Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

SAFETY DATA SHEET

AMERSPERSE 280
1. Identification of the substance/preparation and of the company/undertaking
Product name : AMERSPERSE 280
Material Uses : Industrial applications: Microbiocide for cooling water treatment

Manufacturer / Supplier :
Drew Marine Drew Marine
Ashland Specialty Chemical Company Ashland Specialty Chemical Company
Malledijk 20 One Drew Plaza
3208 LA Spijkenisse Boonton, NJ 07005
Netherlands United States
Tel. No.: Tel. No.:
+31 181 457 070 +1 (973) 263 7600
Fax: Fax:
+31 181 625 792 +1 (973) 263 4491
Emergency telephone number
(Germany) : +49 621 60-43333
Fax:
(Germany) : +49 621 60-92664

2. Composition/information on ingredients
Substance/Preparation : Preparation

Chemical name* CAS No. % EC Number Classification

Sodium dimethyldithiocarbamate 128-04-1 10-20 204-876-7 Xn; R21/22
Disodium ethylenebis(N,N'-dithiocarbamate 142-59-6 10-20 205-547-0 Xn; R22
Xi; R37
R43
N; R50/53
See Section 16 for the full text of the R Phrases declared above

* Occupational Exposure Limit(s), if available, are listed in Section 8

3. Hazards identification
The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
Classification : Harmful, Dangerous for the environment
R22- Harmful if swallowed.
R43- May cause sensitization by skin contact.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
Effects and symptoms
Skin contact : Hazardous in case of skin contact (sensitizer).

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4. First-aid measures
First-Aid measures
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Obtain medical attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. If large quantities of
this material are swallowed, call a physician immediately. Loosen tight clothing
such as a collar, tie, belt or waistband.
Skin contact : In case of contact, immediately flush skin copiously with water for at least 15
minutes while removing contaminated clothing and shoes. Cold water may be
used. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Obtain medical attention.
Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
flush eyes with a copious amount of water for at least 15 minutes. Cold water
may be used. Obtain medical attention.

5. Fire-fighting measures
Extinguishing Media
Suitable : Not applicable.
Hazardous thermal (de)composition : These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO,
products NO2...), sulphur oxides (SO2, SO3, etc.). Dimethylamine , Hydrogen Cyanide
(HCN) ,CS2
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
(SCBA) and full turnout gear.

6. Accidental release measures

Personal Precautions : Splash goggles. Full suit. Boots. Gloves.
Environmental precautions and : Absorb with an inert material and put the spilled material in an appropriate
cleanup methods waste disposal. Neutralize the residue with a dilute solution of acetic acid.
Note: See section 8 for personal protective equipment and section 13 for waste disposal.

7. Handling and storage

Handling : Do not breathe gas/fumes/vapour/spray. Wear suitable protective clothing. If
ingested, seek medical advice immediately and show the container or the
label. Keep away from incompatibles such as oxidizing agents, acids.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
Packaging materials
Recommended use : Use original container.

8. Exposure controls/personal protection

Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne
concentrations of vapours below their respective occupational exposure limits.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and
before eating, smoking, using lavatory, and at the end of day.

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Respiratory system : Wear appropriate respirator when ventilation is inadequate.

Skin and body : Lab coat.

Hands : Impervious gloves.
Eyes : Safety glasses.

9. Physical and chemical properties

Physical state : Liquid.
Colour : Yellow / Green
Odour : Rotten eggs.
Boiling point : 100°C (212°F)
Melting point : <0°C (32°F)
Density : 1.17 g/cm3
Vapour pressure : The highest known value is 2.33 kPa (17.5 mmHg) (at 20°C) (Water).
Evaporation Rate : <1 compared to Ether (anhydrous).

Solubility : Easily soluble in cold water.

pH : 9 to 11 [Basic.]
Flash point : Not applicable.

10. Stability and reactivity

Stability : The product is stable.
Conditions to Avoid : Exposure to heat
Materials to avoid : Reactive with oxidizing agents, acids.
Incompatible with: acids , oxidizing agents

Hazardous decomposition products : These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO,
NO2...), sulphur oxides (SO2, SO3, etc.). Dimethylamine , Hydrogen Cyanide
(HCN) ,CS2

11. Toxicological information

Acute toxicity
Ingredient Name Test Result Route Species
Sodium dimethyldithiocarbamate LD50 300 mg/kg Oral Rabbit
LD50 1500 mg/kg Oral Mouse
LD50 1000 mg/kg Oral Rat
LD50 >1150 Dermal Rabbit
mg/kg
Disodium ethylenebis(N,N'-dithiocarbamate) LD50 395 mg/kg Oral Rat
LD50 580 mg/kg Oral Mouse

Chronic toxicity : Repeated or prolonged exposure is not known to aggravate medical condition.
Sensitization : Hazardous in case of skin contact (sensitizer).
Carcinogenic effects : Not available.

Mutagenic Effects : Not available.

Reproduction toxicity : Not available.

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12. Ecological information

Ecotoxicity Data
Ingredient Name Species Period Result
AMERSPERSE 280 Fish (LC50) 96 hours 0.1 to 0.3 mg/l

Persistence/degradability : Not available.

13. Disposal considerations

Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
residues ; Contaminated packaging environmental control regulations.

European Waste Catalogue (EWC) : 07 04 00

Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
Additional Information : 07 04 00 waste from the MFSU of organic pesticides (except 02 01 05)

14. Transport information

International transport regulations
Land - Road/Railway
UN number : 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(NABAM)
ADR/RID Class : 9
Packing group : -
ADR/RID label :

Other information : Hazard identification number

90
Sea
UN number : 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(NABAM)
IMDG Class : 9
Packing group : -
IMDG label :

Other information : Emergency Schedules (EmS)

6.1-02

Marine pollutant
IMDG Class: Marine Pollutant. (Pollutant.)

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15. Regulatory information

EU Regulations
Hazard symbol(s) :

Harmful, Dangerous for the environment

Risk Phrases : R22- Harmful if swallowed.
R43- May cause sensitization by skin contact.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
Safety Phrases : S24- Avoid contact with skin.
S37- Wear suitable gloves.
S46- If swallowed, seek medical advice immediately and show this container
or label.
S57- Use appropriate containment to avoid environmental contamination.
S61- Avoid release to the environment. Refer to special instructions/Safety
data sheets.
Contains : Disodium ethylenebis(N,N'-dithiocarbamate 205-547-0
Product Use : Classification and labelling have been performed according to EU directives
67/548/EEC, 88/379/EEC, including amendments and the intended use.
- Industrial applications.

16. Other information

Full text of R-Phrases with no. : R21/22- Harmful in contact with skin and if swallowed.
appearing in Section 2 - United R22- Harmful if swallowed.
Kingdom (UK) R37- Irritating to respiratory system.
R43- May cause sensitization by skin contact.
R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
Text of classifications appearing in : Xn - Harmful
Section 2 - United Kingdom (UK) Xi - Irritant
N - Dangerous for the environment.
HISTORY
Date of printing : 10/17/2002.
Date of issue : 10/16/2002.
Version : 3
AMERSPERSE® is a registered trademark of Ashland Inc.
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
are the only hazards that exist.
Date of issue Version
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