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CHAMPION X - CORR22228A

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SAFETY DATA SHEET

CORR22228A

Section: 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : CORR22228A

Other means of identification : Not applicable.

Recommended use : CORROSION INHIBITOR

Restrictions on use : Refer to available product literature or ask your local Sales Representative for
restrictions on use and dose limits.

Company : ChampionX LLC


11177 S. Stadium Drive
Sugar Land, Texas 77478
USA
TEL: (281) 632-6500

Emergency telephone : (800) 424-9300 (24 Hours) CHEMTREC


number

Issuing date : 04/27/2022

Section: 2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 3
Acute toxicity (Oral) : Category 4
Acute toxicity (Inhalation) : Category 4
Acute toxicity (Dermal) : Category 4
Skin irritation : Category 2
Eye irritation : Category 2A
Specific target organ toxicity : Category 1 (Eyes)
- single exposure
Specific target organ toxicity : Category 3 (Central Nervous System)
- single exposure

GHS Label element


Hazard pictograms :

Signal Word : Danger

Hazard Statements : Flammable liquid and vapour.


Harmful if swallowed, in contact with skin or if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause drowsiness or dizziness.
Causes damage to organs (Eyes).

Precautionary Statements : Prevention:


Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not

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SAFETY DATA SHEET
CORR22228A

breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/ eye


protection/ face protection.
Response:
IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel
unwell. Rinse mouth. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Call a POISON CENTER
or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. IF exposed: Call a POISON CENTER or doctor/ physician.
Storage:
Store in a well-ventilated place.
Disposal:
Dispose of contents/ container to an approved waste disposal plant.

Other hazards : None known.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No. Concentration: (%)


Alkylamines Proprietary 60 - 100
Methanol 67-56-1 10 - 30
Cyclic amine derivatives, acetate Proprietary 5 - 10
Quaternary ammonium compound Proprietary 1-5

Section: 4. FIRST AID MEASURES

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Get medical attention.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild
soap if available. Wash clothing before reuse. Thoroughly clean shoes before
reuse. Get medical attention if irritation develops and persists.

If swallowed : Rinse mouth. Get medical attention if symptoms occur.

If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention.

Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put
yourself at risk of injury. If in doubt, contact emergency responders. Use
personal protective equipment as required.

Notes to physician : Treat symptomatically.

Most important symptoms : See Section 11 for more detailed information on health effects and symptoms.
and effects, both acute and
delayed

Section: 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Foam


Carbon dioxide

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CORR22228A

Dry powder
Other extinguishing agent suitable for Class B fires
For large fires, use water spray or fog, thoroughly drenching the burning
material.

Unsuitable extinguishing : None known.


media

Specific hazards during : Fire Hazard


firefighting Keep away from heat and sources of ignition.
Flash back possible over considerable distance.
Beware of vapours accumulating to form explosive concentrations. Vapours can
accumulate in low areas.

Hazardous combustion : Decomposition products may include the following materials: Carbon oxides
products nitrogen oxides (NOx) Hydrogen chloride

Special protective equipment : Use personal protective equipment.


for firefighters

Specific extinguishing : Use water spray to cool unopened containers. Fire residues and contaminated
methods fire extinguishing water must be disposed of in accordance with local
regulations. In the event of fire and/or explosion do not breathe fumes.

Section: 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Ensure adequate ventilation. Remove all sources of ignition. Ensure clean-up is
protective equipment and conducted by trained personnel only. Refer to protective measures listed in
emergency procedures sections 7 and 8.

Environmental precautions : Do not allow contact with soil, surface or ground water.

Methods and materials for : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain
containment and cleaning up spillage, and then collect with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal
according to local / national regulations (see section 13). For large spills, dike
spilled material or otherwise contain material to ensure runoff does not reach a
waterway. Flush away traces with water.

Section: 7. HANDLING AND STORAGE

Advice on safe handling : Avoid contact with skin and eyes. Open drum carefully as content may be under
pressure. Take necessary action to avoid static electricity discharge (which
might cause ignition of organic vapours). Do not ingest. Keep away from fire,
sparks and heated surfaces. Do not breathe dust/fume/gas/mist/vapours/spray.
Wash hands thoroughly after handling. Use only with adequate ventilation.

