SAFETY DATA SHEET

LARGE SPACE AIR FRESHENER - CUCUMBER MELON

REFILL PACK

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : LARGE SPACE AIR FRESHENER - CUCUMBER MELON REFILL

PACK

Other means of identification : Not applicable

Recommended use : Air Freshener

Restrictions on use : Reserved for industrial and professional use.

Product dilution information : Product is sold ready to use.

Company : Ecolab Inc.

1 Ecolab Place
St. Paul, Minnesota USA 55102
1-800-352-5326

Emergency health : 1-800-328-0026 (US/Canada), 1-651-222-5352 (outside US)

information

Issuing date : 10/28/2019

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 4
Eye irritation : Category 2A
Skin sensitization : Category 1

GHS label elements

Hazard pictograms :

Signal Word : Warning

Hazard Statements : Combustible liquid.

May cause an allergic skin reaction.
Causes serious eye irritation.

Precautionary Statements : Prevention:

Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Wash skin
thoroughly after handling. Contaminated work clothing must not be
allowed out of the workplace. Wear protective gloves/ eye protection/
face protection.
Response:
IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If skin irritation or rash
occurs: Get medical advice/ attention. If eye irritation persists: Get
medical advice/ attention. Wash contaminated clothing before reuse.
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to
extinguish.

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SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - CUCUMBER MELON REFILL PACK

Storage:
Store in a well-ventilated place. Keep cool.
Disposal:
Dispose of contents/ container to an approved waste disposal plant.

Other hazards : None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture : Mixture

Chemical name CAS-No. Concentration (%)

Butanoic acid, 3-oxo-, ethyl ester 141-97-9 30 - 60
Propylene glycol 57-55-6 30 - 60
solvents /additives 105-53-3 30 - 60
Geraniol 106-24-1 0.1 - 1

SECTION 4. FIRST AID MEASURES

In case of eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical advice/ attention.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use
a mild soap if available. Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention.

If swallowed : Rinse mouth. Get medical attention if symptoms occur.

If inhaled : Get medical attention if symptoms occur.

Protection of first-aiders : If potential for exposure exists refer to Section 8 for specific personal
protective equipment.

Notes to physician : Treat symptomatically.

Most important symptoms : See Section 11 for more detailed information on health effects and
and effects, both acute and symptoms.
delayed

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Unsuitable extinguishing : High volume water jet

media

Specific hazards during fire : Fire Hazard

fighting Keep away from heat and sources of ignition.
Flash back possible over considerable distance.

Hazardous combustion : Decomposition products may include the following materials:

products Carbon oxides

Special protective equipment : Use personal protective equipment.

for fire-fighters

920065 2/9
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - CUCUMBER MELON REFILL PACK

Specific extinguishing : Fire residues and contaminated fire extinguishing water must be
methods disposed of in accordance with local regulations. In the event of fire
and/or explosion do not breathe fumes.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Remove all sources of ignition. Ensure clean-up is conducted by

protective equipment and trained personnel only. Refer to protective measures listed in sections
emergency procedures 7 and 8.

Environmental precautions : Do not allow contact with soil, surface or ground water.

Methods and materials for : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so.
containment and cleaning up Contain spillage, and then collect with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place
in container for disposal according to local / national regulations (see
section 13). For large spills, dike spilled material or otherwise contain
material to ensure runoff does not reach a waterway.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Do not get in eyes, on skin, or on clothing. Keep away from fire,
sparks and heated surfaces. Take necessary action to avoid static
electricity discharge (which might cause ignition of organic vapors).
Wash hands thoroughly after handling. In case of mechanical
malfunction, or if in contact with unknown dilution of product, wear full
Personal Protective Equipment (PPE).

Conditions for safe storage : Keep away from heat and sources of ignition. Keep away from
oxidizing agents. Keep out of reach of children. Store in suitable
labeled containers.

Storage temperature : 0 °C to 50 °C

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Components CAS-No. Form of Permissible Basis

exposure concentration
Propylene glycol 57-55-6 TWA 10 mg/m3 AIHA WEEL

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations

below occupational exposure standards.

Personal protective equipment

Eye protection : Wear eye protection/ face protection.

Hand protection : Wear the following personal protective equipment:

Standard glove type.
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.

Skin protection : No special protective equipment required.

Respiratory protection : No personal respiratory protective equipment normally required.

920065 3/9
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - CUCUMBER MELON REFILL PACK

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. Wash face, hands and any exposed skin thoroughly after
handling.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid
Color : clear, yellow
Odor : citrus
pH : Not applicable
Flash point : Not applicable
Odor Threshold : No data available
Melting point/freezing point : No data available
Initial boiling point and : No data available
boiling range
Evaporation rate : No data available
Flammability (solid, gas) : Not applicable
Upper explosion limit : No data available
Lower explosion limit : No data available
Vapor pressure : No data available
Relative vapor density : No data available
Relative density : No data available
Water solubility : No data available
Solubility in other solvents : No data available
Partition coefficient: n- : No data available
octanol/water
Autoignition temperature : No data available
Thermal decomposition : No data available
Viscosity, kinematic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Molecular weight : No data available
VOC : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : Stable under normal conditions.

Possibility of hazardous : No dangerous reaction known under conditions of normal use.

reactions

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : None known.

920065 4/9
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - CUCUMBER MELON REFILL PACK

Hazardous decomposition : In case of fire hazardous decomposition products may be produced

products such as:
Carbon oxides

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of : Inhalation, Eye contact, Skin contact

exposure

Potential Health Effects

Eyes : Causes serious eye irritation.

Skin : May cause allergic skin reaction.

Ingestion : Health injuries are not known or expected under normal use.

Inhalation : Health injuries are not known or expected under normal use.

Chronic Exposure : Health injuries are not known or expected under normal use.

Experience with human exposure

Eye contact : Redness, Pain, Irritation

Skin contact : Redness, Irritation, Allergic reactions

Ingestion : No symptoms known or expected.

Inhalation : No symptoms known or expected.

