Quantentheoretischen Kinematik Und Mechanik", Zeit-: Coijteijt of &lid Bkciikjzcs (18ational Aeronautics and Space
Quantentheoretischen Kinematik Und Mechanik", Zeit-: Coijteijt of &lid Bkciikjzcs (18ational Aeronautics and Space
Quantentheoretischen Kinematik Und Mechanik", Zeit-: Coijteijt of &lid Bkciikjzcs (18ational Aeronautics and Space
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(lIISk-TB-773791 Tile ICTaAL COIJTEIJT OF
QU&IITUB THEOiigTZCaL KZlfEH&TICS &lid BKCiikJZCS
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_ i SUMMARY First,
plied in this exact
paper for definitions
the terms: are sup-
position, i
_ velocity, energy, etc. (of the electron, for
! instance), such that they are valid also in :
_ quantum mechanics; then we shall show that
=! canonically conjugated variables can be de-
_ term,ned simultaneously only with a charac-
_ teristic uncertainty _I]. This uncertainty ,
:_" is the intrinsic reason for the occurrence
of statistical relations in quantum mechan-
ics. Their mathematical formulation is made
_ possible by the Dirac-Jordan theory (2). Be-
_ ginning from the basic principles thus oh-
" rained, we shall show how macroscopic pro- 1-*
cesses can be understood from the viewpoint |:
_
of quantum mechanics
experiments
(3). Several imaginary
are discussed to elucidate the
F
theory (4).
I
I
, ORIGINAL PAGE Ig
OF POOR QUALITY
it_
_1. ..q.z
2
J
quantum mechanics.*
!
!
less In principle, there is no shortage of experiments that 1
F ...........
,- _ ORIGINAL PAGE |g
i ' OF POOR qUALITY
5
the "size" of the electron. If two very fast particles strike
the electron sequentially in the very brief time interval At,
then the two positions of the electron defined by these two
particles lie very close together, separated by a distance AI.
From the laws observed for m-particles we conclude that AI can
be reduced to a magnitude of the order of 10-12 cm, provided
At is sufficiently small and the particles selected are suf- /17--6
ficiently fast. That is the meaning, when we say that the e-
lectron is a particle whose radius is not greater than 10-12 cm.
El-- fE = _ h
=D or 3w- w3= _=-;
Finally, let us point out the experiments that allow the meas-
urement of the energy or the value of the action variables J.
Such experiment_ are particularly important since only with
their aid will we be able to define what we mean, when we talk
about the discontinuous change of the energy or or J. The
8
Franck-Hertz collision experiments permit the tracing back of
the energ_ measurements on atoms to the energy measurements of
electrons moving in a straight line, because of the validity
of the energy theorem in the quantum theory. In principle,
this measurement can be made as precise as desired, if only
9
. OF POOR QOALFrV
a _ dp cr since _--_. _
., ; _t, _ h. (_)
i
We would like to summarize the results of the previous section
and generalize them in tLis statement: All concepts used in
classical theory to describe a mechanical system can also be
defined exactly for atomic processes, in analogy to the classic
concepts. But purely from experimentation, the experiments that
10
ORIGINAL PAGE_
' OF POOR QUALITY
i.e.,
We thus have for the probability amplitude correspondtn8 to p:
,(,,.)=
1'1
J , ORIG,,._ = Pj
OF POGR 4UALITY
S{_,p)prop =l,=
_ +h-'_-I"_ that is S_prope pt*
_! where
/181 t
- Thus, assumption (3) for S(n,q) corresponds to the experiment-
al fact that the value p' of _ and the value q' of _ were mess-
_ ured [with the precision restriction (6)]. _
!
!
12
!
'_ formulation of quantum mechanics, independent of all coordi-
nate systems. If we wanted to derive physical results from
13
' ORiGiNAL _A_ _
OF POOR QUALITY
After passing through field FI, the function will have become*
Let us assume that here the 8m are arbitrarily fixed, such /183
that the Cnm is unequivocally determined by F]. The matrix
Cnm transforms the energy value before passing through F I to
that after passing through F]. If behind F] we perform a de-
termination of the stationary states - for instance, by means
of an inhomogeneous magnetic field - then we shall find, with
14
%
[,
, o
ORIGINAL PACT _
OF POOR QUALITY
Cnm. When the beam passes through F2, we repeat the same pro-
cedure used for F I. Let dnm be the coefficients of the trans-
formation matrix that converts the energies before F2 to those
after F2. If no determination of the state is performed bet-
ween F I and F2, then the eigen-function is transformed accord-
ing to the following pattern:
s(E.,p) r-_
' _.,..s(_.,p) _-_
" _. _,_.._.,S(E,, _,). (8)
m m I
15
statistically, and in an uncontrollable manner. As a conse-
16
do not believe that Schroedinger's considerations address the
essence of the problem, for the following reasons: according
to Schroedinger, in highly excited states a sum of the eigen-
i vibrations will yield a not overly large wave packet, that in
i its turn, under periodic changes of its size, performs the ,
periodic motions of the classical "electron". The following /185
ij objections can be raised here: If the wave packet had such
properties as described here, then the radiation emitted by
s
the atom could be developed into a Fourier series in which the
]
state, the slower will be the scattering of the wave packet !-_v?
But it will occur, if one waits long enough. The argument used _"-
above for the radiation emitted by an atom can be used, for the '.
time being, against all attempts of a direct transition from
way
insufficient
out is already
radiation
blocked
at higher
for thestates;
hydrogenin atom,
the second
because
place,
of l\_-_'i
the transitionwithout
derstandable from quantum to classical
borrowing mechanics
from electrodynamics. must be un-
Bohr* has _0 [_
.o.
