Material Safety Data Sheet

What is a Material Safety Data Sheet (MSDS)?
A material safety data sheet is a technical document which provides detailed and
comprehensive information on a controlled product related to:
 health effects of exposure to the product
 hazard evaluation related to the product’s handling, storage or use
 measure to protect workers at risk of exposure
 emergency procedures.
The data sheet may be written, printed or otherwise expressed, and must meet the
availability, design and content requirements of WHMIS legislation. The legislation
provides for flexibility of design and wording but requires that a minimum number of
categories of information be completed and that all hazardous ingredients meeting
certain criteria be listed subject to exemptions granted under the Hazardous Materials
Information Review Act.
The Purpose of the Data Sheet
The data sheet is the second element of the WHMIS information delivery system and is
intended to supplement the alert information provided on labels. The third element of the
system is the education of employees in hazard information on controlled products,
including instruction in the content and significance of information on the MSDS.
Responsibilities Related to the MSDS
Suppliers
1. Develop or obtain a MSDS for each controlled product imported or sold for use in a
workplace
2. Ensure the MSDS for the controlled product:
 Discloses information that is current at the time of sale or importation of the
product
 Was prepared and dated not more than three years before the date of sale or
importation
 Is available in both official languages
3. Ensure the purchaser of the controlled product has a copy of the current MSDS at the
time of or prior to the purchaser receiving the controlled product
4. Make available any information that is considered confidential (trade secret)
information and therefore exempt from disclosure to any physician or nurse who
requests that information for the purpose or making a medical diagnosis or providing
medical treatment
Employer
1. Ensures that an up-to-date supplier MSDS is obtained from the supplier the first time
a controlled product is received in the workplace
2. Evaluates the data sheet received to determine its date of production. The data
sheet must be dated within 3 years of current date
3. Maintains up-to-date MSDSs:
 As soon as practical but no later than 90 days after new hazard information
becomes available to the employer
 At least every three years
4. Ensures a copy of all data sheets which are required for the workplace are made
readily available at the worksite to:
 Workers who may be exposed to the controlled product
 The occupational health committee (OHC)
Note: The MSDSs may be made available on a computer if the employer takes all
reasonable steps to keep the terminal in working order, makes the data sheets
readily available to the employee and provides training in accessing the computer
stored data to the employee.
5. Ensure that the employee who works with a controlled product or in proximity to a
controlled product is instructed in:
 The content required on the MSDS
 The purpose and significance of information contained in it
Instruction must ensure that employees know procedures for the safe use, storage,
handling and disposal of controlled products including procedures in the event of an
emergency involving a controlled product.
6. Provide confidential (trade secret) information to a doctor or nurse who request this
information for purposes of making a medical diagnosis or rendering medical
treatment in an emergency
7. The employer can produce data sheets in order to provide additional information or
alter the format used as long as there is no less information provided than the
original supplier MSDS contained
Worker
Following training by the employer:
1. Follows the safe work or preventative measures as instructed by the employer
2. Knows where the sheets are located and how to find pertinent information on safe
use and first aid measures
Material Safety Data Sheet Content
A supplier material safety data sheet must provide at least nine categories or sections of
content and approximately sixty items of information distributed among those categories.
An MSDS must be reviewed at least every three years. The categories must have the
following similar headings:
I. Hazardous Ingredients
This section will include:
 The chemical names and concentrations concerning the hazardous
ingredients
 The LD 50 and LC50 indicate the short term toxic potential
 CAS number which is useful in locating more information especially if the
product is known by numerous names\
II. Preparation Information

This section includes:
 The name address and telephone number of who prepared the MSDS
 The date the MSDS was prepared
o If more than three years old, it must be updated
III. Product Information

This section:
 Identifies the product by the name on the supplier label
 Provides the chemical name, family and formula (including molecular weight)
 Lists the product identifiers, manufacturer and supplier names, addresses
and emergency telephone numbers
IV. Physical Data

This section includes information indicating how it looks and how it will behave when it is
used, stored, spilled and how it will react with other products indicated through:
 The state it is in e.g. liquid
 The odour and appearance of the product
 The specific gravity, vapour density, evaporation rate, boiling point and the
freezing point
 The vapour pressure, the higher the concentration the higher the possible air
concentration
 The odour threshold, which is the lowest airborne concentration of a chemical
that can be perceived by smell
 The pH reflecting the corrosive or irritant nature of the product
V. Fire and Explosion Hazard

