GulfSea SuperBear 3006

Gulf Marine Pte. Ltd.

Chemwatch: 5612-19 Issue Date: 20/06/2023
Version No: 3.1 Print Date: 24/01/2024
Safety Data Sheet S.GHS.SGP.EN.E

SECTION 1 Identification of the substance / mixture and of the company / undertaking

Product Identifier
Product name GulfSea SuperBear 3006
Chemical Name Not Applicable
Synonyms Not Available
Chemical formula Not Applicable
Other means of identification 1CS23061-00

Relevant identified uses of the substance or mixture and uses advised against
Marine System Oil
Relevant identified uses
Use according to manufacturer's directions.

Details of the manufacturer or supplier of the safety data sheet

Registered company name Gulf Marine Pte. Ltd.
Address 37 Tuas Road 638503 Singapore
Telephone +65 6592 0120
Fax Not Available
Website Not Available
Email sds@gulf-marine.com

Emergency telephone number

Association / Organisation Gulf Marine Pte. Ltd.
Emergency telephone
+65 6592 0120
numbers
Other emergency telephone
Not Available
numbers

SECTION 2 Hazards identification

Classification of the substance or mixture

Classification Not Applicable

Label elements

Hazard pictogram(s) Not Applicable

Signal word Not Applicable

Hazard statement(s)
Not Applicable

Precautionary statement(s) Prevention

Not Applicable

Precautionary statement(s) Response

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Not Applicable

Precautionary statement(s) Storage

Not Applicable

Precautionary statement(s) Disposal

Not Applicable

SECTION 3 Composition / information on ingredients

Substances
See section below for composition of Mixtures

Mixtures
CAS No %[weight] Name
132752-19-3 <1 tetrapropenylphenol derivatives calcium salts
Not Available balance Ingredients determined not to be hazardous

SECTION 4 First aid measures

Description of first aid measures

If this product comes in contact with eyes:
Wash out immediately with water.
Eye Contact
If irritation continues, seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Skin Contact
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Inhalation
Other measures are usually unnecessary.
Immediately give a glass of water.
Ingestion
First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5 Firefighting measures

Extinguishing media
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
Water spray or fog - Large fires only.

Special hazards arising from the substrate or mixture

Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Use water delivered as a fine spray to control fire and cool adjacent area.
Fire Fighting
Avoid spraying water onto liquid pools.
DO NOT approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
Combustible.
Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent rupture of containers.
On combustion, may emit toxic fumes of carbon monoxide (CO).
May emit acrid smoke.
Mists containing combustible materials may be explosive.
Fire/Explosion Hazard Combustion products include:
carbon dioxide (CO2)
phosphorus oxides (POx)
sulfur oxides (SOx)
other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.

SECTION 6 Accidental release measures

Personal precautions, protective equipment and emergency procedures

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See section 8

Environmental precautions
See section 12

Methods and material for containment and cleaning up

Remove all ignition sources.
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Minor Spills Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Wipe up.
Place in a suitable, labelled container for waste disposal.
Moderate hazard.
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
No smoking, naked lights or ignition sources.
Increase ventilation.
Major Spills
Stop leak if safe to do so.
Contain spill with sand, earth or vermiculite.
Collect recoverable product into labelled containers for recycling.
Absorb remaining product with sand, earth or vermiculite.
Collect solid residues and seal in labelled drums for disposal.
Wash area and prevent runoff into drains.
If contamination of drains or waterways occurs, advise emergency services.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

Precautions for safe handling

Hydrogen sulfide (H2S or Sour Gas) may be present when loading and unloading transport vessels. Stay upwind and
away from newly opened hatches and allow to vent thoroughly before handling material. Steam may be used to vent
hatches. Keep all sources of ignition away from loading area.
Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Prevent concentration in hollows and sumps.
DO NOT enter confined spaces until atmosphere has been checked.
Avoid smoking, naked lights or ignition sources.
Safe handling Avoid contact with incompatible materials.
When handling, DO NOT eat, drink or smoke.
Keep containers securely sealed when not in use.
Avoid physical damage to containers.
Always wash hands with soap and water after handling.
Work clothes should be laundered separately.
Use good occupational work practice.
Observe manufacturer's storage and handling recommendations contained within this SDS.
Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions.
DO NOT allow clothing wet with material to stay in contact with skin
Store in original containers.
Keep containers securely sealed.
No smoking, naked lights or ignition sources.
Other information Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Protect containers against physical damage and check regularly for leaks.
Observe manufacturer's storage and handling recommendations contained within this SDS.