Toxicity

Product
Acute oral toxicity : No data available
Acute inhalation toxicity : No data available
Acute dermal toxicity : No data available
Skin corrosion/irritation : No data available
Serious eye damage/eye : No data available
irritation
Respiratory or skin : No data available
sensitization
Carcinogenicity : No data available
Reproductive effects : No data available
Germ cell mutagenicity : No data available
Teratogenicity : No data available
STOT-single exposure : No data available
STOT-repeated exposure : No data available
Aspiration toxicity : No data available
Components
Acute oral toxicity : Butanoic acid, 3-oxo-, ethyl ester

920065 5/9
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - CUCUMBER MELON REFILL PACK

LD50 Rat: 11,550 mg/kg

Propylene glycol
LD50 Rat: 22,000 mg/kg

solvents /additives
LD50 Rat: 15,794 mg/kg

Geraniol
LD50 Rat: 4,200 mg/kg

Components
Acute inhalation toxicity : Propylene glycol
4 h LC50 Rat: > 158.5 mg/l
Test atmosphere: dust/mist

Components
Acute dermal toxicity : solvents /additives
LD50 Rabbit: > 16,960 mg/kg

Geraniol
LD50 Rabbit: > 5,000 mg/kg

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Environmental Effects : Harmful to aquatic life.

Product
Toxicity to fish : No data available
Toxicity to daphnia and other : No data available
aquatic invertebrates
Toxicity to algae : No data available
Components
Toxicity to fish : Butanoic acid, 3-oxo-, ethyl ester
96 h LC50 Danio rerio (zebra fish): > 100 mg/l

Propylene glycol
96 h LC50: > 10,000 mg/l

solvents /additives
96 h LC50 Pimephales promelas: 12 mg/l

Components
Toxicity to daphnia and other : Butanoic acid, 3-oxo-, ethyl ester
aquatic invertebrates 48 h EC50 Daphnia magna (Water flea): > 100 mg/l

Propylene glycol
48 h EC50: 18,340 mg/l

solvents /additives
48 h EC50 Daphnia magna (Water flea): 202.3 mg/l

Components

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SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - CUCUMBER MELON REFILL PACK

Toxicity to algae : Butanoic acid, 3-oxo-, ethyl ester

72 h EC50 Desmodesmus subspicatus (green algae): > 100 mg/l

Propylene glycol
96 h EC50: 19,000 mg/l

solvents /additives
72 h EC50 Desmodesmus subspicatus (green algae): > 800 mg/l

Geraniol
72 h EC50: 5.93 mg/l

Persistence and degradability

Readily biodegradable.

Bioaccumulative potential
No data available

Mobility in soil
No data available

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods : Do not contaminate ponds, waterways or ditches with chemical or

used container. Where possible recycling is preferred to disposal or
incineration. If recycling is not practicable, dispose of in compliance
with local regulations. Dispose of wastes in an approved waste
disposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be taken to

an approved waste handling site for recycling or disposal. Do not re-
use empty containers. Dispose of in accordance with local, state, and
federal regulations.

SECTION 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are
in compliance with the selected mode of transport.

Land transport (DOT)

Not dangerous goods

Sea transport (IMDG/IMO)

Not dangerous goods

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.

920065 7/9
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - CUCUMBER MELON REFILL PACK

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)

Serious eye damage or eye irritation
Respiratory or skin sensitization

SARA 302 : This material does not contain any components with a section 302
EHS TPQ.

SARA 313 : This material does not contain any chemical components with known
CAS numbers that exceed the threshold (De Minimis) reporting levels
established by SARA Title III, Section 313.

California Prop. 65
This product does not contain any chemicals known to the State of California to cause cancer, birth, or
any other reproductive defects.

California Cleaning Product Right to Know Act of 2017 (SB 258)

This regulation applies to this product.
Chemical Name CAS-No. Function List(s)
Butanoic acid, 3-oxo-, ethyl ester 141-97-9 Fragrance Not Applicable
Propylene glycol 57-55-6 Fragrance 12
solvents /additives 105-53-3 Fragrance Not Applicable
Amyl cinnamal 122-40-7 Fragrance FRA
3-p-cumenyl-2- 103-95-7 Fragrance Not Applicable
methylpropionaldehyde
Linalool 78-70-6 Fragrance FRA
Benzyl benzoate 120-51-4 Fragrance FRA
Geraniol 106-24-1 Fragrance FRA
Citronellol 106-22-9 Fragrance FRA
Benzyl salicylate 118-58-1 Fragrance FRA
solvents /additives 111-80-8 Fragrance Not Applicable
*refer to ecolab.com/sds for electronic links to designated lists

The ingredients of this product are reported in the following inventories:

United States TSCA Inventory :

All substances listed as active on the TSCA inventory

Canadian Domestic Substances List (DSL) :

All components of this product are on the Canadian DSL

Australia Inventory of Chemical Substances (AICS) :

On the inventory, or in compliance with the inventory

New Zealand. Inventory of Chemical Substances :

not determined

Japan. ENCS - Existing and New Chemical Substances Inventory :

On the inventory, or in compliance with the inventory

Korea. Korean Existing Chemicals Inventory (KECI) :

On the inventory, or in compliance with the inventory

Philippines Inventory of Chemicals and Chemical Substances (PICCS) :

On the inventory, or in compliance with the inventory

920065 8/9
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - CUCUMBER MELON REFILL PACK

China. Inventory of Existing Chemical Substances in China (IECSC) :

On the inventory, or in compliance with the inventory

Taiwan Chemical Substance Inventory (TCSI) :

On the inventory, or in compliance with the inventory

SECTION 16. OTHER INFORMATION

NFPA: HMIS III:

Flammability

HEALTH 2*
2
Instability
Health

2 0 FLAMMABILITY 2
PHYSICAL HAZARD 0
0 = not significant, 1 = Slight,
Special hazard 2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Issuing date : 10/28/2019

Version : 1.2
Prepared by : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is
indicated by a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

920065 9/9
 SAFETY DATA SHEET
Large Space Air Freshener - Ocean Spray Refill Pack

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Large Space Air Freshener - Ocean Spray Refill Pack

Other means of identification : Not applicable

Recommended use : Air Freshener

Restrictions on use : Reserved for industrial and professional use.

