M HCl solution is added 50 ml of 0.1 M KOH solution. The of the

log 5 0.6990
resultant solution is
1) 1.6990 2) 1.3010 3) 7 4) 2.5990
1.6 109 mole 2 / litre 2
27. If the solubility product of AgCl is , its solubility is
1.6 109 mole / litre 0.8 105 mole / litre 4 105 mole / litre
1) 2) 3) 4)

16 105 mole / litre

28. If 50% of a chemical reaction is completed in 30 minutes, the time taken to complete the
90% of the reaction is
1) 60 minutes 2) 50 minutes 3) 40 minutes 4) 100 minutes

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 N2 & H 2 NH 3
29. When four moles of each are taken in one litre vessel, at equilibrium 2 moles

N 2 3H 2 2 NH 3 Kc
is formed . Then of the reaction is
1.33 litre 2 / mol 2 2.33 litre 2 / mol 2 3.33 litre 2 / mol 2 4.33 litre 2 / mol 2
1) 2) 3) 4)
30. The difference between heat of reaction at constant pressure and heat of reaction at

N 2 g 3 H 2 g 2 NH 3 g 5270 C
constant volume for the reaction at in kcal is
1) - 3.2 2) - 6.4 3) - 1.6 4) - 32
31. The time (in hours) required to decompose 18 grams of water electrically by passing 2 amp
current is
1) 26.8 2) 2.68 3) 0.268 4) 0.0268

32. Which of the following is emulsifier for water in benzene ?

N
2C
lH
3CN

2O
Hl
2H
C'X
HgI 2
1) soap 2) casein 3) kerosene 4) solid

33.
X is

2NxH
2 ZnalcKOHH No.(fbondsiA)
CH 3COCH 3 C2 H 6 CH 3CHO CH 2 CH 2

O 1)
ydr(aA
z)oben4H
2O
2) 3) 4)

yH
LiAlH4Azo(bBe)n4HNo.(fbondsB)
34.

2N
2
O 2O

Ratio between x,y and A,B respectively are

1)5:4 and 6:7 2) 4:5 and 7:6 3) 5:2 and 6:7 4) 2:5 and 7:6

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 D glu cos e 1110 D glu cos e 190
35. The specific rotation for , . An

52.70
equilibrium mixture containing and - forms has specific rotation of . The
percentage composition of the different anomers is
form 60% form 40% form 36% form 64%
1) 2)
form 30% form 70% form 45.6%
3) 4)

form 54.4%

36. Which of the following has anti-blood clotting action ?

1) Phenacetin 2) Ibuprofin 3) Aspirin 4) Paracetamol
37. Which of the following is correct statement regarding biodegradable polymers ?
1) All biodegradable polymers are polyesters 2) Poly lactic acid is a poly amide
3) Nylon 2- Nylon 6 is a polyester

C
H C
O
H
4) Dextron was the first biodegradable polymer used

3 K
M
nH
O xH
e4a,tK
H3O

C
H
2
38.
2
C
H C
H
K
M
n3H
O
e4a,KyH
tH C
3OO
H

C
O
K
C
O
K
x and y are respectively
C
H
O
C
H
O
1) 2)

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 C
O
K
C
H
O C
O
H
C
H
O
3) 4)
39. Bauxite containing iron oxide as impurity is purified by
1) Hall-Herouit process 2) Serpecks process 3) Hoopes process 4) Baeyers process

40. Which of the following characteristics represents triclinic structure?

a b c ; 900 a b c ; 900
1) 2)
a b c ; 900 a b c ; 900
3) 4)

KEY :

1) 3 2) 2 3) 3 4) 2 5) 1 6) 3 7) 4 8) 1 9) 4 10) 3
11) 3 12) 1 13) 2 14) 3 15) 3 16) 4 17) 3 18) 3 19) 3 20) 2
21) 2 22) 2 23) 1 24) 2 25) 1 26) 2 27) 3 28) 4 29) 1 30) 1
31) 1 32) 4 33) 3 34) 1 35) 2 36) 3 37) 4 38) 1 39) 4 40) 1

PAPER-2

121. ThemolecularweightofO2andSO2are32and64respectively.At150Cand150mmHg
pressure,onelitreofO2containsNmolecules.Thenumberofmoleculesintwolitresof
SO2underthesameconditionsortemperatureandpressurewillbe
1)N/2 2)N 3)2N 4)4N
122. Heliumatomistwotimesheavierthanahydrogenmoleculeat298K,theaveragekinetic
energyofheliumis
1)twotimesthatofahydrogenmolecule2)sameasthatofahydrogenmolecule
3)fourtimesthatofahydrogenmolecule4)halfthatofahydrogenmolecule
123. Theedgelengthoffacecentredunitcubiccellis508pm.Iftheradiusofthecationis110
pm,theradiusoftheanionis

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 1)144 pm 2) 288 pm 3) 618 pm 4)398 pm
124. TheorbitaldiagraminwhichAufbauprincipleisviolatedis

2s 2p 2s 2p 2s 2p 2s 2p
1) 2) 3) 4)
125. Considerthefollowingstatements:

I.Asigma( ) bondisformedwhentwosorbitalsoverlap
( )
II.Api bondisformedwhentwoporbitalsaxiallyoverlap

III.A bondisweakerthan bond
Which of the above statements is/are correct ?
1)IandII 2)IIandIII 3)Ialone 4)IIalone
126. Theboilingpointofanazeotropicmixtureofwaterandethanolislessthanthatofwaterand
ethanol.Themixtureshows
1)negativedeviationsfromRaoultslaw 2)positivedeviationsfromRaoultslaw
3)nodeviationfromRaoultslaw
4)deviationswhichcannotbepredictedfromthegiveninformation
127. Ifanendothermicreactionisnonspontaneousatfreezingpointofwaterandbecomes
feasibleatitsboilingpoint,then
H S H S
1) is ve, is +ve 2) and both are +ve
H S H S
3) and both are -ve 4) is +ve, is ve

128. Whichofthefollowingwillnotchangetheconcentrationofammoniaintheequilibrium

H
N2(g)+3H2(g) 2NH3(g); =xkJ
1)Increase of pressure 2) Increase of temperature
3) Decrease of volume 4) Addition of catalyst
129. Whichofthefollowingismostsoluble?

1)Bi2S3(Ksp=1 1067) 2) MnS(Ksp=7 1018)

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3) CuS(Ksp=8 10 )37
4) Ag2S(Ksp=6 1051)
130. Inwhichofthefollowingreactions,hydrogenisactingasanoxidizingagent?
1)Withiodinetogivehydrogeniodide 2)Withlithiumtogivelithiumhydride
3)Withnitrogentogiveammonia 4)Withsulphurtogivehydrogensulphide
131. ThestandardpotentialforthecellZn:Zn2+(1M)||Cu2+(1M);Cuinvoltsis
(E0forZn2+/Zn=0.76;E0forCu2+/Cu=+0.34)
1) -0.76 + (-0.34) 2) -0.34 + 0.76 3) 0.34 (-0.76) 4) -0.76 - (+0.34)
132. Theminimumenergynecessarytopermitareactionis
1)Internalenergy 2)Thresholdenergy
3)Activinationenergy 4)Freeenergy
133. Deficiencyofwhichofthefollowingvitaminecauseshaemorrhageandlenthenstimeofblood
clolling
1)Vitamin - A 2) Vitamin - E 3) Vitamin - C 4) Vitamin - K
134. Whichofthefollowingisrequiredinlowestconcentrationforcoagulatingasolhaving
positivelychargedcolloidalparticle?
1)KCl 2)K2SO4 3)K3[Fe(CN)6] 4)K4[Fe(CN)6]
135. Themaximumvalencyofhalogengroupelementwithrespecttooxygenis
1) 1 2)5 3)6 4)7
136. WhichofthefollowingdoesnotillustratetheanomalouspropertiesofLi?
1)ThemeltingandboilingpointsofLiarecomparativelyhigh
2)LiformsanitrideLi3Nunlikegroupofalkalimetals
3)Liismuchsofterthantheotheralkaligroupmetals
4)Li+ionanditscompoundsaremoreheavilyhydratedthanthoseoftherestofthegroup
137. ThedecreasingorderofthesecondionizationpotentialofK,CaandBais
1)K>Ca>Ba 2)Ca>Ba>K 3)Ba>K>Ca 4)K>Ba>Ca
138. Whichofthefollowingisusedinhightemperaturethermometry?
1)Al 2)Ga 3)Tl 4)Hg
139. Identifythecorrectstatementwithrespecttocarbonmonoxide?
1)itcombineswithwatertoformcarbonicacid2)itreactswithhaemoglobininredbloodcells
3)itisapowerfuloxidizingagent 4)itisusedtoprepareaerateddrinks

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140. Whichisnotanacidicsalt?
1)NaH2PO3 2)NaH2PO2 3)Na3HP2O6 4)Na2H2P2O7
141. Hypoisusedinphotographfor
1)Developingpicture 2)Pictureprintig
3)Thecolourofpicture 4)Thefixationofpicture
142. Whichofthefollowinghalogenshasmetalliccharacter?
1) F2 2) Cl2 3) Br2 4)I2
143. MolecularshapesofSF4,CF4andXeF4are
1)Thesame,with2,0and1lonepairsofelectronsrespectively
2)Thesame,with1,1and1lonepairsofelectronsrespectively
3)Different,with0,1and2lonepairsofelectronsrespectively
4)Different,with1,0and2lonepairsofelectronsrespectively
144. The absorption of hydrogen by platinum is known as
1)Hydrogenation 2)Reduction
3)Dehydrogenation 4)Occulusion
145. Froth floatation process may be used to increas the concentration of the mineral in
1) Chalcopyrites 2) Bauxite 3) Haematite 4) Calamine
146. Assertion:Thehighestoxidationstateofchromiuminitscompoundsis+6.
Reason:TheelectronicconfigurationofchromiumviolatesHundsrule
1)Bothassertionandreasonarecorrect,andreasonisthecorrectexplanationoftheassertion
2)Assertionandreasonarecorrect,butreasonisnotthecorrectexplanationoftheassertion
3)Assertioniscorrect,butreasonisincorrect
4)Assertionisincorrect,butreasoniscorrect
147. ThecoordinationandoxidationnumberofXinthecompoundrespectivelyare[X(SO4)
(NH3)5]Clwillbe
1)10and3 2)6and4 3)2and6 4)6and3
148. Which one among the following pairs of ions cannot be separated by H2S in dilute
hydrochloric acid ?
1)Bi3,Sn4+ 2)Al3+,Hg2+ 3)Zn2+,Cu2+ 4)Ni2+,Cu2+
149. MatchListIwithListIIandselectthecorrectanswerusingthecodesgivenbelowthelists
ListI ListII

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 A)Nylon 1)Polyester
B)Terylene 2)Polytetrafluoroethylene
C)Teflon 3)Syntheticrubber
D)Neoprene 4)Polyamide
1)A2,B3,C1,D4 2)A2,B3,C4,D1
3)A4,B1,C3,D2 4)A4,B1,C2,D3
150. ThepassageofcurrentliberatesH2atcathodeandCl2atanode.Thesolutionis
1)Copperchlorideinwater 2)NaClinwater
3)Ferricchlorideinwater 4)AuCl3inwater
151. AhydrocarbonhasC=85.72%andremaningH.Thehydrocarbonis
1)C2H4 2)C2H6 3)C2H2 4)CH4
152. ThetotalnumberofisomersforC4H8is
1)5 2)6 3)7 4)8
153. Nucleophilicityorderiscorrectlyrepresentedby

CH 3 NH 2 HO F CH3 ; NH2 HO ; F
1) 2)
CH 3 NH 2 HO F NH 2 F HO CH 3
3) 4)
154. Ethynecanbeoxidisedtooxalicacidbyusing
1)Chronicacid 2)Alkaline KMnO4
3) Hypochlorous acid 4)Allreagents
155. Whichofthefollowingsubstancesdoesnotgiveiodoformreaction?
1)C6H5COCH3 2)CH3OH 3)CH3CH2OH 4)CH3CHO
156. Reactionbetweensodiumethoxideandbromoethaneyields
1)Methylethylether 2)Dimethylether 3)Diethylether 4)Propane
NaOH


157. ThereactionC2H5CHO+CH3CHO C2H5CH=CHCHO+H2Oisknownas
1)Clemensonsreaction 2)SimpleAldolcondensation
3)CrossedAldolcondensation 4)Cannizzaroreaction
158. WhichofthefollowingcompoundswillreactwithNaHCO3solutiontogivesodiumsaltand
carbondioxide?
1)Aceticacid 2)nHexanol 3)Aceticacidandphenol 4)Phenol

