Material Safety Data Sheet

1. Product and company identification

Product name : MPA-1
Supplier : Baker Hughes, Inc.
12645 W. Airport Blvd.
Sugar Land, TX 77478
For Product Information/MSDSs Call: 281-351-8131
Material Uses : Special: Bonding agent for cement
Code : 415030
Validation date : 12/12/2011.
Print date : 12/12/2011.
Version : 1
Responsible name : Global Regulatory Affairs - Telephone 281-276-5400 or 800-231-3606
In case of emergency : CHEMTREC 800-424-9300 (U.S. 24 hour)
(001)281-276-5400
CANUTEC 613-996-6666 (Canada 24 hours)CHEMTREC Int'l 01-703-527-
3887 (International 24 hour)

2. Hazards identification
Physical state : Solid. [Powder.]
Odor : Odorless.
Color : White.
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Emergency overview : MAY CAUSE EYE AND SKIN IRRITATION. CONTAINS MATERIAL THAT MAY
CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. POSSIBLE CANCER
HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON
ANIMAL DATA.
Fine dust clouds may form explosive mixtures with air. Handling and/or processing of
this material may generate a dust which can cause mechanical irritation of the eyes,
skin, nose and throat. Keep away from heat, sparks and flame. Prevent dust
accumulation. Do not breathe dust. Avoid contact with eyes. Avoid prolonged or
repeated contact with skin. Use only with adequate ventilation. Keep container tightly
closed and sealed until ready for use. Wash thoroughly after handling.
Routes of entry : Dermal contact. Inhalation.
Potential acute health effects
Inhalation : Exposure to airborne concentrations above statutory or recommended exposure limits
may cause irritation of the nose, throat and lungs.
Ingestion : No known significant effects or critical hazards.
Skin : Slightly irritating to the skin.
Eyes : Slightly irritating to the eyes. No significant irritation expected other than possible
mechanical irritation.
Potential chronic health effects
Chronic effects : Contains material that may cause target organ damage, based on animal data.
Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation.
Carcinogenicity : Contains material which may cause cancer, based on animal data. Risk of cancer
depends on duration and level of exposure.
Target organs : Contains material which may cause damage to the following organs: lungs, upper
respiratory tract, skin.
Over-exposure signs/symptoms
Inhalation : respiratory tract irritation, coughing
Ingestion : None known.

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2. Hazards identification
Skin : irritation, redness
Eyes : irritation, watering, redness
Medical conditions : Pre-existing disorders involving any target organs mentioned in this MSDS as being at
aggravated by over- risk may be aggravated by over-exposure to this product.
exposure
See toxicological information (Section 11)

3. Composition/information on ingredients
Name CAS number %
Kaolin, calcined 92704-41-1 98 - 99.6
Titanium oxide 13463-67-7 0.4 - 2

4. First aid measures

Eye contact : Get medical attention immediately. Immediately flush eyes with plenty of water for at
least 15 minutes, occasionally lifting the upper and lower eyelids.
Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention immediately.
Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
Ingestion : Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical
attention immediately.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

5. Fire-fighting measures
Flammability of the product : Fine dust clouds may form explosive mixtures with air.
Extinguishing media
Suitable : Use dry chemical powder.
Not suitable : Do not use water jet.
Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal : metal oxide/oxides
decomposition products
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

6. Accidental release measures

Personal precautions : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing dust. Provide adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Put on
appropriate personal protective equipment (see Section 8).
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Methods for cleaning up

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6. Accidental release measures

Small spill : Move containers from spill area. Vacuum or sweep up material and place in a
designated, labeled waste container. Use spark-proof tools and explosion-proof
equipment. Dispose of via a licensed waste disposal contractor.
Large spill : Move containers from spill area. Approach release from upwind. Dike spill area and do
not allow product to reach sewage system or surface or ground water. Notify any
reportable spill to authorities. (See section 12 for environmental risks and 13 for disposal
information.) Vacuum or sweep up material and place in a designated, labeled waste
container. Avoid creating dusty conditions and prevent wind dispersal. Use spark-proof
tools and explosion-proof equipment. Dispose of via a licensed waste disposal
contractor. Note: see section 1 for emergency contact information and section 13 for
waste disposal.

7. Handling and storage

Handling : Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing dust. Avoid the
creation of dust when handling and avoid all possible sources of ignition (spark or flame).
Prevent dust accumulation. Use only with adequate ventilation. Electrical equipment
and lighting should be protected to appropriate standards to prevent dust coming into
contact with hot surfaces, sparks or other ignition sources. Empty containers retain
product residue and can be hazardous. Do not reuse container.
Storage : Store in accordance with local regulations. Store in a dry, cool and well-ventilated area,
away from incompatible materials (see Section 10). Eliminate all ignition sources.
Separate from oxidizing materials. Keep container tightly closed and sealed until ready
for use. Containers that have been opened must be carefully resealed and kept upright
to prevent leakage. Do not store in unlabeled containers. Use appropriate containment
to avoid environmental contamination.

