Ink for R-301(Black, Blue) 2015-06-19

1/6

Safety Data Sheet

Date of issue2015-06-19
Revision Date-

Identification of the mixture and of the company

Product name Ink for R-301(Black, Blue)
Company ZEBRA CO., LTD.
2-9 Higashi-gokencho Shinjuku-ku Tokyo JAPAN
TEL: +81-3-3268-1193
FAX: +81-3-3268-1197
Emergency telephone +81-3-3268-1193
This phone number is available only during office hours: 9 a.m. to half past 5 p.m.
Japan time)
Product use Infill Ink for writing implement

Hazards identification
GHS classification
Physical hazards
Flammable liquids Not classified
Pyrophoric liquids Not classified
Self-heating mixtures Not classified
Corrosive to metals Not classified
Health hazards
Acute toxicity-Oral Classification not possible
Acute toxicity-Dermal Classification not possible
Acute toxicity-Inhalationvapour Classification not possible
Acute toxicity-Inhalationmist Classification not possible
Skin corrosion / irritation Classification not possible
Serious eye damage / eye irritation Classification not possible
Respiratory or skin sensitization Classification not possibleClassification not possible
Germ cell mutagenicity Classification not possible
Carcinogenicity Classification not possible
Reproductive toxicity Classification not possible
Specific target organ toxicity (Singel exposure) Classification not possible
Specific target organ toxicity(Repeated exposure) Classification not possible
Aspiration hazard Classification not possible
Environmental hazards
Hazardous to the aquatic environment(acute) Classification not possible
Hazardous to the aquatic environment(chronic) Classification not possible

GHS label elements

Pictograms or Symbol
Exclamation mark
No pictogram
Signal Word
No signal word

-1-
 Ink for R-301(Black, Blue) 2015-06-19
2/6

Hazard statement
No hazard statement
Precautionary Statements
Prevention
Read label and Material Safety Data Sheet before use.
Wear protective gloves/eye protection.
Wash hand throughly after handling
Avoid release to the environment
Response
Nothing in particular
Storage
Store in a well ventilated place. Keep cool and container tightly closed.
Disposal
Dispose of contents/container to in accordance with local government regulation.

Composition/information on ingredients
Mixture
Component and Amount
Reference Number in Gazetted List in Japan
Component Amount CAS No. Japanese Chemical Substances Control Act
Dyes 0-50% Nondisclosure Nondisclosure(registered)
Water 0-90% 7732-18-5
Glycerol 10-25% 56-81-5 (2)-242
Additives 0-5% Nondisclosure Nondisclosure(registered)
Other components 0-90% Nondisclosure Nondisclosure(registered)

First-aid measures
After inhalation:
Call a doctor/physician if you feel unwell.
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
After skin contact:
If skin irritation occurs: Get medical advice/attention
Call a doctor/physician if you feel unwell.
After eye contact:
Rinse continuously with water for several minutes.
Remove contact lenses if present and easy to do . Continue rinsing
If eye irritation persists : Get medical advice/attention
After ingestion:
Call a doctor/physician if you feel unwell.
Protection of the person who takes first aid
Nothing in particular.

Fire-fighting measures
Suitable Extinguishing media
Carbon dioxide, dry chemical powder, water fog, foam
Prohibition extinguishing media for safety reason
Water spray (straight)

-2-
 Ink for R-301(Black, Blue) 2015-06-19
3/6

Specific hazards
This product is not combustible.But evaporated residue is combustible.
May produce toxic fumes if burning.
Specific fire fighting procedures
If safe to do so, move undamaged containers from the fire area.
If can't move the container , cool containers and surrounding with spray water.
Cool containers with large quantities of water until well after extinguished the fire.
Special protective equipment for fire-fighters
Fire-fighting should be performed from the windward side.
Respiratory protection, and other suitable protective equipment

Accidental release measures

Personal precautions
The pollution area should be established as off limits without concerned persons.
Protective equipment and emergency measure
Do not touch the leakage or its damaged container without suitable protection.
Do not walk through the leakage.
Keep sufficient ventilation if the area is indoor.
Remove ignition sources.
Environmental precautions
Keep away from drains, and prevent from releasing to the environment.
Methods for cleaning up
Use non-flammable absorbent materials, and put them in airtight container.
Dispose of absorbent in accordance with law.
Prevention of secondary disaster
Remove nearby ignition source and hot surface.