This section describes:
 The temperature and conditions that can cause the chemical to catch fire or
explode
o UEL (upper explosion limit) or UFL (upper flammable limit) will indicate
the highest concentration of a substance in the air that will produce a fire
or explosion when a source of ignition (heat, spark or flame) is present
o LEL (lower explosion limit) or LFL (lower flammable limit) will indicate the
lowest concentration of a substance in the air that will produce a fire or
explosion when a source or ignition is present
o From the LEL to the UEL, the mixture is explosive. Below the UEL the
mixture is too lean to burn; above the LEL the mixture is too rich to burn.
However, concentrations above the UEL are still very dangerous because
if the concentration is lowered (by introducing fresh air), it will enter the
explosive range
 Means of extinction including the type of fire extinguisher required
 Personal Protective Equipment required for fire fighting
 Some of the storage requirements however more of this information is found
in the reactivity data section
VI. Reactivity Data:

 The chemical stability of the product and its reactions to light, heat, moisture,
shock and incompatible materials
 Storage requirements based on the reactivity or instability of the product
 Incompatible products that must not be mixed or stored near each other
 The need for disposal before they become extremely reactive
VII. Toxicology Properties:
 The harmful effects of exposure
 How the product is likely to enter the body and what effects it has on the
organs in the body
 The short-term (acute) and long-term (chronic) health effects from exposure
to the product
 The exposure limits, which indicates the maximum concentration in air of a
hazardous substance (gas, vapour, dust, mist, fume) to which nearly all
workers (without personal protective equipment) can be repeatedly exposed
without adverse health effects. Exposure limits are expressed in three ways:
o TWA (time weighted average) indicating the maximum average
concentration to which workers can safety be exposed for a normal 8-
hour workday or 48-hour workweek
o STEL (short-term exposure limit) indicating the maximum concentration to
which workers can safely be exposed for a period of up to 15 minutes.
The STEL is higher than the TWA. It may not be sustained more than four
times a day
o C (ceiling) describes the concentration that may not be safely exceeded
at any time, even for an instant. The C is higher that the STEL
 If these limits are to be exceeded, the worker must use recommended
personal protective equipment. Exposure limits are expressed as ppm for
gases and vapours and as mg/m3 for dusts, fumes and mists
 Note these limits may be expressed as OEL, PEL and TLV
 Information used to assess the health problems of any employee who uses
the chemical and determine if that worker’s problems are related to the
chemical
VIII. Preventative Measures:

This section provides:
 Instruction for the safe use, handling and storage of the product
 The personal protective equipment or safety devices required
 The steps for cleaning up spills
 Information on the waste disposal requirements
IX. First Aid Measures:

 Specific first aid measures related to acute effects of exposure to the product
 First aid steps in the correct sequence
 Information to assist in planning for emergencies
The MSDS may contain additional sections providing further information related to the
specific product.
Location of the MSDSs

 Hard copy readily available
 Computer terminals
 Employees and others must know where the MSDS is and how to use them
MSDS revisions are required every 3 years or sooner if new product information is
available.
Trade Secret Exemptions
Information may be withheld to protect industries’ right to protect confidential business

information. This information is referred to as trade secrets.
The producer of the product can withhold:

 The name and concentration of any ingredient
 Name of relevant toxicological studies
Once a claim if filed to withhold information the product label must state:
 Date the exemption filed
 Claim registration number
The MSDS must state:
 That an exemption has been granted
 Date it is granted
 Registry number
 Product hazards
Medical Access
Doctors and nurses can access withheld information however this information remains
confidential.

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What is a Material Safety Data Sheet (MSDS) and what is its purpose?

What information must a supplier MSDS provide?

What is a Material Safety Data Sheet (MSDS)?

The Purpose of the Data Sheet

Responsibilities Related to the MSDS

Material Safety Data Sheet Content

II. Preparation Information

III. Product Information

IV. Physical Data

V. Fire and Explosion Hazard

VI. Reactivity Data:

VIII. Preventative Measures:

IX. First Aid Measures:

Location of the MSDSs

Trade Secret Exemptions

Information may be withheld to protect industries’ right to protect confidential business

The producer of the product can withhold:

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