Product dilution information : Product is sold ready to use.

Company : Ecolab Inc.

1 Ecolab Place
St. Paul, Minnesota USA 55102
1-800-352-5326

Emergency health : 1-800-328-0026 (US/Canada), 1-651-222-5352 (outside US)

information

Issuing date : 10/28/2019

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 4
Eye irritation : Category 2A

GHS label elements

Hazard pictograms :

Signal Word : Warning

Hazard Statements : Combustible liquid.

Causes serious eye irritation.

Precautionary Statements : Prevention:

Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Wash skin thoroughly after handling. Wear protective gloves/ eye
protection/ face protection.
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical advice/ attention. In case of fire: Use
dry sand, dry chemical or alcohol-resistant foam to extinguish.
Storage:
Store in a well-ventilated place. Keep cool.
Disposal:
Dispose of contents/ container to an approved waste disposal plant.

Other hazards : None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

920067 1/9
SAFETY DATA SHEET
Large Space Air Freshener - Ocean Spray Refill Pack

Pure substance/mixture : Mixture

Chemical name CAS-No. Concentration (%)

Butanoic acid, 3-oxo-, ethyl ester 141-97-9 30 - 60
Propylene glycol 57-55-6 30 - 60
solvents /additives 105-53-3 30 - 60
benzyl acetate 140-11-4 5 - 10

SECTION 4. FIRST AID MEASURES

In case of eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical advice/ attention.

In case of skin contact : Rinse with plenty of water.

If swallowed : Rinse mouth. Get medical attention if symptoms occur.

If inhaled : Get medical attention if symptoms occur.

Protection of first-aiders : If potential for exposure exists refer to Section 8 for specific personal
protective equipment.

Notes to physician : Treat symptomatically.

Most important symptoms : See Section 11 for more detailed information on health effects and
and effects, both acute and symptoms.
delayed

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Unsuitable extinguishing : High volume water jet

media

Specific hazards during fire : Fire Hazard

fighting Keep away from heat and sources of ignition.
Flash back possible over considerable distance.

Hazardous combustion : Decomposition products may include the following materials:

products Carbon oxides

Special protective equipment : Use personal protective equipment.

for fire-fighters

Specific extinguishing : Fire residues and contaminated fire extinguishing water must be
methods disposed of in accordance with local regulations. In the event of fire
and/or explosion do not breathe fumes.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Remove all sources of ignition. Ensure clean-up is conducted by

protective equipment and trained personnel only. Refer to protective measures listed in sections
emergency procedures 7 and 8.

Environmental precautions : Do not allow contact with soil, surface or ground water.

920067 2/9
SAFETY DATA SHEET
Large Space Air Freshener - Ocean Spray Refill Pack

Methods and materials for : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so.
containment and cleaning up Contain spillage, and then collect with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place
in container for disposal according to local / national regulations (see
section 13). For large spills, dike spilled material or otherwise contain
material to ensure runoff does not reach a waterway.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Avoid contact with skin and eyes. Keep away from fire, sparks and
heated surfaces. Take necessary action to avoid static electricity
discharge (which might cause ignition of organic vapors). Wash hands
thoroughly after handling. In case of mechanical malfunction, or if in
contact with unknown dilution of product, wear full Personal Protective
Equipment (PPE).

Conditions for safe storage : Keep away from heat and sources of ignition. Keep away from
oxidizing agents. Keep out of reach of children. Store in suitable
labeled containers.

Storage temperature : 0 °C to 50 °C

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Components CAS-No. Form of Permissible Basis

exposure concentration
Propylene glycol 57-55-6 TWA 10 mg/m3 AIHA WEEL
benzyl acetate 140-11-4 TWA 10 ppm ACGIH

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations

below occupational exposure standards.

Personal protective equipment

Eye protection : Wear eye protection/ face protection.

Hand protection : Wear the following personal protective equipment:

Standard glove type.
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.

Skin protection : No special protective equipment required.

Respiratory protection : No personal respiratory protective equipment normally required.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. Wash face, hands and any exposed skin thoroughly after
handling.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid
Color : clear, yellow

920067 3/9
SAFETY DATA SHEET
Large Space Air Freshener - Ocean Spray Refill Pack

Odor : Perfumes, fragrances

pH : Not applicable
Flash point : 70 °C closed cup
Odor Threshold : No data available
Melting point/freezing point : No data available
Initial boiling point and : No data available
boiling range
Evaporation rate : No data available
Flammability (solid, gas) : Not applicable
Upper explosion limit : No data available
Lower explosion limit : No data available
Vapor pressure : No data available
Relative vapor density : No data available
Relative density : No data available
Water solubility : No data available
Solubility in other solvents : No data available
Partition coefficient: n- : No data available
octanol/water
Autoignition temperature : No data available
Thermal decomposition : No data available
Viscosity, kinematic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Molecular weight : No data available
VOC : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : Stable under normal conditions.

Possibility of hazardous : No dangerous reaction known under conditions of normal use.

reactions

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : None known.

Hazardous decomposition : In case of fire hazardous decomposition products may be produced

products such as:
Carbon oxides

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of : Inhalation, Eye contact, Skin contact

exposure

920067 4/9
SAFETY DATA SHEET
Large Space Air Freshener - Ocean Spray Refill Pack

Potential Health Effects

Eyes : Causes serious eye irritation.

Skin : Health injuries are not known or expected under normal use.

Ingestion : Health injuries are not known or expected under normal use.

Inhalation : Health injuries are not known or expected under normal use.

Chronic Exposure : Health injuries are not known or expected under normal use.

Experience with human exposure

Eye contact : Redness, Pain, Irritation

Skin contact : No symptoms known or expected.

Ingestion : No symptoms known or expected.

Inhalation : No symptoms known or expected.