8. Exposure controls/personal protection

Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling

Ingredients: List name ppm mg/m Other ppm mg/m Other ppm mg/m Other Notations

Titanium oxide US ACGIH - 10 - - - - - - -

OSHA PEL - 15 - - - - - - - [a]
OSHA PEL 1989 - 10 - - - - - - - [a]

Form: [a]Total dust

Consult local authorities for acceptable exposure limits.
Only components of this product with established exposure limits appear in the box above.
If OSHA permissible exposure levels are shown above they are the OSHA 1989 levels or are from subsequent
OSHA regulatory actions. Although the 1989 levels have been vacated the 11th Circuit Court of Appeals, Baker
Hughes recommends that these lower exposure levels be observed as reasonable worker protection.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace atmosphere
procedures or biological monitoring may be required to determine the effectiveness of the ventilation
or other control measures and/or the necessity to use respiratory protective equipment.
Engineering measures : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits. Use explosion-proof ventilation equipment.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Ensure that
eyewash stations and safety showers are close to the workstation location. Take off
contaminated clothing and wash before reuse.
Personal protection

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8. Exposure controls/personal protection

Respiratory : Approved/certified disposable particulate dust mask. Use a properly fitted, air-purifying
or air-fed respirator complying with an approved standard if a risk assessment indicates
this is necessary. Respirator selection must be based on known or anticipated exposure
levels, the hazards of the product and the safe working limits of the selected respirator.
Hands : Chemical-resistant gloves.
Eyes : Wear chemical safety goggles. When transferring material wear face-shield in addition to
chemical safety goggles.
Skin : Wear long sleeves and other protective clothing to prevent repeated or prolonged skin
contact.

9. Physical and chemical properties

Physical state : Solid. [Powder.]
Flash point : Not available.
Auto-ignition temperature : Not available.
Flammable limits : Not available.
Color : White.
Odor : Odorless.
pH : 6 to 8
Boiling/condensation point : Not available.
Initial Boiling Point : Not available.
Melting/freezing point : >1300C (>2372F)
Relative density : 2 to 3
Density : 16.66 to 24.99 (lbs/gal)
Vapor density : Not available.
Odor threshold : Not available.
Evaporation rate : Not available.
VOC : Not available.
Viscosity : Not available.
Solubility (Water) : Insoluble
Vapor pressure : Not available.
Pour Point : Not available.
Partition coefficient : Not available.
(LogKow)

10 . Stability and Reactivity

Chemical stability : The product is stable.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.
Conditions to avoid : Avoid the creation of dust when handling and avoid all possible sources of ignition (spark
or flame). Take precautionary measures against electrostatic discharges. To avoid fire
or explosion, dissipate static electricity during transfer by grounding and bonding
containers and equipment before transferring material. Prevent dust accumulation.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
Conditions of reactivity : Non-flammable in the presence of the following materials or conditions: open flames,
sparks and static discharge and heat.

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11 . Toxicological information
Carcinogenicity
Classification
Product/ingredient name ACGIH IARC EPA NIOSH NTP OSHA
Titanium oxide A4 2B - - - -
Chronic toxicity Remarks

1) Titanium oxide

Not available.

12 . Ecological information
Aquatic ecotoxicity
Product/ingredient name Result Species Exposure
Titanium oxide Acute LC50 5.5 ppm Fresh water Daphnia - Water flea - Daphnia 48 hours
magna - Juvenile (Fledgling,
Hatchling, Weanling) - <24 hours
Acute LC50 >1000000 ug/L Fish - Mummichog - Fundulus 96 hours
Marine water heteroclitus
Chronic NOEC 1 ppm Fresh Daphnia - Water flea - Daphnia 48 hours
water magna - Juvenile (Fledgling,
Hatchling, Weanling) - <24 hours
Conclusion/Summary : Not available.
Biodegradability
Conclusion/Summary : Not available.

13. Disposal considerations

Waste disposal : The generation of waste should be avoided or minimized wherever possible. Empty
containers or liners may retain some product residues. This material and its container
must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental protection
and waste disposal legislation and any regional local authority requirements. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.

14 . Transport information
Regulatory UN number Proper shipping Classes PG* Label Additional
information name information
DOT Classification Not - - - -
regulated.
TDG Classification Not - - - -
regulated.
IMDG Class Not - - - -
regulated.
IATA-DGR Class Not - - - -
regulated.
PG* : Packing group
DOT Reportable Not applicable.
Quantity
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14 . Transport information
Marine pollutant Not applicable.

North-America NAERG : Not available.

15 . Regulatory information
HCS Classification : Carcinogen
Target organ effects
U.S. Federal regulations : United States inventory (TSCA 8b): All components are listed or exempted.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Titanium dioxide
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
MPA-1: Immediate (acute) health hazard, Delayed (chronic) health hazard
CERCLA: Hazardous substances.: No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) :
Not listed
United States inventory : All components are listed or exempted.
(TSCA 8b)
Canada
WHMIS (Canada) : Class D-2A: Material causing other toxic effects (Very toxic).
Canada (CEPA DSL): : All components are listed or exempted.

16 . Other information
Label requirements : MAY CAUSE EYE AND SKIN IRRITATION. CONTAINS MATERIAL THAT MAY
CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. POSSIBLE CANCER
HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER, BASED ON
ANIMAL DATA.
Hazardous Material :
Information System (U.S.A.)
Health 1
Flammability 0 BJS
Physical hazards 0

Personal protection b
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS ratings are not required on MSDSs under 29 CFR
1910.1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented
HMIS program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS
materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection :
Association (U.S.A.)

0 Flammability
Health 1 0 Instability
Special

Date of printing : 12/12/2011.

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16 . Other information
Indicates information that has changed from previously issued version.
Notice to reader
NOTE: The information on this MSDS is based on data which is considered to be accurate. Baker Hughes,
however, makes no guarantees or warranty, either expressed or implied of the accuracy or completeness of this
information.

The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may
be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim
liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or
disposal of this product.

This MSDS was prepared and is to be used for this product. If the product is used as a component in another
product, this MSDS information may not be applicable.

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