Cycloalkanes 3

1
Atoms, Molecules
and Ions
8 Type I. MCQ with only ONE Correct Alternate
1. A sample of CaCO 3 is 50% pure. On heating 1.12 L of CO 2 6. Consider following laws of chemical combination with
(at STP) is obtained. Residue left (assuming non-volatile examples:
impurity) is: I. Law of multiple proportion : N 2O, NO, NO 2
(a) 7.8 g (b) 3.8 g II. Law of reciprocal proportion : H 2O, SO 2, H 2S
(c) 2.8 g (d) 8.9 g Which is correct with examples?
2. In the decomposition of 10 g of MgCO 3, 0.1 mole CO 2 and (a) I and II (b) I only
4.0 g MgO are obtained. Hence, percentage purity of (c) II only (d) None of these
MgCO 3 is: 7. H 2S contains 94.11% sulphur; SO 2 contains 50% oxygen
(a) 50% (b) 60% and H 2O contains 11.11% hydrogen. Thus:
(c) 40% (d) 84% (a) law of multiple proportion is followed
3. Consider the following pairs: (b) law of reciprocal proportion is followed
I. CH 4 , C 2H 6 II. CO, CO 2 (c) law of conservation of mass is followed
III. NO, NO 2 IV. H 2O, H 2O 2 (d) all of the above
35 37
In which cases, law of multiple proportion is followed? 8. Sodium combines with 17 Cl and 17 Cl to give two samples of
(a) I, II (b) I, II, III sodium chloride. Their formation follows the law of:
(c) I, III, IV (d) I, II, III, IV (a) gaseous diffusion (b) conservation of mass
4. Two substances of carbon and oxygen have respectively (c) reciprocal proportion (d) none of these
72.73% and 47.06% oxygen. Hence, they follow: 9. According to Daltons atomic theory, the smallest particle
(a) law of multiple proportion in which matter can exist, is called:
(b) law of reciprocal proportion (a) an atom (b) an ion
(c) law of definite proportion (c) an electron (d) a molecule
(d) law of conservation of mass 10. The nucleus of an atom consists of:
5. In which case purity of the substance is 100%? (a) neutron (b) proton
(a) 1 mol of CaCO 3 gave 11.2 L CO 2 (at STP) (c) electron (d) both (a) and (b)
35 37
(b) 1 mol of MgCO 3 gave 40.0 g MgO 11. 17 Cl and 17 Cl are two isotopes of chlorine. If average
(c) 1 mol of NaHCO 3 gave 4 g H 2O atomic mass is 35.5 then ratio of these two isotopes is:
(d) 1 mol of Ca(HCO 3 )2 gave 1 mol CO 2 (a) 35 : 37 (b) 1 : 3
(c) 3 : 1 (d) 2 : 1
4 Objective Chemistry