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159. AnilinereactswithNaNO2andHClaticetemperaturetogive
1)Nitroaniline 2) Phenol
3)Chloroaniline 4)Diazoniumchloride
160.Glucosecannotbeclassifiedas
1)Ahexose 2)Acarbohydrate 3)Anoligosaccarude 4)Analdose

Answers
1) 3 2) 2 3) 1 4) 2 5) 3 6) 2 7) 2 8) 4 9) 2 10) 2
11) 3 12) 2 13) 4 14) 4 15) 4 16) 3 17) 1 18) 2 19) 2 20) 2
21) 1 22) 4 23) 4 24) 4 25) 1 26) 3 27) 4 28) 1 29) 4 30) 2
31) 1 32) 2 33) 3 34) 2 35) 2 36) 3 37) 2 38) 1 39) 4 40) 3

PAPER-3

46. Which of the following combinations are correct

I) Debroglie's theory - dual nature of matter
II) Bohr's theory - dual nature of electron
III) Schrodinger equation - dual nature of electron
IV) Plank's equation - dual nature of light
a) All b) I, III, IV only c) I, II, III only d) II, IV only
47. In which of the following conversion there is no change in hybridisation of central atom
NH 3 NH 4 BF3 BF4 PCl5 PCl6 SiF4 SiF62
a) b) c) d)
48. Which of the following has highest ionisation potential
a) He b) Li+ c) Na+ d) Be+2
49. Dalton's law is not applicable to a mixture of
N 2 O2 He Ne H 2 O2 NH 3 HCl
a) b) c) d)
50. 1mole ammonia contain
6.023 10 23 atoms
a) b) 10 moles of electrons
c) three atoms of hydrogen d) 1 mole of nitrogen

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51. Which of the following is used to remove both temporary and permanant hardness of water
a) Soap b) Washing soda c) Slaked lime d) Both a and b
52. Which of the following salt dissolves in excess NaOH
AlCl3 FeSO4 FeCl3 AgNO3
a) b) c) d)
53. Which of the following is partially ionic
BeH 2 MgH 2 CaH 2 SrH 2
a) b) c) d)
54. Which of the following is not true about potash alum
a) It is used as styptic b) It is used as mordant
c) It undergoes anionic hydrolysis d) It is a double salt
55. Which of the following has highest calorofic value
a) Water gas b) Producer gas c) Coal gas d) Carburetted water gas
XeO3
56. Wrong statement about is
a) It is hygroscopic b) It contains a lone pair on central atom
d p
c) 'Xe' is in second excited state d) It contains three bonds
57. DO values of four water samples A, B, C, D are 1ppm, 4ppm, 2ppm and 0.5ppm respectively.
The best sample is
a) B b) D c) C d) A
58. Which of the following is not a IUPAC name
I) Ethylene chloride II) Acetylene tetra chloride
III) Hexachloro benzene IV) Methyl formate
a) All b) II, III, IV only c) I, II, IV only d) I, II only
59. Which of the following molecule cannot show structural isomerism
a) Acetic acid b) Acetaldehyde c) Ethylalcohol d) Ethylene
60. Stationary phase in paper chromatography is
a) Solid only b) Solid (or) liquid c) Liquid only d) Liquid (or) gas
61. Which of the following is not a pair of diastereomers

a) Maleic acid and fumaric acid b) -glucose and -glucose
c) (+) - tartaric acid and mesotartaric acid d) D (-)-fructose and L(+)-fructose
KMnO4 / OH
C2 H
4
Cl2
CCl4

A alc . KOH
B NaNH 2
Mineral oil
C D
62. . Incorrect statement is

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 a) A is a vicinal dihalide b) B is allyl halide
c) C has two acidic hydrogens d) D is a dicarboxylic acid

Be2C
H 2O
A 3 moles Cl2
h
B ( CH 3 ) 2 CO
C
63. . C is
a) 30 alcohol b) a ketone c) a trichloro ketone d) a 20 alcohol
NaNO2 HCl
C6 H 5OH
Zn
A
Conc
. HConc . HNO3
SO , below 600 C
B Sn / HCl
C 273 K
D
2 4

64. . Wrong match is

a) A-Aromatic hydrocarbon b) B-oil of mirbane
c) C-weak base in aqueous solution d) D-Stable at high temperature
C2 H 5OH
one

mole
Cl2
A
PCl5 B aq KOH
C Li AlH 4
D
65. . Regarding 'D' incorrect statement is
a) It is an alkane b) It is used as a fuel
c) It is highly soluble in water d) It reacts with RMgX to give an alkane
66. Most acidic of the following is

HCOOH CH 3COOH CF3COOH C6 H 5OH

a) b) c) d)
67. The halogen atom not present in halothane is
a) Fluorine b) Iodine c) Chlorine d) Bromine
68. Which of the following does not contain a primary amine group
a) Glycine b) Tryptophan c) Proline d) Asparatic acid
69. Which of following is a homopolymer
a) Nylon 6, 6 b) PET c) Nylon-2-Nylon-6 d) Nylon-6
70. Which of the following is an anti depressant drug
a) Valium b) Morphine c) Iproniazid d) Aspirin
71. Assertion (A) : Glucose contains an aldehyde group
Reason (R) : Glucose reacts with mild oxidising agent to produce a mono carboxylic acid
containing six carbon atoms
a) Both (A) and (R) are true and (R) is the correct explanation of (A)
b) Both (A) and (R) are true and (R) is not the correct explanation of (A)
c) (A) is true but (R) is false d) (A) is false but (R) is true
72. False statement about a catalyst is
a) It can initiate a process b) It is required in small quantities
c) It may undergo a physical change d) It is selective in its action
73. Which of the following has highest vapour pressure

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 0.1M K 4 [ Fe(CN )6 ] 0.1M Na2 SO4
a) b) 0.1M urea c) d) 0.2M NaCl
74. Density of a solution is 1g/cc. Most concentrated solution is
a) 1N b) 1m c) 1M d)all are equally concentrated
HBr H 2O H 3O Br
75. , reaction proceeds in
a) Foward direction b) Backward direction c) Cannot be predicted
d) Both forward and backward reactions are equally favoured
H 2 SO4
76. 100ml of 0.1M is mixed with 100ml 0.1M NaOH solution and the solution is diluted to
one litre. pH of the resulting solution is
a) 12 b) 7 c) 2 d) 8
NH 4 HS ( s ) NH 3( g ) H 2 S( g )
77. For the process the . Partial pressure of ammonia at equilibrium
is 20atm. Total pressure at equilibrium is........atm
a) 40 b) 400 c) 20 d) 80
A( g ) B( g ) C( g )
78. The reaction proceeds by first order kinetics. The initial pressure of A is
100mm. After 10 minutes the total pressure is 150mm. Rate constant of the reaction
is.......min1
a) 10 b) 0.2303 c) 0.0693 d) 0.693
0
EZn 2
/ Zn
0.76V 0
EFe 2
/ Fe
0.44V Fe( s ) / Fe 2 (1M ) / / Zn 2 (1M ) / Zn( s )
79. ; ; EMF of the cell is
a) -0.32V b) +0.32V c) -1.2V d) +1.2V

1090 28
80. Bond angle is less than for
O3 OF2 SCl2 NH 3
I) II) III) IV)
a) All b) I, II, IV only c) II, III, IV only d) II, IV only
81. Which of the following is non-spontaneous at all temperatures
a) solubility of iodine in water b) formation of ozone from oxygen

Cl Br2
c) oxidation of by d) All of these

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82. Enthalpy of combustion for graphite, hydrogen and ethylene are -394, -286 and -1410
kJ/mole respectivel. Enthalpy of formation of ethylene is.............kJ/mole
a) +50 b) -50 c) -2770 d) +2770
83. Which of the following acid forms two types of salts
H 3 PO4 H 3 PO3 H 4 P2O7
a) b) c) d) both b and c
MgCl2 .2 H 2O X
MgCl2
84. . X is

3500 C 3500 C Cl2 / h 8900 C

a) b) dry HCl, c) d)
85. The element exhibiting highest oxidation state belongs to ........ group
a) 7th b) 8th c) 9th d) 10th

[Co( NH 3 )5 Br ]SO4 [Co( NH 3 )5 SO4 ]Br

86. and are .......... isomers
a) Hydrate b) Ligand c) Ionisation d) Coordination
3 pz
87. orbital is represented as
(3,1,1) (3,1, 0) (3,1, 1) (3, 0,1)
a) b) c) d)
88. Which of the following has largest atomic radius
a) La b) Lu c) Ce d) Eu
89. Electron affinity and ionisation potential of an element are x ev/atom and y ev/atom
respectively. Electronegativity of the element is
x y x y x y
5.6 544 129
a) x + y b) c) d)
90. What weight of 50% pure limestone can liberate 2.24l of carbondioxide at STP
a) 5g b) 20g c) 2.5g d) 10g
***

CHEMISTRY

46) b 47) a 48) d 49) d 50) b 51) d 52) a 53) b 54) c 55) c

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56) c 57) a 58) c 59) d 60) c 61) d 62) b 63) a 64) d 65) a
66) c 67) b 68) c 69) d 70) c 71) a 72) a 73) b 74) c 75) a
76) c 77) a 78) c 79) a 80) c 81) d 82) a 83) d 84) b 85) b
86) c 87) b 88) d 89) b 90) b

PAPER-4

M 2 SO4 K sp 3.2 105

+
121. (M is a monovalent metal ion) has a of at 25C. The maximum

SO42
concentration of ions possible in a saturated solution of this solid is
4
4 10 M 5 106 M 2 102 M 8 103 M
1) 2) 3) 4)
M (OH ) x K sp 4 109 103
122. has a of and its solubility is M. The value of x is
1) 4 2) 1 3) 3 4) 2
K sp
123. When equal volumes of the following solutions are mixed, the precipitation of AgCl( =
1.8 1010
) will occur with
104 M ( Ag ) and 104 M (Cl ) 105 M ( Ag ) and 105 M (Cl )
1) 2)
105 M ( Ag ) and 106 M (Cl )
3) 4)
1010 M ( Ag ) and 1010 M (Cl )

As 3 As2 S3 Zn2 ZnS H 2S

124. Why does only get precipitated as and not as when is passed
As3 Zn 2
through an acidic solution containing and ?
As2 S3
1) The solubility product of is less than that of ZnS
As 3
2) Enough ions are present in an acidic medium
3) A zinc salt does not ionize in an acidic medium
4) The solubility product changes in the presence of an acid

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 103 Ag
125. 50mL of a solution containing mol of is mixed with 50mL of a 0.1M HCl solution.
Ag K sp 1.0 1010
How many moles of remains in solution ( of AgCl = )?
9 7 8
2.5 10 2.5 10 2.5 10 2.5 1010
1) 2) 3) 4)
CH 3COONa CH 3COOH CH 3COOH
126. When is added to the pH of .
1) increases 2) decreases 3) remains same 4) becomes zero
127. Which of the following statements is incorrect ?
1) Specific conductance of an electrolytic solution decreases with dilution
2) Conductance of an electrolytic solution increases with dilution
3) Equivalent conductance of an electrolytic solution increases with dilution
4) Conductance of an electrolytic solution decreases with dilution
128. The conductance of a solution of an electrolyte is equal to that of its specific conductance.
The cell constant of the conductivity cell is equal to
1) resistance 2) faraday 3) zero 4) unity
129. The equivalent conductance of an acetic acid solution of concentration 0.01M is 1.65m S m2
mol 1
at 298 K. The dissociation constant of acetic acid at this temperature is (given,
0 39.0m S m2 mol 1
)
1.8 104 4.0 1010 1.8 105 1.8 106
1) 2) 3) 4)

130. The increase in equivalent conductance of a weak electrolyte with dilution is due to
1) increase in degree of dissociation and decrease in ionic mobility
2) decrease in degree of dissociation and decrease in ionic mobility
3) increase in degree of dissociation and increase in ionic mobility
4) decrease in degree of dissociation and increase in ionic mobility
131. The variation of equivalent conductance of strong electrolyte with (concentration) 1/2 is
represented by

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c c
1) 2)

c c
3) 4)
132. Which pair will show common ion effect ?
BaCl2 Ba ( NO3 )2 NaCl HCl
1) 2)
NH 4OH NH 4Cl NaCN KCN
3) 4)

133. Which of the following has the lowest value of Ksp at 25C ?
Mg (OH )2 Ca (OH ) 2 Ba (OH )2 Be (OH )2
1) 2) 3) 4)

134. Sodium metal in liquid ammonia is

1) an ionic conductor 2) an electronic conductor
3) a mixed conductor 4) non-conductor