Toxicity

Product
Acute oral toxicity : No data available
Acute inhalation toxicity : No data available
Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg
Skin corrosion/irritation : No data available
Serious eye damage/eye : No data available
irritation
Respiratory or skin : No data available
sensitization
Carcinogenicity : No data available
Reproductive effects : No data available
Germ cell mutagenicity : No data available
Teratogenicity : No data available
STOT-single exposure : No data available
STOT-repeated exposure : No data available
Aspiration toxicity : No data available
Components
Acute oral toxicity : Butanoic acid, 3-oxo-, ethyl ester
LD50 Rat: 11,550 mg/kg

Propylene glycol
LD50 Rat: 22,000 mg/kg

solvents /additives
LD50 Rat: 15,794 mg/kg

benzyl acetate
LD50 Rat: > 2,000 mg/kg

920067 5/9
SAFETY DATA SHEET
Large Space Air Freshener - Ocean Spray Refill Pack

Components
Acute inhalation toxicity : Propylene glycol
4 h LC50 Rat: > 158.5 mg/l
Test atmosphere: dust/mist

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Environmental Effects : Harmful to aquatic life.

Product
Toxicity to fish : No data available
Toxicity to daphnia and other : No data available
aquatic invertebrates
Toxicity to algae : No data available
Components
Toxicity to fish : Butanoic acid, 3-oxo-, ethyl ester
96 h LC50 Danio rerio (zebra fish): > 100 mg/l

Propylene glycol
96 h LC50: > 10,000 mg/l

solvents /additives
96 h LC50 Pimephales promelas: 12 mg/l

benzyl acetate
96 h LC50: 4 mg/l

Components
Toxicity to daphnia and other : Butanoic acid, 3-oxo-, ethyl ester
aquatic invertebrates 48 h EC50 Daphnia magna (Water flea): > 100 mg/l

Propylene glycol
48 h EC50: 18,340 mg/l

solvents /additives
48 h EC50 Daphnia magna (Water flea): 202.3 mg/l

Components
Toxicity to algae : Butanoic acid, 3-oxo-, ethyl ester
72 h EC50 Desmodesmus subspicatus (green algae): > 100 mg/l

Propylene glycol
96 h EC50: 19,000 mg/l

solvents /additives
72 h EC50 Desmodesmus subspicatus (green algae): > 800 mg/l

Persistence and degradability

Readily biodegradable.

Bioaccumulative potential
No data available

920067 6/9
SAFETY DATA SHEET
Large Space Air Freshener - Ocean Spray Refill Pack

Mobility in soil
No data available

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods : Do not contaminate ponds, waterways or ditches with chemical or

used container. Where possible recycling is preferred to disposal or
incineration. If recycling is not practicable, dispose of in compliance
with local regulations. Dispose of wastes in an approved waste
disposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be taken to

an approved waste handling site for recycling or disposal. Do not re-
use empty containers. Dispose of in accordance with local, state, and
federal regulations.

SECTION 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are
in compliance with the selected mode of transport.

Land transport (DOT)

Not dangerous goods

Sea transport (IMDG/IMO)

Not dangerous goods

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)

Serious eye damage or eye irritation

SARA 302 : This material does not contain any components with a section 302
EHS TPQ.

SARA 313 : This material does not contain any chemical components with known
CAS numbers that exceed the threshold (De Minimis) reporting levels
established by SARA Title III, Section 313.

California Prop. 65
This product does not contain any chemicals known to the State of California to cause cancer, birth, or
any other reproductive defects.

920067 7/9
SAFETY DATA SHEET
Large Space Air Freshener - Ocean Spray Refill Pack

California Cleaning Product Right to Know Act of 2017 (SB 258)

This regulation applies to this product.
Chemical Name CAS-No. Function List(s)
Butanoic acid, 3-oxo-, ethyl ester 141-97-9 Fragrance Not Applicable
Propylene glycol 57-55-6 Fragrance 12
solvents /additives 105-53-3 Fragrance Not Applicable
benzyl acetate 140-11-4 Fragrance Not Applicable
Linalool 78-70-6 Fragrance FRA
Alpha-Isomethyl Ionone 127-51-5 Fragrance FRA
Hexyl cinnamal 101-86-0 Fragrance FRA
Benzyl salicylate 118-58-1 Fragrance FRA
Benzyl benzoate 120-51-4 Fragrance FRA
Coumarin 91-64-5 Fragrance FRA
Citral 5392-40-5 Fragrance FRA
solvents /additives 68901-15-5 Fragrance Not Applicable
*refer to ecolab.com/sds for electronic links to designated lists

The ingredients of this product are reported in the following inventories:

United States TSCA Inventory :

All substances listed as active on the TSCA inventory

Canadian Domestic Substances List (DSL) :

All components of this product are on the Canadian DSL

Australia Inventory of Chemical Substances (AICS) :

On the inventory, or in compliance with the inventory

New Zealand. Inventory of Chemical Substances :

not determined

Japan. ENCS - Existing and New Chemical Substances Inventory :

On the inventory, or in compliance with the inventory

Korea. Korean Existing Chemicals Inventory (KECI) :

On the inventory, or in compliance with the inventory

Philippines Inventory of Chemicals and Chemical Substances (PICCS) :

On the inventory, or in compliance with the inventory

China. Inventory of Existing Chemical Substances in China (IECSC) :

On the inventory, or in compliance with the inventory

Taiwan Chemical Substance Inventory (TCSI) :

On the inventory, or in compliance with the inventory

SECTION 16. OTHER INFORMATION

920067 8/9
SAFETY DATA SHEET
Large Space Air Freshener - Ocean Spray Refill Pack

NFPA: HMIS III:

Flammability

HEALTH 2
2

Instability
Health

2 0 FLAMMABILITY 2
PHYSICAL HAZARD 0
0 = not significant, 1 = Slight,
Special hazard 2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Issuing date : 10/28/2019

Version : 1.1
Prepared by : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is
indicated by a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

920067 9/9
 SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - TROPICAL LILY AND
MANGO REFILL PACK

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : LARGE SPACE AIR FRESHENER - TROPICAL LILY AND MANGO
REFILL PACK

Other means of identification : Not applicable

Recommended use : Air Freshener

Restrictions on use : Reserved for industrial and professional use.