12. Ionic mass of X 3 is 17. If it has 10 electrons, then number 32 2.66 1023
(c) mol
of neutrons are: 6.02 1023
(a) 10 (b) 13
(d) none of the above
(c) 7 (d) 17
24. Number of mol of 126C in 1 amu is:
13. M 2+ ion is isoelectronic of SO 2 and has ( Z + 2) neutrons (Z
1
is atomic number of M ). Thus, ionic mass of M 2+ is: (a) (b) N 0
N0
(a) 70 (b) 66
1
(c) 68 (d) 64 (c) N 02 (d)
+ 2+ N 0 12
14. X , Y and Z are isoelectronic of CO 2. Increasing order
of protons in X + , Y 2+ and Z is: 25. Mass of one 147 N-atom is:
(a) X + = Y 2+ = Z (b) X + < Y 2+ < Z (a) 14 amu (b) 7 amu
(c) Z < X + < Y 2+ (d) Y 2+ < X + < Z (c) 14 g (d) 7 g
26. If two compounds have same empirical formula but
15. X , Y 2 and Z 3 are isotonic and isoelectronic. Thus,
different molecular formula, they must have:
increasing order of atomic number of X, Y and Z is: (a) same viscosity
(a) X < Y < Z (b) Z < Y < X (b) same vapour density (VD)
(c) X = Y = Z (d) Z < X < Y (c) different molecular weight
16. Number of atoms in increasing order in 1.6 gram CH 4 , 1.7 (d) different percentage composition
g NH 3 and 1.8 g H 2O is: 27. If the equivalent weight of an element is 32, then the
(a) H 2O = NH 3 = CH 4 (b) H 2O < NH 3 < CH 4 percentage of oxygen in its oxide is:
(c) CH 4 < NH 3 < H 2O (d) CH 4 = NH 3 < H 2O (a) 16 (b) 40
17. Which has maximum number of H-atoms per gram of the (c) 32 (d) 20
substance? 28. A hydrocarbon has 3 g carbon per gram of hydrogen,
(a) CH 4 (b) CuSO 4 5H 2O hence, simplest formula is:
(c) H 2O 2 (d) H 2O
(a) CH 4 (b) C 6H 6
18. If each O-atom has two equivalents, volume of one
(c) C 3H 8 (d) CH 2
equivalent of O 2 gas at STP is:
(a) 22.4 L (b) 11.2 L 29. Molar ratio of Na 2SO 3 and H 2O is 1 : 7 in Na 2SO 3 xH 2O.
(c) 5.6 L (d) 44.8 L Hence, their mass percentage is:
(a) 12.5 : 87.5 (b) 87.5 : 12.5
19. Each drop of H 2O has 0.018 mL at room temperature.
(c) 50 : 50 (d) 75 : 25
Number of H 2O molecules in one drop is:
30. Which has maximum percentage of chlorine?
(a) 1 103 (b) 6.02 1020
(a) C 6H 6Cl 6 (b) C 6H 5Cl
(c) 22.4 103 (d) 6.02 3 102
(c) CH 3Cl (d) CCl 4
20. 1 g CH 4 and 4 g of compound X have equal number of 31. In which of the following pairs do the two species resemble
moles. Thus, molar mass of X is: each other most closely in chemical properties?
(a) 16 g mol 1 (b) 32 g mol 1 (a) 11 H and 12 H (b) 168O and 168O 2
(c) 4 g mol 1 (d) 64 g mol 1 (c) 24
12 Mg
24
and 12 Mg 2+ (d) 14
7N and 147 N 3
23
21. Mass of one atom of an element is 6.64 10 g. This is 32. One isotope of a non-metallic element has mass number
equal to: 127 and 74 neutrons in the nucleus. The anion derived
(a) 6.64 1023 amu (b) 40.0 amu from the isotope has 54 electrons. Hence, symbol for the
1 anion is:
(c) amu (d) 6.64 amu (a) 127
(b) 127
40 54 X 53 X
74 74
22. If Avogadros number would have been 1 1010, instead (c) 53 X (d) 54 X
of 6.02 1023 then mass of one atom of H would be: 33. Which of the following is the richest source of ammonia on
(a) 1 amu (b) 1 1010 amu a mass percentage basis?
(c) 6 amu (d) 6 1013 amu (a) NH 4 NO 3 (b) NH 2CONH 2
23. Mass of one atom of X is 2.66 1023 g, then its 32 g is (c) NH 3 (d) HNC(NH 2 )2
equal to: 34. Which of the following substances contains greatest mass
(a) 32 2.66 1023 mol of chlorine?
32 (a) 5.0 g Cl 2 (b) 0.5 mol Cl 2
(b) mol
2.66 10 6.02 1023
23 (c) 0.10 mol KCl (d) 30.0 g MgCl 2
Atoms Molecules and Ions 5