135. Assertion(A): The conductivity of 0.1M solutions of different electrolytes is same.

Reason (R): The conductivity depends on the size of the ions.
1) Both A and R are true and R explains A 2) Both A and R are true but R doesnt explain A
3) Both A and R are false 4) A is false but R is true

136. Specific conductivity of a solution

1) increases with dilution 2) decreases with dilution
3) remains unchanged with dilution 4) First increases then decreses

137. The resistance of 1N solution of acetic acid is 250 ohm when measured in a cell of cell
cm 1
-1 -1
constant 1.15 . The equivalent conductance (in ohm cm2 equi ) of 1N acetic acid is
1) 4.6 2) 9.2 3) 18.4 4) 0.023

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138. The equivalent conductivity of 0.1M weak acid is 100 times less than that at infinite dilution.
The degree of dissociation is
1) 100 2) 10 3) 0.01 4) 0.001

139. Highest conductance is expected for the ion in aqueous state.

Li Na Rb Cs
1) 2) 3) 4)

-1
140. For an electrolytic solution of 0.05 mole litre , the conductivity has been found to be
-1 -1
0.0110 cm . The molar conductivity (in Scm2 mole ) is
1) 0.055 2) 550 3) 0.22 4) 220

141. The common name of 2-methyl 1 -propanol

1) 2-methyl1-2-propanol 2) Sec.butyl alcohol
3) Isobutyl alcohol 4) Tertiary butyl alcohol

142. When equal weights of methyl alcohol and ethyl alcohol react with excess of sodium metal the
H2
volume of liberated is more in the case of
C2 H 5 OH CH 3 OH H2
1) 2) 3) Equal in both 4) is not liberated

143. In the conversion of starch to ethyl alcohol, the following enzymes are used
1) Invertase, Zymase, Emulsin 2) Maltase, Zymase, Emulsin
3) Diastase, Maltase, Zymase 4) Invertase, Diastase, Zymase

CaCl2
144. Assertion (A) : cant be used for drying ethyl alcohol
CaCl2
Reason (R) : Ethyl alcohol forms addition compound with
1) Both (A) and (R) are true and (R) is the correct explanation of (A)
2) 1) Both (A) and (R) are true and (R) is not the correct explanation of (A)
3) (A) is true but (R) is false 4) (A) is false but (R) is true

145. Phenol is prepared commercially form

1) Ethylbenzene 2) Isopropylbenzene 3) n-propylbenzene 4) Toluene

146. The acidic character of phenol is due to

1) Greater resonance stabilization of phenoxide ion over phenol
2) Greater resonance stabilization of phenol over phenoxide ion

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 3) Because of tautomerism occurring in phenol
4) Because oxygen is more electronegative of phenol, ethyl alcohol and water is

147. Which of the following compound gives ethylmethyl ketone on oxidation

1) Propan 2-ol 2) Butan-1-ol 3) Butan-2-ol 4)2-Methyl butan-2-ol

Cl2 3Cl2

CH 3CH 2OH CH
3CHO Cl3CCHO
step 1 step 2
148.
Cl2
In the above reaction the role of in step 1 & step 2 respectively is :
1) Oxidation, chlorination 2) Reduction, Chlorination
3) Oxidation, addition 4) Reduction, substitution
149. Rate of electrophilic substitution reaction in phenol is
1) Equal to that to benzene 2) Faster than that of benzene
3) Slower than that of benzene 4) Very slower than that Nitrobenzene

150. 2 Methyl phenol is

1) m - cresol 2) o - cresol 3) m - xylene 4) o - xylene

151. Phenol on heating with aq. KOH and chloroform undergoes

1) Kolbe reaction 2) Rosenmund reaction
3) Reimer Tiemann reaction 4)Cannizzaro reaction

152. Which of the following has the least value of pKa ?

O H O H

O H
O H NO2

CH 3 NO2
1) 2) 3) 4)

153. When ethyl hydrogen sulphate is heated with excess of alcohol at 410 K, the product obtained
is
1) Ethane 2) Ethylene 3) Diethyl ether 4) Diethyl sulphate

154. The alcohol which is least soluble in water is

O H O H
1) 2)

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 OH
O H
3) 4)

C5 H11OH
155. How many isomeric alcohols having molecular formula would give positive
iodoform test ?
1) 2 2) 1 3) 3 4) 4

156. Which of these alcohols can be prepared by reaction of Grignard reagent with a ketone,
followed by hydrolysis ?
1) 2-Methyl-1-butanol 2) 2-Methyl-2-butanol
3) 3-Methyl-2-butanol 4) 3-Methyl-1-butanol

157.

C O O H CH 3COCl
A ' A ' is
NaOH
O H

COCH 3 C O O H

OCOCH 3 OCOCH 3
1) 2)

COOCOCH 3 COCH 3

O H O H
3) 4)

NaHCO3 CO2
158. Assertion (A) : Phenol decomposes solution to evolve gas
Reason (R) : Picric acid is 2, 4, 6 - trinitrophenol
1) Both (A) and (R) are true and (R) is the correct explanation of (A)
2) 1) Both (A) and (R) are true and (R) is not the correct explanation of (A)
3) (A) is true but (R) is false 4) (A) is false but (R) is true

159. Which of the following alcohol gives blue colour in victor mayer test ?
1) n propyl alcohol 2) Isopropyl alcohol
3) Isobutyl alcohol 4)Tertiary butyl alcohol

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 160. The electrophile in Reimer Tiemann reaction is
AlCl3 BF3 CS2 CCl2
1) 2) 3) 4)

1) 3 2) 4 3) 1 4) 1 5) 3 6) 1 7) 4 8) 4 9) 310) 3

11) 112) 313) 414) 315) 416) 217) 118) 319) 420) 4

21) 322) 223) 324) 125) 226) 127) 328) 129) 230) 2

31) 332) 433) 334) 435) 136) 237) 238) 439) 240) 4

PAPER-5

CHEMISTRY
121) The following are some statements about electrolytic cell
A)inthis,chemicalenergyconvertedintoelectricalenergy
B)inthiscell,electronsflowfromcathodetoanode
C)inthis,cellreductiontakesplaceatcathode
D)inthis,cathodeisa+veelectrode
Thecorrectcombinationis
1)onlyB 2)onlyC 3)onlyC,D 4)onlyB,C
H 2 SO4
122) In electrolysis of dilute , what is liberated at anode in presence of inert electrode ?
H2 SO2 SO3 O2
1) 2) 3) 4)
123) Products of electrolysis of aq NaCl using inert Pt electrodes
Cl2 H2 Cl2 , NaOH H2
1) at anode, at cathode 2) at anode at cathode
H 2 , NaOH Cl2
3) at anode, at cathode 4) None of the above
CuSO4
124) When aqueous is electrolysed using inert Pt electrodes, the following changes
occur
1) Colour disappears 2) pH decreases

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 CuSO4
3) Conc of solution decreases 4) All
125) The following ion/s is/are not discharged either at cathode or at anode, during electrolysis
in aqueous solution (By using pt electrodes)
SO42 NO3 K
1) 2) 3) 4) All

NH 4Cl , NaOH NaCl

126) At given temperature, the conductivities at infinite dilution of and

109.9 ohm1 cm2eq 1.

are 128, 217.8 and If the equivalent conductance of 0.01N solution of

NH 4OH 9.3 ohm 1cm 2eq 1 , NH 4OH

is then the degree of ionization of at given
temperature is
1) 0.039 2) 0.1 3) 0.39 4) 0.62
127) The correct relationship between electrochemical equivalent (e) and chemical equivalent
(E) of a substance liberated at the electrode is
e E 96500 e 96500 E e E 96500 e E 96500
1) 2) 3) 4)
CuCl2
128) Molten is electrolysed using platinum electrode. The reaction occurring at anode is
2Cl Cl2 g 2e Cl2 g 2e 2Cl
1) 2)
Cu 2 2e Cu s Cu s Cu 2 2e
3) 4)
129) Which of the following reaction is possible at anode ?
2Cr 3 7 H 2O Cr2O72 14 H F2 2 F
1) 2)
1
O2 2 H H 2O
2 Cu 2 2e Cu
3) 4)
pH
130) After the electrolysis of aqueous solution of NaCl using Pt electrodes, the of the
solution
1) increases 2) decreases 3) remains constant 4) becomes zero

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 131) During the electrolysis of aqueous solution of the following, molarity of the solution
increases without changing the chemical composition
CuSO4 H 2 SO4
1) NaCl 2) HCl 3) 4)
g.coulomb 1
132) What is the electrochemical equivalent (in ) of silver ? (at wt.Ag = 108, Faraday)
1) 108 F 2) 108 / F 3) F / 108 4) 1/108 F
133) (A) : Hydrogen gas always evolved only at cathode during electrolysis
H
(R) : ions undergo reduction by gaining electrons at cathode
The correct answer is
1) Both A and R are true and R is the correct explanation of A
2) Both A and R are true and R is not the correct explanation of A
3) A is true and R is false 4) A is false and R is true

134) One faraday of electricity is passed separately through one litre of one molar aqueous
solutions of
AgNO3 SnCl4 CuSO4 .
I) II) III) The number of moles of Ag, Sn and
Cu deposited at cathode are respectively
1) 1,0.25, 0.5 2) 1,0.5, 0.25 3) 0.5, 1, 0.25 4) 0.25, 0.5, 1
KNO3
135) The electrolysis of an aqueous solution of between platinum electrode gives
NO2 H2 O2
1) K at the cathode at the anode 2) at cathode and at anode
H2 NO2 O2
3) at cathode and at anode 4) K at cathode and at anode
136)
A B C
1M CuSO4 1M CuSO4 1M KCl

Pt electrodes Cu electrodes Pt electrodes

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 PH
If volume of aq. Electrolytic solution is maintained constant in all the cells, changes
in A, B and C during electrolysis is (in the same order) :
1) increases in all the three 2) decreases in all three
3) increases, constant, decreases 4) decreases, constant, increases
NH 4Cl , NaOH NaCl
137) At given temperature, the conductivities at infinite dilution of and

109.9 Ohm 1cm2eq 1. NH 4OH

are 128, 217.8 and Calculate equivalent of at same

Ohm 1cm 2eq 1

temperature in
1) 235.9 2) 20.1 3) 199.8 4) 23.59
138) According to 2nd law of Faradays electrolysis the correct one is
wt.of H 2 liberated eq.wt.of H 2 mAg E Ag

wt.of Cl2 liberated eq.wt .of Cl 2 mcu ECu
i) ii)
mAg ECu mH 2 EH 2

mCu E Ag mCu ECu
iii) iv)
The correct combination is
1) only ii,iv 2) only i 3) only i,ii,iv 4) only ii,iii

m KCl KNO3 1cm2 mol 1 cl
139) The value of for and are 149.86 and 154.96 . Also is

71.440 hm 1 Cm 2 mol 1. NO3
The value of is

76.54 ohm 1cm 2 mol 1 133.08 ohm 1cm 2 mol 1

1) 2)

37.7 ohm 1cm 2 mol 1

3) 4) unpredictable
140) Copper can be deposited from acidified copper sulphate and alkaline cuprous cyanide. If
the same current is passed for a definite time :
1) The amount of copper deposited from acidic copper sulphate will be higher

26 | P a g e
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 2) The amount of copper deposited from alkaline cuprous cyanide will be higher
3) The same amount of copper will be deposited 4) None of the above
141) Which of the following having least pka value
O
oH
N2N
o2 o2O
N oH
N2N
o2
O
H O
H
N
o2
1) 2) 3) 4)
142) The acidic character of phenol is due to
1) Greater resonance stabilization of phenoxide ion over phenol
2) Greater resonance stabilization of phenol over phenoxide ion
3) Because of tautomerism occurring in phenol
4) Because oxygen is more electronegative than hydrogen
143) Phenol on heating with KOH and chloroform undergoes
1) Kolbe reaction 2) Resenmund reaction
3) Reimer Tiemann reaction 4) Cannizzaro reaction
144) Assertion (A): Phenols are more acidic than alcohols
Reason (R): Phenoxide is more stable than alkoxide due to resonance
1) Both A and R are true and R explains A
2) Both A and R are true and R doesnt explain A
3) A is true but R is false 4) A is false but R is true
145) When phenol is treated with excess bromine water, it gives
1) m Bromophenol 2) o and p Bromophenols
3) 2, 4 dibromophenol 4) 2, 4, 6 Tribromophenol
146) The IUPAC name of methyl isopropyl ketone is
1) 3 methyl 2 penxtanone 2) 3 methyl butan -2 one
3) 2 pentanone 4) 2 methyl pentetanone
147) Which carboxylic acid/s gives acetaldehyde on strong heating in presence of catalyst
1) Only formic acid 2) Only acetic acid
3) Mixture of formic acid and acetic acid 4) Calcium acetate
148) Alkenes can be converted into aldehydes and ketones by an acidified aqueous solution of

