Location via proxy:   [ UP ]  
[Report a bug]   [Manage cookies]                
Scribd Logo
Upload

Welcome to Scribd!

  • 97 views

    Term Odin A Mica

    Uploaded by

    beymar
    This document defines key thermodynamic concepts such as heat capacity, molar heat capacity, specific heat, and ideal gas behavior. It provides formulas for calculating molar heat capacity at constant pressure and volume for monoatomic, diatomic, and polyatomic ideal gases. Tables list standard values of molar heat capacities and related properties for common gases.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Term Odin A Mica

    Uploaded by

    beymar
    97 views3 pages
    This document defines key thermodynamic concepts such as heat capacity, molar heat capacity, specific heat, and ideal gas behavior. It provides formulas for calculating molar heat capacity at constant pressure and volume for monoatomic, diatomic, and polyatomic ideal gases. Tables list standard values of molar heat capacities and related properties for common gases.

    Original Description:

    Documento

    Original Title

    Term Odin a Mica

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    This document defines key thermodynamic concepts such as heat capacity, molar heat capacity, specific heat, and ideal gas behavior. It provides formulas for calculating molar heat capacity at constant pressure and volume for monoatomic, diatomic, and polyatomic ideal gases. Tables list standard values of molar heat capacities and related properties for common gases.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    97 views3 pages

    Term Odin A Mica

    Uploaded by

    beymar
    This document defines key thermodynamic concepts such as heat capacity, molar heat capacity, specific heat, and ideal gas behavior. It provides formulas for calculating molar heat capacity at constant pressure and volume for monoatomic, diatomic, and polyatomic ideal gases. Tables list standard values of molar heat capacities and related properties for common gases.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    You are on page 1of 3

    Formulario Termodinámica

    FMF − 107 AÑO 2011.

    1. Capacidad Calorı́fica (C ) 7. Calor Especifico molar a Presión Constante


    ((cm ) p )
    Q
    C=
    ∆T a) gas monoatómico

    2. Capacidad Calorı́fica Especifica o Calor 5


    (cm ) p = R
    Especifico (c) 2
    C Q b) gas diatómico
    c= =
    m m∆T
    7
    (cm ) p = R
    3. Capacidad Calorı́fica Molar o Calor Especifico 2
    molar (cm )
    c) gas poliatómico
    C Q
    cm = = (cm ) p = 4R
    n n∆T

    4. Masa molar ( Mm ), Masa(m) y Moles(n) 8. Razón de los Calor Especifico molares y


    los Calor Especificoa a ( P = cte, yV = cte)
    m = n Mm (γ)
    (cm ) p cp
    γ= =
    5. Calor Especifico Molar(cm ) y Calor Especifico (cm )v cv
    (c)
    a) gas monoatómico
    C = m c = n cm
    5
    C = ( n Mm ) c = n c m γ=
    3
    c Mm = c m
    b) gas diatómico
    6. Calor Especifico molar a Volumen Constante
    ((cm )v ) 7
    γ=
    5
    a) gas monoatómico
    c) gas poliatómico
    3
    (cm )v = R 4
    2 γ=
    3
    b) gas diatómico
    9. Relación entre los Calor Especifico
    5
    (cm )v = R
    2
    (cm ) p = (cm )v + R
    c) gas poliatómico R
    (c p ) = (cv ) +
    (cm )v = 3R Mm

    1
    10. Tabla Resumen se puede reescribir como
    Q = ∆U + W
    gas (cm )v (cm ) p (γ) En adelante, el calor cedido al sistema
    será considerado positivo, y el calor
    extraı́do del sistema, negativo. Al
    3 5 5
    monoatómico 2R 2R 3 trabajo lo consideraremos positivo
    cuando lo realizada el sistema, y
    negativo, al trabajo que el sistema
    5 7 7
    diatómico 2R 2R 5 recibe (ver figura (1)).

    4
    poliatómico 3R 4R 3

    11. Constante Universal de los Gases ( R)

    J
    R = 8314 Figura 1:
    kmol K
    J
    R = 8, 314
    mol K
    b) forma diferencial
    l atm
    R = 0, 0821
    mol K δU = δQ − δW
    cal
    R = 1, 987 δW = P δV
    mol K
    se puede reescribir como
    12. Condiciones estándar o Temperatura y
    δQ = δU + δW
    Presión standard
    14. Gas Ideal
    a) Ley del gas ideal
    T = 273, 15 K = 0 o C
    P = 1, 013 · 105 Pa = 1 atm PV = nRT

    b) Energı́a Interna con (cv )

    1 kmol de gas ideal ocupa un volumen δU = m cv δT


    22, 4 m3 U = m cv T
    13. Primera Ley de la Termodinámica c) Energı́a Interna con ((cm )v )

    a) forma integral δU = n (cm )v δT


    U = n (cm )v T
    ∆U = Q − W
    Z V 15. Calorı́as y Energı́a
    f
    W= P δV
    Vi
    1 cal = 4, 184 J

    2
    16. Valores experimentales de los calores especı́ficos
    molares de algunos gases

    gas (cm ) p (cm )v (cm ) p − (cm )v (γ)

    [ molJ ·K ] [ molJ ·K ] [ molJ ·K ]

    monoatomico ideal (3 grados de libertad) 20, 8 12, 5 8, 3 1, 67


    Helio, He 20, 8 12, 5 8, 3 1, 66
    Argón, Ar 20, 8 12, 5 8, 3 1, 67
    biatomico ideal (5 grados de libertad) 29, 1 20, 8 8, 3 1, 4
    Hidrogeno, H2 28, 8 20, 4 8, 4 1, 41
    Nitrogeno, N2 29, 1 20, 8 8, 3 1, 4
    Oxı́geno, O2 29, 4 21, 1 8, 3 1, 4
    poliatomico ideal (6 grados de libertad) 33, 3 24, 9 8, 4 1, 3
    CO2 37 28, 5 8, 5 1, 3
    NH3 36, 8 27, 8 9 1, 31
    Vapor de agua, H2O 36, 2 27, 8 8, 4 1, 3
    Metano, CH4 35, 6 27, 2 8, 4 1, 31
    Cloroformo, CHCl3 (más de 6 grados de libertad) 72 63, 6 8, 4 1, 13
    Alcohol etı́lico, C2 H6O (más de 6 grados de libertad) 87, 4 79, 1 8, 4 1, 11

    You might also like