Location via proxy:   [ UP ]  
[Report a bug]   [Manage cookies]                
Scribd Logo
Upload

Welcome to Scribd!

  • 124 views

    P8 8

    Uploaded by

    Alan Jose
    The document describes an adiabatic plug flow reactor (PFR) converting reactant A to products B and C using a catalyst. It asks to: 1) Plot conversion and temperature down the PFR until 80% conversion is reached, assuming no pressure drop. 2) Calculate the catalyst weight needed for 80% conversion in a continuous stirred tank reactor (CSTR). 3) Ask a critical thinking question about what can be learned from graphs of temperature and conversion vs catalyst weight. 4) Repeat the PFR calculation accounting for pressure drop using two particle sizes. Plot conversion, temperature and pressure along the reactor length.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd

    P8 8

    Uploaded by

    Alan Jose
    124 views5 pages
    The document describes an adiabatic plug flow reactor (PFR) converting reactant A to products B and C using a catalyst. It asks to: 1) Plot conversion and temperature down the PFR until 80% conversion is reached, assuming no pressure drop. 2) Calculate the catalyst weight needed for 80% conversion in a continuous stirred tank reactor (CSTR). 3) Ask a critical thinking question about what can be learned from graphs of temperature and conversion vs catalyst weight. 4) Repeat the PFR calculation accounting for pressure drop using two particle sizes. Plot conversion, temperature and pressure along the reactor length.

    Original Description:

    fogler

    Original Title

    P8-8

    Copyright

    © © All Rights Reserved

    Available Formats

    DOCX, PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    The document describes an adiabatic plug flow reactor (PFR) converting reactant A to products B and C using a catalyst. It asks to: 1) Plot conversion and temperature down the PFR until 80% conversion is reached, assuming no pressure drop. 2) Calculate the catalyst weight needed for 80% conversion in a continuous stirred tank reactor (CSTR). 3) Ask a critical thinking question about what can be learned from graphs of temperature and conversion vs catalyst weight. 4) Repeat the PFR calculation accounting for pressure drop using two particle sizes. Plot conversion, temperature and pressure along the reactor length.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    124 views5 pages

    P8 8

    Uploaded by

    Alan Jose
    The document describes an adiabatic plug flow reactor (PFR) converting reactant A to products B and C using a catalyst. It asks to: 1) Plot conversion and temperature down the PFR until 80% conversion is reached, assuming no pressure drop. 2) Calculate the catalyst weight needed for 80% conversion in a continuous stirred tank reactor (CSTR). 3) Ask a critical thinking question about what can be learned from graphs of temperature and conversion vs catalyst weight. 4) Repeat the PFR calculation accounting for pressure drop using two particle sizes. Plot conversion, temperature and pressure along the reactor length.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 5

    P8-8 The elementary irreversible gas-phase reaction

    A→B+C
    is carried out adiabatically in a PFR packed with a catalyst. Pure A enters the reactor at a
    volumetric flow rate of 20 dm3/s at a pressure of 10 atm and a temperature of 450 K.
    a) Plot the conversion and temperature down the plug-flow reactor until an 80%
    conversion (if possible) is reached. (The maximum catalyst weight that can be packed
    into the PFR is 50 kg.) Assume that ∆P = 0.0.
    b) What catalyst weight is necessary to achieve 80% conversion in a CSTR?
    c) Write a question that requires critical thinking and then explain why your question
    requires critical thinking. [Hint: See Preface Section B.2.]
    d) Now take the pressure drop into account in the PFR.

    𝑑𝑃 𝛼 𝑇 𝑃0
    =− ( ) (1 + 𝜀𝑋)
    𝑑𝑊 2 𝑇0 (𝑃⁄𝑃0 )

    The reactor can be packed with one of two particle sizes. Choose one.
    α = 0.019/kg cat for particle diameter D1
    α = 0.0075/kg cat for particle diameter D2
    Plot the temperature, conversion, and pressure along the length of the reactor. Vary the
    parameters α and P0 to learn the ranger of values in which they dramatically affect the
    conversion.

