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    KC and KP Exam Qu - MS

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    Hanna
    This document contains exam questions about chemical equilibrium. 1. The first question asks students to calculate the partial pressure of NO2 given the value of Kp and the partial pressure of N2O4. 2. The second question involves calculating the value of Kp for the reaction 2SO3(g) ⇌ 2SO2(g) + O2(g) using mole fractions and partial pressures at equilibrium. 3. The third question asks students to calculate the value of Kp for the reaction 2NOCl(g) ⇌ 2NO(g) + Cl2(g) by determining mole fractions and partial pressures at equilibrium for the reaction. It also asks about

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    KC and KP Exam Qu - MS

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    Hanna
    296 views3 pages
    This document contains exam questions about chemical equilibrium. 1. The first question asks students to calculate the partial pressure of NO2 given the value of Kp and the partial pressure of N2O4. 2. The second question involves calculating the value of Kp for the reaction 2SO3(g) ⇌ 2SO2(g) + O2(g) using mole fractions and partial pressures at equilibrium. 3. The third question asks students to calculate the value of Kp for the reaction 2NOCl(g) ⇌ 2NO(g) + Cl2(g) by determining mole fractions and partial pressures at equilibrium for the reaction. It also asks about

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    Kc and Kp Exam Qu - MS

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    This document contains exam questions about chemical equilibrium. 1. The first question asks students to calculate the partial pressure of NO2 given the value of Kp and the partial pressure of N2O4. 2. The second question involves calculating the value of Kp for the reaction 2SO3(g) ⇌ 2SO2(g) + O2(g) using mole fractions and partial pressures at equilibrium. 3. The third question asks students to calculate the value of Kp for the reaction 2NOCl(g) ⇌ 2NO(g) + Cl2(g) by determining mole fractions and partial pressures at equilibrium for the reaction. It also asks about

    Copyright:

    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    296 views3 pages

    KC and KP Exam Qu - MS

    Uploaded by

    Hanna
    This document contains exam questions about chemical equilibrium. 1. The first question asks students to calculate the partial pressure of NO2 given the value of Kp and the partial pressure of N2O4. 2. The second question involves calculating the value of Kp for the reaction 2SO3(g) ⇌ 2SO2(g) + O2(g) using mole fractions and partial pressures at equilibrium. 3. The third question asks students to calculate the value of Kp for the reaction 2NOCl(g) ⇌ 2NO(g) + Cl2(g) by determining mole fractions and partial pressures at equilibrium for the reaction. It also asks about

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    Kc and Kp Exam Questions - MS

    2
    1. (i) Kp = p(NO2)
    p(N2O4)
    There must be some symbolism for pressure, and no [ ] 1
    2
    (iI) (Kp = p(NO2) = 48)
    p(N2O4)
    2
    p(NO2) = 48 × 0.15 = 7.2 (1)
    p(NO2) = 2.7 (1) atm (1) accept 2.683 / 2.68 / 2.7
    Answer and units conditional on (iii). 3 [4]
    2. (a) Pressure NOT partial pressure )
    intensity or change of colour ) Any one
    volume ) 1
    2
    (b) Kc = [NO2(g)] / [N2O4(g)] State symbols required 1
    –2
    (c) Mol NO2 at equilibrium = 0.0120 / 1.20 × 10 (1)
    2 –3 –3
    Kc = (0.0120) ÷ (0.0310) = 4.6 / 4.65 × 10 (1) mol dm (1) 3
    (d) (i) Amount of NO2 reduced 1
    (ii) No effect 1
    (e) As Kc is bigger, more NO2 is produced so heat helps forward reaction /
    by Le Chatelier’s principle reaction goes forward to use up heat /
    as temperature increases Stotal must be more positive so Ssurroundings
    (= –H/T must be less negative 1 [8]

    PSO2 2  PO2
    3. (a) (i) Kp = (1) [ ] no mark ( ) OK 1
    PSO3 2

    (ii) 2SO3  2SO2 + O2


    Mols at start 2 0 0
    mols at equ 0.5 1.5 0.75 (1)
    Mark by process
    1 mark for working out mole fraction 1 mark for × 10
    1 mark for correct substitution in Kp and answer 1 mark for unit
    1.5
    i.e. PSO2 = × 10 = 5.46
    2.75
    0.7
    PO2 = × 10 = 2.73
    2.75
    0.5
    PSO3= × 10 = 1.83
    2.75
    n.b. could show mole fraction for all 3 and then × 10 later to
    give partial pressure.
    2 2
    Kp = (5.46) × (2.73) / (1.83) = 24.5 (1) atm (1) 5

    (b) (i) No effect (1) 1


    (ii) No effect (1) 1 [8]

    Reigate Grammar School 1


    4. (a) (i) KP = p (CO2) allow without brackets, IGNORE p [ ] 1
    (ii) 1.48 (atm)
    Penalise wrong unit
    1 –1
    Answer is consequential on (a) (i) e.g. must have atm 1
    1.48
    p(Cl 2 )  p(NO) 2
    (b) (i) Kp = allow without brackets, penalise [ ] 1
    (p(NOCl)) 2
    (ii) 2NOCl 2NO + Cl2
    Start 1 0 0
     –0.22 +0.22 +0.11
    eq moles 0.78 0.22 0.11 (1)
    total moles of gas 1.11
    mole fractions above values ÷1.11 (1)
    0.7027 0.1982 0.09910
    partial pressure / atm above values × 5.00 (1)
    3.51 0.991 0.495
    2
    0.495 atm  (0.991 atm)
    Kp = (1)
    (3.51 atm) 2
    = 0.0395/ 0.0394 atm (1)
    range of answers 0.0408 / 0.041  0.039 / 0.0392 NOT 0.04
    ACCEPT  2 S. F
    Correct answer plus some recognisable working (5)
    Marks are for processes
     Equilibrium moles
     Dividing by total moles
     Multiplying by total pressure
     Substituting equilibrium values into expression for KP 5
    Calculating the value of KP with correct consequential unit.

    (iii) As the reaction is endothermic – stand alone (1)


    the value of KP will increase (as the temperature is increased) - (1)
    st
    consequential on 1 answer (if exothermic (0) then KP decreases (1))
    For effect on KP mark, must have addressed whether reaction is
    endothermic or exothermic 2

    (iv) Because (as the value of KP goes up), the value of


    2 2
    pCl2 × (pNO) / (pNOCl) (the quotient) must also go up (1)
    and so the position of equilibrium moves to the right – stand alone (1)
    But mark consequentially on change in K in (iii)
    If “position of equilibrium moves to right so Kp increases” (max 1) 2
    IGNORE references to Le Chatelier’s Principle
    [12]

    Reigate Grammar School 2


    Reigate Grammar School 3

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