This document discusses silicone solutions for various applications in the oil and gas industry, including:
1) Drilling mud additives like AFE-0310 that control air entrapment.
2) Antifoam dispersions like FBL-1165 and fluids like PMX 200 that are used to reduce foaming during oil/gas separation and crude oil processing.
3) Demulsifiers including various DM products that are efficient coalescing agents for separating water from crude oil.
4) Antifoams like DSP AF and DC 1430 that are used for scrubbing H2S/CO2 in gas and removing foam during regeneration.
5) Various silicone products
This document discusses silicone solutions for various applications in the oil and gas industry, including:
1) Drilling mud additives like AFE-0310 that control air entrapment.
2) Antifoam dispersions like FBL-1165 and fluids like PMX 200 that are used to reduce foaming during oil/gas separation and crude oil processing.
3) Demulsifiers including various DM products that are efficient coalescing agents for separating water from crude oil.
4) Antifoams like DSP AF and DC 1430 that are used for scrubbing H2S/CO2 in gas and removing foam during regeneration.
5) Various silicone products
This document discusses silicone solutions for various applications in the oil and gas industry, including:
1) Drilling mud additives like AFE-0310 that control air entrapment.
2) Antifoam dispersions like FBL-1165 and fluids like PMX 200 that are used to reduce foaming during oil/gas separation and crude oil processing.
3) Demulsifiers including various DM products that are efficient coalescing agents for separating water from crude oil.
4) Antifoams like DSP AF and DC 1430 that are used for scrubbing H2S/CO2 in gas and removing foam during regeneration.
5) Various silicone products
This document discusses silicone solutions for various applications in the oil and gas industry, including:
1) Drilling mud additives like AFE-0310 that control air entrapment.
2) Antifoam dispersions like FBL-1165 and fluids like PMX 200 that are used to reduce foaming during oil/gas separation and crude oil processing.
3) Demulsifiers including various DM products that are efficient coalescing agents for separating water from crude oil.
4) Antifoams like DSP AF and DC 1430 that are used for scrubbing H2S/CO2 in gas and removing foam during regeneration.
5) Various silicone products
THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 1 Well drilling & oil /gas production Silicone usage drilling water oil / gas / H2O gas scrubber absorbent regenerator injection separation A/F A/F
A/F gas
A/F A/F Separator Demulsifier crude oil discharged water water
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THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 2 DRILLING MUD
Drilling mud (Drilling lubricant)
need : air entrapment control during use products: AFE-0310 for water based drilling mud AFE-0110 also suitable but no PARCOM data AFE-0310 advantage: Price efficiency Additive level : 0.1 to 0.4 % Cloud point independance Temperature resistance Low toxicity (Parcom data) ACP-0100 compound may also be dispersed in solvent for geographic areas where freezing of the emulsion could be an issue (white spirit, kerosene, any aromatic material,)
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THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 3 GAS OIL SEPARATION separator crude
Antifoam ANTIFOAM DISPERSION ANTIFOAM FLUID - FBL-1165 Polydimethyl siloxane - PMX 200/ 12,500 cSt - PMX200/ 60,000 cSt Fluorosilicone - FS 1265 / 10,000 cSt - FS 2638 Additive level below 10 ppm Fluid should be dispersed in solvent before use (polar solvent such as ketones are suitable for FS) WE HELP YOU INVENT THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 4 Dow Corning antifoams efficiency by sparge test in Abu Dhabi crude oil with 20% (v/v) n-hexane, flow rate = 24l/h
THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 5 WELL WATER INJECTION / SECONDARY RECOVERY
deaerator tower water
Antifoam to injection well
ANTIFOAM DC 2-1517 EU Offshore antifoam
features: water based emulsion
50% active high efficiency (addition level below 5 ppm) no particulate content WE HELP YOU INVENT THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 6 DEMULSIFIER separator crude
DM1 Demulsifier DM2 ACTIVE DEMULSIFIER: DM3 DM4 DM5 Features: Q2-5220 Silicone polyether 100% active efficient coalescing agent and dropper