Pd Cl2 Cu Cl2
and This process is known as

27 | P a g e
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 1) Wackers process 2) Williamsons synthesis
3) Pyrolysis 4) Clemmensons reduction
149) 2,2 Dichloro propane treated with aq KOH gives an unstable product. It is
CH 3CO CH 3 CH 3CH OH CH 3
1) 2)
CH 3C OH 2 CH 3 CH 3CH OH CH 2CHO
3) 4)
150) Ketones cannot be prepared by
1) Rosenmunds reaction 2) The hydrolysis of terminal gem dihalides
3) The oxidation of primary alcohols 4) All of these
C4 H10O
151) The number metameric ethers possible with the formula
1) 4 2) 3 3) 2 4) 5
152) In Williamsons synthesis, ethoxyethane is prepared by
1) Passing ethanol over heated alumina
2) heating sodium ehoxide with ethyl bromide
H 2 SO4
3) Treating ethyl alcohol with excess of at 430 440 K
Ag 2O
4) heating ethanol with dry
CH 3 O C2 H 5
153) The products obtained when reacts with cold and dil HI
CH 3 I C2 H 5OH CH 3OH C2 H 5 I
1) 2)
50%CH 3 I 50%C2 H 5OH 2C2 H 5OH
3) 4)
C2 H 5OC2 H 5 Cl
2
dark
X,
154) X is
1) Trichloro diethyl ether 2) Dichloro diethyl ether
3) Trichloro acetaldehyde 4) All the three

1500 CBF500
C2 H 5OC2 H 5 CO 3
atm
X,
155) In the reaction What is X?
1) Diethyl carbonate 2) Ethyl carbonate
3) Diethyl peroxide 4) Ethyl propionate

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 156) In which of the following reactions ethyl chloride is not formed ?
AlCl3
C2 H 5OC2 H 5 PCl5 C2 H 5OC2 H 5 CH 3COCl

1) 2)

5
3
h C2 H 5OH PCl3

C
2HO
C
H
C2 H 5OC2 H 5 Cl2
3)
3 4)

157) The IUPAC name of is

1) Ethoxy propane 2) 1, 1 dimethyl ether 3) 2 ethoxy isopropane 4) 2 ethoxy propane
158) The organic compound which gives peroxy compound on exposure to atmospheric air in
the presence of sun light is
C2 H 5OC2 H 5 CHCl3 CH 3CH 2OH CH 3CHO
1) 2) 3) 4)
159) The products found when diethyl ether is reacted with cold HI are
C2 H 5 I C2 H 5OH 2C2 H 5 I H 2O
1) 2)
2C2 H 5OH C2 H 5O O C 2 H 5 H 2 O
3) 4)
160) Diethyl ether is formed when ethyl alcohol is heated with
H 2 SO4 1700 C H 2 SO4 1400 C
1) Conc. at 2) Conc. at
Al2O3 3600 C AlCl3 1400 C
3) at 4) at

1) 2 2) 4 3) 1 4) 4 5) 4 6) 1 7) 2 8) 1 9) 1 10) 1
11) 4 12) 2 13) 4 14) 1 15) 2 16) 4 17) 1 18) 3 19) 1 20) 2
21) 4 22) 1 23) 3 24) 1 25) 4 26) 2 27) 3 28) 1 29) 3 30) 4
31) 2 32) 2 33) 1 34) 2 35) 4 36) 3 37) 4 38) 1 39) 1 40) 2

PAPER-6

CHEMISTRY

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 H 2 O2
121. The reaction taking place at anode in fuel cell is
1) O2 ( g ) 2 H 2O( ) 4e 4OH ( aq) 2) H 2 ( g ) 2OH (aq ) 2 H 2O(l ) 2e

3) O2 ( g ) 2 H 2O(l ) 4OH (aq) 4e 4) 2 H 2 ( g ) O2 ( g ) 2 H 2O(l )

122. At 250C, the reduction potential of hydrogen electrode is 0.236 V . The pH of the acid
solution used for the construction of the electrode is
1) 2 2) 4 3) 3 4) 1
123. Zinc is used to protect corrosion of iron because
1) E red. of Zn < E red. of iron 2) E red. of Zn > E red. of iron
3) E red. of Zn = E red. of iron 4) Zn is cheaper than iron
124. The standard reduction potential values of three metallic cations X, Y and Z are 0.52, - 3.03
and
1.18 V respectively. The order of reducing power of the corresponding metals is
1) Y > Z > X 2) X > Y > Z 3) Z > Y > X 4) Z > X > Y

125. From the following E0 values of half cells

i) A + e A ; E0 = 2.24 V

ii) B + e B2 ; E0 = + 0.25 V

iii) C + 2e C3 ; E0 = 1.25 V

iv) D + 2e D2 ; E0 = + 1.68 V
What combination of two half cells would result in a cell with a largest potential
1) ii and iii 2) ii and iv 3) i and iii 4) i and iv
Zn | ZnCl2 || NiSO4 | Ni
(0.2 M ) (0.02 M )
126. The EMF of the cell for the cell reaction approximately is

E 0 Zn 2 | Zn 0.76V E 0 Ni 2 | Ni 0.24 V
,
1) 1.03 V 2) 1.03 V 3) 0.49 V 4) - 0.49 V
127. Assertion (A): When iron rod is immersed in NaCl solution such that half of its length is
corroded and other half part when exposed to air is not corroded.
Reason (R): Metal portion with more access of O2 corrodes

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 1) Both A and R are true and R explains A 2) Both A and R are true but R does not explains A
3) A is true but R is false 4) A is false but R is true
128. During the discharging of lead storage battery the reaction occurring at the anode is
represented by

Pb Pb+2 + 2e- Pb+2 + 2e- Pb

1) 2)

PbSO4 Pb+2 + SO4- 2 PbSO4 PbO2 + 4 H + + SO4- 2 + 2e-

3) 4)
Mg Cu2 Mg 2 Cu
129. The EMF of the galvanic cell, is,
E 0 Mg 2|Mg 2.37 V E 0 Cu 2|Cu 0.34 V
Given ;
1) 2.03 V 2) -1.3 6 V 3) 2.71 V 4) -2.71 V
130. At what concentration of ZnSO4 the reduction potential of zinc electrode is 0.82 V (SRP of
Zinc electrode is -0.76V)
1) 0.01 M 2) 0.1 M 3) 0.02 M 4) 0.2 M
131. The SRP value of chlorine electrode is + 1.36 V, Then the single electrode potential of Pt, Cl 2

(1 atm) | Cl (0.01 M) is
1) 1.36 V 2) + 1.36 V 3) +1.48 V 4) 1.42 V
132. Blue colour is obtained when a wire of copper is immersed in aqueous solution of silver
nitrate. It is due to the formation

1) Ag 2) Cu+ ion 3) Ag+ion 4) Cu+2 ion

133. Consider the cell given below
Ag s | Ag || Cu 2 | Cu s

Ag e Ag;
E0 = x
Cu 2 2e Cu;
E0 = y

The E0 of the cell is

1) x + 2y 2) 2x + y 3) y-2x 4) y-x
Cu 2 | Cu,Hg 2 / Hg Zn 2 | Zn
134. The S.R.P. of and are respectively 0.34V, 0.85V and -0.76V. The
correct statement is:

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 1) Cu reduces Zn+2 2) Zn is oxidised by Cu+2

3) Zn reduces both Cu, Hg 4) Hg reduces Zn+2

+1 +1
135. By how much will the potential of Ag | Ag electrode change, if the aqueous solution of Ag
is diluted by 10 times
1) increase by 0.03V 2) decrease by 0.03V 3) increase by 0.059V 4) decrease by 0.059V

136. For the following reaction ,NH HS NH + H S , the total pressure at
4 (s) 3(g) 2 (g)
equilibrium is 20 atm. The value of Kp is
2 2 2
1) 100 atm 2) 225 atm 3) 30 atm 4) 15 atm

137. Favourable conditions for the formation of Ammonia by Habers process are P and
...T
1) High, high 2) High, low 3) Low, high 4) Low, low

1
138. In an exothermic reaction A B, the activation energy is 100 KJ mol . The enthalpy of the

reaction is 240 KJ mol1. The activation energy of the reverse reaction B A is
1 1 1 1
1) 340 KJ mol 2) 480 KJ mol 3) 200 KJ mol 4) 280 KJ mol
139. The hydrolysis of an ester in alkaline medium is a
1) First order, unimolecular reaction 2) second order, bimolecular reaction
3) first order, bimolecular reaction 4) second order, unimolecular reaction
140. In a first order reaction, the concentration of the reactant, decreases from 0.8M to 0.4M in
15 minutes. The time taken for the concentration to change from 0.1M to 0.025M is
1) 30 minutes 2) 15 minutes 3) 7.5 minutes 4) 60 minutes
COOH

COOH
COOH OH

OCH3 NO2
141. I. II. III. IV.
The correct order of acidic nature of the above compounds is
1) I > II > III > IV 2) III > II > I > IV 3) I = IV > II > III 4) III > II > IV > I

32 | P a g e
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LiAlH 4

142. 2C6H5NO2 X + 4H2O. The number of and bonds present in the compound
X is

1) 27 .6 2) 27 ,7 3) 25 ,6 4) 25 ,7
143. Carbyl amine reaction with chloroform and alcoholic KOH is given by
I) n butyl amine II) Isobutyl amine
III) Secondary butyl amine IV) Tertiary butyl amine
1) All 2) I, II only 3) III, IV only 4) I, II, IV only
144. Identify A and B in the reaction
B A


CH3CH3 CH3 COOH CH3CH2OH
A B
1. HI + Red P LiAlH4

2. Ni / LiAlH4
3. LiAlH4 HI + Red P
4. Pd BaSO4 Zn + HCl
145. The correct order of increasing order of basic nature for the bases C6H5NH2(A), NH3(B),
C2H5NH2(C) and (C2H5)2NH(D) is
1) A < B < C < D 2) B < C < A < D 3) D < C < B < A 4) A < C < D < B
1mole Cl2
Re d P
KCN


H / H 2O

146. CH3COOH A B C. Hence C is

1) Oxalic acid 2) Maleic acid 3) Fumaric acid 4) Malonic acid
147. Nitrobenzene is converted to aniline. In this reaction the equivalent weight of nitrobenzene is
1) 61.5 2) 20.5 3) 50 4) 31.7
H 2O /

148. CH3COOH + NH3 X Y. Y on hydrolysis gives P + Q. P and Q
respectively are
1) CH3COOH and NH3 2) CH3H2OH and NH4Cl
3) CH3COOC2H5 + NO2 4) CH3CH2 ONO + CO2
149. Which among the following undergoes haloform test but cannot give Fehlings test ?
1) Ethanal 2) Propanone 3) Ethanoic acid 4) Butan-1-ol
150. When acetic acid is treated with P 4O10, compound A is obtained along with H 2O. A reacts
with
aniline in the presence of pyridine to give
1) Benzanilide 2) Acetanilide 3) Benzalidene aniline 4) Phenyl isocyanide
151. In rubber industry, which of the following acts as an antioxidant
1) C2H5NH2 2) C6H5NHSO2C6H5 3) C6H5CH=NC6H5 4) C6H5N2Cl

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 Dry
distillation
152. CH3COOH + Ca X + CaCO3; X Y. The functional group in Y is
1) CHO 2) CO - 3) COOH 4) O
153. Assertion (A): C6H5 COOH is stronger acid than CH3 COOH
Reason (R): sp2 carbon atom of C6H5 group is more electronegative than the sp 3 carbon
atom
of CH3 group
1) A is true, R is true and R is correct explanation of A
2) A is true, R is true and R is not correct explanation of A
3) A is true, R is false 4) A is false, R is true
154. Correct statements regarding acetic acid are
A) Its boiling point is greater than that of water
B) It exists as polymer in water
C) It liberates hydrogen gas when reacted with sodium metal
D) it liberates CO2 with sodium bicarbonate
1) A, B 2) B, C, D 3) A,C, D 4) A, B, C
Zn KOH

155. 1 mole of nitrobenzene + x [H] A
Zn NH 4Cl

1 mole of nitrobenzene + y [H] B. The ratio of x and y is
1) 5 : 4 2) 5 : 2 3) 1 : 1 4) 3 : 2
156. The correct order of spin only magnetic moment (in BM) of Mn , Cr and V+2 is
+2 +2

1) Mn+2 > V+2 > Cr+2 2) V+2 > Cr+2>Mn+2 3) Mn+2 > Cr+2 >V+2 4) V+2 > Cr+2> Mn+2
157. Which of the following exhibit Geometrical isomerism (a, b = ligand, AA = bidentate ligand)