F
!
18
I ORIG.,_AL =_'4"
OF POOR OUALI'P[ T
_ (wavelength of the light used for the observation). Thus,
each position determination reduces the wave packet again to l
its original dimension i. The "values" of the variables p
and q are known to a certain precision, during all experi-
dH #H
P=- q= . J
But as we mentioned, the orbit can only be calcu]%ted statis-
tically from the initial conditions, which we may consider a J
consequence uncertainty existing in principle, in the initial
conditions. The laws of statistics are different for quantum
mechanics and classical theory. Under certain conditions, this
can lead to gross macroscopic differences between classical and
quantum theory. Before discussing an example of this, I want
to show by means of a simple mechanical system - the force-free
motion of a mass point - how the transition to the classical
1 t
q ----._p, + q, ; p -- p,, (11)
19
I
f ' ORIGINALPAGE_J
OF POOR QUALITY
I;
i_ sought, S(qo,q) , the differential equation
'-: li k 0 !
"_c I,,,_ _-_q,_
+eoj s(q.,e)= es(q.,_) (1_)
:, ,,,, __
(,,).-
! S(qe, e) _ const.e ..... _.-t..... (IS) .
i
We obtain
t Bdm f I t ,%
20
" oRIGINALpAGE_
OF PoOR QUALITY
i -- , (, ;,))+""I
'_ The term in q,2 can be included in the constant factor (inde-
.P
-} pendent of g); by integration we obtain
_:i
_{,-_,,)r , l,'
$(_,,j) -- eou.t.e lqt= 1 , (16
! (,_;,,_.,,)(,-
onst. e- " s qL'(I
J From which follows
(,--,._,.)'
- S(e_._J]._(_,__-- eonst.e e_t(i"+P_"-. (IT)
"probabilityto p_c_:et"
According (15), 13 has become largerto bythea time
is proportional factort, ofinversely
}:I_.
tions
of
As statistics
an example and
that those from quantumbetween
the difference theory thecanclassical
lead to gross
laws !
macroscopic differences in the results from both theories, un- '
der certain conditions, shall be briefly discussed for the
reflection of an electron flow by a grating. If the lattice
m
w
i which location ona grating line it would impact, then the elec-
{ tron would acquire such a velocity, due to this determination,
that the de Broglie wavelength of the electron would be reduced
to the point that in this approximation, the electron would be
a-tually reflected in the direction prescribed by classical
theory, without contradicting the laws of quantum theory.
i i gl i i el i i
,?.2
' ' ORIGINAL PAGE
t OFPOORQUALrrf
23
e
!
transition-point in time can be determined with that precision. I
We conceive of the experiment above entirely in the sense of I
|
the old _nterpretation of quantum theory, as explained by
Planck, Einstein and Bohr when we speak of a discontinuous {
24
(Z"
ORIGINAL PAGE
OF POOR QUAL_P(
s(q,o + (,-4),,,
26
i OR,GINAL PAG_ ?_
OF POOR QUALITY I
_;! ent from zero in only a small area around a point in Q-space, i
'_ and propagates with the velocity of the atoms in the direction
_} of the beam. The probability of a relative amplitude q for
some values Q is given by the integral of _
S(Q,_,t) = %s,(0,t),/,,(,_;,v)e h i,
_=l,t
-_ _/i -- ,'_ S, (Q, t) ea (El, q) 1 (22)
The periodic term in (201 has disappeared and with it, the pos-
tistical
less position
of the phase determination
of the incidentwill always
light be the itsame,
for which was regard-
deter- }
E1t I =h, and a problem complex discussed by Ehrenfest* and two '
other researchers by means of Bohr's correspondence principle,
27
_ mm - ...................
!
{
i
period. Supposedly, in this case there are not only the exact
_ energy values from quantum theory, but also - with a lower a
priori probability that can be qualitatively indicated - energy
values that do not differ too much from the quantum theory-based
values. In quantum mechanics, such a behavior is to be inter-
i pretated as follows: since the energy is really changed, due to
: other disturbances or to quantum jumps, each energy measurement
has to be performed in the interval between two disturbances,
28
i long in relation to the period _ of the wheel; the discrete
energy steps are correspondingly dense, and denser, she greater
29
l
w
i wheel
quantumis mechanics,
at least ofthetheinteraction
same order energy
of magnitude, as
between rack one
and of
,_ the rotator's energy steps (even for a small rack mass, a high
P
wheel and rack!} Once the coupling is dissolved, the rack and
3O
e
,
&
0
that starting from exact data we can only draw statistical "::'
31
l I
r
b
i
4
i Addendum at the time of correction. After closing this paper,
I new investigations by Bohr have led to viewpoints that allow a
32
!
$
and by wave theory on the other. For instance, in the use of /19.8
an imaginary r-ray microscope, the divergence of the ray beam
must be taking into account. The first consequence of this is
i that in the observation of the electron's position, the direc-
tion of the Comptom recoil will only be known with some uncer-
tainty, which will then lead to relation (I). It is further-
more not sufficiently stressed that rigorously, the simple
theory of the Compton effect can be applied only to free elec-
trons. As professor Bohr made very clear, the care necessary in
the application of the uncertainty relationship is essential
above all in a general discussion of the transition from micro
to macro-mechanics. Finally, the considerations on resonance
33