Conditions for safe storage : Keep away from heat and sources of ignition. Keep in a cool, well-ventilated
place. Keep away from oxidizing agents. Keep out of reach of children. Keep
container tightly closed. Store in suitable labelled containers.

Suitable material : Keep in properly labelled containers.

Unsuitable material : not determined

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SAFETY DATA SHEET
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Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Form of exposure Permissible Basis


concentration
Methanol 67-56-1 TWA 200 ppm ACGIH
STEL 250 ppm ACGIH
TWA 200 ppm NIOSH REL
260 mg/m3
STEL 250 ppm NIOSH REL
325 mg/m3
TWA 200 ppm OSHA Z1
260 mg/m3

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below
occupational exposure standards.

Personal protective equipment

Eye protection : Safety goggles


Face-shield

Hand protection : Wear impervious chemical-resistant gloves when handling this product.
The following glove types are recommended based on our review of glove
manufacturer information and/or other available sources.
butyl-rubber
Other glove types may be used for short term, incidental contact if determined
by testing to provide adequate worker protection.
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.

Skin protection : Wear suitable protective clothing.

Respiratory protection : Use local exhaust ventilation or other engineering controls as necessary to
control airborne vapour and mist.
When significant vapours are generated, an approved air purifying respirator is
recommended to supplement other control measures for short term exposure.
Use a particulate pre-filter where operations generate significant mists or
aerosols.
Recommended gas and vapour cartridge:
Multi-purpose combination filter
Methanol Warning! Protection provided by air purifying respirators is limited due
to methanol’s ability to break through filter media and its poor warning
properties. For prolonged exposures, entry into unknown environments or where
methanol is suspected to exceed exposure limits, use a positive pressure, full-
facepiece SCBA or supplied-air respirator.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove
and wash contaminated clothing before re-use. Wash face, hands and any
exposed skin thoroughly after handling.

The Personal Protective Equipment (PPE) recommendations provided above have been made in good faith based
on typical expected conditions of use. PPE selection should always be completed in conjunction with a proper risk

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SAFETY DATA SHEET
CORR22228A

assessment and in accordance with a PPE management program.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid
Colour : black
Odour : sweet
Flash point : 28.3 °C, Method: PMCC
pH : 9.2
Odour Threshold : no data available
Melting point/freezing point : Pour point: -40 °C
Initial boiling point and boiling : no data available
range
Evaporation rate : no data available
Flammability (solid, gas) : Not applicable.
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapour pressure : no data available
Relative vapour density : no data available
Relative density : 1.0184, (20 °C),
Density : no data available
Water solubility : soluble
Solubility in other solvents : no data available
Partition coefficient: n- : no data available
octanol/water
Auto-ignition temperature : no data available
Thermal decomposition : no data available
Viscosity, dynamic : 30 - 40 mPa.s (24 °C)
Viscosity, kinematic : 22.7 mm2/s (40 °C)
Molecular weight : no data available
VOC : no data available

Section: 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : Stable under normal conditions.

Possibility of hazardous : No dangerous reaction known under conditions of normal use.


reactions

Conditions to avoid : Heat, flames and sparks.

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Incompatible materials : Strong oxidizing agents

Hazardous decomposition : In case of fire, hazardous decomposition products may be produced such as:
products Carbon oxides
nitrogen oxides (NOx)
Hydrogen chloride

Section: 11. TOXICOLOGICAL INFORMATION

Information on likely routes of : Inhalation, Eye contact, Skin contact


exposure

Potential Health Effects

Eyes : Causes serious eye irritation.

Skin : Harmful in contact with skin. Causes skin irritation.

Ingestion : May cause blindness if swallowed. Harmful if swallowed.

Inhalation : Harmful if inhaled. Inhalation may cause central nervous system effects.

Chronic Exposure : May cause damage to organs.

Experience with human exposure

Eye contact : Redness, Pain, Irritation

Skin contact : Redness, Irritation

Ingestion : No information available.

Inhalation : Dizziness, Drowsiness

Toxicity

Product
Acute oral toxicity : Acute toxicity estimate: 349.77 mg/kg
Acute inhalation toxicity : Acute toxicity estimate: 1.16 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Acute dermal toxicity : Acute toxicity estimate: 1,062 mg/kg
Skin corrosion/irritation : no data available
Serious eye damage/eye : no data available
irritation
Respiratory or skin : no data available
sensitization
Carcinogenicity : no data available
Reproductive effects : no data available

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Germ cell mutagenicity : no data available


Teratogenicity : no data available
STOT - single exposure : no data available
STOT - repeated exposure : no data available
Aspiration toxicity : no data available

Section: 12. ECOLOGICAL INFORMATION

Toxicity

Environmental Effects : Toxic to aquatic life.