    Additional information:
    𝐶𝑃𝐴 = 40 𝐽⁄𝑚𝑜𝑙 ∙ 𝐾 𝐶𝑃𝐵 = 25 𝐽⁄𝑚𝑜𝑙 ∙ 𝐾 𝐶𝑃𝐶 = 15 𝐽⁄𝑚𝑜𝑙 ∙ 𝐾
    𝑜 𝑜
    𝐻𝐴 = −70 𝑘𝐽⁄𝑚𝑜𝑙 𝐻𝐵 = −50 𝑘𝐽⁄𝑚𝑜𝑙 𝐻𝐶𝑜 = −40 𝑘𝐽⁄𝑚𝑜𝑙
    All heats of formation are referenced to 273 K.
    𝐸 1 1 dm3
    𝑘 = 0.133 exp [ ( − )] with 𝐸 = 31.4 kJ⁄mol
    𝑅 450 𝑇 kg ∙ cat ∙ s

    Jawab:
    𝑑𝑋 𝑟′
    a) Neraca mol (PFR): 𝑑𝑊 = − 𝐹 𝐴
    𝐴0
    𝐹𝐴0 = 𝐶𝐴0 ∙ 𝑣0
    𝒅𝑿 𝒓′
    =− 𝑨
    𝒅𝑾 𝑪𝑨𝟎 ∙𝒗𝟎
    1−𝑋 𝑃 𝑇0
    Stoikhiometri: 𝐶𝐴 = 𝐶𝐴0 ( )
    1+𝜀𝑋 𝑃0 𝑇
    𝜀 = 𝑦𝐴0 ∙ 𝛿
    = 1 ∙ (1 + 1 − 1)
    𝜀=1
    𝑃 = 𝑃0
    𝟏−𝑿 𝑻𝟎
    𝑪𝑨 = 𝑪𝑨𝟎 ( )
    𝟏+𝑿 𝑻
    Hukum laju: −𝑟𝐴′ = 𝑘𝐶𝐴
    𝐸 1 1
    𝑘 = 0.133 exp [𝑅 (450 − 𝑇)]
    𝟏−𝑿 𝑻𝟎 𝟑𝟏𝟒𝟎𝟎 𝟏 𝟏
    −𝒓𝑨 = 𝑪𝑨𝟎 ( ) × 𝟎. 𝟏𝟑𝟑 𝐞𝐱𝐩 [ (𝟒𝟓𝟎 − 𝑻)]
    𝟏+𝑿 𝑻 𝟖.𝟑𝟏𝟒
    −∆𝐻𝑅𝑥 ∙𝑋
    Neraca energi (adiabatis): 𝑇 = 𝑇0 + 𝐶𝑃𝐴

    𝟐𝟎𝟎𝟎𝟎𝑿
    𝑻 = 𝟒𝟓𝟎 + = 𝟒𝟓𝟎 + 𝟓𝟎𝟎𝑿
    𝟒𝟎
    1−𝑋 𝑇
    𝑑𝑋 𝑘𝐶𝐴0 ( )
    1+𝑋 𝑇0
    Gabungan: 𝑑𝑊 = − 𝐶𝐴0∙𝑣0

    𝟏−𝑿 𝑻𝟎
    𝒅𝑿 𝒌( )
    𝟏+𝑿 𝑻
    =
    𝒅𝑾 𝒗𝟎

    Penyelesaian dengan polymath:


    Hubungan Suhu (T) terhadap Berat Katalis (W)

    Hubungan Konversi (X) terhadap Berat Katalis (W)

    𝐹𝐴0 ∙𝑋
    b) Neraca mol (CSTR): 𝑊 = − 𝑟𝐴′
    𝐶𝐴0 ∙𝑣0 ∙𝑋
    𝑊= 1−𝑋 𝑇 31400 1 1
    𝐶𝐴0 ( ) ×0.133 exp[ ( − )]
    1+𝑋 𝑇0 8.314 450 𝑇

    𝒗𝟎 ∙𝑿
    𝑾= 𝟏−𝑿 𝑻𝟎 𝟑𝟏𝟒𝟎𝟎 𝟏 𝟏
    ( ) ×𝟎.𝟏𝟑𝟑 𝐞𝐱𝐩[ ( − )]
    𝟏+𝑿 𝑻 𝟖.𝟑𝟏𝟒 𝟒𝟓𝟎 𝑻

    𝑇 = 450 + 500𝑋 = 450 + 500(0,8) = 850 𝐾


    20 𝑑𝑚3 ⁄𝑠×0,8
    𝑊=− 1−0,8 450 𝐾 31400 J⁄mol 1 1 = 𝟑𝟗, 𝟒 𝒌𝒈
    ( ) ×0.133 exp[ ( − )]
    1+0,8 850 𝐾 8.314 𝐽⁄𝑚𝑜𝑙∙𝐾 450 𝐾 850 𝐾

    c) Pertanyaan: apakah saja yang dapat dipelajari dari grafik hubungan antara suhu dan
    berat katalis terhadap konversi?
    Pertanyaan tersebut memerlukan pemikiran kritis karena mendata kesimpulan yang bisa
    didapat melalui grafik tersebut.

    d) Penyelesaian menggunakan polymath:

    Hubungan Konversi (X) terhadap Berat Katalis (W)

    Hubungan Suhu (T) terhadap Berat Katalis (W)


    Hubungan Suhu (T) terhadap Berat Katalis (W)

    You might also like