Ma2b2 M AA 2 Ma6 Ma5b

1) 2) 3) 4)
158. One mole of octahedral complex [ Co (NH 3)x(Cl)y]Clz with excess silver nitrate solution gives
two
moles of silver chloride precipitate. Then the values of x, y, z are respectively
1) 4, 2, 1 2) 5, 1, 3 3) 6, 0, 3 4) 5, 1, 2
159. The EAN of Ni in K2[Ni(CN)4] is
1. 36 2) 38 3) 34 4) 54
160. In K2[Ni(CN)4] the primary valency of the central metal ion is satisfied by
1. K+ ions 2) Two CN-1 ions 3) Four CN-1 ions 4) Both K+ & CN-1
ions

121) 2 122) 2 123) 1 124) 1 125) 4 126) 3 127) 3 128) 1 129) 3 130) 1

131) 3 132) 4 133) 4 134) 2 135) 4 136) 1 137) 2 138) 1 139) 2 140) 1

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141) 2 142) 4 143) 1 144) 3 145) 1 146) 4 147) 2 148) 1 149) 2 150) 2

151) 3 152) 2 153) 1 154) 3 155) 1 156) 3 157) 1 158) 4 159) 3 160) 2

PAPER-7

1
121. The rate of formation of
SO3 in the reaction 2 SO2 O2 2SO3 is
100 g min . Rate

of disappearance of 2 is
O
1) 50g min -1 2) 100g min-1 3) 20g min-1 4) 40g min-1
122. The increase in rate constant of a reaction is more when the temperature increases from
1) 280-290 K 2) 320-330 K 3) 340-350 K 4) 360-370 K
123. Which one of the following reaction is an example of first order reaction
2 N 2O5 2 N2O4 O2 2 H O
2 2 2O O2
2H
1) 2)
3) Radio active decay 4) All the above
1
A2 B C
124. The reaction 2 in a gaseous phase shows an increase in pressure from
d A2
100mm to 120 mm in 5 min. So dt is
1) 18
mm.min-1 2) 4mm.min-1 3) 16mm min-1 4) 8mm min-1
125. An endothermic reaction A B has an activation energy 15 Kcal. mole -1 and the
enthalpy of reaction is 5 kcal. mole-1. The activation energy of backward reaction is
1) 20kcal. mole-1 2) 15 kcalmole-1 3) 10 kcal.mole-1 4) zero
126. For the reaction A products, concentration of 'A' is changed from 0.044 M to 0.032 in
25 min, average rate during this interval is

1)
0.0048 molelt 1.sec 1 2)
0.00048 molelt 1.sec 1

3)
4.8 104 mole. lt 1.min 1 4)
0.048 molelt 1.sec 1

127. The correct order of Cl O bond energy in

ClO , ClO2 , ClO3 , ClO4 is

1)
ClO ClO2 ClO3 ClO4 2)
ClO4
ClO3 ClO2 ClO

3)
ClO4 ClO2 ClO3 ClO 4)
ClO3 ClO ClO2 ClO4

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128. Rate constant of a reaction is found to be
2 105 lit mol 1 sec 1 then the order of
reaction is
1) zero 2) first 3) second 4) third
129. Assertion (A) : Order of reaction is evaluated from the mechanism of a reaction
Reason (R) : Order of reaction can be zero
1) Both A and R are correct and R is the correct explanation of A.
2) Both A and R are correct but R is not the correct explanation of A.
3) A is True but R is False. 4) R is True but A is False.

130. For
N 2O5 2 NO2 1/ 2O2 ; it is formed that
d N 2O5 d NO2 d O2
K1 N 2O5 ; K 2 N 2O5 ; K 3 N 2O5
dt dt dt

the correct relation is

1) 1
K 2, K 3K
2 3 2) K K K
1 2 3 3) 12K 4K K
2 3 4) 1 2 K K 2 4K3
131. The following are some statements about halogens
A) Chlorine reacts with excess of ammonia and forms
B) Iron reacts with chlorine to form ferrous chloride
C) Fluorine oxidises potassium hydrogen sulphate to potassium sulphate
D) Bleaching powder is a mixed salt
The correct answer is
1) A & C 2) B & D 3) A & D 4) A,C&D

132. The rate constant of a reaction at 200 K is 10 times less than rate constant at 400 K. Then the
value of activation energy (R=universal gas constant)
1) 921.2 R 2) 1842.4 R 3) 460.6 R 4) 230. 3R
133. For the first order reaction Products, which one of the following is the correct plot of log(a-
x) versus time?

log(a-x) log(a-x)

1) t 2) t

log(a-x) log(a-x)

3) t 4) t

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134. In 3d series which element has highest melting point value and highest IP value respectively
are
1) V, Zn 2) Zn,V 3) Cr, Cu 4) Cr, Ni
Ni CO 4
135. The oxidation state of Ni in is
1) + II 2) zero 3) +III 4) +IV

136.
CrO42 and MnO4 ions exhibit colour due to
1) Presence of unpaired electrons in d-orbitals of Cr and Mn
2) Charge transfer phenomenon 3) d-d transition
4) close packing crystal structures
k A B n
m
137. The rate law for a reaction between the substance A and B is given by rate =
on
halving the concentration of A and doubling the concentration of B, the ratio of new rate to
the earlier rate of reaction will be

1) m + n 2) n - m 3) 2mn 4) 2n m
fast
2O3 3O2
O3 O2 O
138. The chemical reaction proceeds as follows and .
slow
O O
3 2O2 The rate law expression is

r k O3 r k O3 O2 r k O3 O2 r k O3 O2
2 2 1 2 2
1) 2) 3) 4)

139. a)
CaOCl2 cold water Ca 2 , Cl , x

b)
CaOCl2 hot water Ca 2 , Cl , y

c)
CaOCl2 long standing
Ca 2 , Cl 1 , y
x and y are

1)
ClO , ClO2 2)
ClO
, ClO3

3)
ClO2 , ClO3

4)
ClO3 , ClO4

140. 50 g of a good sample of

CaOCl2 is made to react with
CO2 . The volume of
Cl2
liberated at S.T.P is
1) 5.6 lit 2) 11.2 lit 3) 22. 4 lit 4) 4.48 lit

4HF X
F2 H 2O
141.
6HF Y Cl2 H 2O
HCl Z

The correct statement is

1) x, y are ozonised oxygen, Z is hypochlorous acid
2) x is paramagnetic, y is diamagnetic, Z is bleaching agent
3) Bromine water is less bleaching agent than Z.

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 4) All the above

142. For easy transportation,

F2 is converted into

1)HF 2) NaF 3)
ClF3 4)
F2O

143.
Cl 2 can not form addition compounds with

1) NO 2) CO 3)
SO2 4)
H 2S

144. When Chlorine is made to react with

Na 2 S 2O3 , the products formed are

1)
Na 2 SO3 S HCl 2)
Na 2 SO4 S HCl

3)
Na 2 S S HCl 4)
Na 2 SO4 HCl

145. I) Fluorine reacts with cold, dilute alkalies liberating 2 gas

O
II) Chlorine reacts with hot, conc. alkalies to form chlorides and chlorates
III) Bromine reacts with cold, dil. alkali to form bromide and hypobromite
The correct combination is
1) Only I & II are correct 2) Only II and III are correct
3) Only I and II are correct 4) Only III is correct

146. The hybridisation of chlorine in

ClO , ClO2 , ClO3 and
ClO4 ions are
3 3 3 2 3 3
1) sp , sp d , sp d , sp d 2) sp d , sp d , sp d , sp 3
3 3 3 2 3

2 2 2 2
3) sp , sp , sp , sp 4) sp 3 , sp 3 , sp 3 , sp 3
147. The anhydride of perchloric acid is

1) 2 Cl O 2) 2 ClO 3) 2 6 Cl O 4) 2 7 Cl O
148. Among the oxyacids of chlorine the strongest acid & strongest oxidising agent are

1)
HClO, HClO2 2) HClO, HClO3 3) HClO, HClO4 4) HClO4 , HClO
149. For which one of the following values log K is maximum (K = rate constant)

1)
A 106 , Ea 50 K .Cal , T 500 K 2)
A 104 , Ea 100 Cal , T 300 K

3)
A 108 , E 10 Cal , T 600 K
a 4)
A 102 , Ea 200 K .Cal , T 400 K
150. Which of the following graph is kinetically wrong

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 1) time 2) time

3) time 4) time
2A B C D
151. Rate law for from the following data
S.No. [A] (M) [B] (M) Rate M/S
1 0.01 0.01 2.5
2 0.01 0.02 5
3 0.03 0.02 45
1 2 1
r K A B r K A B r K A B1
3
3 3 2
1) 2) 3)
r K A B
2 1
4)
xA yB z.C
152.
d A d B d C
1.5
If , dt dt dt then x, y and z are
1) 1, 1, 1 2) 3, 2, 3 3) 3, 3, 2 4) 2, 2, 3
3
153. Units of rate constant of 2 order is
3 3
mole 1 lit 1 lit 2 1 mole 2 1
.
1) lit time 2) mole time 3) mole time 4) lit time
154. Which of the following pairs of ions are colourless
3 2
1)
Ti , Cu 2)
Sc 3 , Zn 2 3)
Co 2
, Fe 3
4)
Ni 2 , V 3
155. For a reaction and at 300K. The value of 'K' at 310K will be

1) 8.4 105 2) 8.4 1010 3) 4.2 105 4) zero

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156. The following pairs of ions have the same electronic configuration

1) Cr 3 and Fe 3 2) Fe 3 and Co 3 3) Fe 3 and Mn 2 4) Sc 3 and Cr 3

157. Configuration Element

1)
5s1 4d 5 A) Cu

2)
6 s1 5d 10 B) Pd

3)
4 s1 3d 10 C) Mo

4)
5s o 4d 10 D) Cr
E) Au
The correct match is
1) 1 - E, 2 - C, 3 - A, 4 - B 2) 1 - C, 2 - E, 3 - B, 4 - A
3) 1 - C, 2 - E, 3 - A, 4 - B 4) A - C, 2 - A, 3 - A, 4 - B
158. The number of unpaired 'd' electrons in is equal to that of
1) s - electrons in Mg 2) s - electrons in Ne 3) p - electrons in 4) d - electrons in Fe
159. Which is not true with regard to transition elements
1) they readily form complex compounds 2) they show variable valency
3) their ions are colourless 4) their ions contains partially filled 'd' orbitals
160. Stable oxidation state of cobalt is +III due to
1) half filled 'd' orbitals 2) completely filled 'd' orbitals
3) half filled orbitals 4) completely filled orbitals

KEY

121) 3 122) 1 123) 4 124) 4 125) 3 126) 3 127) 2 128) 3 129) 4 130) 4

131) 3 132) 1 133) 2 134) 1 135) 2 136) 2 137) 4 138) 2 139) 2 140) 1

141) 4 142) 3 143) 4 144) 2 145) 2 146) 4 147) 4 148) 4 149) 3 150) 4

151) 4 152) 3 153)2 154)2 155)3 156)3 157)3 158)4 159)3 160) 4

PAPER-8

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 w
NH 2CO NH 2
v
136. 0.6% aqueous is isotonic with
w

v
a) 0.1M aqueous KCl b) 0.6% aqueous KCl
w
C6 H12O6 C6 H12O6
v
c) 0.1M aqueous d) 0.6% aqueous
137. Aqueous solution contains 4 solutes A, B, C, D of different masses. If sum of the mole
fractions of A, B and D is 0.4 then mole fraction of C may be
a) 0.8 b) 0.55 c) 0.6 d) 0.05
138. Molality of an aqueous solution 4.5m. mole fraction of solute is
a) 0.45 b) 0.2 c) 0.075 d) 0.1
G
139. For which one of the following reaction, the graph of against T is almost horizontal to
temperature axis
C O CO 2C O 2CO
s 2 g 2 g s 2 g g
(a) (b)
2CO O 2CO 2 Mg O 2 MgO
g 2 g 2 g s 2 g s
(c) (d)
140. In the Bessemerization process, Bessemer Converter is lined with 'X' when pig iron contains
phosphorous, while it is lined with 'Y' when pig iron contains manganese as impurity. Here X
and Y are
a) SiO2, SiO2 b) CaO, CaO c) SiO2, CaO d) CaO, SiO2

