SAFETY DATA SHEET

Creation Date Dec. 4 2018 Revision Date 8 April 2020 Revision # 02

1. Identification
Product Name: Alcohol 94% Alc/Vol, Rhum 95% alc/vol, Alcohol 96%

Cat No. : +12209012, 995556S, 991497S

Synonyms Ethyl alcohol 94 - 96 %, Ethanol

Recommended Use General Solvent for food, beverage, drug, pesticide or biocidal use

Uses advised against Use in accordance with manufacturer’s recommendations

Details of the supplier of the safety data sheet

Company Emergency Telephone Number

Kruger Wines and Spirits 450-645-9777
500 D’Avaugour Street
Suite 2050
Boucherville, Quebec,
Canada, J4B 0G6
Tel: (450) 645-9777

2. Hazard(s) identification
Physical hazards Flammable liquids Category 2
Health hazards Serious eye damage/eye irritation Category 2
OSHA defined hazards Not classified

Label Elements

Signal Word: Danger

Hazard Statements: Highly flammable liquid and vapor. Causes serious irritation

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 Precautionary Statements
Prevention Keep away from heat/sparks/open flames/hot surfaces-no smoking. Keep container tightly closed
Ground/bond container and receiving equipment. Use explosion-proof electrical electrical/ventilation
/lighting equipment. Use only non-sparking tools. Take precautionary measure against static discharge.
Wash thoroughly after handling. Wear protective gloves/eye protection/face protection

Response If on skin(hair). Take off immediately all conamining clothing. Rinse skin with water/shower. If eyes If in
eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. In case of fire:

If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Continue rinsing. If eye
irritation persists: Get medical advice/attention.

Fire Use appropriate media to extinguish.

Storage Store in a well-ventilated place. Keep cool.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.

Hazards not otherwise

classified (HNOC): No known

Other hazards: None

Unknown Acute Toxicity

3. Composition / information on ingredients

Component CAS-No Weight %
Ethyl alcohol 64-17-5 93-96
Water 7732-18-5 4-7

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 4. First-aid measures
General Advice

Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and
persits

Skin Contact: Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical
attention if irritation develops and persists.

Inhalation Move to fresh air. Call a physician if symptoms develop or persist.

Ingestion Rinse mouth. Get medical attention if symptoms occur.

Most important symptoms/effects: Headache. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling,
and blurred vision. Coughing.

Notes to Physician Provide general supportive measures and treat symptomatically. Thermal burns: Flush with
water immediately. While flushing, remove clothes which do not adhere to affected area.
Call an ambulance. Continue flushing during transport to hospital. Keep victim under
observation

5. Fire-fighting measures
Suitable Extinguishing Media: Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).

Unsuitable Extinguishing Media Do not use water jet as an extinguisher, as this will spread the fire.

Specific Hazards Arising from

the Chemical Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a
source of ignition and flash back. During fire, gases hazardous to health may be formed.
Combustion products may include: carbon oxides..

Hazardous Combustion

Protective Equipment and Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Products

Precautions for Firefighters In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
so without risk. Use water spray to keep fire-exposed containers cool.

Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.

General fire hazards Highly flammable liquid and vapor.

NFPA
Health Flammability Instability Physical hazards
2 3 1 N/A

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 6. Accidental release measures
Personal Precautions Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
Protective equipment ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
And emergency procedures protective equipment and clothing during clean-up. Do not touch damaged containers or spilled
material unless wearing appropriate protective clothing. Ventilate closed spaces before entering
them. Local authorities should be advised if significant spillages cannot be contained. For
personal protection, see section 8 of the SDS.

Methods for Containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
and Clean Up combustibles (wood, paper, oil, etc.) away from spilled material. Take precautionary measures
against static discharge. Use only non-sparking tools. This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this ispossible.
Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Following product recovery, flush area with water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental
precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage

Handling precaution Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. When using do not smoke. Explosion-proof general and local exhaust
ventilation. Take precautionary measures against static discharges. All equipment used when
handling the product must be grounded. Use non-sparking tools and explosion-proof equipment.
Avoid contact with eyes. Avoid prolonged exposure. Wear appropriate personal protective
equipment. Observe good industrial hygiene practices.

