Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

DREWCLEAN 2000
1. Identification of the substance/preparation and of the company/undertaking
Product name : DREWCLEAN 2000
Material Uses : Industrial applications: Quick separating degreaser.

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification

Low boiling point hydrogen treated naphtha; heavy 64742-48-9 80-90 265-150-3 Xn; R65
R66
Terpene hydrocarbons (mixture) 1-5 Xi; R38
(R)-p-Mentha-1,8-diene 1-5 227-813-5 R10
Xi; R38
R43
N; R50/53
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Harmful, Dangerous for the environment
R43- May cause sensitization by skin contact.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R65- Harmful: may cause lung damage if swallowed.
R66- Repeated exposure may cause skin dryness or cracking.
Effects and symptoms
Inhalation : Slightly hazardous in case of inhalation.
Ingestion : Slightly hazardous in case of ingestion.
Skin contact : Hazardous in case of skin contact (sensitizer).

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4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention.
Ingestion : If swallowed, do NOT induce vomiting. Do NOT induce vomiting unless
directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Aspiration hazard if swallowed- can enter lungs and
cause damage. Loosen tight clothing such as a collar, tie, belt or waistband.
Obtain medical attention. Get medical attention if symptoms appear.
Skin contact : In case of contact, immediately flush skin copiously with water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse. Clean shoes thoroughly before reuse. Obtain medical attention.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Obtain
medical attention.

5. Fire-fighting measures
Extinguishing Media
Suitable : SMALL FIRE: Use dry chemical powder or CO2.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water.
products
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing
might not be sufficient; consult a specialist BEFORE handling this product.
Environmental precautions and : Keep away from heat. Keep away from sources of ignition. Stop leak if
cleanup methods without risk. Finish cleaning by spreading water on the contaminated surfac
and allow to evacuate through the sanitary system.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Keep away from heat. Keep away from sources of ignition. Ground all
equipment containing material. Do not breathe gas/fumes/vapour/spray. If
ingested, seek medical advice immediately and show the container or the
label. Keep away from incompatibles such as oxidizing agents.
Storage : Keep container in a cool, well-ventilated area. Keep container tightly closed
and sealed until ready for use. Avoid all possible sources of ignition (spark or
flame).
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection

Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Ensure that eyewash stations and safety showers are close to the workstation
location.
Hygiene measures : Wash hands after handling compounds and before eating, smoking, using
lavatory, and at the end of day.
Occupational Exposure Limits

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 DREWCLEAN 2000

Ingredient Name Occupational Exposure Limits

Low boiling point hydrogen treated naphtha; heavy RPC (United Kingdom (UK), 2000). Notes: Supplier's
information
TWA: 1200 mg/m3

Respiratory system : Wear appropriate respirator when ventilation is inadequate.

Skin and body : Lab coat.

Hands : Impervious gloves.
Eyes : Safety glasses.

9. Physical and chemical properties

Physical state : Liquid.
Colour : Green.
Odour : Pleasant.
Boiling point : 177°C (351°F)
Melting point : <-20°C (-4°F)
Density : 0.78 to 0.8 g/cm3
Vapour density : >1 (Air = 1)
Vapour pressure : <0.29 kPa (<2.2 mmHg) (at 20°C)
Evaporation Rate : <1 compared to Ether (anhydrous).

Solubility : Insoluble in cold water.

pH : Not applicable.
Flash point : CLOSED CUP: >61°C (141.8°F).(Pensky-Martens.)
Autoignition temperature : The lowest known value is >200°C (392°F) (Low boiling point hydrogen
treated naphtha; heavy).
Lower explosion limit : The greatest known range is LOWER: 0.6% UPPER: 7% (Low boiling point
hydrogen treated naphtha; heavy)

10. Stability and reactivity

Stability : The product is stable.
Materials to avoid : Reactive with oxidizing agents.
Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water.

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
Low boiling point hydrogen treated naphtha; LD50 >2000 Oral Rat
heavy mg/kg
LD50 >2000 Dermal Rabbit
mg/kg
Terpene hydrocarbons (mixture) LD50 3500 mg/kg Oral Rat
LD50 >5000 Dermal Rabbit
mg/kg
(R)-p-Mentha-1,8-diene LD50 4400 mg/kg Oral Rat
LD50 5600 mg/kg Oral Mouse
LD50 >5000 Dermal Rabbit
mg/kg

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 DREWCLEAN 2000

Chronic toxicity : Repeated or prolonged exposure is not known to aggravate medical condition.
Sensitization : Hazardous in case of skin contact (sensitizer).
Carcinogenic effects : Not available.

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.

12. Ecological information

Ecotoxicity Data
Ingredient Name Species Period Result
Low boiling point hydrogen treated naphtha; heavy Fish (LC50) 96 hours >100 mg/l

Persistence/degradability : Not available.

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 14 02 02

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 14 02 02 solvent mixes or organic liquids free of halogenated solvents

14. Transport information

International transport regulations
Land - Road/Railway
UN number : Not regulated.
Proper shipping name : -
ADR/RID Class : -
Other information : Remarks
Not controlled under ADR (Europe).
Sea
UN number : Not regulated.
Proper shipping name : -
IMDG Class : -
Other information : Remarks
Not controlled under IMDG.

15. Regulatory information

EU Regulations
Hazard symbol(s) :

Harmful, Dangerous for the environment

Risk Phrases : R43- May cause sensitization by skin contact.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R65- Harmful: may cause lung damage if swallowed.
R66- Repeated exposure may cause skin dryness or cracking.

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 DREWCLEAN 2000

Safety Phrases : S23- Do not breathe vapour/spray.

S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.
S38- In case of insufficient ventilation, wear suitable respiratory equipment.
S46- If swallowed, seek medical advice immediately and show this container
or label.
S56- Dispose of this material and its container at hazardous or special waste
collection point.
Contains : (R)-p-Mentha-1,8-diene 227-813-5
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications, Used by Spraying.

16. Other information

Full text of R-Phrases with no. : R10- Flammable.
appearing in Section 2 - United R38- Irritating to skin.
Kingdom (UK) R43- May cause sensitization by skin contact.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
R65- Harmful: may cause lung damage if swallowed.
R66- Repeated exposure may cause skin dryness or cracking.
Text of classifications appearing in : Xn - Harmful
Section 2 - United Kingdom (UK) Xi - Irritant
N - Dangerous for the environment.
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
DREWCLEAN® is a registered trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
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