141. Set - I Set - II

1) Ostwald-Dynamic method A) Osmotic pressure
2) Cotrells method B) Depression of F.P
3) Rasts camphor method C) Elevation of B.P
4) Berkeley and Hartleysmethod D) Lowering of vapour pressure
Correct match is
A 4, B 3, C 2, D 1 A 1, B 2, C 3, D 4
a) b)
A 2, B 3, C 4, D 1 A 2, B 4, C 3, D 1
c) d)
142. Incorrect statement about the manufacture of steel from pig iron is
a) The quality of steel manufactured in open hearth process is very high
b) The composition of steel can be controlled in Bessemer process
c) Iron ore, scrap iron and low grade pig iron can not be used in Bessemer process
d) Loss of iron due to slag formation is minimised in open - hearth process
143. The purest form of commercial iron is
a) Pig iron b) Cast iron c) Wrought iron d) Pig iron and cast iron

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144. Which of the following metals can be used for precipitation of silver from sodium
argentocyanide solution
a) Zn b) Cu c) Al d) All
Cr2O3
145. (A) : Reduction of with Aluminium is possible.
G 0 f Cr2O3 G 0 f Al2O3
(R) : of is - 540 kj/mole and of is - 827
kj/mole.
a) Both A and R are true and R explains A b) Both A and R are true and R is not explains A
c) A is true, R is false d) A is false, R is true
146. Heating mixture of Cu2O and Cu2 S will give
a) Cu + SO2 b) Cu + SO3 c) CuO + CuS d) Cu2SO3
147. The process of smelting is usually carried out in
a) Reverberatory furnace b) Blast furnace c) Open hearth furnace d) Muffle furnace
148. Which method of purification is represented by the following equitations
Ti 2 I
2
TiI
523 K
4 1700 K
Ti 2 I 2

a) Mond process b) Van Arkel method c) Zone refining d) Poling

149. Which of the following represents the graph between log P (on y-axis) and 1/T on x-axis ?
where P is vapour pressure of liquid.

a) b) c) d)
150. In Blast furnace in the zone of reduction at 4000C - 7000C the reaction occuring is
Fe O + CO
Fe O + CO CaO + SiO2
CaSiO3
2 3 3 4 2
a) b)
Fe O + 3CO
2 Fe + 3CO
FeO + C
Fe + CO 2 3 2
c) d)
151. Silver containing lead impurity can be purified by
a) Pattisons process b) parkes process c) Cupellation d) Hoopes process

152. Assertion (A): In the metallurgy of Cu, in blast furnace only Cu2S is formed but no Fes is
formed
Reason (R): Copper has greater affinity towards sulphur while Fe has greater affinity
towards
oxygen
a) A and R are true and R is the correct explanation of A.
b) A and R are true and R is not the correct explanation of A.
c) A is true, R is false. d) A is false, R is true.

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153. Assertion (A) : In the extraction of Ag by Cyanide process, Air must be blown in the solution
of Ag2S in dil NaCN
Reason (R): Continuous air blow oxidises Na2S to Na2SO4 and prevents backward reaction
a) A and R are true and R is the correct explanation of A.
b) A and R are true and R is not the correct explanation of A.
c) A is true, R is false. d) A is false, R is true.
154. Water gas is used to reduce
a) NiO 2) UCl4 3) Fused NaCl d) ZnO
155. The chemical composition of 'slag' formed during smelting process in the extraction of
copper is
(a) Cu O+FeS (b) FeSiO (c) CuFeS (d) Cu S+FeS
2 3 2 2
156. Which of the following is not a roasting process
2 ZnS 3O2 2 ZnO 2 SO2
(a) (b)
2CuFeS 2 O2 Cu2 S fused 2 FeS fused 2SO2
600 C 630
Ag 2 S 2 NaCl 2O2 2 AgCl Na2 SO4 ZnS O
2 ZnSO4
(c) (d)
157. Assertion (A) : Efficiency of Reverboratory furnace is less.
Reason (R) : In Reverboratory furnace, heat content of the waste gases cannot be used
repeatedly.

(a) Both A and R are true and R is the correct explanation of A.

(b) Both A and R are true and R is not the correct explanation of A.
(c) A is true, R is false (d) A is false but R is true
158. Regarding purification of metal
A) Carbon powder added also reduces metal oxide to metal in "poling" process
B) Zone refining method is suitable for the purification of semi conductors
C) Zn, Cd, Hg are purified by distillation process.
D) During electrolytic refining of acidified solution or molten salt, pure metal is deposited at
anode
Correct statement is
(a) All are correct (b) Only A & C are correct
(c) Only B & C are correct (d) Only A, B & C are correct
159. The heat capacity of liquid water at constant pressure, C P is 18 Cal deg-1 mol-1. The value
of heat capacity of water at constant volume, CV is approximately
a) 18 Cal deg-1 mol-1 b) 16 Cal deg-1 mol-1
c) 10.8 Cal deg-1 mol-1 d) Cannot be predicted
160. Among
I) 18g water at 298 K II) 18g steam at 373 K III) 18g ice at 263 K IV) 9g ice at 263 K
correct order of internal energy
a) IV > II > I > III b) II > I > III > IV c) III > IV > I > II d) III > I > IV > II
51 31
161. If the sequence of bases in DNA is TGAACCCTT , the sequence of bases in m - RNA is

43 | P a g e
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 31 51 31 51
a) ACUUGGGAA b) TCUUGGGTT
1 1 1
5 3 3 51
c) ACUUCCCAA d) TUCUGTUTU
162. Which of the following statements about DNA is not correct ?
a) It has a double helix structure b) Exterior width of double helix is 2nm
c) The two strands in a DNA molecule are exactly similar
d) It contains the pentose sugar, 2` deoxyribose

163. Match the following

Set - A Set - B
A) Replication 1) formation of RNA from DNA
B) Transcription 2) synthesis of copy of DNA
C) Translation 3) single strand of DNA
D) Template 4) synthesis of proteins by RNA
Now, correct match is
A B C D A B C D
a) 4 3 2 1 b) 1 2 4 3
c) 2 1 4 3 d) 2 1 3 4
164. DNA finger printing is useful for
a) Identifying the criminals b) Determining the paternity of individual
c) Identifying the dead bodies d) All
165. Insulin has two polypeptide chains, these polypeptide chains are held together by
a) Peroxy linkage b) Disulphide linkage c) Diazo bonding d) H - bonding
166. Waxes are esters of higher fatty acids with long chain
a) Monohydric alcohols b) Dihydric alcohols c) Trihydric alcohols d) All the three above
167. Lecithin and cephalin are
a) Neutral fats b) Glycolipids c) Waxes d) Phospholipids
168. Which of the following lipid does not contain phosphoric acid
a) Lecithin b) Cephalin c) Sphingomyelins d) Glycolipids
169. Spermaceti is an ester of
a) Palmitic acid, Cetyl alcohol b) Stearic acid , cetyl alcohol
c) Palmitic acid, myricyl alcohol d) Stearic acid, cholesterol
170. Select the intensive properties from the following.
I) Temperature II) Mass III) Volume IV) Molar heat capacity
a) I, Only b) I, III c) I, IV d) II, III
171. Cyclohexanol on oxidation with conc.nitric acid gives
a) Terephthalic acid b) Adipic acid c) p-xylene d) phthalic acid
gentle strong
heating
heating
172. H3PO4 X Y
X and Y respectivley are
a) HPO3 & H4P2O7 b) H4P2O6 & HPO3 c) H4P2O7 & HPO3 d) H4P2O7 & HPO2

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173. (A) : NH3 is a liquid while the other hydrides of V-A Group elements are gases at room
temp.
(R) : NH3 possess inter molecular hydrogen bonds in liquid state.
a) Both (A) and (R) are true and (R) is the correct explanation of (A)
b) Both (A) and (R) are true and (R) is not the correct explanation of (A)
c) (A) is true but (R) is false d) (A) is false but (R) is true

174. A gas expands from 1.5L to 6.5L against a constant pressure of 0.5 atm. During this process
the gas also absorbs 100 J heat, the change in internal energy of the gas is
a) +152.5 J b) 252.5 J c) 352.5 J d) 152.5 J
175. Standard enthalpy is not zero for
a) liquid Bromine b) graphite c) liquid water d) rhombic sulphur
176. Nitrous acid decomposes to give
a) HNO3, NO b) HNO3, N2O3 c) HNO3, NO2 d) H2N2O2, N2O
177. Estradiol is responsible for the development of
a) Primary male characters b) Secondary female characters
c) Primary female characters d) Secondary male characters
178. Synthetic testosterone promotes
a) Menstrual cycle b) Muscle growth c) Respiration d) Birth control agents

C17 H 33COOH
179. How many position isomers are possible for
a) 18 b) 17 c) 16 d) 9
180. LIST - 1 LIST - 2
A) NCl3 + H2O 1) HOCl
B) PCl3 + H2O 2) H3PO3
C) PCl5 + H2O 3) H3PO4
D) NF3 + H2O 4) H3PO2
5) No Hydrolysis
The correct match is
A 1, B 2, C 3, D 5 A 2, B 4, C 2, D 5
a) b)
A 3, B 2, C 1, D 4 A 5, B 3, C 2, D 1
c) d)

***
KEY

1) c 2) d 3) c 4) a 5) d 6) a 7) b 8) c 9) d 10) a
11) a 12) b 13) b 14) c 15) d 16) c 17) a 18) a 19) a 20) b
21) b 22) a 23) d 24) a 25) b 26) a 27) c 28) c 29) d 30) b
31) a 32) d 33) d 34) a 35) c 36) b 37) c 38) d 39) d 40) c

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 41) a 42) b 43) b 44) c 45) a

PAPER-9

CHEMISTRY
46. The monomer of nylon -6 is
1) Chloroprene 2) Isoprene 3) Caprolactam 4) Styrene
47. If the number average molecular weight and weight average molecular weight of a polymer
are 40,000 and 60,000 respectively, the polydispersity index of the polymer is
1) >1 2) <1 3) 1 4) 0
48. A polymer used as blood plasma, i.e life saving substance is
1) Polyvinyl pyroolidone 2) PTFE
3) Urea formaldehyde resin 4) Polymethyl methacrylate
49. The role of zinc stearate in the process of vulcanization is
1) To accelerate the process 2) To slow down the process
3) To stop the process 4) To initiate the process
50. The correct statement/s regarding PHBV is
I) Excess amounts of hydroxyl butanonic acid makes the polymer more flexible
II) Excess amounts of hydroxyl pentanoic acid makes the polymer more tough
III) It is used in orthopaedic devices
1) all 2) III only 3) I and II 4) I and III
51. A polymer sample contain 40% molecules of molecular mass 20,000,40% have 30,000 and
the rest have 60,000 the number average molecular weight of polymer is
1) 36,000 2) 32,000 3) 43,333 4) 41,000
52. The polymer used in paints and Lacquers is
1) Glyptal 2) Polystyrene 3) Bekalite 4) Neoprene
53. Dextrin is used in
I) Sizing paper II) Adhesive
III) Cotton cell wall material IV) Confectionary
1) I and II only 2) II and III only 3) I,II and IV only 4) All
54. Percentage of sulphur in EBONITE RUBBER
1) 35-40% 2) 40-45% 3) 45-55% 4) 37-39%
Mn Mw
55. Number average molecular mass ( ) and weight average molecular mass of
synthetic polymers are related as
Mn Mw Mn Mw Mn Mw Mn Mw
1) 2) 3) 4)
56. H (vap) for water is 40.7Kj mol-1. The entropy of vapourisation of water is
1) -40.7 KJ mol-1 2) 407 J mol-1 K-1 3) 109 J mol-1 K-1 4) 722 J mol-1