35. When 0.273 g of Mg is heated strongly in a nitrogen (N 2 ) 46. A sample of ammonium phosphate (NH 4 )3 PO 4 contains
atmosphere, 0.378 g of the compound is formed. Hence, 3.18 mol of H-atoms. The number of moles of oxygen
compound formed is: atoms in the sample is:
(a) Mg 3N 2 (b) Mg 3N (a) 0.265 (b) 0.795
(c) Mg 2N 3 (d) MgN (c) 1.06 (d) 3.18
36. A certain metal sulphide, MS 2, is used extensively as a high 47. A sample of CuSO 4 5H 2O contains 3.782 g of Cu. How
temperature lubricant. If MS 2 is 40.06% by mass sulphur, many grams of oxygen are in this sample? (Cu = 63.5)
metal M has atomic mass: (a) 0.952 g (b) 3.80 g
(a) 160 amu (b) 64 amu (c) 4.761 g (d) 8.576 g
(c) 40 amu (d) 96 amu 48. Cortisone is a molecular substance containing 21 atoms of
37. The molar mass of a compound if 0.372 mol of it has a carbon per molecule. The mass percentage of carbon in
mass of 186 g, is: cortisone is 69.98%. Its molar mass is:
(a) 200 g (b) 372 g (a) 176.5 (b) 252.2
(c) 500 g (d) 186 g (c) 287.6 (d) 360.1
38. Which of the following has maximum number of C-atoms? 49. In a hydrocarbon C is 3 g per gram of hydrogen. Hence,
(a) 4.4 g CO 2 (b) 3.0 g C 2H 6 hydrocarbon is:
(c) 4.4 g C 3H 8 (d) 1.3 g C 6H 6 (a) CH 4 (b) C 2H 6
39. Mg 2C 3( X ) is decomposed by H 2O forming a gaseous (c) C 3H 8 (d) C 4 H10
hydrocarbon ( Y ). 8.4 g of X gives mol of Y. 50. One equivalent of magnesium oxide weighs 20 g then one
(a) 0.1 (b) 0.2 equivalent of magnesium chloride weighs:
(c) 0.3 (d) 0.4 (a) 29.75 g (b) 47.5 g
40. Number of atoms in 20 g Ca is equal to number of atoms in: (c) 95.0 g (d) 20.0 g
(a) 20 g Mg (b) 1.6 g CH 4 51. A spherical ball of radius 7 cm contains 56% iron. If density
(c) 1.8 g H 2O (b) 1.7 g NH 3 is 1.4 g /cm 3, number of mol of Fe present approximately is:
41. Na 2SO 3 xH 2O has 50% H 2O by mass. Hence, x is: (a) 10 (b) 15
(a) 4 (b) 5 (c) 20 (d) 25
(c) 6 (d) 7 52. In the following final result is 0.1 mol CH 4 + 3.01 1023
42. Mass of one atom of X is 6.66 1023 g. Hence, number of
molecules CH 4 9.6 g CH 4 = x mol H atoms:
moles of atom X in 40 kg is: (a) 0 mol H atom (b) 0.2 mol H atom
(a) 103 mol (b) 103 mol (c) 0.3 mol H atom (d) 0.4 mol H atom
40 103 40 103 53. If we assume that N 0 = 1.2 1023 mol 1, then molar mass
(c) 23
mol (d) mol
6.66 10 6.022 1023 of O 2 will be taken as:
43. To make 0.01 mol, which of the following has maximum 32
(a) 32 g mol 1 (b) g mol 1
mass? 6
(a) NaHCO 3 (b) Na 2CO 3 1 1023
(c) 32 1023 g mol 1 (d) g mol 1
(c) Na 2SO 4 (d) Na 2C 2O 4 32
44. In a glass-tube, there is 18 g of glucose. 0.08 mol of glucose 54. CO, CO 2, C 2O 3 follow:
is taken. Glucose left in the glass-tube is: (a) law of definite proportion
(a) 0.10 g (b) 17.92 g (b) law of multiple proportion
(c) 3.60 mol (d) 3.60 g (c) law of conservation of mass
45. Rest mass of an electron is 9.11 1031 kg. Molar mass of (d) all of the above
the electron is: 55. In a gas S and O are 50% by mass, hence, their mol ratio is:
(a) 1.50 1031 kg mol 1 (b) 9.11 1031 kg mol 1 (a) 1 : 1 (b) 1 : 2
(c) 5.5 107 kg mol 1 (d) 6.02 1023 kg mol 1 (c) 2 : 1 (d) 3 : 1

