Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

CWT-TITRET AMPOULE
1. Identification of the substance/preparation and of the company/undertaking
Product name : CWT-TITRET AMPOULE
Material Uses : Industrial applications: Analytical reagent.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation
Chemical characterization : Contains : Sulphuric acid: 3%

Chemical name* CAS No. % EC Number Classification

Sulphuric acid 7664-93-9 1-5 231-639-5 C; R35
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification :
This product is not classified according to the EU regulations.
Effects and symptoms
Inhalation : Slightly hazardous in case of inhalation.
Skin contact : Slightly hazardous in case of skin contact (irritant). Skin inflammation is
characterized by itching, scaling, reddening, or, occasionally, blistering.
Eye Contact : Slightly hazardous in case of eye contact (irritant).
Target Organs : Contains material which causes damage to the following organs: lungs,
mucous membranes, upper respiratory tract, skin, eye, lens or cornea, teeth.

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 CWT-TITRET AMPOULE

4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention if symptoms appear.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. Loosen tight clothing
such as a collar, tie, belt or waistband. Get medical attention if symptoms
appear.
Skin contact : Wash with soap and water. Cover the irritated skin with an emollient. Get
medical attention if irritation develops. Cold water may be used.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Get medical attention if irritation occurs.

5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Hazardous thermal (de)composition : These products are sulphur oxides (SO2, SO3, etc.).
products
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Vapour respirator. Boots. Gloves. A self-contained
breathing apparatus should be used to avoid inhalation of the product.
Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Environmental precautions and : Absorb with an inert material and put the spilled material in an appropriate
cleanup methods waste disposal. Finish cleaning by spreading water on the contaminate
surface and allow to evacuate through the sanitary system.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Do not breathe gas/fumes/vapour/spray. If ingested, seek medical advice
immediately and show the container or the label. Use only in accordance
with Drew Test Procedures
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Do not store below 5°C (41°F).
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection

Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Hygiene measures : Wash hands after handling compounds and before eating, smoking, using
lavatory, and at the end of day.
Occupational Exposure Limits

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 CWT-TITRET AMPOULE

Ingredient Name Occupational Exposure Limits

Sulphuric acid EH40-OES (United Kingdom (UK), 2001). Notes: OES
TWA: 1 mg/m3 Form: Solution

Respiratory system : Wear appropriate respirator when ventilation is inadequate. Vapour respirator.
(as filter E)

Skin and body : Lab coat.

Hands : Impervious gloves.
Eyes : Safety glasses.

9. Physical and chemical properties

Physical state : Liquid. (Ampoule)
Colour : Clear. Colourless. / Brown.
Odour : Odourless.
Boiling point : 100°C (212°F)
Melting point : 3°C (37°F)
Density : 1.03 g/cm3 (20°C / 68°F)
Vapour pressure : 2.4 kPa (18 mmHg) (at 20°C)
Evaporation Rate : 0.36 (Water) compared to n-Butyl acetate

Solubility : Easily soluble in cold water.

pH : 1 [Acidic.]
Flash point : Not applicable.

10. Stability and reactivity

Stability : The product is stable.
Materials to avoid : Slightly reactive to reactive with metals, alkalis.
Incompatible with some alkalis. Incompatible with finely-powdered metals.

Hazardous decomposition products : These products are sulphur oxides (SO2, SO3, etc.).

Remarks : Flammable hydrogen gas may be produced on prolonged contact with metals
such as aluminium, tin, lead and zinc.

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
Sulphuric acid LD50 2140 mg/kg Oral Rat
LC50 510 mg/m3 Inhalation Rat
(2 hours)

Chronic toxicity : Repeated exposure to an highly toxic material may produce general
deterioration of health by an accumulation in one or many human organs.
Local effects
Skin irritation : Slightly hazardous in case of skin contact (irritant).
Eye irritation : Slightly hazardous in case of eye contact (irritant).
Specific effects
Carcinogenic effects : Classified A2 (Suspected for humans.) by ACGIH [Sulphuric acid].

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 CWT-TITRET AMPOULE

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.

12. Ecological information

Persistence/degradability : Not available.

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 16 05 02

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 16 05 02 other waste containing inorganic chemicals, e.g. lab chemicals not
otherwise specified, fire extinguishing powders

14. Transport information

International transport regulations
Land - Road/Railway
UN number : Not regulated.
Proper shipping name : -
ADR/RID Class : -
Other information : Remarks
Not controlled under ADR (Europe).
Sea
UN number : Not regulated.
Proper shipping name : -
IMDG Class : -
Other information : Remarks
Not controlled under IMDG.

15. Regulatory information

EU Regulations
Risk Phrases : This product is not classified according to the EU regulations.
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

16. Other information

Full text of R-Phrases with no. : R35- Causes severe burns.
appearing in Section 2 - United
Kingdom (UK)
Text of classifications appearing in : C - Corrosive
Section 2 - United Kingdom (UK)
HISTORY
Date of printing : 10/21/2002.
Date of issue : 7/18/2002.
Version : 2.07

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 CWT-TITRET AMPOULE

CWT-TITRET® AMPOULES is a registered trademark of Ashland Inc.

Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
7/18/2002. 2.07 Page: 5/5
 Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

CWT-TITRET Valve Assembly
1. Identification of the substance/preparation and of the company/undertaking
Product name : CWT-TITRET Valve Assembly
Chemical product name : Diethylene glycol
Chemical formula : C4-H10-O3
Material Uses : Industrial applications: Analytical reagent.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Substance

Chemical name* CAS No. % EC Number Classification

Diethylene glycol 111-46-6 90-100 203-872-2 Xn; R22
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The substance is classified as dangerous according to Directive 2001/59/EC.
Classification : Harmful
R22- Harmful if swallowed.
Effects and symptoms
Target Organs : Causes damage to the following organs: kidneys, liver, skin, eyes, eye, lens or
cornea.

4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. If large quantities of
this material are swallowed, call a physician immediately. Loosen tight clothing
such as a collar, tie, belt or waistband.

Date of issue : 10/16/2002. Page: 1/5

 CWT-TITRET Valve Assembly

Skin contact : Wash with soap and water. Get medical attention if irritation develops. Cold
water may be used
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Obtain medical attention.

5. Fire-fighting measures
Extinguishing Media
Suitable : SMALL FIRE: Use dry chemical powder or CO2.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water.
products
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing
might not be sufficient; consult a specialist BEFORE handling this product.
Environmental precautions and : Absorb with an inert material and put the spilled material in an appropriate
cleanup methods waste disposal. Finish cleaning by spreading water on the contaminate
surface and allow to evacuate through the sanitary system.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Keep away from heat. Keep away from sources of ignition. Empty containers
pose a fire risk, evaporate the residue under a fume hood. Do not breathe
gas/fumes/vapour/spray. If ingested, seek medical advice immediately and
show the container or the label. Keep away from incompatibles such as
oxidizing agents. Use only in accordance with Drew Test Procedures.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection

Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Ensure that eyewash stations and safety showers are close to the workstation
location.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and
before eating, smoking, using lavatory, and at the end of day.
Occupational Exposure Limits

Ingredient Name Occupational Exposure Limits

Diethylene glycol EH40-OES (United Kingdom (UK), 2001). Notes: OES
TWA: 101 mg/m3
TWA: 23 ppm

Skin and body : Lab coat.

Hands : Impervious gloves.
Eyes : Safety glasses.

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 CWT-TITRET Valve Assembly

9. Physical and chemical properties

Physical state : Liquid.
Colour : Colourless.
Odour : Odourless.
Boiling point : 245°C (473°F)
Melting point : -6°C (21°F)
Density : 1.118 g/cm3
Vapour density : 3.7 (Air = 1)
Vapour pressure : 0.00067 kPa (0.005 mmHg) (at 20°C)
Evaporation Rate : <0.01 compared to Butyl acetate.

Solubility : Easily soluble in cold water.

Octanol/water partition coefficient : The product is more soluble in water; log(octanol/water)-2

pH : Not available.
Flash point : OPEN CUP: 124°C (255.2°F).
Autoignition temperature : >220°C (428°F)
Lower explosion limit : LOWER: 1.8% UPPER: 12.2%

10. Stability and reactivity

Stability : The product is stable.
Materials to avoid : Reactive with oxidizing agents.
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water.

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
Diethylene glycol LD50 12565 Oral Rat
mg/kg
LD50 4400 mg/kg Oral Rabbit
LD50 3300 mg/kg Oral Cat
LD50 11890 Dermal Rabbit
mg/kg

Chronic toxicity : Repeated or prolonged exposure is not known to aggravate medical condition.
Carcinogenic effects : Not available.

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.

12. Ecological information

Persistence/degradability : Not available.

Bioaccumulative potential : This product shows a low bioaccumulation potential.

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 CWT-TITRET Valve Assembly

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 16 05 03

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 16 05 03 other waste containing organic chemicals, e.g. lab chemicals not
otherwise specified

14. Transport information

International transport regulations
Land - Road/Railway
UN number : Not regulated.
Proper shipping name : -
ADR/RID Class : -
Other information : Remarks
Not controlled under ADR (Europe).
Sea
UN number : Not regulated.
Proper shipping name : -
IMDG Class : -
Other information : Remarks
Not controlled under IMDG.

15. Regulatory information

EU Regulations
Hazard symbol(s) :

Harmful
Risk Phrases : R22- Harmful if swallowed.
Safety Phrases : S46- If swallowed, seek medical advice immediately and show this container
or label.
Contains : Diethylene glycol 203-872-2
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

16. Other information

Full text of R-Phrases with no. : R22- Harmful if swallowed.
appearing in Section 2 - United
Kingdom (UK)
Text of classifications appearing in : Xn - Harmful
Section 2 - United Kingdom (UK)
HISTORY
Date of printing : 10/21/2002.
Date of issue : 10/16/2002.
Version : 3
CWT-TITRET® Valve Assemly

Date of issue : 10/16/2002. Page: 4/5

 CWT-TITRET Valve Assembly

Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
10/16/2002. 3 Page: 5/5