Handling and storage

Handling
Technical measures
Do suitable equipment measures and use suitable protection that refer to
"Exposure control/ personal protection".
Local exhaust ventilation and general ventilation
Use local exhaust ventilation and general ventilation that refer to
"Exposure control/ personal protection".
Caution
When handling do not use high temperature articles, spark and fire.
Handle container with care, do not make it turn over, drop, give impact and drag.
Do not breathe, contact and swallow.
Maintain air concentrations below exposure limit using exhaust ventilation.
Do not eat, drink or smoke when using this product.
Wash hand throughly after handling.
Use only outdoors or in awell-ventilated area.
Avoid release to the environment.
Avoid contact
Refer to section 10 about stability and reactivity.
Storage
Incompatible materials
Refer to section 10 about stability and reactivity.

-3-
 Ink for R-301(Black, Blue) 2015-06-19
4/6

Storage condition
Store away from heat/sparks/open flames No smoking
Store in a well ventilated place. Keep cool and container tightly closed.
Store locked up.
The Containers
Use the container that our company filled up when ship products

Exposure control/ personal protection

Exposure limit values
Permissible concentration Administrative levels
Chemical name The Japan Society for Ministry of Health, Labour and
Occupational Health ACGIH TLV-TWA
Welfare(JAPAN)
Glycerol Not established 10mg/m3 (mist, TWA, 2009) Not established

Equipment measures
Put up local exhaust ventilation.Use explosion-proof electrical/ventilating/lighting.
Take precautionary measures against static discharge.
Put up emergency eyewash and shower in case of storage or handling about this product.

Protection
Respiratory protection
If necessary use suitable respiratory protection.
Hand protection
Use suitable protective gloves.
Eye protection
Use suitable eye protection.
Skin/body protection
If necessary use suitable face protection.
Hygiene measures
Do not eat ,drink or smoke when using this product.
Wash thoroughly after handling.

.Physical and chemical properties

Appearance Coloring Liquid
Odour Peculiar odour
8-9
Melting point / Coagulating point No data available
Boiling point 100
Flash point 111
Explosive limit UEL No data available
Explosive limit LEL No data available
Vapour pressure No data available
Vapour density No data available
Specific gravity No data available
Water solubility Soluble in water.
Partition coefficient n-octanol/water No data available
Ignition point 410
Decomposition point No data available

-4-
 Ink for R-301(Black, Blue) 2015-06-19
5/6

Stability and reactivity

Chemical stability This product is stable in normal condition.
Materials to Avoid No data available
Conditions to avoid No data available
Incompatible materials No data available
Hazardous decomposition products No data available

Toxicological information
Acute toxicity-Oral Classification not possible
Acute toxicity-Dermal Classification not possible
Acute toxicity-Inhalationvapour Classification not possible
Acute toxicity-Inhalationmist Classification not possible
Skin corrosion / irritation Classification not possible
Serious eye damage / eye irritation Classification not possible
Respiratory or skin sensitization Classification not possibleClassification not possible
Germ cell mutagenicity Classification not possible
Carcinogenicity Classification not possible
Reproductive toxicity Classification not possible
Specific target organ toxicity(Singel exposure) Classification not possible
Specific target organ toxicity(Repeated exposure) Classification not possible
Aspiration hazard Classification not possible

Ecological information
Hazardous to the aquatic environment(acute) Classification not possible
Hazardous to the aquatic environment(chronic) Classification not possible

Degradability No data is available

Bioaccumulative potential No data is available
Mobility in soil No data is available

Disposal considerations
Waste residues
Disposal must be made according to official regulations.
Avoid release to the environment.
Contaminated container and packaging
Do not flush into the sewer.
Remove all contents when you dispose of empty containers.

Transport information
The contents are as follows when transport only ink
International regulation
IMDGmaritime transport
UN No. Not applicable
Class -
Packing Group -
Marine Pollutant -

-5-
 Ink for R-301(Black, Blue) 2015-06-19
6/6

ICAO/IATAair transport
UN No. Not applicable
Class -
Packing Group -
Special precautions
Prevent from falling, sumbling and doing damage when the container loading..
Avoid acute vibration and friction for container.
If there are some indications of hazard in transporting like acute leak in transporting,
take emergency measures and report the accident at once to disaster management agency.
Avoid transport with foods or feeds.
Above regulations are applied to transport of writing instruments filled with the ink.

Regulatory information

Follow all regulation in your country.

Other information
In this sheet, the contents of ingredients and the value of physical and chemical properties
are not guaranteed performance.
The information contained in this sheet is based on the data available at now.
But this shall not constitute a guarantee for any specific or classification.
Please be alert to handling this product because chemicals shall have unknown hazards.
This sheet may be revised when we get new information.
The information is assumed in the case of large-scale handling on business operations.
They cannot be always applicable to general use of writing instruments.

Reference
Globally Harmonized System of Classification and Labelling of Chemicals (GHS) second revised edition 2007
Recommendation of Occupational Exposure Limits(2009-2010) by The Japan Society for Occupational Health
2009 TLVs and BEIs by ACGIH

-6-