Conditions for safe storage, including any incompatibilities

Metal can or drum
Suitable container Packaging as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility Avoid reaction with oxidising agents

SECTION 8 Exposure controls / personal protection

Control parameters

Occupational Exposure Limits (OEL)

INGREDIENT DATA
Not Available
Emergency Limits
Ingredient TEEL-1 TEEL-2 TEEL-3
GulfSea SuperBear 3006 Not Available Not Available Not Available

Ingredient Original IDLH Revised IDLH

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Ingredient Original IDLH Revised IDLH

tetrapropenylphenol derivatives
Not Available Not Available
calcium salts

Occupational Exposure Banding

Ingredient Occupational Exposure Band Rating Occupational Exposure Band Limit
tetrapropenylphenol derivatives
E ≤ 0.01 mg/m³
calcium salts
Notes: Occupational exposure banding is a process of assigning chemicals into specific categories or bands based on a chemical's potency and the
adverse health outcomes associated with exposure. The output of this process is an occupational exposure band (OEB), which corresponds to a
range of exposure concentrations that are expected to protect worker health.

Exposure controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can
be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically
"adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly. The design of a
ventilation system must match the particular process and chemical or contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.

General exhaust is adequate under normal operating conditions. If risk of overexposure exists, wear SAA approved respirator. Correct fit is
essential to obtain adequate protection. Provide adequate ventilation in warehouse or closed storage areas. Air contaminants generated in the
workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to effectively
remove the contaminant.

Type of Contaminant: Air Speed:

0.25-0.5 m/s
solvent, vapours, degreasing etc., evaporating from tank (in still air)
(50-100 f/min)
aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, welding, spray 0.5-1 m/s (100-200
drift, plating acid fumes, pickling (released at low velocity into zone of active generation) f/min.)

Appropriate engineering direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas discharge (active 1-2.5 m/s (200-500
controls generation into zone of rapid air motion) f/min)
grinding, abrasive blasting, tumbling, high speed wheel generated dusts (released at high initial velocity into zone of 2.5-10 m/s
very high rapid air motion). (500-2000 f/min.)

Within each range the appropriate value depends on:

Lower end of the range Upper end of the range

1: Room air currents minimal or favourable to capture 1: Disturbing room air currents
2: Contaminants of low toxicity or of nuisance value only 2: Contaminants of high toxicity
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in motion 4: Small hood - local control only

Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreases
with the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted,
accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of
1-2 m/s (200-400 f/min.) for extraction of solvents generated in a tank 2 meters distant from the extraction point. Other mechanical
considerations, producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by
factors of 10 or more when extraction systems are installed or used.

Individual protection
measures, such as personal
protective equipment

Safety glasses with side shields.

Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent]
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing
the wearing of lenses or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption
Eye and face protection
and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in
their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and
remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in
a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
Skin protection See Hand protection below
Wear chemical protective gloves, e.g. PVC.
Wear safety footwear or safety gumboots, e.g. Rubber
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to
manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance
and has therefore to be checked prior to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be observed when
Hands/feet protection making a final choice.
Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be
washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.
Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:
· frequency and duration of contact,
· chemical resistance of glove material,