Storage ondition Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using
common bonding and grounding techniques. Store in a cool, dry place out of direct sunlight. Store
in tightly closed container. Store in a well-ventilated place. Keep in an area equipped with
sprinklers. Store away from incompatible ma Mterials (see Section 10 of the SD

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 Exposure Guidelines

Component TYPE VALUE

Ethyl alcohol (CAS 64-17-5) STEL 1000 ppm

USA OELs (Occupational Health &

Safety Code)

Ethyl alcohol (CAS 64-17-5) TWA 1880 mg/M3

1000 ppm
Canada Alberta OELs (Occupational
Health & Safety Code)
Ethyl alcohol (CAS 64-17-5) STEL 1000 ppm

Canada British-Cololumbia OELs

(Occupational Health & Safety Code)
Ethyl alcohol (CAS 64-17-5) STEL 1000 ppm

Canada Manitoba OELs (Occupational

Health & Safety Code)
Ethyl alcohol (CAS 64-17-5) STEL 1000 ppm

Canada Ontario OELs (Occupational

Health & Safety Code)

Ethyl alcohol (CAS 64-17-5) TWA 1880 mg/M3

1000 ppm
Canada Quebec OELs (Occupational
Health & Safety Code)
Ethyl alcohol (CAS 64-17-5) 15 minutes 1250 ppm
8 hours 1000 ppm
Canada Saskatchewan OELs
(Occupational Health & Safety Code)

Biological limit values No biological exposure limits noted for the ingredient(s).

Appropriate engineering Explosion-proof general and local exhaust ventilation. Good general ventilation should be used.
controls Ventilation rates should be matched to conditions. If applicable, use process enclosures, local
exhaust ventilation, or other engineering controls to maintain airborne levels below recommended
exposure limits. If exposure limits have not been established, maintain airborne levels to an
acceptable level. Provide eyewash station and safety shower.

Individual protection measures, such as personal protective equipment

Eye/face protection Chemical goggles are recommended.

Skin protection Wear appropriate chemical resistant gloves. Nitrile, butyl rubber or neoprene gloves are
Hand protection recommended. Other suitable gloves can be recommended by the glove supplier. Be aware that
the liquid may penetrate the gloves. Frequent change is advisable

Skin protection
Other Wear appropriate chemical resistant clothing.

Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
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 been established), an approved respirator must be worn.

Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene When using do not smoke. Always observe good personal hygiene measures, such as washing
considerations after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants.

Legend
ACGIH – American Conference of Governmental Industrial Hygienist
OSHA – Occupational Safety and Health Association
NIOSH IDLH: The National Institute for Occupational Safety and Health immediatelyDangerous to life or Health

9. Physical and chemical properties

Appearance
Physical State Liquid
Form Liquid
Color Clear liquid invisible vapor

Odor: Sweet. Alcohol-like

Odor Threshold Not available

pH 6.0-7.0

Melting Point/Range -115- -87°C

Boiling Point/Range 78 - 80°C
Flash Point 15 - 20°C closed cup
Evaporation Rate Expected to be rapid
Flammability (solid, gas)
Flammability or explosive limits
Upper 3.3% (100% Ethanol)
Lower 19% (100% Ethanol)
Vapor Pressure 59.5 hPa (for 100% Ethanol) (68 °F (20 °C))
Vapor density 1.6
Relative density 0.796 - 0.825 g/ml (77 °F (25 °C))
Solubility(ies)
Solubility (water) Miscible.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature 363 °C (for 100% Ethanol)
Decomposition temperature Not available.
Viscosity Not available.
Other information
Explosive properties Not explosive.
Molecular formula C2H60 (Ethanol)
H2O (Water)
Molecular weight 18.02 g/mol (Water)
46.07 g/mol (Ethanol)
Oxidizing properties Not oxidizing.

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 10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.

Chemical stability Material is stable under normal conditions.

Possibility of hazardous Hazardous polymerization does not occur.

Reactions

Conditions to avoid Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Avoid
temperatures exceeding the flash point. Contact with incompatible materials.

Incompatible materials Strong oxidizing agents.

Hazardous decomposition No hazardous decomposition products are known.

products

11. Toxicological information

Information on likely routes of exposure

Inhalation Prolonged inhalation may be harmful.

Skin contact Prolonged skin contact may cause temporary irritation.

Eye contact Causes serious eye irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the
physical, chemical and
toxicological characteristics
Headache. Severe eye irritation. Symptoms may include stinging, tearing, redness,
swelling, and blurred vision. Coughing.
Information on toxicological effects
Acute toxicity

Component LD50 Oral LD50 Dermal LC50 Inhalation

Ethyl alcohol (CAS 64-17-5) 34560 mg/kg (mouse) Not Listed 117-125 mg/L 4 hours (rat)
10470 mg/kg (rat)

Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.

Serious eye damage/eye Causes serious eye irritation.
Irritation

Respiratory or skin sensitization

Respiratory sensitization Not a respiratory sensitizer.

Skin sensitization This product is not expected to cause skin sensitization.

Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1%
are mutagenic or genotoxic.

Carcinogenicity Not classifiable as to carcinogenicity to humans

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 Reproductive toxicity This product is not expected to cause reproductive or
developmental effects

Specific target organ toxicity - Not classifed

single exposure

Specific target organ toxicity

–repeated exposure Not classified

Aspiration hazard Not an aspiration hazard.

Chronic effects Prolonged inhalation may be harmful.

