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MSDS Thinner 65

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Conforms to 93/112/EC and ISO 11014-1

SAFETY DATA SHEET

AMERCOAT 65 THINNER

1 Identification of the substance/preparation and of the company/undertaking


Product name : AMERCOAT 65 THINNER

Product Code : 1006500

Applications : For professional use only. Refer to Technical Data Sheet for further information.

Supplier/ Manufacturer : Ameron BV Protective Coatings Group


J.F.Kennedylaan 7
P.O. Box 6, 4190 CA, Geldermalsen, The Netherlands

Telephone No. : +31 345 587587


Fax : +31 345 587551
Emergency phone : +31 345 587587

2 Composition and Information on Ingredients

Substance/Preparation : Preparation

Preparation : Coatings: Thinning / Cleaning solvents

Europe
Ingredient Name* CAS No. % Symbol R-Phrases
1) Xylene 1330-20-7 60-100 Xn R10, R20/21, R38

Preparation comments : Substances presenting a hazard within the meaning of the Chemicals (Hazard Information and
Packaging) Regulations 1993 and subsequent amendments (Directives 67/548/EEC,
88/379/EEC).
* Occupational Exposure Limit(s), if available, are listed in section 8

3 Hazards Identification

Physical/chemical hazards : Flammable.

Human health hazards : Harmful by inhalation and in contact with skin.


Irritating to skin.

Environmental hazards : Not applicable.

4 First-Aid measures

General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything
by mouth to an unconscious person.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention.

Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything
by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or
waistband. Get medical attention if symptoms appear.

Skin Contact : In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an
emollient. Remove contaminated clothing and shoes. Wash clothing before reuse.
Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately flush eyes with
plenty of water for at least 15 minutes. Get medical attention.

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AMERCOAT 65 THINNER

5 Fire-Fighting Measures
Extinguishing Media

Suitable : Flammable liquid.


SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use alcohol foam, water spray or fog. Sand. Carbon Dioxide (CO2). Do not
use water jet.
Special fire-fighting procedures : Decomposition products thermal decomposition may release hazardous gases. Fire fighters
should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout
gear. Use water spray to keep fire exposed containers cool. Prevent entry into sewers,
basements or confined areas; dike if needed.

6 Accidental Release Measures

Environmental Precautions and : Flammable liquid.


Clean-up Methods Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb
with DRY earth, sand or other non-combustible material. Do not touch spilled material. Prevent
entry into sewers, basements or confined areas; dike if needed. Be careful that the product is
not present at a concentration level above TLV. Check TLV on the MSDS and with local
authorities.

7 Handling and Storage

Handling : Keep locked up. Keep away from heat. Keep away from sources of ignition. Ground all
equipment containing material. Do not breathe gas/fumes/ vapor/spray. Avoid contact with skin
and eyes. Wear suitable protective clothing. If you feel unwell, seek medical attention and show
the label when possible. Eating, drinking and smoking should be prohibited in area where this
material is handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking.
Storage : Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep
container tightly closed and sealed until ready for use. Avoid all possible sources of ignition
(spark or flame). Do not store below 5°C or above 40°C. Store away from direct sunlight. This
product should be stored away from oxidizing materials and strong bases/acids.

8 Exposure Controls and Personal Protection

Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of
vapors below their respective threshold limit value. Ensure that eyewash stations and safety
showers are proximal to the work-station location.
Ingredient Name Occupational Exposure Limits

United Kingdom (UK)


1) Xylene TWA: 441 STEL: 662 (mg/m3) [United Kingdom (UK)] [1997] SKIN

Ingredient comments : All personal protective equipment, including respiratory protective equipment, used to control
exposure to hazardous substances must be selected to meet the requirements of the COSHH
regulations.

Respiratory system : Provide adequate ventilation. Use appropriate respiratory protection if there is the potential to
exceed the exposure limit(s). Vapor respirator or a self-contained breathing apparatus. Be sure
to use an approved/certified respirator or equivalent.

Skin and Body : Overalls buttoned to the neck and wrist. Remove contaminated clothing and shoes. Wash
contaminated skin with soap and water.
Hands : Protective gloves and protectives skin cream After handling, always wash hands thoroughly with
soap and water.
Eyes : Eye protection: Chemical safety goggles should be worn under normal conditions of use.
Selection of specific eye protection depends on work activity and amount of product released.

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AMERCOAT 65 THINNER

9 Physical and Chemical Properties


Physical state : Liquid.

Color : Clear

Odor : Aromatic.