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· glove thickness and

· dexterity
Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent).
· When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240
minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.
· When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN
374, AS/NZS 2161.10.1 or national equivalent) is recommended.
· Some glove polymer types are less affected by movement and this should be taken into account when considering gloves for long-term use.
· Contaminated gloves should be replaced.
As defined in ASTM F-739-96 in any application, gloves are rated as:
· Excellent when breakthrough time > 480 min
· Good when breakthrough time > 20 min
· Fair when breakthrough time < 20 min
· Poor when glove material degrades
For general applications, gloves with a thickness typically greater than 0.35 mm, are recommended.
It should be emphasised that glove thickness is not necessarily a good predictor of glove resistance to a specific chemical, as the permeation
efficiency of the glove will be dependent on the exact composition of the glove material. Therefore, glove selection should also be based on
consideration of the task requirements and knowledge of breakthrough times.
Glove thickness may also vary depending on the glove manufacturer, the glove type and the glove model. Therefore, the manufacturers technical
data should always be taken into account to ensure selection of the most appropriate glove for the task.
Note: Depending on the activity being conducted, gloves of varying thickness may be required for specific tasks. For example:
· Thinner gloves (down to 0.1 mm or less) may be required where a high degree of manual dexterity is needed. However, these gloves are only
likely to give short duration protection and would normally be just for single use applications, then disposed of.
· Thicker gloves (up to 3 mm or more) may be required where there is a mechanical (as well as a chemical) risk i.e. where there is abrasion or
puncture potential
Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed
moisturiser is recommended.
Body protection See Other protection below
Overalls.
P.V.C apron.
Other protection Barrier cream.
Skin cleansing cream.
Eye wash unit.

Recommended material(s) Respiratory protection

GLOVE SELECTION INDEX Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001,
Glove selection is based on a modified presentation of the: ANSI Z88 or national equivalent)
"Forsberg Clothing Performance Index". Selection of the Class and Type of respirator will depend upon the level of breathing
The effect(s) of the following substance(s) are taken into account in the computer- zone contaminant and the chemical nature of the contaminant. Protection Factors
generated selection: (defined as the ratio of contaminant outside and inside the mask) may also be important.
GulfSea SuperBear 3006
Required Maximum gas/vapour
Material CPI Half-face Full-Face
minimum concentration present in air
Respirator Respirator
NATURAL RUBBER A protection factor p.p.m. (by volume)

NATURAL+NEOPRENE A A-AUS /
up to 10 1000 -
Class1 P2
NEOPRENE A
A-AUS /
NEOPRENE/NATURAL A up to 50 1000 -
Class 1 P2
NITRILE A up to 50 5000 Airline * -
NITRILE+PVC A up to 100 5000 - A-2 P2
PE/EVAL/PE A up to 100 10000 - A-3 P2
PVC A 100+ Airline**
TEFLON A
* - Continuous Flow ** - Continuous-flow or positive pressure demand
PVA B A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or
hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur
* CPI - Chemwatch Performance Index dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO =
A: Best Selection Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic
B: Satisfactory; may degrade after 4 hours continuous immersion compounds(below 65 degC)
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove, a final Cartridge respirators should never be used for emergency ingress or in areas of
selection must be based on detailed observation. - unknown vapour concentrations or oxygen content.
* Where the glove is to be used on a short term, casual or infrequent basis, factors such The wearer must be warned to leave the contaminated area immediately on
as "feel" or convenience (e.g. disposability), may dictate a choice of gloves which might detecting any odours through the respirator. The odour may indicate that the mask is
otherwise be unsuitable following long-term or frequent use. A qualified practitioner not functioning properly, that the vapour concentration is too high, or that the mask is
should be consulted. not properly fitted. Because of these limitations, only restricted use of cartridge
respirators is considered appropriate.
Ansell Glove Selection Cartridge performance is affected by humidity. Cartridges should be changed after 2
hr of continuous use unless it is determined that the humidity is less than 75%, in
Glove — In order of recommendation which case, cartridges can be used for 4 hr. Used cartridges should be discarded
daily, regardless of the length of time used
AlphaTec 02-100
AlphaTec® 15-554
AlphaTec® Solvex® 37-185
AlphaTec® 38-612
AlphaTec® 53-001
AlphaTec® 58-005
AlphaTec® 58-008
AlphaTec® 58-530B

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AlphaTec® 58-530W
AlphaTec® 58-735

The suggested gloves for use should be confirmed with the glove supplier.