Product dilution information : Product is sold ready to use.

Company : Ecolab Inc.

1 Ecolab Place
St. Paul, Minnesota USA 55102
1-800-352-5326

Emergency health : 1-800-328-0026 (US/Canada), 1-651-222-5352 (outside US)

information

Issuing date : 10/28/2019

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 4
Skin sensitization : Category 1

GHS label elements

Hazard pictograms :

Signal Word : Warning

Hazard Statements : Combustible liquid.

May cause an allergic skin reaction.

Precautionary Statements : Prevention:

Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Contaminated
work clothing must not be allowed out of the workplace. Wear
protective gloves/ eye protection/ face protection.
Response:
IF ON SKIN: Wash with plenty of soap and water. If skin irritation or
rash occurs: Get medical advice/ attention. Wash contaminated
clothing before reuse. In case of fire: Use dry sand, dry chemical or
alcohol-resistant foam to extinguish.
Storage:
Store in a well-ventilated place. Keep cool.
Disposal:
Dispose of contents/ container to an approved waste disposal plant.

Other hazards : None known.

920068 1/8
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - TROPICAL LILY AND MANGO REFILL PACK

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture : Mixture

Chemical name CAS-No. Concentration (%)

Butanoic acid, 3-oxo-, ethyl ester 141-97-9 30 - 60
Propylene glycol 57-55-6 30 - 60
Amyl cinnamal 122-40-7 5 - 10

SECTION 4. FIRST AID MEASURES

In case of eye contact : Rinse with plenty of water.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use
a mild soap if available. Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention.

If swallowed : Rinse mouth. Get medical attention if symptoms occur.

If inhaled : Get medical attention if symptoms occur.

Protection of first-aiders : If potential for exposure exists refer to Section 8 for specific personal
protective equipment.

Notes to physician : Treat symptomatically.

Most important symptoms : See Section 11 for more detailed information on health effects and
and effects, both acute and symptoms.
delayed

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Unsuitable extinguishing : High volume water jet

media

Specific hazards during fire : Fire Hazard

fighting Keep away from heat and sources of ignition.
Flash back possible over considerable distance.

Hazardous combustion : Decomposition products may include the following materials:

products Carbon oxides

Special protective equipment : Use personal protective equipment.

for fire-fighters

Specific extinguishing : Fire residues and contaminated fire extinguishing water must be
methods disposed of in accordance with local regulations. In the event of fire
and/or explosion do not breathe fumes.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Remove all sources of ignition. Ensure clean-up is conducted by

protective equipment and trained personnel only. Refer to protective measures listed in sections

920068 2/8
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - TROPICAL LILY AND MANGO REFILL PACK

emergency procedures 7 and 8.

Environmental precautions : Do not allow contact with soil, surface or ground water.

Methods and materials for : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so.
containment and cleaning up Contain spillage, and then collect with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place
in container for disposal according to local / national regulations (see
section 13). For large spills, dike spilled material or otherwise contain
material to ensure runoff does not reach a waterway.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Do not get in eyes, on skin, or on clothing. Keep away from fire,
sparks and heated surfaces. Take necessary action to avoid static
electricity discharge (which might cause ignition of organic vapors).
Wash hands thoroughly after handling. In case of mechanical
malfunction, or if in contact with unknown dilution of product, wear full
Personal Protective Equipment (PPE).

Conditions for safe storage : Keep away from heat and sources of ignition. Keep away from
oxidizing agents. Keep out of reach of children. Store in suitable
labeled containers.

Storage temperature : 0 °C to 50 °C

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Components CAS-No. Form of Permissible Basis

exposure concentration
Propylene glycol 57-55-6 TWA 10 mg/m3 AIHA WEEL

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations

below occupational exposure standards.

Personal protective equipment

Eye protection : Wear eye protection/ face protection.

Hand protection : Wear the following personal protective equipment:

Standard glove type.
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.

Skin protection : No special protective equipment required.

Respiratory protection : No personal respiratory protective equipment normally required.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. Wash face, hands and any exposed skin thoroughly after
handling.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

920068 3/8
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - TROPICAL LILY AND MANGO REFILL PACK

Appearance : liquid
Color : clear, yellow
Odor : Floral
pH : Not applicable
Flash point : 70 °C closed cup
Odor Threshold : No data available
Melting point/freezing point : No data available
Initial boiling point and : No data available
boiling range
Evaporation rate : No data available
Flammability (solid, gas) : Not applicable
Upper explosion limit : No data available
Lower explosion limit : No data available
Vapor pressure : No data available
Relative vapor density : No data available
Relative density : No data available
Water solubility : No data available
Solubility in other solvents : No data available
Partition coefficient: n- : No data available
octanol/water
Autoignition temperature : No data available
Thermal decomposition : No data available
Viscosity, kinematic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Molecular weight : No data available
VOC : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : Stable under normal conditions.

Possibility of hazardous : No dangerous reaction known under conditions of normal use.

reactions

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : None known.

Hazardous decomposition : In case of fire hazardous decomposition products may be produced

products such as:
Carbon oxides

SECTION 11. TOXICOLOGICAL INFORMATION

920068 4/8
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - TROPICAL LILY AND MANGO REFILL PACK

Information on likely routes of : Inhalation, Eye contact, Skin contact

exposure

Potential Health Effects

Eyes : Health injuries are not known or expected under normal use.

Skin : May cause allergic skin reaction.

Ingestion : Health injuries are not known or expected under normal use.

Inhalation : Health injuries are not known or expected under normal use.

Chronic Exposure : Health injuries are not known or expected under normal use.

Experience with human exposure

Eye contact : No symptoms known or expected.

Skin contact : Redness, Irritation, Allergic reactions

Ingestion : No symptoms known or expected.

Inhalation : No symptoms known or expected.