8 Type II. MCQ with ONE or more than ONE Correct Alternates
1. Which is/are correct about 4.25 g NH 3? 2. Which of the following are isoelectronic of O 2 ?
(a) It contains 0.25 mol of NH 3 (a) N 3 (b) F
(b) It contains 0.75 mol of H-atoms (c) Ti + (d) Na +
(c) It contains total of 1.0 mol of N and H atoms 3. Among the following groupings which represents the
(d) It contains 1.5 1023 molecules of NH 3 collection of isoelectronic species?
(a) NO, CN , N 2, O 2 (b) NO + , C 2
2 , O 2 , CO
2
(c) N 2, C 2 , CO, NO (d) CO, NO , CN , C 2
+
2
6 Objective Chemistry

2 3
4. The atomic number of an element is always equal to: (c) 1D (d) 1T
(a) number of neutrons in the nucleus 8. 35 37
and 17 Cl differ in:
17 Cl
(b) half of the atomic weight
(c) electrical charge of the nucleus (a) atomic number (b) number of neutrons
(d) number of protons (c) number of electrons (d) atomic mass
5. A bivalent metal ion has equivalent mass of 12. Then: 9. Isoelectronic species are represented by pairs:
(a) equivalent mass of its oxide is 28 (a) N 3 , O 2 (b) CO, CN
(b) molar mass of its oxide is 40
(c) O 2
2 , F2 (d) O 2 , CN
(c) equivalent mass of its hydride is 13
(d) molar mass of its hydride is 14 10. X is isoelectronic of CO and has ( Z + 2) neutrons
6. Volume of a gas at NTP is 1.12 107 cc. The number of (Z = atomic number of X ). Thus,
molecules is thus equal to: (a) ionic mass of X is 28
(a) 3.01 1012 (b) 3.01 1018 (b) ionic mass of X is 30
(c) 3.01 1024 (d) 3.01 1030 (c) atomic number of X is 13
7. Which of the following may contain one proton and one (d) atomic number of X is 14
neutron?
(a) H +2 (b) 42 He

8 Type III. Testing of Numerical Skill

1. 1021 molecules are removed from 200 mg of CO 2. Thus,
2XHCO 3 H 2O + CO 2 + X 2CO 3
number of moles of CO 2 left is

2. Al 2(SO 4 )3 xH 2O has 8.20 per cent Al by mass. Calculate YCO 3 YO + CO 2
value of x.
16.8 g of XHCO 3 gave 6.2 g of mixture of H 2O and CO 2.
3. In addition to carbon monoxide (CO) and carbon dioxide Identify the substances.
(CO 2 ), there is a third compound of carbon called carbon 5. Cesium atoms are the largest naturally occurring atoms.
suboxide. If a 2.500 g sample of carbon suboxide contains The radius of cesium atom is 2.62 . How many cesium
1.32 g of C and 1.18 g of O, show that the law of multiple atoms would have to be laid side by side to give a row of
proportions is followed. What is possible formula of carbon cesium atoms 2.50 cm long? Assume that the atoms are
suboxide? spherical.
4. XHCO 3 and YCO 3 are two pure substances of equal molar
masses decomposing as shown

