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350ML STP 20tuff Stuff MSDS

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REVISION DATE: 10-2005

SAFETY DATA SHEET


TUFF STUFF MULTI-PURPOSE FOAM CLEANER AEROSOL
According to Regulation (EC) No 1907/2006
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

PRODUCT NAME TUFF STUFF MULTI-PURPOSE FOAM CLEANER AEROSOL


APPLICATION Cleaning agent
SUPPLIER Clorox Europe Ltd,
Unit 16, Rassau Industrial Estate,
Ebbw Vale,
Gwent NP23 5SD, UK
Tel: 44 (0) 1495 350234
Fax: 44 (0) 1495 350234
EURegulatory@clorox.com
EMERGENCY TELEPHONE 44 (0) 1495 350234

2 HAZARDS IDENTIFICATION

Extremely flammable.
CLASSIFICATION F+;R12.

PHYSICAL AND CHEMICAL HAZARDS


Extremely flammable. Aerosol cans may explode in a fire.

3 COMPOSITION/INFORMATION ON INGREDIENTS

Name EC No. CAS-No. Content Classification

2-BUTOXYETHANOL 203-905-0 111-76-2 1-5% Xn;R20/21/22 Xi;R36/38

CITRUS FRAGRANCE 3611-D < 1% Xi;R36/37/38. R43.

ISOBUTANE 200-857-2 75-28-5 5-10% F+;R12

The Full Text for all R-Phrases are Displayed in Section 16

4 FIRST-AID MEASURES

INHALATION
Vapours may cause drowsiness and dizziness. Move the exposed person to fresh air at once. Provide rest, warmth and fresh air. Get
medical attention if any discomfort continues.
INGESTION
Rinse mouth thoroughly. Get medical attention. Provide rest, warmth and fresh air.

SKIN CONTACT
Prolonged contact may cause redness and irritation. Wash the skin immediately with soap and water. Do not use solvents or thinners.

EYE CONTACT
May irritate eyes. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while
lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

5 FIRE-FIGHTING MEASURES

EXTINGUISHING MEDIA
Use: Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc. Foam.

SPECIAL FIRE FIGHTING PROCEDURES


Move container from fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out.

UNUSUAL FIRE & EXPLOSION HAZARDS


Extremely flammable. Aerosol cans may explode in a fire.

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REVISION DATE: 10-2005

TUFF STUFF MULTI-PURPOSE FOAM CLEANER AEROSOL


SPECIFIC HAZARDS
Fire creates: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).

PROTECTIVE MEASURES IN FIRE


Self contained breathing apparatus and full protective clothing must be worn in case of fire.

6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.

ENVIRONMENTAL PRECAUTIONS
Avoid discharge to the aquatic environment.

SPILL CLEAN UP METHODS


Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Once the propellant has completely vented, absorb
any remaining liquid in vermiculite, dry sand or earth and place into containers. Containers with collected spillage must be properly labelled
with correct contents and hazard symbol.

7 HANDLING AND STORAGE

USAGE PRECAUTIONS
Read and follow manufacturer's recommendations. Keep away from heat, sparks and open flame. Provide good ventilation. Avoid contact
with eyes. Wash hands after handling.
STORAGE PRECAUTIONS
Keep away from heat, sparks and open flame. Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50°C.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Name Std TWA - 8 hrs STEL - 15 min Notes

2-BUTOXYETHANOL WEL 25 ppm 50 ppm Sk

WEL = Workplace Exposure Limit.


Sk = Can be absorbed through skin.
HAND PROTECTION
For prolonged or repeated skin contact use suitable protective gloves.

EYE PROTECTION
Wear approved chemical safety goggles where eye exposure is reasonably probable.

HYGIENE MEASURES
DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove
any clothing that becomes contaminated. Wash promptly if skin becomes contaminated. When using do not eat, drink or smoke.

9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE Aerosol Liquid


ODOUR Characteristic
SOLUBILITY Soluble in water
RELATIVE DENSITY 1.005 - 1.009 @ 15.6 °C pH-VALUE, CONC. SOLUTION 12.0 - 13.0

10 STABILITY AND REACTIVITY

STABILITY
Stable under normal temperature conditions.

CONDITIONS TO AVOID
Avoid heat, flames and other sources of ignition.