Toxicity

Product
Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg
Acute inhalation toxicity : No data available
Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg
Skin corrosion/irritation : No data available
Serious eye damage/eye : No data available
irritation
Respiratory or skin : No data available
sensitization
Carcinogenicity : No data available
Reproductive effects : No data available
Germ cell mutagenicity : No data available
Teratogenicity : No data available
STOT-single exposure : No data available
STOT-repeated exposure : No data available
Aspiration toxicity : No data available
Components
Acute inhalation toxicity : Propylene glycol
4 h LC50 Rat: > 158.5 mg/l
Test atmosphere: dust/mist

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

920068 5/8
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - TROPICAL LILY AND MANGO REFILL PACK

Environmental Effects : Harmful to aquatic life.

Product
Toxicity to fish : No data available
Toxicity to daphnia and other : No data available
aquatic invertebrates
Toxicity to algae : No data available
Components
Toxicity to fish : Butanoic acid, 3-oxo-, ethyl ester
96 h LC50 Danio rerio (zebra fish): > 100 mg/l

Propylene glycol
96 h LC50: > 10,000 mg/l

Components
Toxicity to daphnia and other : Butanoic acid, 3-oxo-, ethyl ester
aquatic invertebrates 48 h EC50 Daphnia magna (Water flea): > 100 mg/l

Propylene glycol
48 h EC50: 18,340 mg/l

Components
Toxicity to algae : Butanoic acid, 3-oxo-, ethyl ester
72 h EC50 Desmodesmus subspicatus (green algae): > 100 mg/l

Propylene glycol
96 h EC50: 19,000 mg/l

Amyl cinnamal
72 h EC50: 1.18 mg/l

Persistence and degradability

Biodegradable

Bioaccumulative potential
No data available

Mobility in soil
No data available

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods : Do not contaminate ponds, waterways or ditches with chemical or

used container. Where possible recycling is preferred to disposal or
incineration. If recycling is not practicable, dispose of in compliance
with local regulations. Dispose of wastes in an approved waste
disposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be taken to

an approved waste handling site for recycling or disposal. Do not re-
use empty containers. Dispose of in accordance with local, state, and

920068 6/8
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - TROPICAL LILY AND MANGO REFILL PACK

federal regulations.

SECTION 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are
in compliance with the selected mode of transport.

Land transport (DOT)

Not dangerous goods

Sea transport (IMDG/IMO)

Not dangerous goods

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)

Respiratory or skin sensitization

SARA 302 : This material does not contain any components with a section 302
EHS TPQ.

SARA 313 : This material does not contain any chemical components with known
CAS numbers that exceed the threshold (De Minimis) reporting levels
established by SARA Title III, Section 313.

California Prop. 65
This product does not contain any chemicals known to the State of California to cause cancer, birth, or
any other reproductive defects.

California Cleaning Product Right to Know Act of 2017 (SB 258)

This regulation applies to this product.
Chemical Name CAS-No. Function List(s)
Butanoic acid, 3-oxo-, ethyl ester 141-97-9 Fragrance Not Applicable
Propylene glycol 57-55-6 Fragrance 12
Amyl cinnamal 122-40-7 Fragrance FRA
Perfume ingredient 105-95-3 Fragrance Not Applicable
Linalool 78-70-6 Fragrance FRA
Citronellol 106-22-9 Fragrance FRA
solvents /additives 35044-68-9 Fragrance Not Applicable
solvents /additives 18127-01-0 Fragrance Not Applicable
Benzyl benzoate 120-51-4 Fragrance FRA
*refer to ecolab.com/sds for electronic links to designated lists

The ingredients of this product are reported in the following inventories:

United States TSCA Inventory :

920068 7/8
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - TROPICAL LILY AND MANGO REFILL PACK

All substances listed as active on the TSCA inventory

Canadian Domestic Substances List (DSL) :

This product contains one or several components listed in the Canadian NDSL.

Australia Inventory of Chemical Substances (AICS) :

not determined

New Zealand. Inventory of Chemical Substances :

not determined

Japan. ENCS - Existing and New Chemical Substances Inventory :

not determined

Korea. Korean Existing Chemicals Inventory (KECI) :

not determined

Philippines Inventory of Chemicals and Chemical Substances (PICCS) :

On the inventory, or in compliance with the inventory

China. Inventory of Existing Chemical Substances in China (IECSC) :

On the inventory, or in compliance with the inventory

Taiwan Chemical Substance Inventory (TCSI) :

On the inventory, or in compliance with the inventory

SECTION 16. OTHER INFORMATION

NFPA: HMIS III:

Flammability

HEALTH 2*
2
Instability
Health

2 0 FLAMMABILITY 2
PHYSICAL HAZARD 0
0 = not significant, 1 = Slight,
Special hazard 2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Issuing date : 10/28/2019

Version : 1.1
Prepared by : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is
indicated by a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

920068 8/8
 SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - SEA SALT AND
BAMBOO REFILL PACK

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : LARGE SPACE AIR FRESHENER - SEA SALT AND BAMBOO
REFILL PACK

Other means of identification : Not applicable

Recommended use : Air Freshener

Restrictions on use : Reserved for industrial and professional use.

Product dilution information : Product is sold ready to use.

Company : Ecolab Inc.

1 Ecolab Place
St. Paul, Minnesota USA 55102
1-800-352-5326

Emergency health : 1-800-328-0026 (US/Canada), 1-651-222-5352 (outside US)

information

Issuing date : 10/29/2019

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Flammable liquids : Category 4
Eye irritation : Category 2A
Skin sensitization : Category 1

GHS label elements

Hazard pictograms :

Signal Word : Warning

Hazard Statements : Combustible liquid.

May cause an allergic skin reaction.
Causes serious eye irritation.

Precautionary Statements : Prevention:

Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Wash skin
thoroughly after handling. Contaminated work clothing must not be
allowed out of the workplace. Wear protective gloves/ eye protection/
face protection.
Response:
IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If skin irritation or rash
occurs: Get medical advice/ attention. If eye irritation persists: Get
medical advice/ attention. Wash contaminated clothing before reuse.
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to
extinguish.