SECTION 9 Physical and chemical properties

Information on basic physical and chemical properties

Appearance Brown colored liquid; does not mix with water. Brown

Physical state Liquid Relative density (Water = 1) 0.8929 (15°C)

Partition coefficient n-octanol
Odour Not Available Not Available
/ water
Odour threshold Not Available Auto-ignition temperature (°C) Not Available
Decomposition
pH (as supplied) Not Applicable Not Available
temperature (°C)
Melting point / freezing point
Not Available Viscosity (cSt) 11.1 (100°C)
(°C)
Initial boiling point and boiling
Not Available Molecular weight (g/mol) Not Applicable
range (°C)
Flash point (°C) 220 Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Applicable Oxidising properties Not Available
Surface Tension (dyn/cm or
Upper Explosive Limit (%) Not Available Not Available
mN/m)
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water Immiscible pH as a solution (1%) Not Applicable
Vapour density (Air = 1) Not Available VOC g/L Not Available

SECTION 10 Stability and reactivity

Reactivity See section 7

Unstable in the presence of incompatible materials.
Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.
Possibility of hazardous
See section 7
reactions
Conditions to avoid See section 7
Incompatible materials See section 7
Hazardous decomposition
See section 5
products

SECTION 11 Toxicological information

Information on toxicological effects

The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives using animal
Inhaled models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an
occupational setting.
The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because of the lack of
Ingestion
corroborating animal or human evidence.
Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce health damage
following entry through wounds, lesions or abrasions.
Skin Contact Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin
prior to the use of the material and ensure that any external damage is suitably protected.
Although the liquid is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce transient discomfort
Eye
characterised by tearing or conjunctival redness (as with windburn).
Chronic Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure.

TOXICITY IRRITATION
GulfSea SuperBear 3006
Not Available Not Available

tetrapropenylphenol TOXICITY IRRITATION

derivatives calcium salts Not Available Not Available

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS. Unless otherwise
specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

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No significant acute toxicological data identified in literature search.

