Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

DESCALE-IT
1. Identification of the substance/preparation and of the company/undertaking
Product name : DESCALE-IT
Material Uses : Industrial applications: Rust and scale remover

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification

Hydrochloric acid 7647-01-0 20-30 231-595-7 C; R34
Xi; R37
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Corrosive
R34- Causes burns.
R37- Irritating to respiratory system.
Effects and symptoms
Inhalation : Hazardous in case of inhalation (lung irritant). Inhalation of the spray mist
may produce severe irritation of respiratory tract, characterized by coughing,
choking or shortness of breath. Overexposure by inhalation may cause
respiratory irritation.
Ingestion : May be fatal if swallowed. May cause burns to mouth, throat and stomach.
Skin contact : Corrosive to skin on contact. Skin contact may produce burns.
Eye Contact : Corrosive to eyes.
Target Organs : Contains material which causes damage to the following organs: lungs, liver,
skin, eye, lens or cornea.

Date of issue : 10/16/2002. Page: 1/5

 DESCALE-IT

4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention immediately.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. Loosen tight clothing
such as a collar, tie, belt or waistband. Get medical attention if symptoms
appear.
Skin contact : In case of contact, immediately flush skin copiously with water for at least 15
minutes while removing contaminated clothing and shoes. Cold water may be
used. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Obtain medical attention immediately.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Obtain medical attention immediately.

5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Unusual fire/explosion Hazards : Flammable hydrogen gas may be produced on prolonged contact with metals
such as aluminium, tin, lead and zinc.
Hazardous thermal (de)composition : These products are halogenated compounds.
products
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Vapour respirator. Boots. Gloves. A self-contained
breathing apparatus should be used to avoid inhalation of the product.
Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Environmental precautions and : Stop leak if without risk. Absorb with dry earth, sand or other noncombustible
cleanup methods material. Use water spray curtain to divert vapour drift. Prevent entry into
sewers, basements or confined areas; dike if needed. Call for assistance on
disposal. Neutralize the residue with a dilute solution of sodium
carbonate.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Keep container dry. Do not breathe gas/fumes/vapour/spray. Wear suitable
protective clothing. If ingested, seek medical advice immediately and show
the container or the label. Keep away from incompatibles such as oxidizing
agents, alkalis.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.

Date of issue : 10/16/2002. Page: 2/5

 DESCALE-IT

8. Exposure controls/personal protection

Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Hygiene measures : Wash hands after handling compounds and before eating, smoking, using
lavatory, and at the end of day.
Occupational Exposure Limits

Ingredient Name Occupational Exposure Limits

Hydrochloric acid EH40-OES (United Kingdom (UK), 2001). Notes: OES
STEL: 8 mg/m3 Form: Multiple forms
STEL: 5 ppm Form: Multiple forms
TWA: 2 mg/m3 Form: Multiple forms
TWA: 1 ppm Form: Multiple forms

Respiratory system : Wear appropriate respirator when ventilation is inadequate. Vapour respirator.

Skin and body : Full suit.

Hands : Impervious gloves.
Eyes : Face shield.

9. Physical and chemical properties

Physical state : Liquid.
Colour : Colourless. / Light brown.
Odour : Pungent.
Boiling point : 108°C (226°F)
Melting point : -50°C (-58°F)
Density : 1.15 g/cm3
Vapour density : 1.01 (Air = 1)
Vapour pressure : 20.99 kPa (157.5 mmHg) (at 20°C)
Evaporation Rate : 0.36 (Water) compared to n-Butyl acetate

Solubility : Easily soluble in cold water.

Octanol/water partition coefficient : The product is more soluble in octanol; log(octanol/water) =0.3

pH : -1 [Acidic.]
Flash point : Not applicable.

10. Stability and reactivity

Stability : The product is stable.
Materials to avoid : Extremely reactive or incompatible with alkalis.
Reactive with oxidizing agents.
Hazardous decomposition products : These products are halogenated compounds.

Remarks : Flammable hydrogen gas may be produced on prolonged contact with metals
such as aluminium, tin, lead and zinc.

Date of issue : 10/16/2002. Page: 3/5

 DESCALE-IT

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
Hydrochloric acid LD50 915 mg/kg Oral Rat
LD50 151 mg/kg Oral Mouse
LD50 2950 mg/kg Oral Mouse
LDLo 150 mg/kg Oral Mouse
LDLo 110 mg/kg Oral Mouse

Chronic toxicity : Repeated or prolonged contact with spray mist may produce chronic eye
irritation and severe skin irritation. Repeated or prolonged exposure to spray
mist may produce respiratory tract irritation, leading to frequent attacks of
bronchial infection.
Skin irritation : Hazardous in case of skin contact (corrosive).
Eye irritation : Hazardous in case of eye contact (corrosive).
Carcinogenic effects : Not available.

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.

12. Ecological information

Persistence/degradability : Not available.

Bioaccumulative potential : This product shows a low bioaccumulation potential.

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 06 01 02

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 06 01 02 hydrochloric acid

14. Transport information

International transport regulations
Land - Road/Railway
UN number : 1789
Proper shipping name : Hydrochloric acid
ADR/RID Class : 8
Packing group : II
ADR/RID label :

Other information : Hazard identification number

80
Sea
UN number : 1789
Proper shipping name : Hydrochloric acid

Date of issue : 10/16/2002. Page: 4/5

 DESCALE-IT

IMDG Class : 8
Packing group : II
IMDG label :

Other information : Emergency Schedules (EmS)

8-03

15. Regulatory information

EU Regulations
Hazard symbol(s) :

Corrosive
Risk Phrases : R34- Causes burns.
R37- Irritating to respiratory system.
Safety Phrases : S26- In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.
S45- In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
Contains : Hydrochloric acid 231-595-7
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

16. Other information

Full text of R-Phrases with no. : R34- Causes burns.
appearing in Section 2 - United R37- Irritating to respiratory system.
Kingdom (UK)
Text of classifications appearing in : C - Corrosive
Section 2 - United Kingdom (UK) Xi - Irritant
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
10/16/2002. 3 Page: 5/5