II Lloyd's

Register
MARINE BUNKER AND INTERMEDIATE FUEL OILS

LLOYD'S REGISTER GMT LTD

THE WILTON CENTRE
WILTON
REDCAR
CLEVELAND
TS17 0RZ
UNITED KINGDOM
TEL: +44 (0)1642 440991
EMAIL: FOBASsamples@lr.org
WEB: www.lr.org/lrgmt

MARINE BUNKER OILS

INTERMEDIATE FUEL OIL ISO 8217: 2005 I 2010

CLASSES RMA10, RMB30, RMD80,
RME180, RMG180 RMF180, RMG380,
RMH380, RMK380, RMG500, RMK500
RMH700, RMK700

MARINE BUNKER FUEL OIL ISO 8217: 2005 / 2010

CLASSES RMA10, RMB30, RMD80,
RME180, RMG180 RMF180, RMG380,
RMH380, RMK380, RMG500, RMK500
RMH700, RMK700

MARINE BUNKER DISTILLATE OIL ISO 8217: 2005 / 2010

CLASSES DMA, DMB, DMC, DMX, DMZ

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION

These oils are used as fuels in industrial heating plant (boilers and furnaces), in marine boilers and in low
speed diesel engines.
Fuel Oils, Residual: CAS No. 68476-33-5 EINECS No. 270-675-6

COMPANY IDENTIFICATION: LLOYD'S REGISTER GMT LIMITED

THE WILTON CENTRE
WILTON
REDCAR
CLEVELAND
TS17 0RZ
UNITED KINGDOM
TEL: +44 (0)1642 440991

EMERGENCY TELEPHONE NO: +44 (0)1642 440991

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2. COMPOSITION/INFORMATION ON INGREDIENTS

Residual Fuel Oils are paraffinic, naphthenic and aromatic hydrocarbons mainly from blends of residues from
crude oil distillation but which may contain proportions of petroleum middle distillates and catalytically or
thermally cracked components. Small quantities of Hydrogen Sulphide and light hydrocarbons may be
present. Compounds of trace metals such as Vanadium are commonly present in the ash after combustion.

3. HAZARD IDENTIFICATION

Residual fuel oils are customarily supplied as "heated oils", usually in the temperature range 60 - 75 "C.

Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion
hazards even at temperatures below the normal flash point of the fuel. Tank headspaces should always be
regarded as potentially flammable.

(Note: flash point must not be regarded as a reliable Indicator of potential flammablllty).

If hot product causes burns, the affected area should be flooded immediately with, or immersed in, cold
water for 10 minutes, or longer if pain persists. Burns should be covered with clean cotton or gauze, and
medical advice sought as soon as possible.

Injection of fuel under the skin may have serious ettects, seek medical advice urgently.

Residual fuel oils, particularly when catalytically and thermally cracked hydrocarbons are present, may
contain polycyclic aromatic hydrocarbons (PCAs); some PCAs have been classified as category 2
carcinogens.

Hydrogen Sulphide (H2S) gas may accumulate in the confined vapour spaces above fuel oil in storage tanks
and the bulk storage compartments of transport vehicles. Hydrogen Sulphide is an extremely toxic gas. An
Occupational Exposure Standard for Hydrogen Sulphide is listed in HSE Guidance Note EH4O: currently:

Long term exposure limit - (8 hour TWA reference period) - 1 O ppm, 14 milligrams per cubic metre.

Short term exposure limit - (10 minute TWA reference period) - 15 ppm, 21 milligrams per cubic metre.

There is no appropriate occupational exposure limit for this material, due to the presence of polycyclic
aromatic hydrocarbons. Avoid, as far as is practicable, the inhalation of vapour, mists or fumes generated
during use. If operations are such that excessive generation of vapour, mists or fume is generated, to which
operators may be unavoidably exposed, suitable approved respiratory equipment should be worn.

The use of respiratory equipment must be strictly in accordance with the manufacturer's instructions and any
statutory requirements covering its selection and use.

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4. FIRST AID

INHALATION: Fumes or vapour may cause irritation to eyes and mucous membranes, and drowsiness
leading to loss of consciousness. Hydrogen Sulphide (H2S) gas may accumulate in vapour spaces above
fuel oil in tanks.

First Aid: If inhalation of vapour causes irritation or drowsiness remove IMMEDIATELY to fresh air. Get
medical advice.

SKIN CONTACT: Unlikely to cause irritation on single contact. Prolonged or repeated contact may cause
dermatitis which could eventually lead to irreversible skin disorders. Injection of fuel under pressure through
the skin may have serious effects which at first may not seem serious but, within hours, may become very
painful.

First Aid: Wash skin as soon as possible with soap and water. Change contaminated clothing immediately
and launder before reuse. Get medical advice if irritation persists.
Any injection of fuel under the skin should be considered an EMERGENCY
Flood with cold water for at least 1 0 minutes and URGENTLY seek Medical Advice.

EVE CONTACT: May cause short-term irritation with redness and stinging.

First Aid: Wash out immediately with large amounts of water. If redness and/or irritation continues get
medical advice.

INGESTION: The swallowing of small amounts is unlikely to have adverse effects; larger amounts
may cause irritation with diarrhoea and vomiting.

First Aid: Wash mouth out with water and give water to drink. If a large amount has been swallowed get
medical advice; DO NOT INDUCE VOMITING BECAUSE OF THE DANGER OF ASPIRATION.

5. FIRE-FIGHTING MEASURES

EXTINGUISHING MEDIA: Extinguish with Dry Powder or Foam. For small fires use CO2.