8 Type IV Comprehension Based MCQ

Example 1. Study following observations and answer the (a) 1.66 1024 g (b) 3.33 1024 g
questions at the end of it. (c) 2.5 1024 g (d) 1 1023 g
The following is a crude but effective method for estimating the
order of magnitude of Avogadros number using stearic acid Example 2. Read the following passage regarding fertiliser
(C18H 36O 2 ). When stearic acid is added to water, its molecules K 2 O and answer the questions at the end of it.
collect at the surface and form a monolayer; that is, the layer is Potash is any potassium mineral that is used for its potassium
only one molecule thick. The cross-sectional area of each stearic content. Most of the potash produced in the United States goes
acid molecule has been measured to be 0.21 nm 2. In one into fertilizer. The major sources of potash are potassium
experiment it is found that 1.4 104 g of stearic acid is needed chloride (KCl) and potassium sulphate (K 2SO 4 ). Potash
production is often reported as the potassium oxide (K 2O)
to form a monolayer over water in a dish of diameter 20 cm. (the equivalent or the amount of K 2O that could be made from a
area of a circle of radius r is r 2. ) given mineral. KCl costs Rs. 50 per kg.
Q. I. Based on these measurements value of Avogadros Q. I. What is the cost of K per mol of the KCl sample?
number is: (a) Rs. 13.42 mol 1 (b) Rs. 3.73 mol 1
(a) 3 1023 (b) 6 1023 (c) Re. 1.00 mol 1
(d) Rs. 2.00 mol 1
(c) 4 1023 (d) 1 1023 Q. II. For what price must K 2SO 4 be sold in order to supply the
Q. II. What is equivalent of 1g H in amu for this value of same amount of potassium as in KCl?
Avogadros number? (a) Rs. 58.40 kg 1 (b) Rs. 50.00 kg 1
(c) Rs. 42.82 kg 1 (d) Rs. 25.00 kg 1
Atoms Molecules and Ions 7

Q. III. What mass (in kg) of K 2O contains the same number of Q. I. Which isotope has maximum number of atoms per gram
moles of K atoms as 1.00 kg KCl? of each?
(a) 0.158 kg (b) 0.315 kg (a) Mg-24 (b) Mg-25
(c) 1.262 kg (d) 0.631 kg (c) Mg-26 (d) equal
100
Q. II. Number of atoms in one mole of each isotope is placed in
increasing order:
(a) 24 Mg < 25Mg < 26Mg
Relative abundance

80
26
(b) Mg < 25Mg < 24 Mg
60 26 25 24
(c) Mg = Mg = Mg
(d) given data is insufficient
40
Q. III. Average atomic mass of Mg is approximately:
20 (a) 25.0 (b) 24.3
(c) 25.2 (d) 25.8

24 25 26
Atomic mass (amu)

Example 3. The mass spectrum (given below) of magnesium

has three peaks, which indicates that magnesium has three
isotopes. Questions given below are based on this mass
spectrum.

8 Type V. Miscellaneous Exercise

A. Assertion/Reason Type Questions 3. 20 g CaCO 3 (50% pure) on strongly heating gives 15.6 g
Codes : residue.
(a) Both A and R are true and R is the correct explanation 4. Mass of 1 mol of electrons is 5.48 107 kg.
of A. 5. Number of atoms in 1.6 g CH 4 , 1.7 g NH 3 and 1.8 g H 2O are
(b) Both A and R are true but R is not the correct equal.
explanation of A. 6. If 1 mol of H 2 is taken out from 2 g H 2, 1 g H 2 is left.
(c) A is true but R is false. 7. 1 amu is equal to 1.66 1024 g.
(d) A is false but R is true. 8. Out of CH 3Cl, C 6H 6Cl 6, and CCl 3CHO, maximum
1. Assertion (A) : When 10 g of CaCO 3 is decomposed, percentage of chlorine is in C 6H 6Cl 6.
5.6 g of residue is left and 4.4 g of CO 2 escapes. 9. 1 ppm is equal to 1 mg per kg.
Reason (R) : Law of mass conservation is followed. 10. Equivalent mass of NH 3 is 17.
2. Assertion (A) : SO 2 and SO 3 obey law of multiple
proportion. C. Fill in the Blanks
Reason (R) : Every sample of SO 2 contains 1 part 1. NO and NO 2 follow the law of
sulphur and 1 part oxygen by mass. 2. SO 3 contains sulphur and oxygen in the mass ratio of
3. Assertion (A) : SO 2 from oxidation of sulphur or H 2S
contains sulphur and oxygen in the mass ratio of 1 : 2. 3. Hydrocarbon containing 3 g carbon per gram hydrogen is