Harmful to aquatic life with long lasting effects.

Components
Toxicity to fish : Methanol
LC50: 15,400 mg/l
Exposure time: 96 h

Components
Toxicity to daphnia and other : Methanol
aquatic invertebrates EC50 : > 10,000 mg/l
Exposure time: 48 h

Quaternary ammonium compound


EC50 Daphnia magna (Water flea): 0.016 mg/l
Exposure time: 48 h

Components
Toxicity to algae : Methanol
EC50 : 22,000 mg/l
Exposure time: 72 h

Components
Toxicity to bacteria : Methanol
> 1,000 mg/l

Components
Toxicity to fish (Chronic : Methanol
toxicity) NOEC: 7,900 mg/l
Exposure time: 8.3 d

Persistence and degradability

no data available

Mobility

no data available

Bioaccumulative potential

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SAFETY DATA SHEET
CORR22228A

no data available

Other information

no data available

Section: 13. DISPOSAL CONSIDERATIONS

The information presented only applies to the material as supplied. The classification or waste code may not apply if
the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine
the toxicity and physical properties of the material generated at the time of disposal to determine the proper waste
identification and disposal methods in compliance with applicable regulations.

Disposal methods : The product should not be allowed to enter drains, water
courses or the soil. Where possible recycling is preferred to
disposal or incineration. If recycling is not practicable, dispose
of in compliance with local regulations. Dispose of wastes in
an approved waste disposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be


taken to an approved waste handling site for recycling or
disposal. Do not re-use empty containers.

Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance
with the selected mode of transport.

The presence of an RQ component (Reportable Quantity for U.S. DOT) in this product causes it to be regulated with
an additional description of RQ for road, or as Environmentally hazardous for road and air, ONLY when the net
weight in the package exceeds the calculated RQ for the product.

Land transport (DOT)


Proper shipping name : FLAMMABLE LIQUID, N.O.S.
Technical name(s) : Methanol
UN/ID No. : UN 1993
Transport hazard class(es) : 3
Packing group : III
Reportable Quantity (per : 17,777 lbs
package)
RQ Component : Methanol

Air transport (IATA)


Proper shipping name : FLAMMABLE LIQUID, N.O.S.
Technical name(s) : Methanol
UN/ID No. : UN 1993
Transport hazard class(es) : 3
Packing group : III
Reportable Quantity (per : 17,777 lbs
package)
RQ Component : Methanol

Sea transport (IMDG/IMO)

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SAFETY DATA SHEET
CORR22228A

Proper shipping name : FLAMMABLE LIQUID, N.O.S.


Technical name(s) : Methanol
UN/ID No. : UN 1993
Transport hazard class(es) : 3
Packing group : III

Section: 15. REGULATORY INFORMATION

TSCA list : No substances are subject to a Significant New Use Rule.

The following substance(s) is/are subject to TSCA 12(b) export


notification requirements: Alkylamines

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity


Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs)
Methanol 67-56-1 5000 17777
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)


Acute toxicity (any route of exposure)
Skin corrosion or irritation
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)

SARA 302 : This material does not contain any components with a section 302
EHS TPQ.

SARA 313 : The following components are subject to reporting levels established
by SARA Title III, Section 313:
Components CAS-No. Weight percent
Methanol 67-56-1 10 - 30 %

California Prop. 65
WARNING: Reproductive Harm - www.P65Warnings.ca.gov
Methanol 67-56-1

INTERNATIONAL CHEMICAL CONTROL LAWS :

United States TSCA Inventory


On the inventory, or in compliance with the inventory.

Section: 16. OTHER INFORMATION

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CORR22228A

NFPA: HMIS III:


Flammability

HEALTH 2
3

Instability
Health

2 0 FLAMMABILITY 3
PHYSICAL HAZARD 0

Special hazard. 0 = not significant, 1 = Slight,


2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Revision Date : 04/27/2022


Version Number : 1.1
Prepared By : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by
a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified in the text.

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