Boiling Point : 138°C (280.4°F)

Density : 0.87 g/cm3 at 25°C (77°F)

Vapor Density : >1 (Air = 1)

Vapor Pressure : 4 kPa (@ 20°C)

Evaporation rate (butyl acetate = : 0.77 (Xylene) compared to (n-BUTYL ACETATE=1)


1)

Flash point : CLOSED CUP: 24°C (75.2°F). (Setaflash.)

Autoignition temperature : The lowest known value is 463.35 to 528.95°C (866 to 984.1°F) (Xylene).

Viscosity : < 12 s (20°C) Din cup 4 mm

10 Stability and Reactivity

Stability : The product is stable.

Conditions to avoid : Do not store below 5°C or above 40°C.

Materials to avoid : This product should be stored away from oxidizing materials and strong bases/acids.

Hazardous Decomposition : Decomposition products thermal decomposition may release hazardous gases. These
Products products are carbon oxides (CO, CO2) nitrogen oxides (NO, NO2...)

11 Toxicological Information

Local effects

Skin irritation : Hazardous in case of skin contact (irritant).


Eye irritation : Not available.

Acute toxicity : Acute oral toxicity (LD50): 4300 mg/kg (rat) (Calculated value for the mixture).
Acute dermal toxicity (LD50): 1800 mg/kg (rabbit) (Calculated value for the mixture).
Chronic toxicity : Repeated or prolonged exposure is not known to aggravate medical condition.

Specific effects

Carcinogenic effects : Classified A4 (Not classifiable for human or animal.) by ACGIH, 3 (Not classifiable for human.)
by IARC [Xylene].

12 Ecological Information
Ecotoxicity : Not available. Prevent entry into sewers, basements or confined areas; dike if needed.

13 Disposal considerations
Methods of disposal; Waste of : Dispose of this material and its container at hazardous or special waste collection points. Waste
residues; Contaminated must be disposed of in accordance with local environmental control regulations.
packaging

14 Transport Information
General : Transport classification notes:
Labelling and packaging requirements may vary with pack and load size. Please refer to the
current transport regulations.

Transport within user's premises always transport in closed containers that are upright and
secure. Ensure that persons transporting the product know what to do in the event of accident or
spillage.

Land - Road/Railway
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AMERCOAT 65 THINNER

UN number : 1307
Proper shipping name : Xylenes
ADR/RID Class : 3
ADR/RID Item number : 31c
Hazchem UK : 3Y
Hazard Identification Number : 30
Road Transport Notes : Category 3
Sea

UN number : 1307
Proper shipping name : Xylenes
IMDG Class : 3.3
Packing Group : III
IMDG Page Number : 3394
Medical First Aid Guide : 310
(MFAG)
Emergency Schedules (EmS) : 3-07
Marine Pollutant : Not pollutant.

Air

UN/ID Number : 1307


Proper shipping name : Xylenes
IATA-DGR Class : 3
Packing Group : III
Packaging Instruction : 309 and 310

15 Regulatory Information

EU Regulations
Hazard symbol(s) :

Classification : Harmful

Risk Phrases : R10- Flammable.


R20/21- Harmful by inhalation and in contact with skin.
R38- Irritating to skin.
Safety Phrases : S23- Do not breathe gas/fumes/vapour/spray [***]
S36/37- Wear suitable protective clothing and gloves.
S38- In case of insufficient ventilation, wear suitable respiratory equipment.
S51- Use only in well-ventilated areas.
Contains : - Xylene

United Kingdom

UK Regulatory references : This product is classified and labelled for supply in accordance with the Chemicals (Hazard
Information and Packaging for Supply) Regulations 1993 and subsequent amendments
(Directive 88/379/EEC).
The safety data sheet does not constitute the users own assessment of the workplace risk as
required by other health and safety legislation e.g. the Control of Substances Hazardous to
Health (COSHH) Regulations.
The Manual Handling operations Regulations may apply to the handling of containers/packages
of this product. To assist employers, the following method of calculating the weight for any pack
size is given. Take the size volume in litres and multiply this figure by the density value given in
section 9. This will give the net weight of the coating in kilograms. Allowance will then have to be
made for the immediate packaging to give an approximate gross weight.

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AMERCOAT 65 THINNER

16 Other Information

Date of printing : 04-08-2000.


Date of issue : 01-03-2000.
Date of Previous Issue : No Previous Validation.
Version : 1
Other information : EH 40 Occupational Exposure Limits.
HS(G)53 Respiratory protective equipment: a practical guide to users.
EH 9 Spraying of highly flammable liquids.
HS(G)22 Electrical apparatus for use in potentially explosive atmospheres.
HS(G)51 Storage of flammable liquids in containers.

Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and
should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.
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