HAZARDOUS DECOMPOSITION PRODUCTS


Fire creates: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).

11 TOXICOLOGICAL INFORMATION

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TUFF STUFF MULTI-PURPOSE FOAM CLEANER AEROSOL


INHALATION
Vapours may cause headache, fatigue, dizziness and nausea. Vapour may irritate respiratory system or lungs. Drowsiness, dizziness,
disorientation, vertigo. Central nervous system depression.
SKIN CONTACT
Prolonged contact may cause irritation.

EYE CONTACT
Spray and vapour in the eyes may cause irritation and smarting.

12 ECOLOGICAL INFORMATION

ECOTOXICITY
Not regarded as dangerous for the environment.

DEGRADABILITY
The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC)
No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and
will be made available to them, at their direct request or at the request of a detergent manufacturer.

13 DISPOSAL CONSIDERATIONS

DISPOSAL METHODS
Dispose of waste and residues in accordance with local authority requirements. Make sure containers are empty before discarding
(explosion risk). Recover and reclaim or recycle, if practical.

14 TRANSPORT INFORMATION

PROPER SHIPPING NAME AEROSOLS


UN NO. ROAD 1950 ADR CLASS NO. 2
ADR CLASS Class 2: Gases ADR LABEL NO. 2.1
RID CLASS NO. 2 UN NO. SEA 1950
IMDG CLASS 2 EMS 2-13
MFAG See Guide UN NO. AIR 1950
AIR CLASS 2

15 REGULATORY INFORMATION

LABELLING

Extremely Flammable

RISK PHRASES
R12 Extremely flammable.

SAFETY PHRASES
S2 Keep out of the reach of children

S16 Keep away from sources of ignition - No smoking.

S25 Avoid contact with eyes.

S51 Use only in well-ventilated areas.

P14 Contains CITRUS FRAGRANCE 3611-D. May produce an allergic reaction.

A1 Pressurised container: protect from sunlight and do not expose to temperatures


exceeding 50°C. Do not pierce or burn, even after use.

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TUFF STUFF MULTI-PURPOSE FOAM CLEANER AEROSOL


A2 Do not spray on a naked flame or any incandescent material.

DETERGENT LABELLING
5 - < 15% Aliphatic hydrocarbons
< 5% Non-ionic surfactants
Perfumes
EU DIRECTIVES
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
STATUTORY INSTRUMENTS
Chemicals (Hazard Information and Packaging) Regulations.

APPROVED CODE OF PRACTICE


Classification and Labelling of Substances and Preparations Dangerous for Supply.

GUIDANCE NOTES
Workplace Exposure Limits EH40.

16 OTHER INFORMATION

REVISION COMMENTS
Supplier name amended. Re-issued in accordance with Regulation (EC) No. 1907/2006 Registration, Evaluation, Authorisation and
Restriction of Chemicals (REACh).
REVISION DATE 10-2005
REV. NO./REPL. SDS GENERATED 3 / 09-2005

RISK PHRASES IN FULL


R12 Extremely flammable.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R36/38 Irritating to eyes and skin.
R36/37/38 Irritating to eyes, respiratory system and skin.
R43 May cause sensitisation by skin contact.

DISCLAIMER
The information supplied here is accurate to the best knowledge and belief of Clorox Europe Ltd, it is however, not intended as a warranty or
representation, and should not be construed as such, for which Clorox Europe Ltd assumes any legal responsibility. Any information or advice obtained
from Clorox Europe Ltd other than by means of this publication, and whether relating to Clorox Europe Ltd's products or other materials is also given in
good faith. It remains at all times the responsibility of the customer, and user, to ensure that the materials are suitable for the particular purpose
intended. Materials not manufactured, or supplied, by Clorox Europe Ltd when used instead of, or in conjunction with materials supplied by Clorox
Europe Ltd, it is the customer's responsibility to ensure that all technical, and other information related to such materials is obtained from the
manufacturer or supplier. Clorox Europe Ltd accepts no liability for the data contained within this document, as the information herein may be applied
under conditions beyond our control, and in situations with which we may be unfamiliar. The information contained within this document is furnished
upon condition that the customer and user of this product makes his own determination of the suitability of the product for his particular purpose.
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