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Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET


DREWCLEAN EST
1. Identification of the substance/preparation and of the company/undertaking
Product name : DREWCLEAN EST

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification


Magnesium nitrate 13446-18-9 20-30 233-826-7 O; R8
Xi; R36/37/38
Ammonium nitrate 6484-52-2 10-20 229-347-8 O; R8
Xi; R36/37/38
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Irritant
R36/37/38- Irritating to eyes, respiratory system and skin.
Effects and symptoms
Inhalation : Hazardous in case of inhalation (lung irritant).
Skin contact : Hazardous in case of skin contact (irritant). Skin inflammation is
characterized by itching, scaling, reddening, or, occasionally, blistering.
Eye Contact : Hazardous in case of eye contact (irritant).

4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. Loosen tight clothing
such as a collar, tie, belt or waistband. Get medical attention if symptoms
appear.

Date of issue : 10/16/2002. Page: 1/5


DREWCLEAN EST

Skin contact : In case of contact, immediately flush skin with plenty of water. Cover the
irritated skin with an emollient. Remove contaminated clothing and shoes.
Cold water may be used. Wash clothing before reuse. Clean shoes
thoroughly before reuse. Obtain medical attention.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Obtain medical attention.

5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Hazardous thermal (de)composition : These products are nitrogen oxides (NO, NO2...).
products
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures


Personal Precautions : Splash goggles. Full suit. Vapour respirator. Boots. Gloves. A self-contained
breathing apparatus should be used to avoid inhalation of the product.
Environmental precautions and : Absorb with an inert material and put the spilled material in an appropriate
cleanup methods waste disposal. Finish cleaning by spreading water on the contaminate
surface and allow to evacuate through the sanitary system.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage


Handling : Do not breathe gas/fumes/vapour/spray. If ingested, seek medical advice
immediately and show the container or the label. Keep away from
incompatibles such as reducing agents.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Do not store below 0°C (32°F).
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection


Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Hygiene measures : Wash hands after handling compounds and before eating, smoking, using
lavatory, and at the end of day.

Respiratory system : Vapour respirator.

Skin and body : Lab coat.


Hands : Impervious gloves.
Eyes : Splash goggles.

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DREWCLEAN EST

9. Physical and chemical properties


Physical state : Liquid.
Colour : Yellow.
Odour : Not available.
Boiling point : 105°C (221°F)
Melting point : -4°C (25°F)
Density : 1.31 g/cm3
Vapour pressure : The highest known value is 2.33 kPa (17.5 mmHg) (at 20°C) (Water).
Evaporation Rate : <1 compared to Ether (anhydrous).

Solubility : Easily soluble in cold water.


pH : 7 to 8 [Basic.]
Flash point : Not applicable.
Viscosity : Dynamic: 3 cP

10. Stability and reactivity


Stability : The product is stable.
Materials to avoid : Reactive with reducing agents.
Slightly reactive to reactive with combustible materials, organic materials,
alkalis.
Hazardous decomposition products : These products are nitrogen oxides (NO, NO2...).

11. Toxicological information


Acute toxicity
Ingredient Name Test Result Route Species
Magnesium nitrate LD50 5440 mg/kg Oral Rat
Ammonium nitrate LD50 2217 mg/kg Oral Rat

Chronic toxicity : Repeated or prolonged exposure is not known to aggravate medical condition.
Skin irritation : Hazardous in case of skin contact (irritant).
Eye irritation : Hazardous in case of eye contact (irritant).
Carcinogenic effects : Not available.

Mutagenic Effects : Not available.


Reproduction toxicity : Not available.

12. Ecological information

Persistence/degradability : Ecological testing has not been conducted on this product.

13. Disposal considerations


Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 16 05 02


Hazardous Waste : To present knowledge of the supplier, this product is not regarded as
hazardous waste as defined by EU Directive 91/689/EC.

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DREWCLEAN EST

Additional Information : 16 05 02 other waste containing inorganic chemicals, e.g. lab chemicals not
otherwise specified, fire extinguishing powders

14. Transport information


International transport regulations
Land - Road/Railway
UN number : Not regulated.
Proper shipping name : -
ADR/RID Class : -
Other information : Remarks
Not controlled under ADR (Europe).
Sea
UN number : Not regulated.
Proper shipping name : -
IMDG Class : -
Other information : Remarks
Not controlled under IMDG.

15. Regulatory information


EU Regulations
Hazard symbol(s) :

Irritant
Risk Phrases : R36/37/38- Irritating to eyes, respiratory system and skin.
Safety Phrases : S23- Do not breathe vapour.
S37/39- Wear suitable gloves and eye/face protection.
S38- In case of insufficient ventilation, wear suitable respiratory equipment.
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications, Used by Spraying.

16. Other information


Full text of R-Phrases with no. : R8- Contact with combustible material may cause fire.
appearing in Section 2 - United R36/37/38- Irritating to eyes, respiratory system and skin.
Kingdom (UK)
Text of classifications appearing in : O - Oxidizing
Section 2 - United Kingdom (UK) Xi - Irritant
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
DREWCLEAN® EST is a registered trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.

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DREWCLEAN EST

Date of issue Version


10/16/2002. 3 Page: 5/5

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