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57. The enthalpies of formation of C2H4(g),CO2(g) and H2O(l) at 250C and 1atm pressure are
52, -394 and -286 kJ mol-1. The enthalpy combustion of C2H4 will be
1) +1412 kJ mol-1 2) -1412kJmol-1 3) +141.2kJmol-1 4) -141.2kJ
mol-1
58. AB,A2 and B2 are diatomic molecules. If the bond enthalpies of A2, AB and B2 are in the
ratio 1:1:0.5 and enthalpy of formation of AB from A2 and B2 is -100KJ mol-1. What is the
bond energy of A2
1) 200KJ mol-1 2) 100 KJ mol-1 3) 300 KJ mol-1 4) 400 KJ
-1
mol
59. At 00C ice and water are in equilibrium and H = 6.0 kJ then S will be
1) 22 JK-1 mol-1 2) 35 JK-1mol-1 3) 48 JK-1 mol-1 4) 100 JK-1
mol-1
60. For an endothermic reaction, S is positive. The reaction is
1) Feasible when TS > H2) feasible when H>TS
3) Feasible at all temperatures 4) not feasible at all
61. One mole of ice is converted into water at 273K. The entropies of H 2O(s) and H2O(l) are
38.20 and 60.01 J mol-1 K-1 respectively. The enthalpy change for the conversion is
1) 59.54J mol-1 2) 5954J mol-1 3) 595.4J mol-1 4) 320.6J mol-1
62. Sign of G is positive at low temperature when
1) H is positive and S is positive 2) H is negative and S is negative
3) H is negative and S is positive 4) H is negative and S is zero
63. Heat content and temperature are
1) Intensive properties 2) Extensive properties
3) Extensive and intensive properties respectively 4) Intensive and Extensive properties
respectively
64. 1gram graphite on combustion in oxygen liberates 7.82K.cals of heat. The amount of hest
evolved when one mole of oxygen is used in this oxidation process is
1) 7.82 k.cal 2) 78.2 k.cal 3) 9.384 k.cal 4) 93.84 k.cal
65. If an endothermic reaction is non-spontaneous at the freezing point of water and becomes
feasible at its boiling point, then
1) H=+ve & S = -ve 2) H = +ve & S = +ve 3) H =-ve & S = -ve 4) H ve & S
= +ve
66. The hats of combustion for C,H2 and CH4 are -349, -241.8 and -906.7KJ respectively. The
heat of formation of CH4 is
1) 174.1 KJ 2) 274.1 KJ 3) 374.1 KJ 4) 74.1 KJ
67. The sequence in which metals of groups 8, 9, 10 form the first triad is
1) Iron, nickel, cobalt 2) Nickel, cobalt, iron
3) Iron, cobalt, nickel 4) Cobalt, nickel, iron
3+
68. The colour of Ti (H2O)6 ion is due to
1) Excitation of electron from t2g to eg orbital 2) Presence of water molecules
3) Intratomic transfer of electrons 4) None of the above
69. The maximum oxidation state of osmium is

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 1) + 6 2) + 7 3) + 8 4) + 5
70. Which of the following has the maximum number of unpaired electrons ?
1) Mg2+ 2) Ti3+ 3) V3+ 4) Fe2+
71. The lanthanide contraction is responsible for the fact that
1) Zr and Y have about the same radius 2) Zr and Nb have similar oxidation state
3) Zr and Hf have about the same radius 4) Zr and Zn have the same oxidation state
72. Which of the following statement is not correct
1) La(OH)3 is less basic than Lu(OH)3
2) In lanthanide series, ionic radius of decreases from La3+ to Lu3+ ion
3) La is actually an element of transition series rather than lanthanides
4) Atomic radius of Zr and Hf are same because of lanthanide contraction
73. Arrange Ce3+, La3+, Pm3+ and Yb3+ in increasing order of their ionic radii
1) Yb3+ < Pm3+ < Ce3+ < La3+ 2) Ce3+ < Yb3+ < Pm3+ < La3+
3) Yb3+ < Pm3+ < La3+ < Ce3+ 4) Pm3+ < La3+ < Ce3+ < Yb3+
74. The radius of La3+ (At.No.of La = 57) is 1.06A0, Which one of the following given values will
be closest to the radius of Lu3+ (At.No.of Lu = 7a)
1) 1.40A0 2) 1.06 A0 3) 0.85 A0 4) 1.60 A0
CoCl3 5 NH 3
75. The primary and secondary valency of Co in the complex respectively are
1) 6 and 3 2) 3 and 6 3) 4 and 3 4) 3 and 5
76. Which of the following statement regarding transition elements is false
1) They form complexes readily 2) All of their ions are colourless
3) They are capable of showing variable valencies
4) Their atoms contain partially filled d orbitals
77. Ozone is an
1) Isotope O2 2) Isomer of O2
3) Allotropic form of oxygen 4) Isomorphic form of oxygen
78. As a fixing reagent in photography, Na2S2O3 is used for
1) Preventing over developing and fogging 2) Reducing the solubility of AgBr
3) converting silver bromide into metallic silver 4) Dissolving out un reacted silver halide
79. During bleaching action SO2 converts into
1) H2S2O7 2) H2SO4 3) H2SO3 4) SO3
80. The hybridization of sulphur in S2Cl2 molecule is
1) sp2 2) sp3 3) sp 4) sp3d
81. The ion with pyramidal shape is
S 2O82 SO42 SO32 S 2O32
1) 2) 3) 4)

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82. Fluorine reacts with cold and dil. NaOH and the products are
HF NaF O2 NaF H 2O O2 NaF H 2O OF2
1) 2) 3) 4)
HF H 2O NaF

83. Oxidation states of chlorine in the products when chlorine reacts with cold and dil. NaOH
are
1) -1, +5 2) -1,+3 3) -1,+1 4) 0,-1
84. Mustard gas formula is

C2 H 5 3 CCH 2Cl CH 3Cl C2 H 4Cl 2 S C2 H 4Cl2

1) 2) 3) 4)
85. The correct order of reactivity of hydrogen halides with ethyl alcohol is
HI HBr HCl HF HBr HCl HI HF
1) 2)
HCl HBr HF HI HF HCl BHr HI
3) 4)
86. Iodine dissolves in aqueous KI due to the formation of
I 4 I 3 I 2 I
1) 2) 3) 4)
87. In the known interhalogen compounds the maximum oxidation state of halogen atom is
1) 8 2) 7 3) 5 4) 1
88. Which of the following set of elements are transition elements?
1) Ac,Rf,Hs 2) Cs,Ba,La 3) Ga,In,Ti 4) Po,At,Rn
89. Calamine is the mineral of
1) Ti 2) Co 3) Zn 4) Fe
90. Number of ionizable and non ionizable Cl- ions in CoCl35NH3 respectively are
1) 0,3 2) 1,2 3) 2,1 4) 3,0

1) 3 2) 1 3) 1 4) 1 5) 2 6) 2 7) 1 8) 3 9) 2 10) 1
11) 3 12) 2 13) 4 14) 1 15) 1 16) 2 17) 1 18) 3 19) 4 20) 2
21) 4 22) 3 23) 1 24) 3 25) 4 26) 3 27) 1 28) 1 29) 3 30) 2
31) 2 32) 3 33) 3 34) 2 35) 2 36) 3 37) 3 38) 3 39) 3 40) 1
41) 2 42) 2 43) 1 44) 3 45) 3

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 136. Xenon cannot react with
Cl2 OSeF5 OTeF5 F2
a) b) c) d)
137. Which of the following is a super fluid
a) He at 4.2K b) He at 2.2K c) He at 25K d) He at 273K
138. In Fischer Ringes process 10% of X and 90% of Y is used. X is
CaF2 CaC2 CaCl2 CaCN 2
a) b) c) d)
139. During fractional distillation of liquid air helium and neon are separated using
O2 N2 CO2 H2
a) Liquid b) Liquid c) Liquid d) Liquid
140. Assertion (A) : At high temperature inert gas adsorbed on coconut charcoal get desorbed
Reason (R) : Inert gases on coconut charcoal are physically adsorbed
a) Both (A) and (R) are true and (R) is the correct explanation of (A)
b) Both (A) and (R) are true and (R) is not the correct explanation of (A)
c) (A) is true but (R) is false d) (A) is false but (R) is true
141. In Ramsey-Rayleigh I method X is useful in removing oxygen as Y. In Fischer-Ringes
process Y oxidizes Z to A. Z is
N2 CO2
a) b) CO c) d) NO
d p XeO3
142. Number of bonds in are same as present in
ClO3 ClO4 SO3 CO32
a) b) c) d)
143. is used to detect thickness of metal sheets
a) Rn b) Xe c) Kr d) Ar
144. First noble gas compound prepared was
XeF6 Xe Pt F4 Xe Pt F6 XeO F4
a) b) c) d)
145. The inert gas whose boiling point is closest to oxygen is
a) Ar b) Kr c) Xe d) Ne
146. Which of the following is hygroscopic and explosive

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 XeO4 XeF4 XeF6 XeO3
a) b) c) d)
CH 3CH 2COOCH CH 2
147. IUPAC name of is
a) Vinyl propanoate b) Ethenyl propanoate c) Vinyl propionate d) Ethyl propenoate
CH 3OH
148. is called as
a) Carbinol b) Wood spirit c) Methanol d) All
149. IUPAC name of benzyl alcohol is
a) Phenol b) Hydroxy methyl benzene
c) Phenyl methanol d) 1-hydroxy-1-phenyl methane
150. Common name of 1, 2-dichloro ethane is
a) Ethylidene chloride b) Ethylene dichloride
c) Acetylene dichloride d) Ethane dichloride
CH (COOH )3
151. IUPAC name of is
a) Methane 1, 1, 1-tricraboxylic acid b) 2-carboxy propane dioicacid
c) Tricarboxy methane d) Dicarboxy ethanoic acid
C4 H 8
152. Number of isomeric alkenes (structural and stereo) with the formula
a) 2 b) 3 c) 5 d) 4
153. Number of optically active isomers for 2, 3-butane diol are
a) 2 b) 3 c) 4 d) 6
154. The molecule which cannot show geometrical isomerism is
CH 3 CH CHCl CH 3CH NOH
a) b)
CH 3CH C (CH 3 ) 2
c) 1, 2-dichloro cyclopropane d)
155. Number of conformational isomers possible for ethane are
a) 1 b) 3 c) 2 d) Infinite
156. Acetaldehyde is isomeric with
a) Acetone b) Vinyl alcohol c) Epoxide d) Both b and c
157. Minimum number of carbon atoms required for an unsubstituted alkane to exhibit optical
isomerism
a) 1 b) 4 c) 6 d) 7

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 158. Formula of canary yellow solution formed to identify phosphorous in organic compound is
( NH 4 )3 PO4 MoO4 ( NH 4 )3 PO4 MoO3 ( NH 4 )3 PO412 MoO3 ( NH 4 ) 2 MoO4
a) b) c) d)
159. Organic compound (containing S, N) is heated with excess sodium to prepare sodium
fusion extract. This extract cannot give
FeSO4 FeCl3
a) Prussian blue colour with & b) Black precipitate with lead acetate
FeCl3
c) Voilet colour with sodium nitroprusside d) Red colour with
160. 0.35 grams of an organic compound produced 0.17 grams of ammonia in kjeldahl method.
Percentage of nitrogen in the compound is
a) 28 b) 50 c) 40 d) 60
BaSO4
161. 0.32grams of an organic compound in carius method precipitated 0.466grams of .
Percentage of sulphur in the organic compound is
a) 20 b) 40 c) 60 d) 10
162. Which of the following is not an electrophile
SO2 : CH 2 BF3
a) b) c) CO d)
163. Most reactive of the following is

C H3 C H3 C H3
a) b) c) d) All are equally reactive
164. Which of the following can act both as electrophile and nucleophile
SO2 SCl4 CH 3CN
a) b) c) d) All of these
165. Regarding methyl carbanion the incorrect statement is
sp3
a) Central atom is hybridized b) It has pyramidal shape
c) Central atom is surrounded by eight valence electron
d) It is paramagnetic
166. Most stable carbocation is

C H3 CH 3 C H 2 (CH 3 )2 C H (CH 3 )3 C
a) b) c) d)
CH 3 CH CH 2 HBr
R2O2
CH 3CH 2CH 2 Br
167. . This reaction is an example is

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 a) Electrophilic addition b) Free radical addition
c) Nucleophilic addition d) Free radical substitution
168. Electrophilic substitution reactions are the characteristic reactions of
a) Aromatic compounds b) Alkanes
c) Alkenes d) Carbonyl compounds
169. Which of the following cannot be used for dehydrohalogenation
CH 3ONa NaNH 2 Cu / 3000 C
a) b) c) alc. KOH d)
170. In Dumas method nitrogen is estimated as
NH 3 N2 ( NH 4 ) 2 SO4 ( NH 4 )3 PO4
a) b) c) d)
NH 4OH
171. Which of the following is insoluble in
a) AgI b) AgBr c) AgCl d) All of these
172. Metamerism is not exhibited by
a) Aldehydes b) Ketones c) Ethers d) Esters

173. Which of the following is not a chloro compound
CH 2Cl COOH CH 2Cl CH 2OH CH 3 CO CH 2Cl
a) b) c) d)

CH 3CHCl O CH 2 CH 3

CH 3 CH (CH 3 ) CH (C2 H 5 ) CH 3
174. IUPAC name of is
a) 2-ethyl-3-methyl butane b) 3-ethyl-2-methyl butane
c) 2, 3-dimethyl pentane d) 1-isopropyl butane
175. Number of structural isomers possible by the monochlorination of isopentane are
a) 3 b) 4 c) 5 d) 6
176. Which of the following cannot show configurational isomerism
a) 2-butene b) Lactic acid c) Oleic acid d) n-butane
C10 H 22
177. Number of isomers possible with the formula are
a) 35 b) 18 c) 9 d) 75
30
178. butyl alcohol and isobutyl alcohol are. Isomers