for tetrapropenyl phenol and its derivatives.
The chemical possesses properties indicating a potential hazard for human health (effects on fertility and developmental toxicity at doses that
also cause maternal toxicity). Adequate screening-level data are available to characterize the human health hazard for the purposes of the OECD
Cooperative Chemicals Assessment Programme
SID Initial Assessment Profile (SIAM 22, 18-21 April 2006)
for para-C12-alkylphenols (typically tetrapropenylphenol)
Based on the toxicological findings presented in this review, para-C12-alkylphenols do not appear to meet the EU criteria for classification for
acute toxicity by the oral and dermal routes of exposure, skin sensitisation, repeated dose toxicity or mutagenicity. No information is available
relating to acute toxicity via inhalation exposure, and carcinogenicity. The following characteristics do suggest that the substance warrants
consideration for classification:
Irritation: para-C12-alkylphenols apparently meet the EU criteria for classification as a skin irritant and a severe eye irritant. Classification for
corrosivity could be considered.
Reproductive toxicity: • Fertility: The treatment-related effects on fertility, with supporting pathological changes indicating site of action, appear
to meet the EU criteria for classification. The observation that the fertility effects only occurred in the presence of general toxicity might need to be
taken into account in deciding the most appropriate category. Overall, these findings suggest that category 2 classification for acute toxicity may
be most appropriate, although arguments for category 3 might be considered.
Developmental toxicity: para-C12-alkylphenols caused craniofacial (cleft palate, 3 pups from 1 litter) and long bone malformations (bent long
bones) in rats, but only at doses that caused some non-specific maternal toxicity (reduced body weight gain). These findings are not considered
to be a secondary non- specific consequence of general toxicity and hence classification for developmental toxicity should be considered. A
decision on whether category 2 or 3 is most appropriate may need expert consideration.
Classification for the environment
The substance is classified by the producers as ‘dangerous to the environment (with the symbol N) with the following risk phrases:
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
This is based on the following data:
· Aquatic toxicity: 48-hour Daphnia EC50 <1 mg/L;
· log Kow >3 and measured fish bioconcentration factor of 823;
· Not readily biodegradable.
Acute toxicity data for the oral route of exposure are available for the rat only. LD50 values of 2,100 and 2,200 mg/kg were obtained in two
separate studies. In one study, no deaths were observed with a single oral dose of 500 mg/kg but one rat at this dose level showed bloody urine
that persisted for 48 hours post-dosing. A NOAEL for the effects of a single oral dose cannot be determined. Signs of toxicity observed in the
acute oral toxicity studies included ruffled fur, diarrhoea, diuresis, retarded motion and ataxia.
Dermal: Two studies are available, both in rabbits. The findings indicate that deaths occur with doses above 3,160 mg/kg, and an LD50 of 15,000
mg/kg has been reported. Studies in rabbits indicate that tetrapropenylphenol is a severe skin irritant.
Eye: Studies in rabbits indicate that tetrapropenylphenol is an eye irritant capable of causing corneal opacity and iritis.
Respiratory tract: No data are available concerning respiratory tract irritancy. Given the evidence for skin and eye irritancy, it might be expected
TETRAPROPENYLPHENOL that inhaled tetrapropenylphenol would irritate the respiratory tract.
DERIVATIVES CALCIUM Corrosivity: Necrosis and eschar formation have been reported following dermal application of tetrapropenylphenol to rabbits. From the data
SALTS available it is uncertain whether or not tetrapropenylphenol should be regarded as corrosive or as a severe skin irritant.
Sensitisation: Tetrapropenylphenol was not identified as a cause of skin sensitisation in two studies in guinea pigs
Repeated dose toxicity: Repeated dosing of tetrapropenylphenol to rats in oral studies, both dietary and gavage, produces effects in a number
of organs including the reproductive organs in both sexes.
In the 28-day gavage study in rats, no toxicologically significant treatment-related effects were observed at 5 mg/kg/day. At the next higher dose
of 20 mg/kg/day, adrenal cortical gland hypertrophy was observed in male rats. At 180 mg/kg/day and above, pathological changes and organ
weight changes were observed in a number of organs, including prominent changes in the reproductive organs in both sexes.
In the dietary studies, effects on the testes were noted at 250 mg/kg/day (28-day study) and 106 mg/kg/day (90-day study). No treatment-related
toxicological effects were seen in the dietary studies at 25 and 28 mg/kg/day respectively.
No treatment-related changes were reported in dogs at doses up to 4,000 ppm in the diet (estimated by the author to be equivalent to 180
mg/kg/day assuming a body weight of 11 kg and a daily food consumption of 0.5 kg). The absence of treatment- related changes in dogs
suggests the existence of a species difference.
Genotoxicity: From the in vitro and in vivo studies available it can be concluded that tetrapropenylphenol is not mutagenic.
Carcinogenicity: There are no carcinogenicity studies available for tetrapropenylphenol. Given the lack of evidence for mutagenicity it is likely
that if tetrapropenylphenol had the potential to cause cancer it would involve a threshold mechanism. It is uncertain whether or not the effects on
the uterus and the endometrial gland cysts in the one-generation fertility study at the top dose of 125 mg/kg/day indicate the possibility of uterine
cancer at these sites following prolonged exposure.
Reproductive toxicity: Tetrapropenylphenol has an adverse effect on fertility in rats, causing a marked reduction in fertility at 125 mg/kg/day. At
doses of 25 mg/kg/day and above tetrapropenylphenol causes a reduction in mean pup weight and pathological changes in the reproductive
organs of both sexes. The reduction in fertility and effects on reproductive organs occurred at doses that also caused other toxic effects, including
reduced bodyweight gain and food consumption and changes in the adrenals, kidneys and liver. However, this toxicity was not considered to be
particularly severe such that the adverse effects on fertility could have been a secondary non-specific consequence of general toxicity. The
NOAEL for reproductive effects is 5 mg/kg/day.
Developmental toxicity: Tetrapropenylphenol is also a developmental toxicant in rats, causing teratogenic effects as shown by cleft palate and
ectodactyly (reduced number of digits) as well as a general increase in the total number of skeletal malformations at 300 mg/kg/day. These
manifestations of developmental toxicity occurred in the presence of overt maternal toxicity, indicated by a significant reduction in body weight
gain.
Environmental risk evaluation report: para-C12-alkylphenols (dodecylphenol and tetrapropenylphenol): Environment Agency UK
Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a non-allergic condition
known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of highly irritating compound. Main
criteria for diagnosing RADS include the absence of previous airways disease in a non-atopic individual, with sudden onset of persistent
asthma-like symptoms within minutes to hours of a documented exposure to the irritant. Other criteria for diagnosis of RADS include a reversible
airflow pattern on lung function tests, moderate to severe bronchial hyperreactivity on methacholine challenge testing, and the lack of minimal
lymphocytic inflammation, without eosinophilia. RADS (or asthma) following an irritating inhalation is an infrequent disorder with rates related to
the concentration of and duration of exposure to the irritating substance. On the other hand, industrial bronchitis is a disorder that occurs as a
result of exposure due to high concentrations of irritating substance (often particles) and is completely reversible after exposure ceases. The
disorder is characterized by difficulty breathing, cough and mucus production.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin
STOT - Repeated Exposure
sensitisation
Mutagenicity Aspiration Hazard
Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