Delayed and immediate effects as well as chronic effects from short and long-term exposu

Component CAS-No IARC NTP ACGIH OSHA Mexico

Ethyl alcohol 64-17-5 Group 1 Known A3 x Not Listed

IARC: (International Agency for Research on Cancer)

IARC: (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
Group 2A - Probably Carcinogenic to Humans
Group 2B - Possibly Carcinogenic to Humans

NTP: (National Toxicity Program)

NTP: (National Toxicity Program)
Known - Known Carcinogen Reasonably Anticipated –
Reasonably Anticipated to be a Human carcinogen

ACGIH: (American Conference of Governmental Industrial

Hygienists)
A1-Known Human Carcinogen
A2 - Suspected Human Carcinogen
A3 - Animal Carcinogen
ACGIH: (American Conference of Governmental Industrial
Hygienists)

Mexico - Occupational Exposure Limits - Carcinogens

Mexico - Occupational Exposure Limits - Carcinogens
A1 - Confirmed Human Carcinogen
A2 - Suspected Human Carcinogen
A3 - Confirmed Animal Carcinogen
A4 - Not Classifiable as a Human Carcinogen
A5 - Not Suspected as a Human Carcinogen

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 12. Ecological information
Ecotoxicit The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Component Freshwater Marine Fish Invertebrate Microtox Terrestial

Algae water algae

EC10 11.5 mg/ l 1900 mg/l LC50 11200 mg/l EC50 5012 LC50 5800 EC50 633m
Ethyl alcohol 72 Hr 24 Hr mg/l 48 Hr mg/l 4 Hr g/kg dw
(CAS 64-17-5) NOEC 1580 Plant
EC-50 275 mg/l mg/l NOEC 250 mg/l NOEC 9.6
72 Hr mg/l

Persistence and Degradability Persistence is unlikely based on information available.

Bioaccumulative potential No data available for this product.

Mobility in soil This product is miscible in water.

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
Mobility

Component log Pow

Ethyl alcohol -0.32

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Do not incinerate sealed
containers. Dispose of contents/container in accordance with local/regional/national/international
regulations

Local disposal regulations Dispose in accordance with all applicable regulations.

Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.

Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
Products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).

Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container
is emptied. Empty containers should be taken to an approved waste handling site for recycling
or disposal.

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 14. Transport information

DOT
UN-No UN1170
Proper Shipping Name Ethanol solution
Class 3
Subsidiary group -
Label 3
Packing Group II
Environmental hazards
Marine pollutant No.

Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions 24, IB2, T4, TP1
Packaging exceptions 4b, 150
Packaging non bulk 202
Packaging bulk 242

TDG
UN-No UN1170
Proper Shipping Name Ethanol solution
Hazard Class 3
Packing Group II

IATA
UN-No UN1170
Proper Shipping Name Ethanol solution
Transport Hazard Class
Class 3
Subsidiary risk -
Packing Group II
Environmental No
ERG code 3L
Special precaution for user Read safety instruction, SDS and emergency procedure before handling.

IMDG/IMO
UN-No UN1170
Proper Shipping Name Ethanol Solution
Hazard Class 3
Packing Group I

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4) Not listed.

SARA 304 Emergency release notification Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not regulated

. SARA 302 Extremely hazardous substance

Superfund Amendments and Reauthorization Act of 1986 (SARA) Not listed.

SARA 311/312 Hazardous No

chemical

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 Classified hazard Flammable (gases, aerosols, liquids, or solids)
Categories Serious eye damage or eye irritation
SARA 313 (TRI reporting) Not regulated.

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated.
Safe Drinking Water Act Not regulated.

FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace
Ethyl alcohol (CAS 64-17-5) Low priority

US state regulations
US. Massachusetts RTK - Substance List Ethyl alcohol (CAS 64-17-5)
US. New Jersey Worker and Community Right-to-Know Ac Ethyl alcohol (CAS 64-17-5)
US. Pennsylvania Worker and Community Right-to-Know Law Ethyl alcohol (CAS 64-17-5)
US. Rhode Island RTK Ethyl alcohol (CAS 64-17-5)

California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material
is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For
more information go to www.P65Warnings.ca.gov.

International Inventories
Country(s) or region Inventory name On inventory (yes/no)*

Australia Australian Inventory of Chemical Substances (AICS) Yes

Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China I nventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Yes
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes
Taiwan Taiwan Chemical Substance Inventory (TCSI) Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes

A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s

WHMIS Hazard Class

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 16. Other information
Issue Date June 2nd 2020
Prepared By Michel Marcil

Creation Date June 2

Revision Date 02

HMIS® ratings Health : 2

Flamability: 3
Physical Hazard: 0

Disclaimer Maison des Futailles S.E.C. /Kruger Wine & Spirit. cannot anticipate all conditions under which this
information and its product, or the products of other manufacturers in combination with its product,
may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and
disposal of the product, and to assume liability for loss, injury, damage or expense due to
improper use. The information in the sheet was written based on the best knowledge and
experience currently available.

End of SDS

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