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 a) Chain b) Positional c) Functional d) Metamers
179. Which of the following is not an IUPAC name
a) Benzene amine b) Cyclohexanol
c) Cyclobutane carboxylic acid d) Benzene hexachloride
180. Which of the following is not denoted by secondary suffix
CONH 2 NO2
a) CHO b) c) d) OH
***

Key : CHEMISTRY
136) a 137) b 138) c 139) d 140) a 141) b 142) b 143) c 144) c 145) a
146) d 147) b 148) d 149) c 150) b 151) a 152) d 153) a 154) d 155) d
156) d 157) d 158) c 159) d 160) c 161) a 162) c 163) a 164) d 165) d
166) d 167) b 168) a 169) d 170) b 171) a 172) a 173) b 174) c 175) b
176) d 177) d 178) b 179) d 180) c

PAPER-10

46. (A):CH3COOH; (B) C2H5COOH; (C)C6H5COOH and (D) HCOOH. The decreasing order
of the pKa values of these carboxylic acids is
1)D>C>A>B 2)C>B>A>D 3)B>A>C>D 4)D>A>B>C

47. IntheFischersesterficationfromethanolandethanoicacid,thecorrectbondcleavagesare

1)OHofC2H5OHandCOofCH3COOH

2)OHofC2H5OHandOHofCH3COOH

3)COofC2H5OHandOHofCH3COOH

4)COofC2H5OHandCOofCH3COOH

48. KolbeselectrolysisofconcentratedaqueouspotassiumsaltofXofgivesethaneatanode.

P2 O5 PCl3
X Y X Z
; . The organic compounds Y and Z are respectively
1)CH3COOCH3 and CH3COCl 2) CH3COOCOCH3 and CH3COCl

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 3) CH3COOCOCH3 and CH2ClCHO 4)CH3COOCH3 and CH2ClCHO

H ,Cr2 O27 NH 3
HC CH A B.
49. Compound B on heating at 400 K gives

1)C2H5NHCH3 2)CH3NH2 3)CH3CONH2 4)C2H5NH2

50. A)Sandmeyerreaction i)C6H5NH2 C6H5NC

B) Hofmanns mustard oil reaction ii) C6H5CONH2 C6H5NH2

C) Carbylamine reaction iii) C6H5N2Cl C6H5Cl

D) Hofmanns hypobromite reaction iv) C6H5NH2 C6H5NCS

The correct match is

1)Aiii,Bii;Ci;Div 2)Aiv,Biii;Ci;Dii
3)Aiii,Biv;Ci;Dii 4)Aiii,Biv;Cii;Di

51. ThemediuminwhichethanolisconvertedtoethanalusingPDCasoxidant
1)methylenedichloride 2)carbondisulphide
3)nitrobenzene 4)diethylether

52. Compoundxreactswithcompoundyinthepresenceofzgiving3hydroxybutanal.Then
xyandzarerespectively
1) CH3CHO, CH3CHO and NaCl 2) CH3CHO,CH3COCH3 and HCl
3) CH3CHO, CH3CHO and NaOH 4) C2H5COCH3, CH3CHO and NaOH

53. (A)CH3COOH;(B)CH3COOC2H5;(C)C6H5CHO;(D)CH3COCl; (E)C6H5COCH3

and

(F)CH3CHOHCH3.Iodoformreactionisgivenby
1)only E and F 2) only A, B, D and E
3) only C and D 4) only C, D and F

54. 2Methyl2propanolcanbeobtainedbywhichofthefollowingreactions

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 (i)CH3MgBr,ether (i)C2H5MgBr,ether


(ii)H3O (ii)H3O
1)CH3CHO 2) CH3CHO
(i)CH3MgBr,ether (i)C2H5MgBr,ether


(ii)H3O (ii)H3O
3) CH3COCH3 4) CH3COCH3

55. Acetonecannotbeidentifiedfromacetaldehydebyusing
1)2,4DNP 2)Schiffsreagent 3)Ammonicalsilvercation 4)Fehlingssolution

dil.NaOH heat

A H2O B
56. C6H5CHO+CH3CHO . Number of sp2 hybridised carbon atoms
in the final product B
1) 2 2) 4 3) 9 4) 5

NaNO2 ,HCl,00 C
H
2 SO 4 Sn,HCl

X Y Z
57. C6H6+HNO3 . The end organic product Z in the
above sequence of reaction is
1)C6H5NH2 2)C6H5N2Cl 3)C6H5NHOH 4)C6H5NCl2

58. AnalloyoftwometalsMandNcrystallisesincubicclosepackedlatticeinwhichall
latticepointsareoccupiedbyatomsofM.If25%oftetrahedralvoidsand100%of
octahedralvoidsareoccupiedbyatomsofN,thecompositionofalloyis
1)M2N3 2) MN 3) M3N2 4) M2N

59. Assertion(A):Dioxygenmoleculehasamagneticmomentof2.83BM

Reason(R):Twounpairedelectronsarepresentinamoleculeofdioxygen
1)bothAandRaretrue,RproperlyexplainsA
2)bothAandRaretrueRdoesnotexplainA
3)AistrueandRisfalse 4)AisfalseandRistrue

60. IfaistheedgelengthofalkalimetalB.C.C.structure,theradiusofoneatomofthemetalis

a a 3a 3a
2 2 2 4 2 2
1) 2) 3) 4)
61. xisametalandyisasemiconductor.Uponheating,conductivity
1)ofxincreasesandofyincreases 2)ofxdecreasesandofyincreases
3)ofxdecreasesandofydecreases 4)ofxincreasesandofydecreases

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62. ZnShasstructuresimilartothatofdiamond.TheratioofradiiofcationandanioninZnS
maybe
1)0.93 2)0.72 3)0.52 4)0.36

63. A)Crystalactsasadifractiongratingtoxrays

B)Metallicbondinironisweakerthanthatinpotassium

C)DensityofsubstancedecreasesuponFrenkeldefect

D)Colourlesszincoxidebecomesyellowuponheating
1)A,BandCaretrue 2)B,CandDaretrue
3)AandDaretrue 4)CandDaretrue

64. Forwardreactionoftheequilibrium,CaCO3(s) CaO(s) + CO2(g) is favoured by
1)addingmorelimestoneatequilibrium
2)removingsomelimeatequilibrium
3)byincreasingpressure
4)byincreasingtemperature
65. Certainamountofdinitrogentetraoxidepresentinaclosedvesselexerts1atmpressureat
270C.Ifthetemperatureisraisedto3270C,40%ofthesubstancedecomposestonitrogen
dioxide.Thenthepressureoftheequilibriummixtureis
1)1.2atm 2)1.6atm 3)2.4atm 4)2.8atm

66. Whichofthefollowingchemicalequilibriumisnotinfluencedwithachangeinpressure

1)2SO3(g) 2SO2(g)+O2(g) 2)2HI(g) H2(g) +I2(g)

3)PCl5(g) PCl3(g) + Cl2(g) 4)N2(g)+3H2(g) 2NH3(g)

67. Equilibrium Equilibriumconstant

H2CO3(aq) H+(aq) +HCO3-(aq) xmolL1

HCO3 (aq)
H+(aq)+CO32-(aq) y mol L-1

H2CO3(aq) 2H+(aq) + CO32-(aq) z mol2L-2
Numerical values of x, y and z are related as

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 xyz
1) x + y = z 2) 3) x > y > z 4)z>x>y

68. Whichofthefollowingisnotacharacteristicpropertyofchemicalequilibrium
1)changeinconcentrationdoesnoteffectequilibriumatconstanttemperature
2)allthereactantsandalltheproductsarepresentatequilibrium
3)equilibriumisalwaysdynamic,butnotstatic
4)catalystincreasestherateofforwardandbackwardreactionstothesameextent

69. The vapour pressures of (i) acetic acid, (ii) mercury, (iii) ethanol and (iv) sodium chloride are
in the order
1)ii>i>iii>iv 2)iii>i>ii>iv
3)i>iii>ii>iv 4)ii>iii>i>iv

PV
T

T
70. Correct graph for a fixed mass of ideal gas

PV
T

1) 2)

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 PV PV
T T

T T

3) 4)
4)

71. Temperatureatwhicharealgasobeysidealgaslawoveranappreciablerangeofpressureis
called
1)inversiontemperature 2)criticaltemperature
3)idealtemperature 4)Boyletemperature

72. Theaveragekineticenergiesofhelium(mol.wt.4),methane(mol.wt.16)andsulphurdioxide
(mol.wt.64),atcertaintemperaturearerespectivelyx,yandzkJmol1.Theratioofx,yand
zis
1)1:4:16 2)1:2:4 3)1:1:1 4)4:2:1

73. The volume of an ideal gas at a pressure of 105Pa and 273.15K is

1)23.40dm3mol1 2)22.71dm3mol1 3)24.38dm3mol1 4)24.79dm3mol1

74. 2gramsofhydrogenundergoeseffusionthroughasmallholeofavesselin23min.Under
similarconditionsthemassofoxygenthatundergoeseffusionthroughthesmallholefrom
samesizeofanothervessel.
1)4g 2)8g 3)16g 4)32g

75. Pressureexertedby2gramsofheliumpresentinavesselis1.5atm.If4gramsofgasxis
introducedintothesamevesselkeepingtheconditionconstant,thepressureis2.25atm.Gas
xis
1)hydrogen 2)methane 3)oxygen 4)sulphurdioxide

76. Criticaltemperaturesofcarbondioxide,ammoniaandoxygenarerespectively304,405and

154K.Thegasthatcanbeliquifiedfirst,whencoolingisstartedfrom500K

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 1)carbondioxide 2)ammonia
3)oxygen 4)allatonce

77. Postulateofkineticgastheorythatexplainsthepressureexertedbyagasisdueto
1)volumeofgasmoleculesisalmostzerocomparedtovolumeofgas
2)molecules of gas colloides with the inner walls of container
3)averagekineticenergyofgasmoleculesisconstantatagiventemperature
4)there exists no atrraction and no repulsion between gas molecules

78. At00C,certainmassofargonpresentina10Lsteelvesselexertsapressureof2atm.The
temperatureatwhichthepressureis1atmis
1)00C 2) 0K 3) -136.50C 4)136.5K

79. Velocityofagasmoleculedecreaseswithanincreasesin
1)temperature 2)density
3) pressure at constant volume 4)volumeatconstantpressure

80. Moleculesofliquidhydrogenchlorideareheldwith

1)London, dispersion forces 2)Dipole-induced dipole forces

3)Dipole-dipole forces 4)Induced dipoleinduced dipole forces

81. FormalchargeonthemiddleoxygenatominLewisstructureofozonemoleculeis
1)+1 2)0 3)1 4)2
82. Theshapeofsulphiteandsulphateanionsarerespectively
1)pyramidalandtetrahedral 2)pyramidalandsquarepolar_
3)squarepolarandtetrahedral 4)squarepolarandpyramidal

83. Correctincreasingorderofoxygenoxygenbondenergies
1)H2O2<O2<O3 2)H2O2<O3<O2 3)O3<H2O2<O2 4)O2<H2O2<O3

84. Whichofthefollowingconversionleadstoanincreaseinstabilitybasedonmolecularorbital
model

N 2 N2 O2 O2
1)N2 N2+ 2) 3)O2 O2+ 4)

85. Maximumnumberofhydrogenbondsformedbyamoleculeofwater
1)1 2)2 3)3 4)4

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86. Leaststableamongthefollowingbasedonconceptofresonance
1)OCl 2)ClO2 3)ClO3 4)ClO4
87. Ratioofnumberofhybridorbitalsandpureatomicorbitalsusedintheformationof
acetylenemolecule
1)4:3 2)1:1 3)3:4 4)2:3

88. Which among the following contains polar bonds but the molecule is nonpolar?

1)NCl3 2)BF3 3)CHCl3 4)H2O

89. Volatilityofwhichofthefollowingisleast?
1)nbutane 2)Neopentane 3)Isopentane 4)npentane
90. Bondspresentinpotassiumferricyanideare
1)ionicandcovalentonly 2)ionicanddativeonly
3)covalentanddativeonly 4)ionic,covalentanddative

Answers
46) 3 47) 1 48) 2 49) 3 50) 3 51) 1 52) 3 53) 1 54) 3 55) 1
56) 3 57) 2 58) 1 59) 1 60) 3 61) 2 62) 4 63) 3 64) 4 65) 4
66) 2 67) 3 68) 1 69) 2 70) 2 71) 4 72) 3 73) 2 74) 2 75) 2
76) 2 77) 2 78) 3 79) 2 80) 3 81) 1 82) 1 83) 2 84) 3 85) 4
86) 1 87) 4 88) 2 89) 4 90) 4

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