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SECTION 12 Ecological information

Toxicity

Endpoint Test Duration (hr) Species Value Source

GulfSea SuperBear 3006 Not Not Not
Not Available Not Available
Available Available Available

Endpoint Test Duration (hr) Species Value Source

tetrapropenylphenol
derivatives calcium salts Not Not Not
Not Available Not Available
Available Available Available

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 4. US EPA,
Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan)
- Bioconcentration Data 8. Vendor Data

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
No Data available for all ingredients No Data available for all ingredients

Bioaccumulative potential
Ingredient Bioaccumulation
No Data available for all ingredients

Mobility in soil
Ingredient Mobility
No Data available for all ingredients

SECTION 13 Disposal considerations

Waste treatment methods

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws operating in their
area. In some areas, certain wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:
Reduction
Reuse
Recycling
Disposal (if all else fails)
This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has been
contaminated, it may be possible to reclaim the product by filtration, distillation or some other means. Shelf life considerations should also be
Product / Packaging disposal applied in making decisions of this type. Note that properties of a material may change in use, and recycling or reuse may not always be
appropriate.
DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
Where in doubt contact the responsible authority.
Recycle wherever possible or consult manufacturer for recycling options.
Consult State Land Waste Authority for disposal.
Bury or incinerate residue at an approved site.
Recycle containers if possible, or dispose of in an authorised landfill.

SECTION 14 Transport information

Labels Required

Marine Pollutant NO

Land transport (UN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

14.7.1. Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable

14.7.2. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
tetrapropenylphenol derivatives
Not Available
calcium salts

Continued...
Chemwatch: 5612-19 Page 9 of 9 Issue Date: 20/06/2023
Part Number: Print Date: 24/01/2024
GulfSea SuperBear 3006
Version No: 3.1

14.7.3. Transport in bulk in accordance with the IGC Code

Product name Ship Type
tetrapropenylphenol derivatives
Not Available
calcium salts

SECTION 15 Regulatory information

Safety, health and environmental regulations / legislation specific for the substance or mixture

tetrapropenylphenol derivatives calcium salts is found on the following regulatory lists

Not Applicable

Additional Regulatory Information

Not Applicable

National Inventory Status

National Inventory Status
Australia - AIIC / Australia
No (tetrapropenylphenol derivatives calcium salts)
Non-Industrial Use
Canada - DSL No (tetrapropenylphenol derivatives calcium salts)
Canada - NDSL Yes
China - IECSC No (tetrapropenylphenol derivatives calcium salts)
Europe - EINEC / ELINCS / NLP No (tetrapropenylphenol derivatives calcium salts)
Japan - ENCS No (tetrapropenylphenol derivatives calcium salts)
Korea - KECI No (tetrapropenylphenol derivatives calcium salts)
New Zealand - NZIoC Yes
Philippines - PICCS No (tetrapropenylphenol derivatives calcium salts)
USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ No (tetrapropenylphenol derivatives calcium salts)
Vietnam - NCI Yes
Russia - FBEPH No (tetrapropenylphenol derivatives calcium salts)
Yes = All CAS declared ingredients are on the inventory
Legend:
No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require registration.

SECTION 16 Other information

Revision Date 20/06/2023

Initial Date 13/06/2023

Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or
other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication and may be subject to modification from
time to time. It is the user's responsibility to verify that this Safety Data Sheet is current prior to use or application. The information given is designed only as a guidance for safe
handling, use, application, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

end of SDS