Safety Data Sheet: 1. Identification of The Substance/Preparation and of The Company Decant Oil
Safety Data Sheet: 1. Identification of The Substance/Preparation and of The Company Decant Oil
Safety Data Sheet: 1. Identification of The Substance/Preparation and of The Company Decant Oil
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label elements
Danger
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Other Information
May be harmful if swallowed. Causes mild skin irritation. Toxic to aquatic life.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No Percent
Clarified oils (petroleum), catalytic cracked; Heavy 64741-62-4 0-100
Fuel oil
Distillates (petroleum), heavy cracked; Heavy Fuel 64741-61-3 0-50
oil
Distillates (petroleum), intermediate catalytic 64741-60-2 0-20
cracked; Cracked gasoil
Sulfur 7704-34-9 0-2
Hydrogen Sulfide 7783-06-4 0-<1
Polycyclic Aromatic Hydrocarbons 130498-29-2 0-<0.2
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Inhalation Remove from exposure, lie down. If breathing has stopped, give artificial respiration. Get
medical attention immediately. If breathing is difficult, administer oxygen. If symptoms
persist, call a physician.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep
eye wide open while rinsing. Do not rub affected area.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. If symptoms persist, call a physician.
Ingestion Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person. Call a physician.
Self-protection of the first aider Remove all sources of ignition. Ensure that medical personnel are aware of the material(s)
involved, take precautions to protect themselves and prevent spread of contamination. Use
personal protective equipment as required. See section 8 for more information. Wear
personal protective clothing (see section 8).
5. FIRE-FIGHTING MEASURES
Small Fire Any extinguisher suitable for Class B fires, dry chemical, CO2, foam (AFFF/ATC), or water
spray can be used.
Large Fire Water spray, fog or alcohol-resistant foam. CAUTION: Use of water spray when fighting fire
may be inefficient. Cool containers with flooding quantities of water until well after fire is out.
Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient.
Specific hazards arising from the Risk of ignition. Keep product and empty container away from heat and sources of ignition.
chemical In the event of fire, cool tanks with water spray. Fire residues and contaminated fire
extinguishing water must be disposed of in accordance with local regulations.
Hazardous combustion products Smoke, CO, and other products of incomplete combustion.
Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge Yes.
Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout
fire-fighters gear. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible
withdraw from area and let fire burn.
Further information ALWAYS stay away from tanks engulfed in fire. Fight fire from maximum distance or use
unmanned hose holders or monitor nozzles. Withdraw immediately in case of rising sound
from venting safety devices or discoloration of tank. Do not direct water at source of leak or
safety devices; icing may occur. Cool containers with flooding quantities of water until well
after fire is out. Do not allow run-off from fire-fighting to enter drains or water courses.
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Personal precautions Evacuate personnel to safe areas. Use personal protective equipment as required. See
section 8 for more information. Avoid contact with skin, eyes or clothing. Ensure adequate
ventilation. Keep people away from and upwind of spill/leak. ELIMINATE all ignition sources
(no smoking, flares, sparks or flames in immediate area). Pay attention to flashback. Take
precautionary measures against static discharges. All equipment used when handling the
product must be grounded. Do not touch or walk through spilled material.
Other Information Ventilate the area. Refer to protective measures listed in Sections 7 and 8.
Environmental precautions
Environmental precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage
if safe to do so. Prevent product from entering drains.
Methods for containment Stop leak if you can do it without risk. Do not touch or walk through spilled material. A vapor
suppressing foam may be used to reduce vapors. Dike far ahead of spill to collect runoff
water. Keep out of drains, sewers, ditches and waterways. Absorb with earth, sand or other
non-combustible material and transfer to containers for later disposal.
Methods for cleaning up Take precautionary measures against static discharges. Dam up. Soak up with inert
absorbent material. Pick up and transfer to properly labeled containers.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
Advice on safe handling Use personal protection equipment. Avoid contact with skin and eyes. Avoid breathing
vapors or mists. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use
grounding and bonding connection when transferring this material to prevent static
discharge, fire or explosion. Use with local exhaust ventilation. Use spark-proof tools and
explosion-proof equipment. Keep in an area equipped with sprinklers. Use according to
package label instructions. Handle in accordance with good industrial hygiene and safety
practice. Avoid contact with skin, eyes or clothing.
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from
heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static
electricity). Keep in properly labeled containers. Do not store near combustible materials.
Keep in an area equipped with sprinklers. Store in accordance with the particular national
regulations. Store in accordance with local regulations. Store locked up.
Skin and body protection Wear suitable protective clothing. Long sleeved clothing. Chemical resistant apron.
Antistatic boots.
Respiratory protection When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators. Use a NIOSH approved respirator when there is a potential
for airborne concentrations to exceed occupational exposure limits. Refer to OSHA 29 CFR
1910.134, ANSI Z88.2, NIOSH Respirator Decision Logic, and the respirator manufacturer
for additional guidance on respiratory protection selection. A Self-Contained Breathing
Apparatus (SCBA) should be used for fire fighting. Use a NIOSH approved
positive-pressure supplied air respirator if there is a potential for uncontrolled release,
exposure levels are unknown, in oxygen deficient (less than 19.5% oxygen), or any other
circumstance where an air-purifying respirator may not provide adequate protection.
General hygiene considerations Do not eat, drink or smoke when using this product. Contaminated work clothing should not
be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is
recommended. Wash hands before breaks and immediately after handling the product.
Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection.
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Inhalation May cause central nervous system depression with nausea, headache, dizziness, vomiting,
and incoordination. The burning of any hydrocarbon as a fuel in an area without adequate
ventilation may result in hazardous levels combustion products, including carbon monoxide
(CO), and inadequate oxygen levels, which may cause unconsciousness, suffocation, and
death. Hydrogen sulfide can cause respiratory paralysis and death, depending on
concentration and duration of exposure. The "rotten egg" odor of hydrogen sulfide is not a
reliable indicator of exposure, since olfactory fatigue (loss of smell) will occur.
