SAFETY DATA SHEET

BIOC36297NR

Section: 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : BIOC36297NR

Other means of identification : Not applicable.

Recommended use : BIOCIDE

Restrictions on use : Refer to available product literature or ask your local Sales Representative for
restrictions on use and dose limits.

Company : Champion Technologies do Brasil Serviços e Produtos Químicos Ltda.

Rua Alcides da Conceição, nº 69
Vale Encantado - Macaé CEP 27933-378
Brazil
TEL: +55 22 2106-6666

Emergency telephone : ABIQUIM/PROQUÍMICA: 0800 110 8270; ChampionX: +55 22 2106-6666

number

Issuing date : 23.03.2021

Section: 2. HAZARDS IDENTIFICATION

GHS Classification
Acute toxicity (Oral) : Category 4
Acute toxicity (Inhalation) : Category 4
Serious eye damage : Category 1
Skin sensitization : Category 1
Carcinogenicity : Category 1A
Reproductive toxicity : Category 2
Acute aquatic toxicity : Category 3
Chronic aquatic toxicity : Category 2

GHS Label element

Hazard pictograms :

Signal Word : Danger

Hazard Statements : Harmful if swallowed or if inhaled.

May cause an allergic skin reaction.
Causes serious eye damage.
May cause cancer.
Suspected of damaging fertility or the unborn child.
Harmful to aquatic life.
Toxic to aquatic life with long lasting effects.

Precautionary Statements : Prevention:

Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Avoid release to the
environment. Wear protective gloves/ protective clothing/ eye protection/ face
protection.
Response:
IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel
unwell. Rinse mouth. IF ON SKIN: Wash with plenty of water. IF INHALED:

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Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER or doctor/ physician if you feel unwell. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician.
Storage:
Store in accordance with local regulations.
Disposal:
Dispose of contents/ container to an approved waste disposal plant.

Other hazards : None known.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture : Mixture

Chemical Name CAS-No. Concentration: (%)

Tetrakis(hydroxymethyl) phosphonium sulfate 55566-30-8 30 - 60
Formaldehyde 50-00-0 0,1 - 1

Section: 4. FIRST AID MEASURES

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Get medical attention immediately.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild
soap if available. Wash clothing before reuse. Thoroughly clean shoes before
reuse. Get medical attention.

If swallowed : Rinse mouth. Get medical attention if symptoms occur.

If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention.

Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put
yourself at risk of injury. If in doubt, contact emergency responders. Use
personal protective equipment as required.

Notes to physician : Treat symptomatically.

Most important symptoms : See Section 11 for more detailed information on health effects and symptoms.
and effects, both acute and
delayed

Section: 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.

Unsuitable extinguishing : None known.

media

Specific hazards during : Not flammable or combustible.

firefighting

Hazardous combustion : Carbon oxides Sulphur oxides Oxides of phosphorus

products

Special protective equipment : Use personal protective equipment.

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for firefighters

Specific extinguishing : Collect contaminated fire extinguishing water separately. This must not be
methods discharged into drains. Fire residues and contaminated fire extinguishing water
must be disposed of in accordance with local regulations. In the event of fire
and/or explosion do not breathe fumes.

Section: 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Ensure adequate ventilation. Keep people away from and upwind of spill/leak.
protective equipment and Avoid inhalation, ingestion and contact with skin and eyes. When workers are
emergency procedures facing concentrations above the exposure limit they must use appropriate
certified respirators. Ensure clean-up is conducted by trained personnel only.
Refer to protective measures listed.

Environmental precautions : Do not allow contact with soil, surface or ground water.

Methods and materials for : Stop leak if safe to do so. Contain spillage, and then collect with non-
containment and cleaning up combustible absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to local / national
regulations (see section 13). For large spills, dike spilled material or otherwise
contain material to ensure runoff does not reach a waterway.

Section: 7. HANDLING AND STORAGE

Advice on safe handling : Do not ingest. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in
eyes, on skin, or on clothing. Wash hands thoroughly after handling. Use only
with adequate ventilation.

Conditions for safe storage : Keep out of reach of children. Store separately from oxidizers. Store separately
from bases. Keep container tightly closed. Store in suitable labelled containers.

Keep out of reach of children. Keep container tightly closed. Store in suitable
labelled containers.