Reason (R) : Different samples of a pure chemical
4. If X 2+ is isotonic (same number of neutrons) of H 2O and
substance always contain the same proportions of
elements by mass. contains 10 electrons then ionic mass of X 2+ is
4. Assertion (A) : In Fe2+ , there are 24 electrons and 30 5. 1 mol of barium nitrate and 1 mol of ammonium
neutrons and thus, ionic mass is 56. phosphate form mol of barium phosphate.
Reason (R) : Ionic mass = neutron + proton 6. Percentage of sodium sulphite (Na 2SO 3 ) in hydrated salt is
50. Hence, molecular formula of hydrated salt is
and proton = electrons in neutral species
7. Concentration 1 ppm = ppb.
B. True/False 8. Concentration 1 microgram per gram = ppm.
1. If there are 10 electrons and 8 neutrons in X 2 , then its 9. H 2O, H 2S and SO 2 follow law of
ionic mass is 18. 10. Atomic mass unit is also called
2. SO 2 contains sulphur and oxygen in 1 : 1 mass ratio.
8 Objective Chemistry

D. Matching B. Law of multiple 2. 10 mL N 2 combines

1. Match % of carbon (in List I) with the compound proportion with 30 mL of H 2 to
form 20 mL of NH 3.
(in List II).
C. Law of definite 3. S and O 2 combine to
List I List II proportion form SO 2 and SO 3.
A. 20% 1. CH 4 D. Law of reciprocal 4. In H 2S and SO 2 mass
B. 52.2% 2. CO 2 proportion ratio of H and O w.r.t.
sulphur is 1 : 16, hence
C. 75% 3. C 2H 6O in H 2O, mass ratio of H
D. 27.3% 4. CN 2OH 4 and O is 1 : 8.
E. 12% 5. CaCO 3 E. Gay Lussacs law 5. 4.2 g MgCO 3 gives 2.0 g
residue on heating.
2. Match Laws of chemical combinations (in List I) with the
examples followed (in List II).

List I List II
A. Law of conservation of 1. CH 4 has carbon and
mass hydrogen in 3 : 1 mass
ratio.

Type I. MCQ with only ONE Correct Alternate

1. (a) 2. (d) 3. (d) 4. (a) 5. (b) 6. (a) 7. (b) 8. (d) 9. (a) 10. (d)
11. (c) 12. (a) 13. (a) 14. (c) 15. (b) 16. (b) 17. (a) 18. (c) 19. (b) 20. (d)
21. (b) 22. (a) 23. (b) 24. (d) 25. (a) 26. (c) 27. (d) 28. (a) 29. (c) 30. (d)
Type II. MCQ with ONE or more than ONE Correct Alternates Type V. Miscellaneous Exercise
1. (a), (b), (c), (d) 2. (a), (b), (d) 3. (d) 4. (c), (d) A. Assertion/Reason Type Questions
5. (b), (c) 6. (a) 7. (c) 8. (b), (d) 9. (a), (b), (c) 1. (a) 2. (b) 3. (d) 4. (a)
10. (a), (c)
B. True/False
Type III. Testing of Numerical Skill 1. F 2. T 3. T 4. T 5. F 6. F 7. T
1. 2.88 103 2. x = 18 3. C 3O 2 8. T 9. T 10. F
4. XHCO 3 = NaHCO 3 , YCO 3 = MgCO 3
5. 4.77 107 atoms C. Fill in the Blanks
1. Multiple proportion 2. 2 : 3 3. CH4 4. 20
Type IV. Comprehension Based MCQ 5. 0.33 6. Na 2SO 3 7H2O 7. 103 8. 1
Example 1 Q. I. (a) Q. II. (b) 9. Reciprocal proportion 10. Dalton (Da)
Example 2 Q. I. (b) Q. II. (c) Q. III. (d)
Example 3 Q. I. (a) Q. II. (c) Q. III. (b) D. Matching
1. (A)(4); (B)(3); (C)(1); (D)(2); (E)(5)
2. (A)(5); (B)(3); (C)(1); (D)(4); (E)(2)