Eye contact Contact with product at elevated temperatures can result in thermal burns. Liquid splashed
in the eyes may cause irritation and reversible damage.
Skin contact May be absorbed through the skin in harmful amounts. Harmful in contact with skin.
Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. May be
harmful if swallowed and enters airways.
Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.
Acute toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 2,395.00 mg/kg
ATEmix (dermal) 1,164.00 mg/kg
ATEmix (inhalation-gas) 35,512.76 mg/l
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Delayed and immediate effects as well as chronic effects from short and long-term exposure
Chemical Name
Distillates (petroleum), heavy Heavy Fuel Oils (HFO) may be fatal if they are swallowed and enter the airway. If inhaled,
cracked; Heavy Fuel oil short-term overexposure can cause immediate unconsciousness and death. In animal
studies, substances in the Heavy Fuel Oil Category demonstrate low oral and dermal
toxicity, minimal eye irritation, minimal to moderate skin irritation with single exposures and
are not skin sensitizers. The other mammalian health effects of HFOs are dependent on
their content of polycyclic aromatic compounds (PAC). PAC content and aromatic ring class
distribution profiles are determined by crude oil stock and the nature and severity of
processing. Repeated dose studies indicate that dermal toxicity induced by different HFO
streams affected essentially the same organ systems (liver, spleen, thymus and bone
marrow). Most studies from these streams did not report adverse effects on fertility, but
some streams caused fetal toxicity. Genetic toxicity studies in vitro demonstrate that many
streams in the heavy fuel oil category are gene mutagens. The carcinogenicity of individual
petroleum streams varies due to factors such as source and processing; IARC and ECHA
C&L Inventory reports individually on the carcinogenicity of these substances.
Distillates (petroleum), intermediate Gas oils and distillate fuels may be fatal if they are swallowed and enter the airway. If
catalytic cracked; Cracked gasoil inhaled, short-term overexposure can cause disorientation, nausea, vomiting, signs of
central nervous system effects such as headache or disorientation, immediate
unconsciousness and death. In animal studies, gas oil streams and distillate fuels
demonstrated minimal acute toxicity by the oral, dermal and inhalation routes, minimal eye
irritation, moderate to severe skin irritation with 24 hours exposure, and no dermal
sensitization. Generally, results suggest that the degree of toxicity is associated with the
concentrations and ring distributions of aromatic constituents in the fuels. When dermal
exposures last 24 hours or longer, moderate to severe skin irritation, but not sensitization,
has been reported in animal studies. Repeated dermal exposures have been reported to
cause systemic effects in animals, including changes in liver and thymus weight and blood
chemistry. Some gas oil streams and distillate fuels can cause gene mutations in studies
using bacteria and animal tissue. Results of developmental studies with gas oils
demonstrate that some gas oils induce developmental effects and others do not. Effects
observed include reduced litter size through resorptions, lower body weights, and fetal
malformations were reported for 2 members of the category. Studies in animals indicate
that gas oils and distillate fuels are potential skin carcinogens after repeated skin
application, but are not associated with tumors in other parts of the body (systemic tumors).
The carcinogenicity of individual petroleum streams varies due to factors such as source
and processing; IARC and ECHA C&L Inventory reports individually on the carcinogenicity
of these substances.
Hydrogen Sulfide Hydrogen Sulfide may be fatal if inhaled. The nervous system and respiratory tract are the
main targets of hydrogen sulfide toxicity. Short term (acute) overexposure may cause
irritation to the eyes, nose or throat. At high enough levels, effects on the nervous system
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No information available.
Carcinogenicity Classification based on data available for ingredients. Contains a known or suspected
carcinogen.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
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Component Information
Chemical Name Partition coefficient
Hydrogen Sulfide 0.45
7783-06-4
Waste from residues/unused Should not be released into the environment. Dispose of in accordance with local
products regulations. Dispose of waste in accordance with environmental legislation.
Contaminated packaging Empty containers pose a potential fire and explosion hazard. Do not cut, puncture of weld
containers.
Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes
Hydrogen Sulfide U135 - - U135
7783-06-4
Polycyclic Aromatic - Included in waste stream: - -
Hydrocarbons K022
130498-29-2
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Quantities Substances
Hydrogen Sulfide 100 lb - - X
7783-06-4
Polycyclic Aromatic - X - -
Hydrocarbons
130498-29-2
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crude oil, and products (both finished and intermediate) from the crude oil refining process and any indigenous components of such
from the CERCLA Section 103 reporting requirements. However, other federal reporting requirements, including SARA Section
304, as well as the Clean Water Act may still apply.
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California Proposition 65
This product does not contain any Proposition 65 chemicals.
US State Regulations
Disclaimer
Tesoro Companies, Inc. (Tesoro) provides the information on this Safety Data Sheet (SDS) in order to meet its obligations
under 29 CFR 1910.1200, and does not hereby make any guarantee of product specifications or suitability for any
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information provided on this SDS. The end user of the product has the responsibility for evaluating the adequacy of the
data under the conditions of use, determining the safety, toxicity and suitability of the product under these conditions,
and obtaining additional or clarifying information where uncertainty exists. No guarantee expressed or implied is made as
to the effects of such use, the results to be obtained, or the safety and toxicity of the product in any specific application.
Furthermore, the information herein is not represented as absolutely complete, since it is not practicable to provide all
relevant information in the format of this document, since additional information may be necessary under exceptional
conditions of use, and since Tesoro prepared this SDS based on information available on the date of its publication.
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