Note - Flash Point 66"C mm, but if fuel contacts hot surface or leaks from high pressure fuel pipes then the
vapour/mist generated will create a flammability hazard.

Fires in closed or confined spaces should be tackled by trained personnel who should wear breathing
apparatus.

6. ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS: See Section 8.

Treat any spillage as a fire hazard. Spray, vapour or mist can be a potential fire or explosion hazard.

May cause damage to surfaces making them SLIPPERY.

Contain spillage - do not wash spillage down drain. Absorb using absorbent clay, diatomaceous clay or other
suitable absorbent.

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7. HANDLING AND STORAGE

7.1 Handling
Marine fuel oils are primarily designed to be used in closed systems associated with boilers or engines. As
such, handling should only be by competent persons. When handling, attention should be given to the
avoidance of skin contact and avoidance of sources of ignition. In normal use, this material is likely to be hot.

7.2 Storage
The design, construction, and maintenance of bulk storage and handling facilities are covered by codes of
practice published by the Institute of Petroleum, British Standards and the Health and Safety Executive.

Any containers should be stored under cover out of direct sunlight, in well ventilated conditions. Care should
be taken to avoid over•stacking.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Protective clothing . Where skin contact is likely protective clothing should be worn including impervious
GLOVES and EYE PROTECTION. Ensure good ventilation. When handling heated material, suitable
protective clothing should be worn to prevent thermal burns.

Respiratory protection • Unlikely to be required in normal use but care should be taken when sampling or
gauging in case of an accumulation of Hydrogen Sulphide (H2S) which is toxic and flammable (see Section
3. HAZARDS IDENTIFICATION).
Protective clothing and respirators must be worn when overhauling plant or storage facililies.

Hand and skin protection • Hand and skin protection recommended at all times. Where exposure is likely
proteclive clothing must be worn, including nitrile gloves approved to BS EN 374 with a breakthrough time of
>360 minutes.

Eye protection • Eye protection approved to BS EN 166 is recommended at all times

9. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE/ ODOUR: Dark brown/ Black viscous liquid with an asphaltic odour.
DENSITY, g/ml: Max 0.991 at 15 deg. C (range 0.94 · 0.991)
BOILING RANGE: 160.0 - 500.0 deg. C
VISCOSITY, mm2/S: 380.0 at 50 deg. C (range 375 • 385)
REID VAPOUR PRESSURE, kPa: <0.1
VAPOUR DENSITY AT 1 BAR (Air=1): >5
EVAPORATION RATE : Very Low
SOLUBILITY IN WATER: Very Low
pH: Mildly Acidic
FLASH POINT: 60.5 "C MIN
FLAMMABILITY LIMITS% VOL: 1·6
PARTITION COEFFICIENT : 2.7 - 6 for components
EXPLOSIVE / OXIDISING PROPERTIES : Not applicable

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10. STABILITY AND REACTIVITY

Conditions to Avoid - excessive heat

Materials to Avoid - may react with strong oxidising materials.

Hazardous Decomposition Products - thermal decomposition may lead to the formation of a multiplicity of
compounds some of which may be hazardous. With incomplete combustion smoke and hazardous fumes
and gases, including carbon monoxide may be formed.

11. TOXICOLOGICAL INFORMATION

Toxicity following a single exposure (oral, dermally or by inhalation) to high levels of residual fuel oils is
normally of a low order. Under certain conditions small quantities of Hydrogen Sulphide, a toxic gas, may be
liberated into the vapour phase. Residual fuel oils may contain polycyclic aromatic hydrocarbons and have
been classified as category 2 carcinogens.

Dusts generated during the removal of combustion deposits will be harmful if inhaled. Repeated contact may
result in serious irreversible disorders.

12. ECOLOGICAL INFORMATION

Expected to harm aquatic organisms; films formed on water may affect oxygen transfer and damage
organisms. Likely to biodegrade slowly.

13. DISPOSAL CONSIDERATIONS

Dispose by incineration or by methods approved by local authority. Do not discharge into the public drainage
system, or marine and inland waterways.
Fuel oils used for marine applications should be disposed of In accordance with MARPOL
Regulations.

14. TRANSPORT INFORMATION

HAZCHEM Code: 3/Z Symbol: None

UN Number (Substance Identification Number): Flash point> 61 'C No number (non hazardous)
IMO: Not classified as hazardous for transportation.
ICAO Hazard Class/lATA Hazard Class: Not restricted.
ADA/RID Hazard Class: 3, 31c (SIN 1202)

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15. REGULATORY INFORMATION

LABELLING
Symbol: Black Skull & Cross Bones
Classification: Toxic. Dangerous for the environment

R45 May cause cancer.

R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
R66 Repeated exposure may cause skin dryness or cracking
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident, or if feeling unwell, seek medical advice immediately - show the label
where possible.
S61 Avoid release to environment. Refer to special instructions/safety data sheet

16. OTHER INFORMATION

Further information can be found in various publications, a list of which may be obtained from the Health and
Safety Executive.

This data sheet has been prepared in accordance with the requirements of the Data Sheet Directive
91/155/EEC as amended by Directive 2001/581EC.

LEGAL NOTICE

The information in this Data Sheet applies only to the products designated herein. It is based on experience
and on the data available to us at the time of its issue and is accurate to the best of our knowledge. The
customer is strongly advised to observe and ensure that its employees and customers observe all directions
contained herein. However, no warranty is made or implied that the information is accurate or complete and
no liability wilt be accepted whatsoever - (other than liability in respect of the matters referred to in Section 2
Unfair Contract Terms Act 1977) arising out of the use of the information or the products designated herein.
Where third party products are used, the customers should himself obtain all necessary technical, health and
safety information about such products from the third party.

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