H ints and Solutions

8 Type I. MCQ with only ONE Correct Alternate
Thus, (a)
1. CaCO 3 (s ) CaO(s ) + CO 2 (g )

1 mol =100 g 1 mol = 56 g 22.4 L at STP 2. MgCO 3 (s ) MgO(s )+ CO 2 (g )
0.05 mol = 5 g pure 0.05 mol = 2.8 g 1.12 L at STP 1 mol = 84 g 40 g 1 mol
Impure CaCO 3 taken = 10 g (5 g pure CaCO 3 + 5 g impurity) 8.4 g (pure) 4.0 g 0.1 mol
in 10 g sample
CaO(s ) left = 2.8 g
Impurity = 5.0 g Thus, % of pure MgCO 3 = 84%
Total residue = 7.8 g Thus, (d)
Atoms Molecules and Ions 9

Thus, (b)
5. (a) CaCO 3 CaO + CO 2
1 mol 22.4 L 21. Mass of one atom = 6.64 1023 g
actual = 11.2 L Thus, atomic mass = 6.64 1023 6.02 1023
Thus, 50% = 40
Thus, (b)
(b) MgCO 3 MgO + CO 2
1 mol 40 g 23. Mass of one atom = 2.66 1023 g
Mass of N 0 atoms = 2.66 1023 6.02 1023 g mol 1
Thus, 100%
= atomic mass

(c) 2NaHCO 3 Na 2CO 3 + H2O + CO 2 Thus, number of moles in 32 g
2 mol 18 g
1 mol 9g 32
=
actual = 4 g 2.66 1023 6.02 1023
Thus, 44.4% Thus, (b)
27. Equivalent weight of element = 32 g
(d) Ca(HCO 3 )2 CaO + H2O + 2CO 2
1 mol 2 mol and that of oxygen = 8 g
actual = 1 mol Thus, one equivalent of oxide = 40 g
Thus, 50% 8
Thus, (b) Percentage of oxygen in oxide = 100
40
A1 X 1 + A2 X 2
11. Average atomic mass A = = 20%
X1 + X 2
Thus, (d)
35X 1 + 37 X 2
35.5 = 29. Na 2SO 3 : H2O
X1 + X 2
Moles 1 : 7
X1 3
On solving = Mass 126 126
X2 1
% 50 50
Thus (c)
Thus, (c)
12. X 3 has 10 electrons.
44. 18 g glucose = 0.10 mol glucose
Thus, protons (= atomic number) in X 3 = 7
withdrawn = 0.08 mol
neutron + proton = ionic mass =17
left = 0.10 0.08 = 0.02 mol = 3.6 g
Thus, neutrons =17 7 =10
Thus, (a) Thus, (d)
13. M 2+ has electrons = 32 (isoelectronic of SO 2 ) 45. Rest mass of electron = 9.11 1031 kg
protons = 34 = Z mass of one mole of electrons = 9.11 1031 6.02 1023
neutrons = 36 = 5.48 107 kg mol 1
Thus, ionic mass =70 Thus, (c)
4
Thus, (a) 51. Volume of spherical ball = r3
3
16. Number of moles in Molecules Atoms 4
= (7 )3
CH4 0.1 0.1 N 0 0.5 N 0 3
4
NH3 0.1 0.1 N 0 0.4 N 0 Mass of spherical ball = (7 )3 1.4 g
3
H2O 0.1 0.1 N 0 0.3 N 0 4 56
Iron in spherical ball = (7 )3 1.4 g
3 100
Thus, (b)
4 (7 )3 1.4 56
19. 0.018 mL = 0.018 g (density of water = 1g/mL) = mol
0.018 3 56 100
= = 0.001 mol
18 = 20 mol
= 6.02 1020 molecules Thus, (c)