920069 1 / 10
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - SEA SALT AND BAMBOO REFILL PACK

Storage:
Store in a well-ventilated place. Keep cool.
Disposal:
Dispose of contents/ container to an approved waste disposal plant.

Other hazards : None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture : Mixture

Chemical name CAS-No. Concentration (%)

Butanoic acid, 3-oxo-, ethyl ester 141-97-9 30 - 60
Propylene glycol 57-55-6 30 - 60
solvents /additives 105-53-3 30 - 60
Ethanone, 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8- 54464-57-2 0.1 - 1
tetramethyl-2-naphthalenyl)-

SECTION 4. FIRST AID MEASURES

In case of eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical advice/ attention.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use
a mild soap if available. Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention.

If swallowed : Rinse mouth. Get medical attention if symptoms occur.

If inhaled : Get medical attention if symptoms occur.

Protection of first-aiders : If potential for exposure exists refer to Section 8 for specific personal
protective equipment.

Notes to physician : Treat symptomatically.

Most important symptoms : See Section 11 for more detailed information on health effects and
and effects, both acute and symptoms.
delayed

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Unsuitable extinguishing : High volume water jet

media

Specific hazards during fire : Fire Hazard

fighting Keep away from heat and sources of ignition.
Flash back possible over considerable distance.

Hazardous combustion : Decomposition products may include the following materials:

products Carbon oxides

Special protective equipment : Use personal protective equipment.

for fire-fighters

920069 2 / 10
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - SEA SALT AND BAMBOO REFILL PACK

Specific extinguishing : Fire residues and contaminated fire extinguishing water must be
methods disposed of in accordance with local regulations. In the event of fire
and/or explosion do not breathe fumes.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Remove all sources of ignition. Ensure clean-up is conducted by

protective equipment and trained personnel only. Refer to protective measures listed in sections
emergency procedures 7 and 8.

Environmental precautions : Do not allow contact with soil, surface or ground water.

Methods and materials for : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so.
containment and cleaning up Contain spillage, and then collect with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place
in container for disposal according to local / national regulations (see
section 13). For large spills, dike spilled material or otherwise contain
material to ensure runoff does not reach a waterway.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Do not get in eyes, on skin, or on clothing. Keep away from fire,
sparks and heated surfaces. Take necessary action to avoid static
electricity discharge (which might cause ignition of organic vapors).
Wash hands thoroughly after handling. In case of mechanical
malfunction, or if in contact with unknown dilution of product, wear full
Personal Protective Equipment (PPE).

Conditions for safe storage : Keep away from heat and sources of ignition. Keep away from
oxidizing agents. Keep out of reach of children. Store in suitable
labeled containers.

Storage temperature : 0 °C to 50 °C

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Components CAS-No. Form of Permissible Basis

exposure concentration
Propylene glycol 57-55-6 TWA 10 mg/m3 AIHA WEEL

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations

below occupational exposure standards.

Personal protective equipment

Eye protection : Wear eye protection/ face protection.

Hand protection : Wear the following personal protective equipment:

Standard glove type.
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.

Skin protection : No special protective equipment required.

920069 3 / 10
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - SEA SALT AND BAMBOO REFILL PACK

Respiratory protection : No personal respiratory protective equipment normally required.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. Wash face, hands and any exposed skin thoroughly after
handling.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid
Color : clear, yellow
Odor : Perfumes, fragrances
pH : Not applicable
Flash point : 70 °C closed cup
Odor Threshold : No data available
Melting point/freezing point : No data available
Initial boiling point and : No data available
boiling range
Evaporation rate : No data available
Flammability (solid, gas) : Not applicable
Upper explosion limit : No data available
Lower explosion limit : No data available
Vapor pressure : No data available
Relative vapor density : No data available
Relative density : No data available
Water solubility : No data available
Solubility in other solvents : No data available
Partition coefficient: n- : No data available
octanol/water
Autoignition temperature : No data available
Thermal decomposition : No data available
Viscosity, kinematic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Molecular weight : No data available
VOC : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : Stable under normal conditions.

Possibility of hazardous : No dangerous reaction known under conditions of normal use.

reactions

Conditions to avoid : Heat, flames and sparks.

920069 4 / 10
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - SEA SALT AND BAMBOO REFILL PACK

Incompatible materials : None known.

Hazardous decomposition : In case of fire hazardous decomposition products may be produced

products such as:
Carbon oxides

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of : Inhalation, Eye contact, Skin contact

exposure

Potential Health Effects

Eyes : Causes serious eye irritation.

Skin : May cause allergic skin reaction.

Ingestion : Health injuries are not known or expected under normal use.

Inhalation : Health injuries are not known or expected under normal use.

Chronic Exposure : Health injuries are not known or expected under normal use.

Experience with human exposure

Eye contact : Redness, Pain, Irritation

Skin contact : Redness, Irritation, Allergic reactions

Ingestion : No symptoms known or expected.

Inhalation : No symptoms known or expected.

Toxicity

Product
Acute oral toxicity : No data available
Acute inhalation toxicity : No data available
Acute dermal toxicity : No data available
Skin corrosion/irritation : No data available
Serious eye damage/eye : No data available
irritation
Respiratory or skin : No data available
sensitization
Carcinogenicity : No data available
Reproductive effects : No data available
Germ cell mutagenicity : No data available
Teratogenicity : No data available
STOT-single exposure : No data available
STOT-repeated exposure : No data available
Aspiration toxicity : No data available
Components

920069 5 / 10
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - SEA SALT AND BAMBOO REFILL PACK

Acute oral toxicity : Butanoic acid, 3-oxo-, ethyl ester

LD50 Rat: 11,550 mg/kg

Propylene glycol
LD50 Rat: 22,000 mg/kg

solvents /additives
LD50 Rat: 15,794 mg/kg

Ethanone, 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-
naphthalenyl)-
LD50 Rat: > 5,000 mg/kg

Components
Acute inhalation toxicity : Propylene glycol
4 h LC50 Rat: > 158.5 mg/l
Test atmosphere: dust/mist

Components
Acute dermal toxicity : solvents /additives
LD50 Rabbit: > 16,960 mg/kg

Ethanone, 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-
naphthalenyl)-
LD50 Rat: > 5,000 mg/kg

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Environmental Effects : Harmful to aquatic life with long lasting effects.