Suitable material : Keep in properly labelled containers.

Unsuitable material : not determined

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Form of exposure Permissible Basis

concentration
Formaldehyde 50-00-0 CEIL 1,6 ppm BR OEL
2,3 mg/m3
Tetrakis(hydroxymethyl) 55566-30-8 TWA 2 mg/m3 ACGIH
phosphonium sulfate
Formaldehyde 50-00-0 TWA 0,016 ppm NIOSH REL
Ceiling 0,1 ppm NIOSH REL
PEL 0,75 ppm OSHA CARC
STEL 2 ppm OSHA CARC
TWA 0,016 ppm NIOSH REL
(Formaldehyde)
Ceiling 0,1 ppm NIOSH REL
(Formaldehyde)

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TWA 0,1 ppm ACGIH

STEL 0,3 ppm ACGIH

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below
occupational exposure standards.

Personal protective equipment

Eye protection : Safety goggles

Face-shield

Hand protection : Recommended preventive skin protection

Gloves
Nitrile rubber
butyl-rubber
Breakthrough time: 1 – 4 hours
Consult PPE manufacturer for the appropriate glove thickness (depending on
the type of gloves and its intended use).
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.

Skin protection : Wear suitable protective clothing.

Respiratory protection : When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove
and wash contaminated clothing before re-use. Wash face, hands and any
exposed skin thoroughly after handling. Provide suitable facilities for quick
drenching or flushing of the eyes and body in case of contact or splash hazard.

The Personal Protective Equipment (PPE) recommendations provided above have been made in good faith
based on typical expected conditions of use. PPE selection should always be completed in conjunction with a
proper risk assessment and in accordance with a PPE management program.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Liquid
Colour : colourless
Odour : Characteristic
Flash point : Not applicable.
pH : 3,2,(100 %)
Odour Threshold : no data available
Melting point/freezing point : Freezing Point: -43,0 °C
Initial boiling point and boiling : no data available
range
Evaporation rate : no data available
Flammability (solid, gas) : Not applicable.
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapour pressure : 48,0 mm Hg,
Relative vapour density : no data available

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Relative density : 1,16,

Density : 1,162 g/cm3 , 9,7 lb/gal
Water solubility : no data available
Solubility in other solvents : no data available
Partition coefficient: n- : no data available
octanol/water
Auto-ignition temperature : no data available
Thermal decomposition : no data available
Viscosity, dynamic : no data available
Viscosity, kinematic : 21 mm2/s (25 °C)
Molecular weight : no data available
VOC : 35,0 %

Section: 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : Stable under normal conditions.

Possibility of hazardous : No dangerous reaction known under conditions of normal use.

reactions

Conditions to avoid : None known.

Incompatible materials : Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid,
perchlorate, concentrated oxygen, permanganate) may generate heat, fires,
explosions and/or toxic vapors.
Contact with strong alkalies (e.g. ammonia and its solutions, carbonates, sodium
hydroxide (caustic), potassium hydroxide, calcium hydroxide (lime), cyanide,
sulfide, hypochlorites, chlorites) may generate heat, splattering or boiling and
toxic vapors.

Hazardous decomposition : Oxides of carbon

products Oxides of phosphorus
Oxides of sulfur
Phosphine (highly toxic and flammable)

Section: 11. TOXICOLOGICAL INFORMATION

Information on likely routes of : Inhalation, Eye contact, Skin contact

exposure

Potential Health Effects

Eyes : Causes serious eye damage.

Skin : May cause allergic skin reaction.

Ingestion : Harmful if swallowed.

Inhalation : Harmful if inhaled.

Chronic Exposure : May cause cancer. Suspected of damaging fertility or the unborn child.

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Experience with human exposure

Eye contact : Redness, Pain, Corrosion

Skin contact : Redness, Irritation, Allergic reactions

Ingestion : No information available.

Inhalation : No information available.

