Step 12: U 0 KJ /mol
Step 12: U 0 KJ /mol
Step 12: U 0 KJ /mol
diketahui :
T1 = 150 C = 423,15 K
P1 = 8 bar
Perubahan reversible.
T2 = 50 C = 323,15 K
P3 = 3 bar
Cp = (7/2) R
Cv= (5/2) R
Ditanya:
W?
Q?
U =?
H= ?
Jawab:
Step 12
H=0 kJ /mol
U =0 kJ /mol
V1
W= RT1 ln
V3
P1T 3
= RT1 ln
P3T 1
3 x 323,15 K
= 8,314 x 10-3 kJ/ K mol (423,15 K) (ln ( ) )
8 x 423,15 K
= 3,518 ln (0,491)
Q= -W
Step 23
W=0
Q = U = Cv T
= Cv (T3 T2 )
H= Cp T
= Cp (T3 T2)
= - 291 kJ/mol
W= W12 +W23
= - 2,502 kJ/mol
Q= Q12 + Q23
= 0,424 kJ/mol
U = U 12+ U 23
= (0 2,0785 ) kJ/mol
= -2,0785 kJ/mol
H= H 12+ H 23
= (0 2,91) kJ/mol
= -2,91 kJ/mol