Product
Toxicity to fish : No data available
Toxicity to daphnia and other : No data available
aquatic invertebrates
Toxicity to algae : No data available
Components
Toxicity to fish : Butanoic acid, 3-oxo-, ethyl ester
96 h LC50 Danio rerio (zebra fish): > 100 mg/l

Propylene glycol
96 h LC50: > 10,000 mg/l

solvents /additives
96 h LC50 Pimephales promelas: 12 mg/l

Ethanone, 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-
naphthalenyl)-
96 h LC50: 1.3 mg/l

Components
Toxicity to daphnia and other : Butanoic acid, 3-oxo-, ethyl ester
aquatic invertebrates 48 h EC50 Daphnia magna (Water flea): > 100 mg/l

920069 6 / 10
SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - SEA SALT AND BAMBOO REFILL PACK

Propylene glycol
48 h EC50: 18,340 mg/l

solvents /additives
48 h EC50 Daphnia magna (Water flea): 202.3 mg/l

Ethanone, 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-
naphthalenyl)-
48 h EC50: 1.38 mg/l

Components
Toxicity to algae : Butanoic acid, 3-oxo-, ethyl ester
72 h EC50 Desmodesmus subspicatus (green algae): > 100 mg/l

Propylene glycol
96 h EC50: 19,000 mg/l

solvents /additives
72 h EC50 Desmodesmus subspicatus (green algae): > 800 mg/l

Ethanone, 1-(1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-
naphthalenyl)-
72 h EC50: > 2.6 mg/l
NOEC: 0.049 mg/l

Persistence and degradability

Readily biodegradable.

Bioaccumulative potential
No data available

Mobility in soil
No data available

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods : Do not contaminate ponds, waterways or ditches with chemical or

used container. Where possible recycling is preferred to disposal or
incineration. If recycling is not practicable, dispose of in compliance
with local regulations. Dispose of wastes in an approved waste
disposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be taken to

an approved waste handling site for recycling or disposal. Do not re-
use empty containers. Dispose of in accordance with local, state, and
federal regulations.

SECTION 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are
in compliance with the selected mode of transport.

Land transport (DOT)

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SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - SEA SALT AND BAMBOO REFILL PACK

Not dangerous goods

Sea transport (IMDG/IMO)

Not dangerous goods

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)

Serious eye damage or eye irritation
Respiratory or skin sensitization

SARA 302 : This material does not contain any components with a section 302
EHS TPQ.

SARA 313 : This material does not contain any chemical components with known
CAS numbers that exceed the threshold (De Minimis) reporting levels
established by SARA Title III, Section 313.

California Prop. 65
This product does not contain any chemicals known to the State of California to cause cancer, birth, or
any other reproductive defects.

California Cleaning Product Right to Know Act of 2017 (SB 258)

This regulation applies to this product.
Chemical Name CAS-No. Function List(s)
Butanoic acid, 3-oxo-, ethyl ester 141-97-9 Fragrance Not Applicable
Propylene glycol 57-55-6 Fragrance 12
solvents /additives 105-53-3 Fragrance Not Applicable
Alpha-Isomethyl Ionone 127-51-5 Fragrance FRA
Ethanone, 1-(1,2,3,4,5,6,7,8- 54464-57-2 Fragrance Not Applicable
octahydro-2,3,8,8-tetramethyl-2-
naphthalenyl)-
tetrahydro-2-isobutyl-4- 63500-71-0 Fragrance Not Applicable
methylpyran-4-ol, mixed isomers
(cis and trans)
3-p-cumenyl-2- 103-95-7 Fragrance Not Applicable
methylpropionaldehyde
Citronellol 106-22-9 Fragrance FRA
Benzyl salicylate 118-58-1 Fragrance FRA
Eugenol 97-53-0 Fragrance FRA
Benzyl benzoate 120-51-4 Fragrance FRA
Hexyl cinnamal 101-86-0 Fragrance FRA
Acetic acid, (3-methylbutoxy)-, 2- 67634-00-8 Fragrance Not Applicable
propenyl ester
solvents /additives 18127-01-0 Fragrance Not Applicable
Isoeugenol 97-54-1 Fragrance FRA
Citral 5392-40-5 Fragrance FRA

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SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - SEA SALT AND BAMBOO REFILL PACK

*refer to ecolab.com/sds for electronic links to designated lists

The ingredients of this product are reported in the following inventories:

United States TSCA Inventory :

All substances listed as active on the TSCA inventory

Canadian Domestic Substances List (DSL) :

All components of this product are on the Canadian DSL

Australia Inventory of Chemical Substances (AICS) :

On the inventory, or in compliance with the inventory

New Zealand. Inventory of Chemical Substances :

not determined

Japan. ENCS - Existing and New Chemical Substances Inventory :

not determined

Korea. Korean Existing Chemicals Inventory (KECI) :

On the inventory, or in compliance with the inventory

Philippines Inventory of Chemicals and Chemical Substances (PICCS) :

On the inventory, or in compliance with the inventory

China. Inventory of Existing Chemical Substances in China (IECSC) :

On the inventory, or in compliance with the inventory

Taiwan Chemical Substance Inventory (TCSI) :

On the inventory, or in compliance with the inventory

SECTION 16. OTHER INFORMATION

NFPA: HMIS III:

Flammability

HEALTH 2*
2
Instability
Health

2 0 FLAMMABILITY 2
PHYSICAL HAZARD 0
0 = not significant, 1 = Slight,
Special hazard 2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Issuing date : 10/29/2019

Version : 1.2
Prepared by : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is
indicated by a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a

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SAFETY DATA SHEET
LARGE SPACE AIR FRESHENER - SEA SALT AND BAMBOO REFILL PACK

guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

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