Toxicity

Product
Acute oral toxicity : Acute toxicity estimate: 1.178 mg/kg
Acute inhalation toxicity : Acute toxicity estimate: 1,25 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Acute dermal toxicity : Acute toxicity estimate: > 5.000 mg/kg
Skin corrosion/irritation :
Method: OECD 404
Test substance: 75% Active Ingredient
Serious eye damage/eye : Species: rabbit
irritation Method: OECD Test Guideline 405
Respiratory or skin : no data available
sensitization
Carcinogenicity : no data available
Reproductive effects : no data available
Germ cell mutagenicity : no data available
Teratogenicity : no data available
STOT - single exposure : no data available
STOT - repeated exposure : no data available
Aspiration toxicity : no data available

Section: 12. ECOLOGICAL INFORMATION

Toxicity

Environmental Effects : Harmful to aquatic life.

Toxic to aquatic life with long lasting effects.

Product
Toxicity to fish : LC50 Lepomis macrochirus (Bluegill sunfish): 93 mg/l
Exposure time: 96 hrs
Test substance: 75% Active Ingredient

LC50 Oncorhynchus mykiss (rainbow trout): 119 mg/l

Exposure time: 96 hrs
Test substance: 75% Active Ingredient

Toxicity to daphnia and other : EC50 Daphnia magna (Water flea): 19,4 mg/l
aquatic invertebrates Exposure time: 48 hrs
Test substance: 75% Active Ingredient

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Toxicity to algae : LC50 Green Algae (Pseudokirchneriella subcapitata,

previously Selenastrum capricornutum): 0,20 mg/l
Exposure time: 96 hrs
Test substance: 75% Active Ingredient

Toxicity to bacteria : EC50 Bacteria: 24 mg/l

Exposure time: 3 hrs
Test substance: 75% Active Ingredient

Components
Toxicity to fish (Chronic : Formaldehyde
toxicity) LC50: 21 mg/l
Exposure time: 96 h

Persistence and degradability

The organic portion of this preparation is expected to be readily biodegradable.

Mobility

The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program
interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total
input and output. The level III model does not require equilibrium between the defined media. The information
provided is intended to give the user a general estimate of the environmental fate of this product under the
defined conditions of the models.
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the
approximate respective percentages;

Air : <5%
Water : 10 - 30%
Soil : 30 - 50%

The portion in water is expected to be soluble or dispersible.

Bioaccumulative potential

This preparation or material is not expected to bioaccumulate.

Other information

no data available

Section: 13. DISPOSAL CONSIDERATIONS

Disposal methods : Dispose of product, waste product and product packaging

should follow the Federal, State, Municipal and local current
regulation. Consult the environmental official organ if
necessary. The classification of waste should be determined
according to Brazilian Normative 10004 "Solid waste -
Classification." The transport and disposal should be
performed by a properly licensed company. Do not reuse
container for any purpose. DO NOT DUMP INTO SEWERS,
ON THE SOIL OR INTO ANY WATER COURSE.

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Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in
compliance with the selected mode of transport.

Land transport (ANTT 5.232)

Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S.
Technical name(s) : Tetrakis(hydroxymethyl) phosphonium sulfate
UN/ID No. : 3082
Transport hazard class(es) : 9
Risk Number : 90
Packing group : III

Air transport (IATA)

Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S.
Technical name(s) : Tetrakis(hydroxymethyl) phosphonium sulfate
UN/ID No. : UN 3082
Transport hazard class(es) : 9
Packing group : III

Sea transport (IMDG/IMO)

Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S.
Technical name(s) : Tetrakis(hydroxymethyl) phosphonium sulfate
UN/ID No. : UN 3082
Transport hazard class(es) : 9
Packing group : III
Marine pollutant : Tetrakis(hydroxymethyl) phosphonium sulfate

Section: 15. REGULATORY INFORMATION

NATIONAL REGULATIONS, BRAZIL

Registrations and Certifications

Brazil: Our FISPQ complies with the Brazilian Rule ABNT NBR 14725.

Section: 16. OTHER INFORMATION

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NFPA: HMIS III:

Flammability

HEALTH 2
0

Instability
Health

2 0 FLAMMABILITY 0
PHYSICAL HAZARD 0
0 = not significant, 1 = Slight,
2 = Moderate, 3 = High
Special hazard. 4 = Extreme, * = Chronic

Revision Date : 23.03.2021

Version Number : 1.8
Prepared By : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by
a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and
belief at the date of its publication. The information given is designed only as a guidance for safe handling,
use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid for
such material used in combination with any other materials or in any process, unless specified in the text.

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