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THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 7 Chemistry
Todays chemistries: Polyglycol ethers (various EO/PO ratios, phenol ethoxylates, etc.) Polysalts (quat amine salts, etc.) Polyamines Sulphonates, formaldehyde resins, etc. Combinations Tomorrows chemistries ?? Silicone Polyethers (SPEs) SPEs + polyethers SPEs + polysalts WE HELP YOU INVENT THE FUTURE.TM TGH/May 25, 1999 8 Why an SPE? Silicones: are very surface active move to surfaces quickly can be more efficient than equivalent organics Coupling a silicone backbone with polyether functionality may give the best of both worlds SPEs are currently available SPEs are currently being used in this application WE HELP YOU INVENT THE FUTURE.TM TGH/May 25, 1999 9 GAS SCRUBBING absorbent treated gas antifoam antifoam
gas SCRUBBER REGENERATOR Antifoam: H2S/CO2 removal : DSP AF, DC 1430 (scrubbing by amine solution: MEA,DEA,TEA, MDEA,DGA,ADIP,BENFIELD) Gas dehydration : DB-310, DB-110A ( scrubbing by glycol ) (DB-100)
Addition level below 50 ppm
WE HELP YOU INVENT THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 10 Refinery & speciality Silicone usage - Gas scrubbing AFE-1430
- Delayed coking PMX200 / 60,000 cSt
FBL-1165
- Diesel antifoam 2-2617, 2-2647
- Waste Water Treatment AFE-0400, AFE-1510, AFE-0310
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THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 11 The Use Of Silicone For Foam Control In Gas Treatment Applications
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THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 12 Gas Treatment Foaming Occurs in both glycol dehydration and amine sweetening operations, although it is typically more of a problem in amine plants Occurs in both absorbers/contactors and regenerators Some level of foam is normal and necessary, but excessive foaming can cause problems
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THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 13 Recommended Use Of Silicone Antifoams SWEET GAS ACID GAS
OUTLET REFLUX SCRUBBER ACCUMULATOR
Antifoam REFLUX CONDENSER
CONTACTOR AMINE BOOSTER
CHARGE REFLUX COOLER PUMP PUMP PUMP FLASH GAS REGENERATOR CHARCOAL FILTER SOUR GAS FLASH TANK INLET OR SKIMMER RECLAIMER SCRUBBER
REBOILER
DRAIN SOLIDS FILTER
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THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 14 Glycol Dehydration System DRY GAS WATER OUT
Antifoam
REGENERATOR CONTACTOR
WET GAS RECLAIMER
REBOILER
DRAIN FLASH TANK Surge OR SKIMMER Drum
SOLIDS FILTER
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THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 15 DECOKER / DELAYED COKING FRACTIONETER
A/F ACTIVE DEAD COKE COKE DRUM DRUM
FOAM
COKE
FURNACE HEATER
Antifoam PMX200 / 60,000 cSt (needs to be diluted prior to use)
FBL-1165 (twice as efficient in this application) WE HELP YOU INVENT THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 16 DC Diesel antifoams basic properties 2-2617 2-2647 Active 100% 100% Viscosity 250 cSt 3400 cSt Spec. gravity 1.05 1.05 Freeze point < -7C < -25C Flash point 61C 59C Si wt 17% 17.8%
Solvent : aromatics or oxigenated solvents
ex : Shellsol AB + 2-Ethyl hexanol
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THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 17 Break times in CEC RF 73-A-93 wet diesel fuel (250 ppm water, 10 ppm antifoam)
30
25 Break time (sec)
20
15 Break time (sec) 2-2617
Break time (sec) 2-2647 10 Control (sec)
0 PkA t0 PkA t1 PkB t0 PkB t1 PkC t0 PkC t1 PkD t0 PkD t1 Type of crude/days of ageing
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THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 18 Dow Corning Product range by Application (exploration & production) Drilling muds & Cementing antifoam AFE-0310 0.1-0.4 % fluid (water based) Well Water injection antifoam 2-1517 EU 0.1-1 ppm
DM2 DM3 <20 ppm DM4 DM5 Q2-5220 WE HELP YOU INVENT THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 19 Dow Corning Product range by Application (refinery & speciality) Decoker antifoam PMX200 / 60,000 cSt 30-40 ppm FBL-1165 below 50 ppm
Gas scrubbing antifoam
AFE- 1430 50 ppm
Diesel additive antifoam 2-2617 <10 ppm
2-2647 <10 ppm
Waste water treatment antifoam AFE-0400 <30 ppm
AFE-1520 <20 ppm AFE-0310 <10 ppm WE HELP YOU INVENT THE FUTURE.TM 2013-02-20 Solutions for the Oil & Gas industry 20
